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At least 937 records · Page 52

Materials, Manufacturing, and Test Development of a Composite Fan Blade Leading Edge Subcomponent for Improved Impact Resistance

Application of polymer matrix composite materials for jet engine fan blades is becoming attractive as an alternative to metallic blades; particularly for large engines where significant weight savings are recognized on moving to a composite structure. However, the weight benefit of the composite is offset by a reduction of aerodynamic efficiency resulting from a necessary increase in blade thickness; relative to the titanium blades. Blade dimensions are largely driven by resistance to damage on bird strike. Further development of the composite material is necessary to allow composite blade designs to approximate the dimensions of a metallic fan blade. The reduction in thickness over the state of the art composite blades is expected to translate into structural weight reduction, improved aerodynamic efficiency, and therefore reduced fuel consumption. This paper presents test article design, subcomponent blade leading edge fabrication, test method development, and initial results from ballistic impact of a gelatin projectile on the leading edge of composite fan blades. The simplified test article geometry was developed to realistically simulate a blade leading edge while decreasing fabrication complexity. Impact data is presented on baseline composite blades and toughened blades; where a considerable improvement to impact resistance was recorded.

Materials↗

Effects of Alternate Leading Edge Cutback on the Space Shuttle Main Engine Low Pressure Fuel Pump

A higher order cavitation oscillation observed in the SSME low pressure fuel pump has been eliminated in water flow testing of a modified subscale replica of the inducer. The low pressure pump was modified by removing the outboard sections of two opposing blades of the four-bladed inducer, blending the "cutback" regions into the blades at the leading edge and tip, and removing material on the suction sides to decrease the exposed leading edge thickness. The leading edge tips of the cutback blades were moved approximately 25 degrees from their previous locations, thereby increasing one blade to blade spacing, decreasing the second, while simultaneously moving the cutback tips downstream. The test was conducted in MSFC's inducer test loop at scaled operating conditions in degassed and filtered water. In addition to eliminating HOC across the entire scaled operating regime, rotating cavitation was suppressed while the range of both alternate blade and asymmetric cavitation were increased. These latter phenomena, and more significantly, the shifts between these cavitation modes also resulted in significant changes to the head coefficient at low cavitation numbers. Reverse flow was detected at a slightly larger flow coefficient with the cutback inducer and suction capability was reduced by approximately 1 velocity head at and above approximately 90% of the reference flow coefficient. These performance changes along with more intense reverse flow are consistent with poor flow area management and increased incidence in the cutback region. Although the test demonstrated that the inducer modification was successful at eliminating the higher order cavitation across the entire scaled operating regime, different, previously unobserved, cavitation oscillations were introduced and significant performance penalties were imposed.

Mulder, Andrew↗

Direct Numerical Simulation of an Airfoil with Sand Grain Roughness on the Leading Edge

As part of a computational study of acoustic radiation due to the passage of turbulent boundary layer eddies over the trailing edge of an airfoil, the Lattice-Boltzmann method is used to perform direct numerical simulations of compressible, low Mach number flow past an NACA 0012 airfoil at zero degrees angle of attack. The chord Reynolds number of approximately 0.657 million models one of the test conditions from a previous experiment by Brooks, Pope, and Marcolini at NASA Langley Research Center. A unique feature of these simulations involves direct modeling of the sand grain roughness on the leading edge, which was used in the abovementioned experiment to trip the boundary layer to fully turbulent flow. This report documents the findings of preliminary, proof-of-concept simulations based on a narrow spanwise domain and a limited time interval. The inclusion of fully-resolved leading edge roughness in this simulation leads to significantly earlier transition than that in the absence of any roughness. The simulation data is used in conjunction with both the Ffowcs Williams-Hawkings acoustic analogy and a semi-analytical model by Roger and Moreau to predict the farfield noise. The encouraging agreement between the computed noise spectrum and that measured in the experiment indicates the potential payoff from a full-fledged numerical investigation based on the current approach. Analysis of the computed data is used to identify the required improvements to the preliminary simulations described herein.

Ribeiro, Andre F. P.↗

Precise Determination of the 1s Lamb Shift in Hydrogen-Like Lead and Gold Using Microcalorimeters

Quantum electrodynamics in very strong Coulomb fields is one scope which has not yet been tested experimentally with sufficient accuracy to really determine whether the perturbative approach is valid. One sensitive test is the determination of the 1s Lamb shift in highly-charged very heavy ions. The 1s Lamb shift of hydrogen-like lead (Pb81+) and gold (Au78+) has been determined using the novel detector concept of silicon microcalorimeters for the detection of hard x-rays. The results of (260 +/- 53) eV for lead and (211 +/- 42) eV for gold are within the error bars in good agreement with theoretical predictions. To our knowledge, for hydrogen-like lead, this represents the most accurate determination of the 1s Lamb shift.

microcalorimeters for↗

Polymer Infused Composite Metal Foam as a Potential Aircraft Leading Edge Material

The leading edge of the aircraft wings must be free from three-dimensional disturbances caused by insect adhesion, ice accretion, and particle wear in order to improve flight performance, safety, and fuel efficiency of the aircraft. An innovative solution was explored in this work by infusing stainless steel composite metal foam (SS CMF) with a hydrophobic epoxy resin system. S-S CMF was made with 100% stainless steel using a powder metallurgy technique. The infused epoxy filled the macro- and microporosities, unique to SS CMF’s structure, creating a product with a density similar to that of aluminum. The contact angle, wear rate, erosion resistance, and insect adhesion of the novel infused composite metal foam were measured and compared to aluminum, epoxy and stainless steel. The infusion process was determined to fill up to 88% of the pores within the SS CMF and was found to reduce wettability and insect residue accretion. The contact angle of the infused SS CMF was 43% higher than its parent material, stainless steel, and 130% higher than aluminum. Insect residue maximum height and areal coverage were reduced by 60 and 30%, respectively, compared to aluminum. Grit blast experiments to simulate erosion resulted in a greater roughness increase for aluminum than for the parent epoxy resin or the resin-infused SS CMF. These results suggest that the durability and performance of infused SS CMF was superior compared to aluminum, which is the current leading edge material of choice. Based on the promising results under relevant wear and erosion conditions, it is concluded that the infused SS CMF can offer a potential tailored replacement to aluminum leading edge material.

Jacob C. Marx↗

Thermal Control in Hypersonic Leading Edges Using Liquid Metal High Temperature Oscillating Heat Pipes

The desire to increase the range and speed of hypersonic vehicles requires sharp, shape-stable Wing Leading Edges (WLE) with performance capabilities well beyond the current state of the art. The concentrated heat flux on sharp leading edges can lead to runaway thermal and mechanical failures. Heat pipes provide a passive solution to minimize the peak temperature, thermal gradients, and resulting thermal stresses near the WLE. Conventional heat pipes have been shown to address these issues at conditions as high as Mach 8. Oscillating heat pipes (OHPs) could be used to extend this benefit to missions with higher Mach numbers since their heat transport capacity typically exceeds that of conventional heat pipes. In the current investigation, several identical liquid metal high-temperature oscillating heat pipes (LMHOHPs) were constructed and tested to demonstrate the concept. The LMHOHPs had six turns, internal diameters of 2 mm, and total lengths of 100 mm. They were additively manufactured from C103 niobium alloy and charged with lithium to reach a fill ratio of approximately 50%. The boundary conditions of the experiment were designed to resemble those of various hypersonic flight profiles. Testing was performed with a system consisting of flow-controlled acetylene torch heating and radiation dominated heat rejection. The LMHOHP’s performance was measured using temperature data from an infrared camera and pyrometer. The experimental results were used to evaluate the capability of C103/lithium LMHOHPs under various flight regimes. A heat transfer model of the LMHOHP was proposed and validated against test data. Insights from the model were then extrapolated to evaluate a Tungsten-RHC/Gallium LMHOHP with anticipated capabilities beyond that of the C103/lithium system.

Max Pawlick↗

Wall-Modeled LES of a Swept Wing with Leading-Edge Ice Using LAVA Curvilinear, Unstructured, and Cartesian Solvers

Wall-modeled large-eddy simulation (LES) of a swept wing with leading-edge ice build up is performed using three mesh paradigms and associated flow solvers and compared to experimental results. The study focuses on an 8.9% scale model of the CRM65 swept wing featuring both high-fidelity and smooth leading-edge ice shapes. The assessment is conducted using the Launch, Ascent, and Vehicle Aerodynamics (LAVA) framework using the three actively supported meshing paradigms in LAVA: structured curvilinear overset, unstructured, andCartesian. For the iced configurations, these paradigms use hybrid body-fitted/source-term immersed-boundary, body-fitted, and ghost-cell immersed-boundary strategies, respectively.The unstructured and Cartesian mesh paradigms are particularly attractive for complex ice shapes as they avoid the manual mesh generation effort associated with the curvilinear approach. For the high-fidelity ice shape, good agreement with the experiment can be obtained with all three strategies; however, the curvilinear method is particularly sensitive to the source-term immersed-boundary timescale and span wise mesh resolution, and the Cartesian implementation is sensitive to the choice of numerical flux. For the smooth ice, larger discrepancies are observed across all methods. However, a mesh refinement study guided by flow visualizations leads to an improved comparison with the experiment that is particularly pronounced for the unstructured mesh paradigm.

TTT↗

USE OF CHEMICAL INVENTORY ACCURACY MEASUREMENTS AS LEADING INDICATORS

Chemical safety and lifecycle management (CSLM) is a process that involves managing chemicals and chemical information from the moment someone begins to order a chemical and lasts through final disposition(1). Central to CSLM is tracking data associated with chemicals which, for the purposes of this paper, is termed the chemical inventory. Examples of data that could be tracked include chemical identity, location, quantity, date procured, container type, and physical state. The reason why so much data is tracked is that the chemical inventory supports many functions. These functions include emergency management, which depends upon the data to more effectively plan for, and respond to, chemical accidents; environmental management that uses inventory information to aid in the generation of various federally-mandated and other regulatory reports; and chemical management that uses the information to increase the efficiency and safety with which chemicals are stored and utilized. All of the benefits of having an inventory are predicated upon having an inventory that is reasonably accurate. Because of the importance of ensuring one's chemical inventory is accurate, many have become concerned about measuring inventory accuracy. But beyond providing a measure of confidence in information gleaned from the inventory, does the inventory accuracy measurement provide any additional function? The answer is 'Yes'. It provides valuable information that can be used as a leading indicator to gauge the health of a chemical management system. In this paper, we will discuss: what properties make leading indicators effective, how chemical inventories can be used as a leading indicator, how chemical inventory accuracy can be measured, what levels of accuracies should realistically be expected in a healthy system, and what a subpar inventory accuracy measurement portends.

99 GENERAL AND MISCELLANEOUS↗

Composite materials with metal oxide attached to lead chalcogenide nanocrystal quantum dots with linkers

Composite materials useful for devices such as photoelectrochemical solar cells include a substrate, a metal oxide film on the substrate, nanocrystalline quantum dots (NQDs) of lead sulfide, lead selenide, and lead telluride, and linkers that attach the NQDs to the metal oxide film. Suitable linkers preserve the 1s absorption peak of the NQDs. A suitable linker has a general structure A-B-C where A is a chemical group adapted for binding to a MO.sub.x and C is a chemical group adapted for binding to a NQD and B is a divalent, rigid, or semi-rigid organic spacer moiety. Other linkers that preserve the 1s absorption peak may also be used.

14 SOLAR ENERGY↗

Event-by-event weighting at next-to-leading order

We present a general method of associating next-to-leading order weights to leading order phase space configurations at hadron colliders. The method relies on a re-organization of phase space for the real radiation contributions, defining a one-to-many map such that each point in the real phase space is associated with a distinct Born topology. As a result virtual and real singularities cancel at each Born phase space point. The new phase space maps can be used in a traditional approach for NLO calculations. However, interesting applications arise when one instead integrates out the real radiation up to a specified scale. This allows one to define NLO weights for individual phase space points that are present at LO. This method allows for the extension of matrix element methods to next-to-leading order, even in the presence of jets. We discuss some recent applications of the matrix element method to Higgs physics at the LHC.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

In situ nucleophilic substitutional growth of methylammonium lead iodide polycrystals.

Methylammonium lead iodide (MAPbIx) perovskites are organic-inorganic semiconductors that serve as the light-harvesting component of the photovoltaics, and are desirable with their long diffusion length yielding power conversion efficiencies of ≥22%. Conventional techniques grow perovskites by spin coating precursors on an oxide or a polymer substrate followed by annealing, however, use of high boiling point solvents and high temperatures hinder device stability and performance. Through a one-step, acid-catalyzed nucleophilic-substitutional crystal growth in polar protic solvents, we show evidence for the substrate- and annealing- free production of MAPbIx polycrystals that are metallic-lead-free with negligibly small amount of PbI2 precipitation (<10%). On the basis of this chemical composition, we have devised an in situ growth of highly air (upto ~1.5 months) and thermally-stable (≤300°C), tetragonal-phased, variable-sized polycrystals (~100 nm-10 μm) amendable for large-area deposition, and ultimately, large-scale manufacturing. This method is encouraging for stable optoelectronic devices, and leads to energy-efficient and low-cost processing.

14 SOLAR ENERGY↗

IMPECCABLE: Integrated Modeling Pipeline for COVID Cure by Assessing Better Leads

ABSTRACT The drug discovery process currently employed in the pharmaceutical industry typically requires about 10 years and $2-3 billion to deliver one new drug. This is both too expensive and too slow, especially in emergencies like the COVID-19 pandemic. In silico methodologies need to be improved both to select better lead compounds, so as to improve the efficiency of later stages in the drug discovery protocol, and to identify those lead compounds more quickly. No known methodological approach can deliver this combination of higher quality and speed. Here, we describe an Integrated Modeling PipEline for COVID Cure by Assessing Better LEads (IMPECCABLE) that employs multiple methodological innovations to overcome this fundamental limitation. We also describe the computational framework that we have developed to support these innovations at scale, and characterize the performance of this framework in terms of throughput, peak performance, and scientific results. We show that individual workflow components deliver 100× to 1000× improvement over traditional methods, and that the integration of methods, supported by scalable infrastructure, speeds up drug discovery by orders of magnitudes. IMPECCABLE has screened ~10 11 ligands and has been used to discover a promising drug candidate. These capabilities have been used by the US DOE National Virtual Biotechnology Laboratory and the EU Centre of Excellence in Computational Biomedicine.

97 MATHEMATICS AND COMPUTING↗

Turbine airfoil with leading edge cooling passage(s) coupled via plenum to film cooling holes, and related method

A turbine airfoil includes a body including a wall defining pressure and suction sides, and a leading edge extending between the pressure and suction sides. A cooling circuit inside the wall of the body includes at least one of: a) a suction side to pressure side cooling sub-circuit including a first cooling passage(s) extending from the suction side to the pressure side around the leading edge to a first plenum, and a plurality of first film cooling holes communicating with the first plenum and extending through the wall on the pressure side; and b) a pressure side to suction side cooling sub-circuit including second cooling passage(s) extending from the pressure side to the suction side around the leading edge to a second plenum, and a plurality of second film cooling holes communicating with the second plenum and extending through the wall on the suction side.

Lacy, Benjamin Paul↗

Resolution Performance of HERA-B Lead-Glass Calorimeters

In preparation of upcoming 12GeV experiments at Thomas Jefferson National Accelerator Facility it is necessary to upgrade existing systems or install new detectors. As part of this effort, an array of lead-glass sampling calorimeters is need for use in the GEP-5 experiment. A sampling calorimeter can be used to determine the energy and spatial position of a high energy particle that enters it while simultaneously stopping the particle. To determine the appropriate construction to meet the needs of upcoming experiments, it was necessary to take an existing model and confirm its energy and position resolution. This model could then be confirmed as an option for the final construction, or used as a starting point to design a better detector. For our test we obtained ten lead-glass calorimeters used in HERA-B and tested them in End Station A at SLAC. I will report on our findings for the HERA-B lead-glass sampling calorimeters. I will cover the results of both the energy and position resolutions as well as the methods used to determine these quantities.

Losada, Anthony↗

Prompt Neutron Decay Constants in a Highly Enriched Uranium-Lead Copper Reflected System

Rossi-{alpha} measurements were performed on highly enriched uranium (HEU)-lead copper reflected systems to determine the prompt neutron decay constants. These constants represent an eigenvalue characteristic of these particular critical configurations, which can be experimentally measured by the Rossi-a or pulse neutron source techniques and calculated by a deterministic or Monte Carlo method. In the measurements presented in this summary, highly enriched uranium interleaved with lead plates and reflected with copper were assembled to a high multiplication and the prompt neutron decay constants were determined by the Rossi-{alpha} technique. This research intended to benchmark the lead neutron cross sections; it was a collaboration between the Japanese Atomic Energy Agency (JAEA) Fast Critical Assembly Facility (FCA) in Tokai, Japan and the Los Alamos National Laboratory (LANL) in the U.S. (authors)

07 ISOTOPE AND RADIATION SOURCES↗

Effects of Lead and Arsenic in Soils from Former Orchards on Growth of Three Plant Species

Abstract Historical use of lead arsenate as a pesticide in former orchards of eastern Washington State (USA) has resulted in legacy lead (Pb) and arsenic (As) soil contamination. However, the impacts on plant growth in soils with residual Pb and As contamination have not yet been quantified. To this end, a comparative study of plant growth impacts was performed for native bluegrass ( Poa secunda ), invasive cheatgrass ( Bromus tectorum ), and buttercrunch lettuce ( Lactuca sativa ). Using standard plant growth protocols, germination frequency and biomass growth were measured over a wide range of Pb and arsenate concentrations, with maximum concentrations of 3400 and 790 mg kg −1 for Pb and As, respectively. Results indicated that only the biomass growth for all species decreased in soils with the highest concentrations of Pb and As in the soil, with no impacts on soils with lower residual Pb and arsenate concentrations. No impact on percentage of germination was observed at any soil concentration. These results can be used to determine site‐specific soil screening levels for use in ecological risk assessments for Pb and arsenate in soils. Environ Toxicol Chem 2022;41:1459–1465. © 2022 Battelle Memorial Institute. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

54 ENVIRONMENTAL SCIENCES↗

Precipitation in a lead calcium tin anode

Samples from a hot rolled sheet of a tin and calcium bearing lead alloy were solution heat treated at 300 Degree-Sign C and cooled down to room temperature at different rates; these samples were left at room temperature to study natural precipitation of CaSn{sub 3} particles. The samples were aged for 45 days before analysing their microstructure, which was carried out in a scanning electron microscope using secondary and backscattered electron detectors. Selected X-ray spectra analyses were conducted to verify the nature of the precipitates. Images were taken at different magnifications in both modes of observation to locate the precipitates and record their position within the images and calculate the distance between them. Differential scanning calorimeter analyses were conducted on selected samples. It was found that the mechanical properties of the material correlate with the minimum average distance between precipitates, which is related to the average cooling rate from solution heat treatment. - Highlights: Black-Right-Pointing-Pointer The distance between precipitates in a lead alloy is recorded. Black-Right-Pointing-Pointer The relationship between the distance and the cooling rate is established. Black-Right-Pointing-Pointer It is found that the strengthening of the alloy depends on the distance between precipitates.

36 MATERIALS SCIENCE↗

Tracking the formation of methylammonium lead triiodide perovskite

The formation mechanism of perovskite methylammonium lead triiodide (CH{sub 3}NH{sub 3}PbI{sub 3}) was studied with in situ X-ray photoelectron spectroscopy (XPS) on successive depositions of thermally evaporated methylammonium iodide (CH{sub 3}NH{sub 3}I) on a lead iodide (PbI{sub 2}) film. This deposition method mimics the “two-step” synthesis method commonly used in device fabrication. We find that several competing processes occur during the formation of perovskite CH{sub 3}NH{sub 3}PbI{sub 3}. Our most important finding is that during vapour deposition of CH{sub 3}NH{sub 3}I onto PbI{sub 2}, at least two carbon species are present in the resulting material, while only one nitrogen species is present. This suggests that CH{sub 3}NH{sub 3}I can dissociate during the transition to a perovskite phase, and some of the resulting molecules can be incorporated into the perovskite. The effect of partial CH{sub 3}NH{sub 3} substitution with CH{sub 3} was evaluated, and electronic structure calculations show that CH{sub 3} defects would impact the photovoltaic performance in perovskite solar cells. The possibility that not all A sites in the APbI{sub 3} perovskite are occupied by CH{sub 3}NH{sub 3} is therefore an important consideration when evaluating the performance of organometallic trihalide solar cells synthesized using typical approaches.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗