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At least 937 records · Page 52

FY2021 Isolated Grids and Grid-Connected Turbine Reference Systems

For individuals, businesses, and communities focused on building resilient electrical grid infrastructure, wind energy can provide an affordable, accessible, and compatible distributed energy resource option that also enhances the capabilities of local grid operations. However, there are technical barriers to realizing the market value and resilience benefits of distributed wind, and there is little to no ability to quantify those benefits so that stakeholders can compare grid investment options. The central aims of this report are: (1) to drive technology transfer of the methods and technologies developed under the Microgrids, Infrastructure Resilience, and Advanced Controls Launchpad (MIRACL) project and (2) increase the number of referenceable case studies available to stakeholders interested in additional value-added capabilities of wind systems beyond bulk energy supply. We achieve this aim by applying three major methods developed under MIRACL to two real-world distributed wind reference systems. The two real-world distributed wind reference systems are the isolated grid of St. Mary’s, Alaska, and the two 10.5-megawatt (MW) front-of-the-meter wind turbine deployments owned and operated by Iowa Lakes Electric Cooperative (ILEC).

17 WIND ENERGY↗

Novel Approaches to the Isolation of Glucaric Acid from Fermentation Broth. Final report

Kalion has successfully demonstrated a fermentation route using glucose as the feedstock. This game-changing technology allows Kalion to economically produce large-scale quantities of high-purity glucaric acid products. Kalion has also developed a novel downstream processing strategy for isolating and purifying glucaric acid forms, including the free acid, monoammonium glucarate, and monopotassium glucarate. Despite the low solubility of these products, significant water removal is needed prior to crystallization, requiring energy intensive evaporation or reverse osmosis. Here, we work in collaboration with the Separations Consortium to develop novel, low-cost means of water removal in Kalion’s glucarate/glucaric acid purification process. This proposed CRADA project with national labs (ORNL, ANL, and NREL) evaluated various technologies developed by the Separations Consortium as applied to glucaric acid purification, intended to generate a scalable, cost-effective, energy-efficient process. Four approaches were evaluated with mock aqueous solutions of glucaric acid or glucarate, and the results analyzed with respect to separation effectiveness and potential cost savings. The leading technology will then be further developed and tested with actual clarified or non-clarified broth (depending on the approach) obtained from 20L fermentations provided by Kalion, that will contain inorganic ions, byproducts, and residual sugars in addition to the product.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effects of Salt Concentration, Ionic Strength, and Water Activity on the Growth of a WIPP Archaeal Isolate, Halobacterium sp.

An extremely halophilic archaeon (Halobacterium sp., WIPP strain), isolated from WIPP halite, was tested for its ability to grow in media containing various combinations of sodium and magnesium chloride that influenced overall ionic strength and water activity. Halobacterium sp. grew well in most tested salt combinations, and its growth appeared to depend more upon the relative contribution of sodium to overall ionic strength than on other parameters. Growth rates were highest when media consisted of at least 2 M NaCl and lowest when NaCl dropped below 20% of the ionic strength (usually less than 0.5 M). High magnesium concentrations (1 and 1.5 M MgCl 2 ) did not prevent Halobacterium sp. growth, as long as the sodium contribution was sufficient. Water activity was not a definitive factor in determining growth, because this value did not reach an extreme lower limit in the experimental media.

59 BASIC BIOLOGICAL SCIENCES↗

Techno-Economic Case Study: Low-Temperature Conversion Performance Based on Isolated Anatomical Fractions of Corn Stover

This report summarizes analysis conducted to support a case study under the Feedstock-Conversion Interface Consortium (FCIC) focused on techno-economic analysis (TEA) modeling to quantify the yield and cost ramifications for processing isolated anatomical fractions of corn stover through a low-temperature conversion (biochemical pathway) biorefinery. It is hypothesized that different individual anatomical fractions of corn stover vary in composition and recalcitrance, such that processing each fraction on its own e.g. through dedicated campaigns may enable economic benefits relative to processing the whole stover material. To investigate this concept, we worked with FCIC researchers to obtain data on compositional analysis, as well as processing conditions and yields, for conversion of whole corn stover plus three individual anatomical fractions (cobs, husks, and stalks) across key steps of the biorefinery conversion process within FCIC research scope, namely pretreatment and enzymatic hydrolysis. After running the data through the TEA models, fractionated cobs and husks achieved higher fuel yields and lower minimum fuel selling prices than whole corn stover, but stalks fared worse than whole stover on both metrics. The most direct takeaway from this assessment is that a biorefinery would stand to benefit economically from maximizing the use of cob and husk fractions while avoiding or minimizing the use of stalks, though recognizing practical constraints with this approach in maintaining an equivalent processing capacity (fixed at 2,000 dry metric tonne per day in all cases).

09 BIOMASS FUELS↗

The role of supernova convection for the lower mass gap and the isolated binary formation of gravitational wave sources

Understanding astrophysical phenomena involving compact objects requires an insight about the engine behind core-collapse supernovae (SNe) and the fate of the stellar collapse of massive stars. In particular, this insight is crucial in developing an understanding of the origin and formation channels of the growing populations of detected black hole-black hole, black holeneutron star and neutron star-neutron star mergers. The timescale of convection growth may have a large effect on the strength of SN explosion and therefore also on the mass distribution of stellar remnants. We adopt new formulas for the relation between the pre-SN star properties and their remnants (Fryer et al. 2022) and check how they impact population of double compact object (DCO) mergers formed via isolated binary evolution. The new formulas give one ability to test wide spectrum of assumptions on the convection growth time. In particular, different variants allow for a smooth transition between having a deep mass gap and a remnant mass distribution filled by massive neutron stars and low mass black holes. We present distribution of masses, mass ratios and the local merger rate densities of DCO for different variants of new formulas and test them together with different approaches to other highly uncertain processes. We find that mass distribution of DCO mergers is sensitive to adopted assumption on SN convection growth timescale up to $m_1$ + $m_2$ ≲ 35$M_⊙$. Between two extreme tested variants the probability of compact object formation within the mass gap may differ up to ~ 2 orders of magnitude.

79 ASTRONOMY AND ASTROPHYSICS↗

Measuring Light Yield with Isolated Protons in MicroBooNE

Liquid Argon Time Projection Chambers (LArTPCs) are precision detectors used extensively in neutrino physics. The MicroBooNE experiment at Fermilab is one of the experiments employing this technique and has collected 5 years of data from 2015-2021. The primary signal in LArTPCs is ionisation, but argon also emits large quantities of scintillation light, which can be used for calorimetry, timing and background rejection. Prompt scintillation light in MicroBooNE is recorded with an array of 32 PhotoMultiplier Tubes (PMTs). To enable the full use of scintillation light in the experiment, it is important to characterize the efficiency of light collection in the detector, i.e. the light yield. We present a new method of measuring the light yield using isolated proton interactions, which enables a position-dependent light yield measurement to map the response of the detector across its volume. This method can be used to calibrate the light response in large-scale LArTPC detectors as well as to test assumptions used in simulating scintillation light.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Condenser Enclosure Vibration Isolation Mount Selection

A mini split cooling system will be used to maintain temperature requirements in a mobile secure transport system. While the split cooling system was designed to be used in static residential or commercial applications, it was selected for this transportation application due to a unique set of security requirements. However, the system’s ability maintain reliability and survive prolonged long-term shock and vibration is a significant concern. The mitigation strategy is to select vibration isolation mounts and perform lifetime shock and vibration testing to demonstrate survivability. The goal of this study is to generate a finite element model of the system and perform modal analysis to inform selection of vibration mounts to minimize the amount of vibrational energy transferred to the split cooling system. The scope of this report is limited to study of the condensing unit only, and geometric variation of the assembly will not be allowed.

42 ENGINEERING↗

Improved Modeling of Waste Isolation Pilot Plant Disposal Room Porosity

Disposal rooms at the Waste Isolation Pilot Plant (WIPP) contain waste and gas, and their porosity evolves over time. This report presents several improvements to the disposal room porosity model and presents new porosity predictions for use in future WIPP Performance Assessment activities. The improvements pertain to three sub-models: the geomechanical model, the waste compaction model, and the gas pressurization model. The impacts of each major improvement were quantified and the new porosity predictions were shown to be both mesh and domain size converged. Also, sensitivity studies on the disposal room horizon, clay seam friction coefficients, and homogenized waste representation were performed to support assumptions in the disposal room porosity model. To compare the legacy and new porosity predictions, the simulation results were plotted as a response surface, where gas pressure and time are inputs and porosity is the output. The new porosity response surface is insensitive to pressures beneath lithostatic pressure and highly sensitive to pressures above lithostatic pressure. The legacy porosity response surface, on the other hand, has moderate porosity gradients over all pressures. The new porosity response surface has a stronger scientific foundation than the legacy surface and may now be used for Compliance Decision Analyses.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Improved Compaction Experiments and Modeling of Waste Isolation Pilot Plant Standard, Non-degraded, Waste Containers

A credible simulation of disposal room porosity at the Waste Isolation Pilot Plant (WIPP) requires a tenable compaction model for the 55-gallon waste containers within the room. A review of the legacy waste material model, however, revealed several out-of-date and untested assumptions that could affect the model’s compaction behavior. For example, the legacy model predicted non-physical tensile out-of-plane stresses under plane strain compression. (Plane strain compression is similar to waste compaction in the middle of a long drift.) Consequently, a suite of new compaction experiments were performed on containers filled with surrogate, non-degraded, waste. The new experiments involved uniaxial, triaxial, and hydrostatic compaction tests on quarter-scale and full-scale containers. Special effort was made to measure the volume strain during uniaxial and triaxial tests, so that the lateral strain could be inferred from the axial and volume strain. These experimental measurements were then used to calibrate a pressure dependent, viscoplastic, constitutive model for the homogenized compaction behavior of the waste containers. This new waste material model’s predictions agreed far better with the experimental measurements than the legacy model’s predictions, especially under triaxial and hydrostatic conditions. Under plane strain compression, the new model predicted reasonable compressive out-of-plane stresses, instead of tensile stresses. Moreover, the new model’s plane strain behavior was substantially weaker for the same strain, yet substantially stronger for the same porosity, than the legacy model’s behavior. Although room for improvement exists, the new model appears ready for prudent engineering use.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Simulations of Criticality Control Overpack Container Compaction at the Waste Isolation Pilot Plant

Criticality Control Overpack (CCO) containers are being considered for the disposal of defense-related nuclear waste at the Waste Isolation Pilot Plant (WIPP). At WIPP, these containers would be placed in underground disposal rooms, which will naturally close and compact the containers closer to one another over several centuries. This report details simulations to predict the final container configuration as an input to nuclear criticality assessments. Each container was discretely modeled, including the plywood and stainless steel pipe inside the 55-gallon drum, in order to capture its complex mechanical behavior. Although these high-fidelity simulations were computationally intensive, several different material models were considered in an attempt to reasonably bound the horizontal and vertical compaction percentages. When exceptionally strong materials were used for the containers, the horizontal and vertical closure respectively stabilized at 43:9 % and 93:7 %. At the other extreme, when the containers completely degraded and the clay seams between the salt layers were glued, the horizontal and vertical closure reached respective final values of 48:6 % and 100 %.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

White Paper on Lithium-Ion Battery Safety for use in Safety Planning at the Waste Isolation Pilot Plant

The Waste Isolation Pilot Plant (WIPP) is an underground facility designed to safely dispose of radioactive waste. The WIPP uses many heavy vehicles to transport materials and equipment underground. Most of these vehicles are powered by traditional internal combustion engines (ICE) with diesel fuel. Recently, electric vehicles (EVs) powered with batteries have been used at the WIPP. EVs have very low operational and maintenance costs, not considering battery replacements, and they have zero emissions during operation. This absence of emissions makes them ideal for underground facilities with limited ventilation. Even if a facility has robust ventilation normally, ventilation systems can break down leading to restrictions in ICE powered operations. Figure 1 shows a rendering of the WIPP.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of the Table of Initial Isolation and Protective Action Distances for the 2024 Emergency Response Guidebook

The transportation of hazardous materials creates numerous opportunities for the release of toxic substances into the environment, whether caused by traffic accidents, train derailments, equipment failures, or human error. Such releases can pose acute hazards to the general public and to emergency response personnel who are the first to arrive at the scene. To help first responders determine whether a shipment is potentially hazardous and decide what actions should be taken if a toxic spill does occur, the Emergency Response Guidebook (ERG) is published by the U.S. Department of Transportation (DOT), Transport Canada, and the Secretariat of Transport and Communications of Mexico; with contributions from Centro de Informaciòn Quìmica para Emergencias of Argentina. The most recent version is the 2024 edition of the ERG (ERG 2024), titled 2024 Emergency Response Guidebook (ERG2024). The ERG provides essential information about firefighting, spill response, and potential public health effects. For chemicals that are toxic by inhalation (TIH) and chemicals that produce TIH gases upon reaction with water (TIH by water reactivity or TIHWR), the ERG provides initial isolation distances (IIDs) and protective action distances (PADs). The IID defines the radius of the zone around the spill that should be accessed solely by people who are directly involved in emergency response. The PAD is the distance downwind of the source of the release within which persons should be either evacuated or sheltered in place, depending on the severity of the incident and the nature of the population (e.g., density, age, health).

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Geochemical Modeling Using OLI Systems Mixed Solvent Electrolyte Model in Support of the Waste Isolation Pilot Plant

Aqueous electrolyte thermodynamic models were developed for synthetic Salado (GWB) and Castile (ERDA-6) brines to inform the experimental design and to facilitate laboratory data interpretation in geochemical studies supporting disposal in the Waste Isolation Pilot Plant (WIPP). The thermodynamic models, which include the relevant vapor-liquid-solid equilibria for the oxidation-reduction conditions of interest, enable computation of system parameters such as activity-based pH, E h [vs. standard hydrogen electrode (SHE)], ionic strength, total dissolved solids, and solution density; the chemical speciation of all phases; saturation tendencies for thermodynamically feasible solids; and changes in brine chemistry because of the addition of H 2 (g), argon, MgO, Fe(0), and other waste form components. The impacts of oxidation-reduction potential (ORP) and pH on aqueous speciation and dominant solid phases were also assessed with the aid of real-solution Pourbaix diagrams for key elements of interest. In addition to the OLI modeling results, limited measurement data for pH and ORP standards are provided, analyzed, and discussed.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

An Assessment of the Error Due to Computing Waste Isolation Pilot Plant Porosity Using the Porosity Response Surface Approach

The Waste Isolation Pilot Plant Performance Assessment (WIPP PA) must predict the likelihood that radionuclides will escape into the biosphere via mechanisms that depend on geohydraulic flow. Ideally, one would predict the geohydraulic flow using coupled geohydraulic and geomechanical simulations, but such coupled simulations are not computationally tractable. Instead, Sandia has historically used a look-up table of porosities for a given fluid pressure and time, called the porosity response surface, but this approach can introduce porosity errors because it largely ignores the porosity’s dependence on the past fluid pressure history. This report discusses efforts to quantify these porosity errors for both the legacy and new porosity response surfaces. Six hundred different fluid pressure histories were fed through the legacy/new geomechanical model and the legacy/new porosity response surface to generate six hundred porosity error histories. The error associated with the legacy porosity surface was substantial, while the error associated with the new porosity surface was typically small, except when fluid pressures exceeded the lithostatic pressure at the repository. In response to the errors at high pressures, a preliminary study of the WIPP PA’s sensitivity to these porosity errors was conducted. The study found that reducing the porosity errors at high pressures negligibly affected predictions of radionuclide releases. Finally, an initial machine-learned model for porosity was developed. This ML model significantly reduced the porosity error at high pressures, but sizable errors remained, so more development is necessary before coupling an ML model to the geohydraulic model.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Effects of Salt Concentration, Ionic Strength, and Water Activity on the Growth of a WIPP Archaeal Isolate, Halobacterium sp.

An extremely halophilic archaeon ( Halobacterium sp., WIPP strain), isolated from WIPP halite, was tested for its ability to grow in media containing various combinations of sodium and magnesium chloride that influenced overall ionic strength and water activity. Halobacterium sp. grew well in most tested salt combinations, and its growth appeared to depend more upon the relative contribution of sodium to overall ionic strength than on other parameters. Growth rates were highest when media consisted of at least 2 M NaCl and lowest when NaCl dropped below 20% of the ionic strength (usually less than 0.5 M). High magnesium concentrations ( 1 and 1.5 M MgCh 2 ) did not prevent Halobacterium sp. growth, as long as the sodium contribution was sufficient. Water activity was not a definitive factor in determining growth, because this value did not reach an extreme lower limit in the experimental media.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Targeted Mobile Measurements to Isolate the Impacts of Aerosols and Meteorology on Deep Convection

One of the main goals of the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Tracking Aerosol Convection Interactions Experiment (TRACER) field campaign near Houston, TX was to improve understanding of meteorology and aerosol effects on deep convective storms. To help TRACER achieve its goals of disentangling aerosol-cloud interactions from meteorology, the Texas A&M University (TAMU) team deployed the new fully mobile Rapid Onsite Atmospheric Measurement Van (ROAM-V) carrying instruments to measure aerosol and atmospheric properties that was moved to multiple locations on a deployment day of isolated convection initiated by the sea breeze.

54 ENVIRONMENTAL SCIENCES↗

Computer vision-based rock bolt detection in orthomosaic imagery obtained in the Waste Isolation Pilot Plant underground facility

Assessing structural integrity of large underground tunnel facilities is often a time consuming and human-labor intensive task. Thus, research using various modes of sensing and automated detection of key structural components in mines is posed to aid in safety assessments and establishing overall structural health. We propose an approach utilizing off-the-shelf camera and lidar technology fixed to a custom sensing platform, image stitching techniques, fine-tuned object detection models, and specialized model-inference methods to automatically detect, count, and map roof bolts for assessment of structural safety in man-made underground tunnels. Results show a novel workflow for effective object counting in orthomosaic tunnel ceiling images generated from collections in GPS-denied mining environments. Additionally, we demonstrate effective fine-tuning of EfficientDet object detectors utilizing state-of-the-art image augmentation techniques known as the mosaic and mixup transformations. Our work is demonstrated on sensed data and imagery collected from the Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) where miles of tunnel ceiling must be assessed for structural integrity.

42 ENGINEERING↗