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At least 937 records · Page 52

Case studies of NOAA 6/TIROS N data impact on numerical weather forecasts

The impact of satellite temperatures from systems which predate the launching of the third generation of vertical sounding instruments aboard TIROS N (13 Oct 1978) and NOAA 6 (27 June 1979) is reported. The first evaluation of soundings from TIROS N found that oceanic, cloudy retrievals over NH mid latitudes show a cold bias in winter. It is confirmed for both satellite systems using a larger data base. It is shown that RMS differences between retrievals and colocated radiosonde observations within the swath 30-60N during the 1979-80 winter were generally 2-3K in clear air and higher for cloudy columns. A positive impact of TIROS N temperatures on the analysis of synoptic weather systems is shown. Analyses prepared from only satellite temperatures seemed to give a better definition to weather systems' thermal structure than that provided by corresponding NMC analyses without satellite data. The results of a set of 14 numerical forecast experiments performed with the PE model of the Israel Meteorological Service (IMS) are summarized; these were designed to test the impact of TIROS N and NOAA 6 temperatures within the IMS analysis and forecast cycle. The satellite data coverage over the NH, the mean area/period S1 and RMS verification scores and the spatial distribution of SAT versus NO SAT forecast differences are discussed and it is concluded that positive forecast impact occurs over ocean areas where the extra data improve the specification which is otherwise available from conventional observations. The forecast impact for three cases from the same set of experiments was examined and it is found that satellite temperatures, observed over the Atlantic Ocean contribute to better forecasts over Iceland and central Europe although a worse result was verified over Spain. It is also shown that the better scores of a forecast based also on satellite data and verified over North America actually represent a mixed impact on the forecast synoptic patterns. A superior 48 hr 500 mb forecast over the western US due to the better initial specification afforded by satellite observed temperatures over the North Pacific Ocean is shown.

Druyan, L. M.↗

Tropical synoptic interpretation of inter-channel correlations from Tiros N

Synoptic variability contained in a set of Tiros N channel brightness temperatures was analyzed for a nine-day period during January 1979, between the dateline and 90 deg W and between 30 deg N and 20 deg S. In the procedure, the spatial coherence of each channel is first described in terms of functions of interchannel differences and geographic and synoptic variations. Second, horizontal and vertical pattern of individual channels are examined through empirical orthogonal functional decomposition. Finally, response surface regression models are developed to predict missing Tiros N channels from available Tiros N and NOAA-5 data. The percentage variance was predicted for each channel from the Tiros N microwave and stratospheric channels. Generally speaking, about 80 percent of the variance in each channel can be predicted for the Tiros model, excepting the two tropospheric moisture channels, where prediction was less successful.

Mcguirk, J. P.↗

N-15/N-14 variations in Cretaceous Atlantic sedimentary sequences - Implication for past changes in marine nitrogen biogeochemistry

Unusually low delta N-15 found in early to middle Cretaceous beds rich in marine organic matter from two separate eastern Atlantic Ocean basins is reported. These findings constitute unambiguous evidence that the N contained in these strata is the end result of biogeochemical processes that differed substantially from those that operated on the N contained in intervening organic carbon-poor strata and younger marine sediments. The data indicate that the low N-15 relative abundance is the consequence of pelagic rather than postdepositional processes. Reduced ocean circulation, increased denitrification, and hence, reduced euphotic zone nitrate availability may have led to Cretaceous phytoplankton assemblages that were periodically dominated by N2-fixing blue-green algae, a possible source of the sedimentary N-15 depletion.

Rau, Greg H.↗

Properties of n-dimensional triangulations

This paper establishes a number of mathematical results relevant to the problem of constructing a triangulation, i.e., a simplical tessellation of the convex hull of an arbitrary finite set of points in n-space. The principal results of the present paper are: (1) a set of n + 2 points in n-space may be triangulated in at most 2 different ways; (2) the 'sphere test' defined in this paper selects a preferred one of these two triangulations; (3) a set of parameters is defined that permits the characterization and enumeration of all sets on n + 2 points in n-space that are significantly different from the point of view of their possible triangulations; and (4) the local sphere test induces a global sphere test property for a triangulation.

Lawson, Charles L.↗

Rapid deactivation of N(2D) by O - Impact on thermospheric and mesospheric odd nitrogen

One- and two-dimensional models of thermospheric odd nitrogen are used to explore the consequences of the recently measured fast quenching of N(2D) by O. A large rate coefficient for this reaction profoundly affects the odd-nitrogen chemistry by removing N(2D) as a source of NO and increasing the concentration of N(4S), which destroys NO. The model calculations show that, as the quenching rate increases, the NO and N(2D) densities decrease, while N(4S) densities increase. Comparisons with Atmosphere Explorer and Solar Mesosphere Explorer satellite observations are made. Use of the fast quenching rate in the models causes the NO peak altitude, typically observed near 110 km, to rise to 140 km.

Fesen, C. G.↗

Modified Chebyshev pseudospectral method with O(N exp -1) time step restriction

The extreme eigenvalues of the Chebyshev pseudospectral differentiation operator are O(N exp 2) where N is the number of grid points. As a result of this, the allowable time step in an explicit time marching algorithm is O(N exp -2) which, in many cases, is much below the time step dictated by the physics of the partial differential equation. A new set of interpolating points is introduced such that the eigenvalues of the differentiation operator are O(N) and the allowable time step is O(N exp -1). The properties of the new algorithm are similar to those of the Fourier method. The new algorithm also provides a highly accurate solution for non-periodic boundary value problems.

Kosloff, Dan↗

An order (n) algorithm for the dynamics simulation of robotic systems

The formulation of an Order (n) algorithm for DISCOS (Dynamics Interaction Simulation of Controls and Structures), which is an industry-standard software package for simulation and analysis of flexible multibody systems is presented. For systems involving many bodies, the new Order (n) version of DISCOS is much faster than the current version. Results of the experimental validation of the dynamics software are also presented. The experiment is carried out on a seven-joint robot arm at NASA's Goddard Space Flight Center. The algorithm used in the current version of DISCOS requires the inverse of a matrix whose dimension is equal to the number of constraints in the system. Generally, the number of constraints in a system is roughly proportional to the number of bodies in the system, and matrix inversion requires O(p exp 3) operations, where p is the dimension of the matrix. The current version of DISCOS is therefore considered an Order (n exp 3) algorithm. In contrast, the Order (n) algorithm requires inversion of matrices which are small, and the number of matrices to be inverted increases only linearly with the number of bodies. The newly-developed Order (n) DISCOS is currently capable of handling chain and tree topologies as well as multiple closed loops. Continuing development will extend the capability of the software to deal with typical robotics applications such as put-and-place, multi-arm hand-off and surface sliding.

Chun, H. M.↗

A nearly-linear computational-cost scheme for the forward dynamics of an N-body pendulum

The dynamic equations of motion of an n-body pendulum with spherical joints are derived to be a mixed system of differential and algebraic equations (DAE's). The DAE's are kept in implicit form to save arithmetic and preserve the sparsity of the system and are solved by the robust implicit integration method. At each solution point, the predicted solution is corrected to its exact solution within given tolerance using Newton's iterative method. For each iteration, a linear system of the form J delta X = E has to be solved. The computational cost for solving this linear system directly by LU factorization is O(n exp 3), and it can be reduced significantly by exploring the structure of J. It is shown that by recognizing the recursive patterns and exploiting the sparsity of the system the multiplicative and additive computational costs for solving J delta X = E are O(n) and O(n exp 2), respectively. The formulation and solution method for an n-body pendulum is presented. The computational cost is shown to be nearly linearly proportional to the number of bodies.

Chou, Jack C. K.↗

The interpretation of solar system abundances at the N = 50 neutron shell

New data on CI chondrite abundances demonstrate a high degree of smoothness for the A = 75 - 100 mass range for odd A nuclei, except a single element peak at K ascribable to the s-process peak for the N = 50 neutron shell. Literature estimates of s-process abundances, Ns, permit a smooth Ns curve to be drawn; however the resultant 'non-s' abundance curve (nominally r-process) does not show a peak analogous to peaks associated with the N = 82 or 126 shells. Assuming the systematics of the r-process even and odd A abundance peaks at the N = 82 and 126 shells apply to N = 50, the odd A r-process peak for N = 50 can be obtained, which in turn permits a new calculation of Ns for odd A.

Burnett, D. S.↗

Metabolism of nonessential N-15-labeled amino acids and the measurement of human whole-body protein synthesis rates

Eight N-15-labeled nonessential amino acids plus (N-15)H4Cl were administered over a 10-h period to four healthy adult males using a primed-constant dosage regimen. The amount of N-15 excreted in the urine and the urinary ammonia, hippuric acid, and plasma alanine N-15 enrichments were measured. There was a high degree of consistency across subjects in the ordering of the nine compounds based on the fraction of N-15 excreted.

Stein, T. P.↗

Model experiment to study the effect of turbulence on risetime and waveform of N waves

Typical measured sonic boom rise times are two to five times longer than rise times calculated using molecular relaxation theory. The difference may be due to atmospheric turbulence. A model experiment was set up to study the influence of turbulence on waveform and rise time of spark-produced N waves. The N waves propagate through turbulence generated by a plane jet. The model turbulence is scaled down from atmospheric turbulence by approximately the same factor as the model N wave is scaled down from the sonic boom. Our experiments show that passage through the turbulence produces a wide variety of changes in the N waveform. Spiked and rounded N waves are observed, and average rise time is increased by a factor of about 2. A tentative observation based on data obtained so far is that rise time is always increased, never decreased, by turbulence.

Lipkens, Bart↗

A modified Chebyshev pseudospectral method with an O(N exp -1) time step restriction

The extreme eigenvalues of the Chebyshev pseudospectral differentiation operator are O(N exp 2) where N is the number of grid points. As a result of this, the allowable time step in an explicit time marching algorithm is O(N exp -2) which, in many cases, is much below the time step dictated by the physics of the partial differential equation. A new set of interpolating points is introduced such that the eigenvalues of the differentiation operator are O(N) and the allowable time step is O(N exp -1). The properties of the new algorithm are similar to those of the Fourier method. The new algorithm also provides a highly accurate solution for non-periodic boundary value problems.

Kosloff, Dan↗

Free fall and evaporation of N-Octane droplets in the atmosphere as applied to the jettisoning of aviation gasoline at altitude

In connection with proposed rapid jettisoning of aviation gasoline at altitude, a theoretical study was made of the free fall and evaporation of N-octane droplets in the atmosphere ; N-octane was selected for study because of the expected similarity of over-all evaporation behavior of N-octane and gasoline. It was concluded that gasoline (or N-octane) droplets larger than 2000 microns in diameter would be unstable ; terminal speeds and Reynolds numbers were obtained for droplets not larger than 2000 microns at altitudes to 11,000 feet. The motion data were used in the calculation of N-octane evaporation rates under various conditions. It was found that a droplet having an original diameter of 2000 microns would fall about 4000 feet from 6000 feet under NACA standard atmosphere conditions before coming virtually to rest. Finally, it was concluded that temperature effects are of paramount importance; at highest air temperatures a 1000-foot ground clearance would probably be adequate to prevent ground contamination, whereas at lowest air temperatures only an atomizing spray arrangement would prevent ground contamination, irrespective of ground clearance.

FIRE HAZARDS↗

Trans-Bis(acetato-0)bis(4-methylpyridine-N)copper(II)

The structure of trans-bis(acetato-O)bis (4-methylpyridine-N)copper(II), (Cu(C2H3O2)2(C6H7N)2), reported herein, represents a monomeric parent acetate complex with a distorted square-planar arrangement of acetate and 4-methylpyridine ligands around the Cu atom with the following distances and angles: Cu-N = 2.027(4) and Cu-O(1) = 1.950 (3) A; O(1)-Cu-N = 89.1 (2) and O(1)-Cu-N' = 90.0(2)deg. The Cu atom resides on a center of inversion. the most important dihedral angles are the angle between the 4-methylpyridine plane and the acetate plane (O(1), O(2), C(21), and C(22)), 78.2 deg, and the angle between the 4-methylpyridine ring and the coordination plane (Cu, N, O(1)), 31.6 deg.

Jedrzejas, Marek J.↗

Theoretical Study of Fe(CO)n-

The structures and CO binding energies are computed for Fe(CO)n- using a hybrid density functional theory (DFT) approach. The structures and ground states can be explained in terms of maximizing the Fe to CO 2pi* donation and minimizing Fe-CO 5 sigma repulsion. The trends in the CO binding energies for Fe(CO)n- and the differences between the trends for Fe(CO)n- and Fe(CO)n are also explained. For Fe(CO)n-, the second, third, and fourth CO bonding energies are in good agreement with experiment, while the first is too small. The first CO binding is also too small using the coupled cluster singles and doubles approach including a perturbation estimate of the connected triple excitations.

Ricca, Alessandra↗

Trans-Bis(acetato-o)bis(4-methylpyridine-N)copper(II)

The structure of trans-bis(acetato-O)bis(4-methyl- pyridine-N)copper(II), (Cu(C2H302)(sub 2)(C6H7N)(sub 2)), re- ported herein, represents a monomeric parent acetate complex with a distorted square-planar arrangement of acetate and 4-methylpyridine ligands around the Cu atom with the following distances and angles: Cu-N = 2.027 (4) and Cu-O1 = 1.950 (3) A; O1-Cu-N = 89.1 (2) and O1 -Cu-N' = 90.9 (2)deg. The Cu atom resides on a center of inversion. The most important dihedral angles are the angle between the 4-methylpyridine plane and the acetate plane (O1, O2, C21 and C22), 78.2 deg and the angle between the 4-methylpyridine ring and the coordination plane (Cu, N, O1), 31.6 deg.

Jedrzejas, Marek J.↗

High Electron Mobility in SiGe/Si n-MODFET Structures on Sapphire Substrates

For the first time, SiGe/Si n-Modulation Doped Field Effect Transistors (n-MODFET) structures have been grown on sapphire substrates. Room temperature electron mobility value of 1271 square centimeters N-sec at an electron carrier density (n(sub e) = 1.33x10(exp 12) per square centimeter)) of 1.6 x 10(exp 12) per square centimeter was obtained. At 250 mK, the mobility increases to 13,313 square centimeters/V-sec (n(sub e)=1.33x10(exp 12) per square centimeter)) and Shubnikov-de Haas oscillations appear, showing excellent confinement of the two-dimensional electron gas.

Mueller, Carl H.↗