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At least 937 records · Page 52

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NASA NTRS1976

The NASA hydrogen energy systems technology study: A summary

The results and conclusions of the study, which found a significant current usage of hydrogen, dominated by chemical-industry needs and supplied mostly from natural gas and petroleum feedstocks are discussed. These needs are expected to increase significantly in the remainder of this century and to largely outgrow the current means of supply. Several hydrogen production methods were evaluated. Those not dependent on fossil resources were found to be presently more costly and technically more difficult than fossil-feedstock-based technologies, but it is clear that they will eventually need to be implemented.

Laumann, E. A.↗

NASA NTRS1977

Performance data for a terrestrial solar photovoltaic/water electrolysis experiment

A description is presented of the equipment used in the experiment, taking into account the surplus solar panel from the Mariner 4 spacecraft which was used as a solar array source and an electrolytic hydrogen generator. Attention is also given to operational considerations and performance data, system considerations and aspects of optimization, and large-scale hydrogen production considerations.

Costogue, E. N.↗

NASA NTRS1977

Solar thermionic power systems for terrestrial applications

The results of a feasibility study which showed that a low-temperature, high-efficient thermionic power system can efficiently convert solar energy to electrical energy without heat transport, as required by most solar thermal systems are described. A 3-dimensional (2-axis tracking) 93 sq m parabolic solar concentrator, consisting of mirrors on a foam glass substrate and designed to a concentration ratio (mirror area/aperture area) of 2000 is considered for producing a design temperature of 1100 C at an efficiency of 74%. A tracking subsystem must track the sun at an accuracy of a nominal plus or minus 1.0 degree for maximum use of the sun's energy. Each complete solar thermionic power system unit rated at about 20 kWe peak can generate approximately 48,000 kWh/yr. In addition, a thermal energy conversion system can be cascaded within the thermionic power system so that the high quality waste heat can be further utilized to increase the net electrical output. Potential applications of a solar thermionic power generation system are remote sites, apartment house complexes, heating and cooling, hydrogen production and large power stations.

Shimada, K.↗

NASA NTRS1977

Thermochemical water decomposition

At present, nearly all of the hydrogen consumed in the world is produced by reacting hydrocarbons with water. As the supply of hydrocarbons diminishes, the problem of producing hydrogen from water alone will become increasingly important. Furthermore, producing hydrogen from water is a means of energy conversion by which thermal energy from a primary source, such as solar or nuclear fusion of fission, can be changed into an easily transportable and ecologically acceptable fuel. The attraction of thermochemical processes is that they offer the potential for converting thermal energy to hydrogen more efficiently than by water electrolysis. A thermochemical hydrogen-production process is one which requires only water as material input and mainly thermal energy, or heat, as an energy input. Attention is given to a definition of process thermal efficiency, the thermodynamics of the overall process, the single-stage process, the two-stage process, multistage processes, the work of separation and a process evaluation.

Funk, J. E.↗

NASA NTRS1979

Methods for calculation of engineering parameters for gas separation

A group additivity method is generated which allows estimation, from the structural formulas alone, of the energy of vaporization and the molar volume at 25 C of many nonpolar organic liquids. Using these two parameters and appropriate thermodynamic relations, the vapor pressure of the liquid phase and the solubility of various gases in nonpolar organic liquids are predicted. It is also possible to use the data to evaluate organic and some inorganic liquids for use in gas separation stages or liquids as heat exchange fluids in prospective thermochemical cycles for hydrogen production.

Lawson, D. D.↗

NASA NTRS1979

Potential heat exchange fluids for use in sulfuric acid vaporizers

A series of perhalocarbons are proposed as candidate heat exchange fluids for service in thermochemical cycles for hydrogen production that involve direct contact of the fluid with sulfuric acid and vaporization of the acid. The required chemical and physical criteria of the liquids are described and the results of some preliminary high temperature test data are presented.

Lawson, D. D.↗

NASA NTRS1980

Methods of calculating engineering parameters for gas separations

A group additivity method has been generated which makes it possible to estimate, from the structural formulas alone, the energy of vaporization and the molar volume at 25 C of many nonpolar organic liquids. From these two parameters and appropriate thermodynamic relationships it is then possible to predict the vapor pressure of the liquid phase and the solubility of various gases in nonpolar organic liquids. The data are then used to evaluate organic and some inorganic liquids for use in gas separation stages or as heat exchange fluids in prospective thermochemical cycles for hydrogen production.

Lawson, D. D.↗

NASA NTRS1981

The derivation of Halley parameters from observations

Nominal value model parameters for the nucleus (size, mass, rotation, albedo, hydrogen production) the dust and gas for P/Halley at 0.9 AU postperihelion are derived from the light curve and spectra of Halley and by modeling the effect of the nongravitational forces, e.g., the outgassing rocket type effect of the nucleus. In those cases where Halley observations are not sufficient, the average value derived from a larger set of other comets is used, or data from comet Bennett, Halley's best analog, are taken. A flow diagram shows how the parameter values are derived and to what extent these derived values are interdependent.

Newburn, R. L.↗

NASA NTRS1982

Eddy mixing coefficient on Saturn

Data on the composition, thermal structure, and Lyman-alpha dayglow of Saturn, when analyzed in conjunction with photochemical models of the hydrocarbons and the atomic hydrogen production, yield the homopause value of the eddy diffusion coefficient to be approximately 100 million/sq cm per sec. The equatorial value of the eddy diffusion coefficient at the homopause of Saturn is thus found to be approximately 100 times greater than on Jupiter. The mesosphere (and presumably, troposphere) of Saturn appears to be considerably more turbulent than the upper atmosphere of Jupiter.

Atreya, S. K.↗

NASA NTRS1981

Silane pyrolysis in a free-space reactor

The Union Carbide process for producing silicon for photovoltaic applications proceeds via high purity silane as an intermediate. Decomposition of silane is accomplished in a freespace reactor which utilizes recirculating product hydrogen and silicon to transfer energy from a heated wall to an entering silane jet. Reaction occurs away from the wall, minimizing problems with wall deposition and contamination. A series of long duration and throughput tests has proven the feasibility of this concept. High purity powder can be produced at flows up to 4.5 kg/hr (10 lb/hr) in a 0.2 m (8 inch) diameter reactor with better than 99.99% conversion efficiency. This work is funded by DOE under JPL's Low Cost Solar Array (LSA) program.

Lay, J. R.↗

NASA NTRS1980

Applications of ion beam technology

Wire adhesion in steel belted radial tires; carbon fibers and composite; cold welding, brazing, and fabrication; hydrogen production, separation, and storage; membrane use; catalysis; sputtering and texture; and ion beam implantation are discussed.

Gelerinter, E.↗

NASA NTRS1982

Hybrid fuel cell/diesel generation total energy system, part 2

Meeting the Goldstone Deep Space Communications Complex (DGSCC) electrical and thermal requirements with the existing system was compared with using fuel cells. Fuel cell technology selection was based on a 1985 time frame for installation. The most cost-effective fuel feedstock for fuel cell application was identified. Fuels considered included diesel oil, natural gas, methanol and coal. These fuel feedstocks were considered not only on the cost and efficiency of the fuel conversion process, but also on complexity and integration of the fuel processor on system operation and thermal energy availability. After a review of fuel processor technology, catalytic steam reformer technology was selected based on the ease of integration and the economics of hydrogen production. The phosphoric acid fuel cell was selected for application at the GDSCC due to its commercial readiness for near term application. Fuel cell systems were analyzed for both natural gas and methanol feedstock. The subsequent economic analysis indicated that a natural gas fueled system was the most cost effective of the cases analyzed.

Blazek, C. F.↗

NASA NTRS1982

The derivation of Halley parameters from observations

Newburn, R. L.↗

NASA NTRS1984

Solar thermochemical process interface study

The design and analyses of a subsystem of a hydrogen production process are described. The process is based on solar driven thermochemical reactions. The subject subsystem receives sulfuric acid of 60% concentration at 100 C, 1 atm pressure. The acid is further concentrated, vaporized, and decomposed (at a rate of 122 g moles/sec H2SO4) into SO2, O2, and water. The produce stream is cooled to 100 C. Three subsystem options, each being driven by direct solar energy, were designed and analyzed. The results are compared with a prior study case in which solar energy was provided indirectly through a helium loop.

Source record↗

NASA NTRS1985

Long-life high performance fuel cell program

A multihundred kilowatt Regenerative Fuel Cell for use in a space station is envisioned. Three 0.508 sq ft (471.9 cm) active area multicell stacks were assembled and endurance tested. The long term performance stability of the platinum on carbon catalyst configuration suitability of the lightweight graphite electrolyte reservoir plate, the stability of the free standing butyl bonded potassium titanate matrix structure, and the long life potential of a hybrid polysulfone cell edge frame construction were demonstrated. A 18,000 hour demonstration test of multicell stack to a continuous cyclical load profile was conducted. A total of 12,000 cycles was completed, confirming the ability of the alkaline fuel cell to operate to a load profile simulating Regenerative Fuel Cell operation. An orbiter production hydrogen recirculation pump employed in support of the cyclical load profile test completed 13,000 hours of maintenance free operation. Laboratory endurance tests demonstrated the suitability of the butyl bonded potassium matrix, perforated nickel foil electrode substrates, and carbon ribbed substrate anode for use in the alkaline fuel cell. Corrosion testing of materials at 250 F (121.1 C) in 42% wgt. potassium identified ceria, zirconia, strontium titanate, strontium zirconate and lithium cobaltate as candidate matrix materials.

Martin, R. E.↗

NASA NTRS1985

Lunar bases and space activities of the 21st century

The present conference gives attention to such major aspects of lunar colonization as lunar base concepts, lunar transportation, lunar science research activities, moon-based astronomical researches, lunar architectural construction, lunar materials and processes, lunar oxygen production, life support and health maintenance in lunar bases, societal aspects of lunar colonization, and the prospects for Mars colonization. Specific discussions are presented concerning the role of nuclear energy in lunar development, achromatic trajectories and the industrial scale transport of lunar resources, advanced geologic exploration from a lunar base, geophysical investigations of the moon, moon-based astronomical interferometry, the irradiation of the moon by particles, cement-based composites for lunar base construction, electrostatic concentration of lunar soil minerals, microwave processing of lunar materials, a parametric analysis of lunar oxygen production, hydrogen from lunar regolith fines, metabolic support for a lunar base, past and future Soviet lunar exploration, and the use of the moons of Mars as sources of water for lunar bases.

Mendell, W. W.↗

NASA NTRS1987

Superthermal electron processes in the upper atmosphere of Uranus: Aurora and electroglow

Strong ultraviolet emissions from the upper atmosphere of Uranus suggest that both auroral and electroglow phenomena are of significant aeronomical consequences in the structure of the upper atmosphere. Combined modeling and data analysis were performed to determine the effect of electroglow and auroral phenomena on the global heat and atomic hydrogen budgets in the Uranus upper atmosphere. The results indicate that the auroral and electroglow heat sources are not adequate to explain the high exospheric temperature observed at Uranus, but that the atomic hydrogen supplied by these processes is more than sufficient to explain the observations. The various superthermal electron distributions modeled have significantly different efficiencies for the various processes such as UV emission, heating, ionization, and atomic hydrogen production, and produce quite different H2 band spectra. However, additional information on the UV spectra and global parameters is needed before modeling can be used to distinguish between the possible mechanisms for electroglow.

Waite, J. H., Jr.↗

NASA NTRS1987

Mesospheric ionization and O2 1Delta(g) depletion

Observations of O2 1Delta(g) emission during solar proton events reveal large depletions below 80 and near 90 km. The lower-altitude depletions are believed to be due to odd hydrogen production and associated depletion of ozone, but the mechanism producing the depletion near 90 km has not yet been established. In this paper, it is proposed that an exothermic charge exchange reaction between O2(+) and O2 1Delta(g) is likely to be responsible for these high-altitude depletions. In particular, it is shown that the vertical structure of the observed change in airglow emission is consistent with this mechanism.

Spear, K. A.↗