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At least 937 records · Page 52

Preparation, Properties, and Application of Lignocellulosic-Based Fluorescent Carbon Dots

We report that carbon dots (CDs) are a relatively new type of fluorescent carbon material with excellent performance and widespread application. As the most readily available and widely distributed biomass resource, lignocellulosics are a renewable bioresource with great potential. Research into the preparation of CDs with lignocellulose (LC-CDs) has become the focus of numerous researchers. Compared with other carbon sources, lignocellulose is low cost, rich in structural variety, exhibits excellent biocompatibility, and the structures of CDs prepared by lignin, cellulose, and hemicellulose are similar. This Review summarized research progress in the preparation of CDs from lignocellulosics in recent years and reviewed traditional and new preparation methods, physical and chemical properties, optical properties, and applications of LC-CDs, providing guidance for the formation and improvement of LC-CDs. In addition, the challenges of synthesizing LC-CDs were also highlighted, including the interaction of different lignocellulose components on the formation of LC-CDs and the nucleation and growth mechanism of LC-CDs; from this, current trends and opportunities of LC-CDs were examined, and some research methods for future research were put forward.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation of the Solution Chemistry of Hybrid Organic–Inorganic Indium Halides for New Material Discovery

Recently, metal halide perovskites (MHPs) have emerged as a new class of materials for optical and electronic applications such as solar cells and ionizing radiation detectors. Although the solution-processability of MHPs is among their greatest advantages, the solution chemistries of most metal halide systems and their relationship with the observed structural and chemical diversity are poorly understood. In this work, we study the solution chemistry of a model indium halide system, methylammonium (MA)–In–Br, using a combination of the UV–vis spectroscopy, electrospray ionization mass spectrometry (ESI-MS) measurements, small-angle X-ray scattering (SAXS), and density functional theory (DFT) calculations. Our results show that indium could form either octahedral [InBr 6 3– ] or tetrahedral [InBr 4 – ] anions in solution or a combination of both, depending on the loading ratios of MABr and InBr 3 reactants. Understanding the solution chemistry of this system and recognizing the optical fingerprints of these polyanions allow for targeted crystallization of two novel compounds: MAInBr 4 featuring tetrahedral [InBr 4 – ] anions and MA 2 InBr 5 containing both octahedral [InBr 6 3– ] and tetrahedral [InBr 4 – ] anions. Further increase of the MABr content leads to the formation of previously reported MA 4 InBr 7 , containing only octahedral [InBr 6 3– ] anions separated by Br – anions. Furthermore, our results suggest that understanding the solution chemistry of multinary metal halide systems could be a valuable tool for discovering functional materials for practical applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Anode sensitivity calibration of photomultiplier tubes used as a readout of the ELOSS detector

We present and discuss the methodology and results for an anode sensitivity calibration of Photomultiplier Tubes (PMTs) that serve as the optical readout of the Energy Loss Optical Scintillation System (ELOSS). The ELOSS detector, under development at the Facility for Rare Isotope Beams (FRIB), is a gaseous Xe scintillation-based detector designed to identify the atomic number (Z) of nuclear reaction fragments by energy-loss measurement. Variation in the anode sensitivity from tube to tube of commercially available PMTs limits ELOSS from reaching its ultimate Z resolution. A methodical approach to calibrating PMT anode sensitivities to a single target value by systematic PMT gain corrections is presented. Although the calibration process is discussed in terms of its impact on ELOSS performance, the presented method is applicable to any optical detector system composed of a large number of PMTs needing anode sensitivity calibration.

Instrumentation for heavy-ion accelerators↗

Two-photon coherent states of the radiation field

The concept of a two-photon coherent state is introduced for applications in quantum optics. It is a simple generalization of the well-known minimum-uncertainty wave packets. The detailed properties of two-photon coherent states are developed and distinguished from ordinary coherent states. These two-photon coherent states are mathematically generated from coherent states through unitary operators associated with quadratic Hamiltonians. Physically they are the radiation states of ideal two-photon lasers operating far above threshold, according to the self-consistent-field approximation. The mean-square quantum noise behavior of these states, which is basically the same as those of minimum-uncertainty states, leads to applications not obtainable from coherent states or one-photon lasers. The essential behavior of two-photon coherent states is unchanged by small losses in the system. The counting rates or distributions these states generate in photocount experiments also reveal their difference from coherent states.

Yuen, H. P.↗

Optical constants of liquid and solid methane

The optical constants n(sub r) + in(sub i) of liquid methane and phase 1 solid methane were determined over the entire spectral range by the use of various data sources published in the literature. Kramers-Kronig analyses were performed on the absorption spectra of liquid methane at the boiling point (111 K) and the melting point (90 K) and on the absorption spectra of phase 1 solid methane at the melting point and at 30 K. Measurements of the static dielectric constant at these temperatures and refractive indices determined over limited spectral ranges were used as constraints in the analyses. Applications of methane optical properties to studies of outer solar system bodies are described.

Martonchik, John V.↗

Design, fabrication and performance of two grazing incidence telescopes for celestial extreme ultraviolet astronomy

The design and performance of grazing incidence telescopes for celestial extreme ultraviolet (EUV) astronomy are described. The telescopes basically consist of a star tracker, collimator, grazing incidence mirror, vacuum box lid, vacuum housing, filters, a ranicon detector, an electronics box, and an aspect camera. For the survey mirror a Wolter-Schwarzschild type II configuration was selected. Diamond-turning was used for mirror fabrication, a technique which machines surfaces to the order of 10 microns over the required dimensions. The design of the EUV spectrometer is discussed with particular reference to the optics for a primarily spectroscopic application and the fabrication of the f/10 optics.

Lampton, M.↗

Distributed processing and fiber optic communications in air data measurement

This paper describes the application of distributed processing, fiber optics, and hardware redundancy to collecting airstream data in Princeton's digitally controlled Variable-Response Research Aircraft (VRA). Microprocessor-controlled instrumentation packages in each wingtip of the aircraft collect angle-of-attack and sideslip data in digital form; after scaling, filtering, and calibrating the data, they send it to the aircraft's microprocessor Digital Flight Control System (micro-DFCS) via digital fiber optic data links. Each wingtip's package is independent of the other; therefore, the system has dual hardware redundancy. The fiber optic link design is presented as well as a description of the calibration and communications software. Translation of the system's dual redundancy into fault tolerance is also covered. Results of preliminary flight tests are included.

Farry, K. A.↗

A fiber optic sensor for ophthalmic refractive diagnostics

This paper demonstrates the application of a lensless fiber optic spectrometer (sensor) to study the onset of cataracts. This new miniaturized and rugged fiber optic probe is based upon dynamic light scattering (DLS) principles. It has no moving parts, no apertures, and requires no optical alignment. It is flexible and easy to use. Results are presented for cold-induced cataract in excised bovine eye lenses, and aging effects in excised human eye lenses. The device can be easily incorporated into a slit-lamp apparatus (ophthalmoscope) for complete eye diagnostics.

Ansari, Rafat R.↗

Optical and infrared variability of B2 1308+326

Optical and infrared polarimetric and photometric observations of the BL Lacertae object B2 1308+326 during its high-luminosity outburst in the spring of 1978 are reported. The energy distribution, polarization at 0.6 and 2.2 microns, flux and polarization variability and position angle and strength of polarization variations of B2 1308+326, which has a luminosity greater than 10 to the 48th ergs/sec, are observed to be similar to those of BL Lac objects of much lower luminosity, suggesting the same emission process. Models of BL Lac object emission accounting for the high luminosity of B2 1308+326 are examined, and the isotropic synchrotron model is found to be more applicable to the optical and infrared emission of BL Lac objects than a model invoking relativistically enhanced emission.

Moore, R. L.↗

Photon number resolving detection with a single-photon detector and adaptive storage loop

Abstract Photon number resolving (PNR) measurements are beneficial or even necessary for many applications in quantum optics. Unfortunately, PNR detectors are usually large, slow, expensive, and difficult to operate. However, if the input signal is multiplexed, photon ‘click’ detectors, that lack an intrinsic PNR capability, can still be used to realize photon number resolution. Here, we investigate the operation of a single click detector, together with a storage line with tunable outcoupling. Using adaptive feedback to adjust the storage outcoupling rate, the dynamic range of the detector can in certain situations be extended by up to an order of magnitude relative to a purely passive setup. An adaptive approach can thus allow for photon number variance below the quantum shot noise limit under a wider range of conditions than using a passive multiplexing approach. This can enable applications in quantum enhanced metrology and quantum computing.

Sullivan, Nicholas M. (ORCID:0000000248447296)↗

Fabrication of carbon film composites for high-strength structures

Physical and mechanical properties of fiber composite materials consisting of carbon films are described. Application of carbon film structural composites for constructing microwave filters or optical instruments is proposed. Applications in aerospace and architectural structures for high strength and low density properties are discussed.

Preiswerk, P. R.↗

Field Evaluation of Anti-Biofouling Compounds on Optical Instrumentation

Biofouling has been a serious question in the stability of optical measurements in the ocean, particularly in moored and drifting buoy applications. Many investigators coat optical surfaces with various compounds to reduce the amount of fouling; to our knowledge, however, there are no objective, in-situ comparative testing of these compounds to evaluate their effectiveness with respect to optical stability relative to untreated controls. We have tested a wide range of compounds at in-situ locations in Halifax Harbour and in the Adriatic Sea on passive optical sensors. Compounds tested include a variety of TBT formulations, antifungal agents, and low-friction silicone-based compounds; time-scales of up to four months were evaluated. The results of these experiments are discussed.

McLean, Scott↗

A Compilation of Global Bio-Optical in Situ Data for Ocean Colour Satellite Applications – Version Three

A global in situ data set for validation of ocean colour products from the ESA Ocean Colour Climate Change Initiative (OC-CCI) is presented. This version of the compilation, starting in 1997, now extends to 2021, which is important for the validation of the most recent satellite optical sensors such as Sentinel 3B OLCI and NOAA-20 VIIRS. The data set comprises in situ observations of the following variables: spectral remote-sensing reflectance, concentration of chlorophyll-a, spectral inherent optical properties, spectral diffuse attenuation coefficient, and total suspended matter. Data were obtained from multi-project archives acquired via open internet services or from individual projects acquired directly from data providers. Methodologies were implemented for homogenization, quality control, and merging of all data. Minimal changes were made on the original data, other than conversion to a standard format, elimination of some points, after quality control and averaging of observations that were close in time and space. The result is a merged table available in text format. Overall, the size of the data set grew with 148 432 rows, with each row representing a unique station in space and time (cf. 136 250 rows in previous version; Valente et al., 2019). Observations of remote-sensing reflectance increased to 68 641 (cf. 59 781 in previous version; Valente et al., 2019). There was also a near tenfold increase in chlorophyll data since 2016. Metadata of each in situ measurement (original source, cruise or experiment, principal investigator) are included in the final table. By making the metadata available, provenance is better documented and it is also possible to analyse each set of data separately.

ocean color↗

Freestanding Photoresist Film: A Versatile Template for Three-Dimensional Micro- and Nanofabrication

Ultrathin freestanding films with well-defined micro/nanostructures and robust mechanical properties are applied in many engineering applications including microelectronics, optics, filtration and separation, biomedical engineering, and nanotechnology. Although considerable efforts have been made toward the fabrication of freestanding thin films, it is still a significant challenge to develop a simple and reliable process for producing freestanding films with ultrathin thickness, well-regulated micro/nanopatterns, robust mechanical properties, macroscopic coverage area, and multi-layered composite structures. In this work, a significant advancement is reported in this regard. This study shows a new sacrificial-layer-free (SLF) lifting-off process, integrated with conventional micro- and nanolithography, enabling the release of micro- and nanopatterned photoresist (PR) films from the supporting substrate with unprecedented pattern coverage and structure characteristics. The freestanding PR film is resilient, can withstand significant bending and deformation, and is sufficiently flexible to be transferred onto substrates with 3D topography as a conformal soft stencil for further technological processing and applications. Moreover, the SLF lifting-off process provides a simple approach to prepare single-layered and multi-layered freestanding composite films. The results suggest that the novel SLF lifting-off process can significantly extend the capability of 3D micro-/nanofabrication.

36 MATERIALS SCIENCE↗

Diode laser absorption sensors for gas-dynamic and combustion flows

Recent advances in room-temperature, near-IR and visible diode laser sources for tele-communication, high-speed computer networks, and optical data storage applications are enabling a new generation of gas-dynamic and combustion-flow sensors based on laser absorption spectroscopy. In addition to conventional species concentration and density measurements, spectroscopic techniques for temperature, velocity, pressure and mass flux have been demonstrated in laboratory, industrial and technical flows. Combined with fibreoptic distribution networks and ultrasensitive detection strategies, compact and portable sensors are now appearing for a variety of applications. In many cases, the superior spectroscopic quality of the new laser sources compared with earlier cryogenic, mid-IR devices is allowing increased sensitivity of trace species measurements, high-precision spectroscopy of major gas constituents, and stable, autonomous measurement systems. The purpose of this article is to review recent progress in this field and suggest likely directions for future research and development. The various laser-source technologies are briefly reviewed as they relate to sensor applications. Basic theory for laser absorption measurements of gas-dynamic properties is reviewed and special detection strategies for the weak near-IR and visible absorption spectra are described. Typical sensor configurations are described and compared for various application scenarios, ranging from laboratory research to automated field and airborne packages. Recent applications of gas-dynamic sensors for air flows and fluxes of trace atmospheric species are presented. Applications of gas-dynamic and combustion sensors to research and development of high-speed flows aeropropulsion engines, and combustion emissions monitoring are presented in detail, along with emerging flow control systems based on these new sensors. Finally, technology in nonlinear frequency conversion, UV laser materials, room-temperature mid-IR materials and broadly tunable multisection devices is reviewed to suggest new sensor possibilities.

Non-NASA Center↗

Structural, Optical, Dielectric, and Magnetic Characteristics of Nd Ions Substituted BaFe{sub 11}(Sn{sub 0.5}Mg{sub 0.5}){sub x}O{sub 19} M-Type Hexaferrite via Co-precipitation

Nanoparticles (NPs) of barium hexaferrite were synthesized by a chemical co-precipitation technique in an aqueous solution with a nominal composition of BaFe{sub 11}(Sn{sub 0.5}Mg{sub 0.5}){sub 1−x}Nd{sub x}O{sub 19} (x = 0, 0.5, 1). XRD and FTIR analyses were performed to study the crystal structure of the magnetic powders (MPs) in order to obtain details on the hexaferrite structure. Grain morphology and elemental composition were assessed by SEM and EDS, respectively, and nano-sized hexagonal platelet-like structures in all MPs were demonstrated. All of the structural parameters such as “a”, “c”, V{sub (cell)} and D{sub x} have been altered with successful incorporation of Nd into hexagonal lattices, thereby the band gap E{sub g} first increased x ≤ 0.5 then decreased up to x = 1 (i.e., drawn via a Tauc plot) from 1.53–1.82 eV. The measurements of dielectric properties depict relaxation behavior at higher frequencies. The dielectric measurements increase with increased hexaferrite. Furthermore, the magnetic properties of all MPs were examined by VSM at room temperature (RT). The saturation magnetization (M{sub s}), remnant magnetization (M{sub r}), and coercivity (H{sub c}) were linearly decreased by the SnMg content, whereas an increasing trend appeared with the additional Nd content. However, the squareness ratio increased with an increase in the content (x). These outcomes make this substitution an excellent candidate for multiple applications such as optical, electrical-based devices, circulators, and recording materials. .

77 NANOSCIENCE AND NANOTECHNOLOGY↗