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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Modeling kinetic effects of charged vacancies on electromechanical responses of ferroelectrics: Rayleighian approach

Understanding the time-dependent effects of charged vacancies on the electromechanical responses of materials is at the forefront of research for designing materials exhibiting metal-insulator transitions and memristive behavior. A Rayleighian approach is used to develop a model for studying the nonlinear kinetics of the reaction leading to generation of vacancies and electrons via the dissociation of vacancy-electron pairs. Also, diffusion and elastic effects of charged vacancies are considered to model polarization-electric potential and strain-electric potential hysteresis loops. The model captures multiphysics phenomena by introducing couplings among polarization, the electric potential, stress, strain, and concentrations of charged (multivalent) vacancies and electrons (treated as classical negatively charged particles), where the concentrations can vary due to association-dissociation reactions. A derivation of coupled time-dependent equations based on the Rayleighian approach is presented. Three limiting cases of the governing equations are considered, highlighting the effects of (1) nonlinear reaction kinetics on the generation of charged vacancies and electrons, (2) Vegard's law (i.e., the concentration-dependent local strain) on asymmetric strain-electric potential relations, and (3) coupling between a fast component and the slow component of the net polarization on the polarization-electric-field relations. The Rayleighian approach discussed in this work should pave the way for developing a multiscale modeling framework in a thermodynamically consistent manner while capturing multiphysics phenomena in ferroelectric materials. Published by the American Physical Society 2025

Kumar, Rajeev (ORCID:0000000194943488)↗
NASA NTRS1974

Measurements of positive ion conversion and removal reactions relating to the Jovian ionosphere

Measured rates are presented for the reaction of He(+) ions with H2 (and D2) molecules to form H(+), H2(+), and HeH(+) ions, as well as for the subsequent reactions of H(+) and HeH(+) ions with H2 to form H3(+). The neutralization of H3(+) /and H5(+)/ ions by dissociative recombination with electrons is shown to be fast. The reaction He(+) + H2 is slow (k 1.1 x 10 to the minus 13th cu cm/sec at 300 K) and produces principally H(+) by the dissociative charge transfer branch. It is concluded that there may be a serious bottleneck in the conversion of two of the primary ions of the upper Jovian ionosphere, H(+) and He(+) (which recombine slowly), to the rapidly recombining H3(+) ion.

Johnsen, R.↗
DOE OSTI2025

Artificial intelligence-based predictive modeling for imaging neutral particle analyzers on the DIII-D tokamak

The Imaging Neutral Particle Analyzer (INPA) at DIII-D is a diagnostic system used to accurately resolve the energy and spatial distributions of fast ions in fusion plasmas. A novel artificial intelligence (AI) technique named INPA-net is based on Reservoir Computing Networks and developed here to predict active and passive signals produced by charge-exchange reactions from injected and edge-cold neutrals, respectively, in magnetically confined fusion plasmas. This model is trained using a set of 21 time domain signals between 0 s to 3.35 s that includes injected beam and thermal plasma information, and 6444 real 2D experimental images of the INPA in 12 plasma discharges at DIII-D. The trained neural network is able to forecast experimental images in real-time. The model achieves an R-squared value of 0.91, which is higher than the 0.83 value achieved by a simple linear regression model. This improvement highlights the model's enhanced predictive accuracy for measured images from the validation set. This AI approach is valuable due to its rapid response times and potential for integration into real-time plasma control systems. A version of this model capable of generating syntehic images would be useful for the real-time monitoring of fast-ion transport. A comprehensive sensitivity study reveals that INPA-net maintains high performance even with variations in the input parameters, indicating the model's robustness and reliability. While developed for the INPA, the underlying architecture is adaptable and may be applied to various 2D imaging diagnostics in fusion research.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1982

A critical velocity interaction between fast barium and strontium atoms and the terrestial ionospheric plasma

A disk of barium and strontium vapor traveling radially outward, perpendicular to the geomagnetic field lines, may be created by the detonation of a high-explosive, radially shaped charge with a liner composed of the two metals in the upper atmosphere. Because of solar radiation resonance, both the barium and the strontium may be optically tracked. Observations indicate the early formation of the metal ions thus evolved into a disk-shaped, stellate structure with a dark hole at the center of a radial structure. The results of these experiments indicate that the process could occur on a cosmic scale, and that unconfirmed aspects of the theory relating to this process could be determined through variation of the parameters in future radial rocket experiments.

Deehr, C. S.↗
DOE OSTI2024

Tuning Exciton Emission via Ferroelectric Polarization at a Heterogeneous Interface between a Monolayer Transition Metal Dichalcogenide and a Perovskite Oxide Membrane

Here we demonstrate the integration of a thin BaTiO 3 (BTO) membrane with monolayer MoSe 2 in a dual gate device that enables in-situ manipulation of the BTO ferroelectric polarization with a voltage pulse. While two-dimensional (2D) transition metal dichalcogenides (TMDs) offer remarkable adaptability, their hybrid integration with other families of functional materials beyond the realm of 2D materials has been challenging. Released functional oxide membranes offer a solution for 2D/3D integration via stacking. 2D TMD excitons can serve as a local probe of the ferroelectric polarization in BTO at a heterogeneous interface. Using photoluminescence (PL) of MoSe 2 excitons to optically readout the doping level, we find that the relative population of charge carriers in MoSe 2 depends sensitively on the ferroelectric polarization. This finding points to a promising avenue for future-generations versatile sensing devices with high sensitivity, fast read-out, and diverse applicability for advanced signal processing.

42 ENGINEERING↗
NASA NTRS1981

On the role of vibrational excitation in dissociative recombination

An improved physical model of dissociative recombination is presented and applied to experimental data on the temperature dependence of rate coefficients for the rare-gas and atmospheric-gas ions. It is shown that in the charge neutralisation of the rare-gas dimer ions, autoionisation plays an important role (at least in comparison with the atmospheric-gas ions) and contributes to the fast fall-off in the rate coefficient with vibrational excitation observed in shock tube studies. Numerical estimates of the observed fall-off in rate coefficient with increasing vibrational excitation are also presented.

Cunningham, A. J.↗
NASA NTRS2011

Polymeric Materials With Additives for Durability and Radiation Shielding in Space

Polymeric materials are attractive for use in space structures because of their light weight and high strength In addition, polymers are made of elements with low atomic numbers (Z), primarily carbon (C), hydrogen (H), oxygen (0), and nitrogen (N) which provide the best shielding from galactic cosmic rays (GCR) (ref. 1). Galactic cosmic rays are composed primarily of nuclei (i.e., fully ionized atoms) plus a contribution of about 2% from electrons and positrons. There is a small but significant component of GCR particles with high charge (Z > 10) and high energy (E >100 GeV) (ref. 2). These so-called HZE particles comprise only 1 to 2% of the cosmic ray fluence but they interact with very high specific ionization and contribute 50% of the long- term dose to humans. The best shield for this radiation would be liquid hydrogen, which is not feasible. For this reason, hydrogen-containing polymers make the most effective practical shields. Moreover, neutrons are formed in the interactions of GCR particles with materials. Neutrons can only lose energy by collisions or reactions with a nucleus since they are uncharged. This is a process that is much less probable than the Coulombic interactions of charged particles. Thus, neutrons migrate far from the site of the reaction in which they were formed. This increases the probability of neutrons reaching humans or electronic equipment. Fast neutrons (> 1 MeV) can interact with silicon chips in electronic equipment resulting in the production of recoil ions which can cause single event upsets (SEU) in sensitive components (ref. 3). Neutrons lose energy most effectively by elastic collisions with light atoms, particularly hydrogen atoms. Therefore, hydrogen-containing polymers are not only effective in interacting with GCR particles; they are also effective in reducing the energy of the neutrons formed in the interactions.

Kiefer, Richard↗
NASA NTRS2016

Implications of L1 Observations for Slow Solar Wind Formation by Solar Reconnection

While the source of the fast solar wind is known to be coronal holes, the source of the slow solar wind has remained a mystery. Long time scale trends in the composition and charge states show strong correlations between solar wind velocity and plasma parameters, yet these correlations have proved ineffective in determining the slow wind source. We take advantage of new high time resolution (12 min) measurements of solar wind composition and charge state abundances at L1 and previously identified 90 min quasi periodic structures to probe the fundamental timescales of slow wind variability. The combination of new high temporal resolution composition measurements and the clearly identified boundaries of the periodic structures allows us to utilize these distinct solar wind parcels as tracers of slowwind origin and acceleration. We find that each 90 min (2000 Mm) parcel of slow wind has near-constant speed yet exhibits repeatable, systematic charge state and composition variations that span the entire range of statistically determined slow solar wind values. The classic composition-velocity correlations do not hold on short, approximately hour long, time scales. Furthermore, the data demonstrate that these structures were created by magnetic reconnection. Our results impose severe new constraints on slow solar wind origin and provide new, compelling evidence that the slow wind results from the sporadic release of closed field plasma via magnetic reconnection at the boundary between open and closed flux in the Sun's atmosphere.

Kepko, L.↗
NASA NTRS2004

Instrumentation for Studies of Electron Emission and Charging From Insulators

Making measurements of electron emission properties of insulators is difficult since insulators can charge either negatively or positively under charge particle bombardment. In addition, high incident energies or high fluences can result in modification of a material s conductivity, bulk and surface charge profile, structural makeup through bond breaking and defect creation, and emission properties. We discuss here some of the charging difficulties associated with making insulator-yield measurements and review the methods used in previous studies of electron emission from insulators. We present work undertaken by our group to make consistent and accurate measurements of the electron/ion yield properties for numerous thin-film and thick insulator materials using innovative instrumentation and techniques. We also summarize some of the necessary instrumentation developed for this purpose including fast response, low-noise, high-sensitivity ammeters; signal isolation and interface to standard computer data acquisition apparatus using opto-isolation, sample-and-hold, and boxcar integration techniques; computer control, automation and timing using Labview software; a multiple sample carousel; a pulsed, compact, low-energy, charge neutralization electron flood gun; and pulsed visible and UV light neutralization sources. This work is supported through funding from the NASA Space Environments and Effects Program and the NASA Graduate Research Fellowship Program.

Thomson, C. D.↗
DOE OSTI2020

The Fast-Track Water Oxidation Channel on BiVO 4 Opened by Nitrogen Treatment

BiVO 4 is one of the most promising photoanode materials for water-splitting systems. Nitrogen incorporation into a BiVO 4 surface overcomes the known bottleneck in its charge-transfer kinetics into the electrolyte. We explored the role of nitrogen in the surface charge recombination and charge-transfer kinetics by employing transient photocurrent spectroscopy at the time scale of surface recombination and water oxidation kinetics, transient absorption spectroscopy, and X-ray photoelectron spectroscopy. We attributed the activity enhancement mechanism to the accelerated V 5+ /V 4+ redox process, in which incorporated nitrogen suppresses a limiting surface recombination channel by increasing the oxygen vacancies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

Theoretical prediction of the impact of Auger recombination on charge collection from an ion track

A recombination mechanism that significantly reduces charge collection from very dense ion tracks in silicon devices was postulated by Zoutendyk et al. The theoretical analysis presented here concludes that Auger recombination is such a mechanism and is of marginal importance for higher density tracks produced by 270-MeV krypton, but of major importance for higher density tracks. The analysis shows that recombination loss is profoundly affected by track diffusion. As the track diffuses, the density and recombination rate decrease so fast that the linear density (number of electron-hole pairs per unit length) approaches a non-zero limiting value as t yields infinity. Furthermore, the linear density is very nearly equal to this limiting value in a few picoseconds or less. When Auger recombination accompanies charge transport processes that have much longer time scales, it can be simulated by assigning a reduced linear energy transfer to the ion.

Edmonds, Larry D.↗
DOE OSTI2023

Engineering giant excitonic coupling in bioinspired, covalently bridged BODIPY dyads

Strong excitonic coupling in photosynthetic systems is believed to enable efficient light absorption and quantitative charge separation, motivating the development of artificial multi-chromophore arrays with equally strong or even stronger excitonic coupling. However, large excitonic coupling strengths have typically been accompanied by fast non-radiative recombination, limiting the potential of the arrays for solar energy conversion as well as other applications such as fluorescent labeling. Here, in this work, we report giant excitonic coupling leading to broad optical absorption in bioinspired BODIPY dyads that have high photostability, excited-state lifetimes at the nanosecond scale, and fluorescence quantum yields of nearly 50%. Through the synthesis, spectroscopic characterization, and computational modeling of a series of dyads with different linking moieties, we show that the strongest coupling is obtained with diethynylmaleimide linkers, for which the coupling occurs through space between BODIPY units with small separations and slipped co-facial orientations. Other linkers allow for broad tuning of both the relative through-bond and through-space coupling contributions and the overall strength of interpigment coupling, with a tradeoff observed in general between the strength of the two coupling mechanisms. These findings open the door to the synthesis of molecular systems that function effectively as light-harvesting antennas and as electron donors or acceptors for solar energy conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Validating the simulation of beam-ion charge exchange in MAST Upgrade

Abstract Simulation of the impact of charge-exchange (CX) reactions on beam ions in the Mega Amp Spherical Tokamak (MAST) Upgrade was compared to measurements carried out with a fission chamber (neutron fluxes) and a fast ion deuterium-alpha (FIDA) diagnostic. A simple model was developed to reconstruct the outer-midplane neutral density based on measurements of deuterium-alpha emission from edge neutrals, and on Thomson scattering measurements of electron density and temperature. The main computational tools used were the ASCOT orbit-following code and the FIDASIM code for producing synthetic FIDA signals. The neutral density reconstruction agrees qualitatively with SOLPS-ITER modelling and yields a synthetic passive FIDA signal that is consistent with measurement. When CX losses of beam ions are accounted for, predicted neutron emission rates are quantitatively more consistent with measurement. It was necessary to account for CX losses of beam ions in simulations to reproduce the measured passive FIDA signal quantitatively and qualitatively. The results suggest that the neutral density reconstruction is a good approximation, that CX with edge neutrals causes significant beam-ion losses in MAST Upgrade, typically 20% of beam power, and that the ASCOT fast-ion CX model can be used to accurately predict the redistribution and loss of beam ions due to CX.

Physics↗
NASA NTRS2001

Charge Exchange Contribution to the Decay of the Ring Current, Measured by Energetic Neutral Atoms (ENAs)

In this paper we calculate the contribution of charge exchange to the decay of the ring current. Past works have suggested that charge exchange of ring current protons is primarily responsible for the decay of the ring current during the late recovery phase, but there is still much debate about the fast decay of the early recovery phase. We use energetic neutral atom (ENA) measurements from Polar to calculate the total ENA energy escape. To get the total ENA escape we apply a forward modeling technique, and to estimate the total ring current energy escape we use the Dessler-Parker-Sckopke relationship. We find that during the late recovery phase of the March 10, 1998 storm ENAs with energies greater than 17.5 keV can account for 75% of the estimated energy loss from the ring current. During the fast recovery the measured ENAs can only account for a small portion of the total energy loss. We also find that the lifetime of the trapped ions is significantly shorter during the fast recovery phase than during the late recovery phase, suggesting that different processes are operating during the two phases.

Jorgensen, A. M.↗
DOE OSTI2024

Validation of a synthetic fast ion loss detector model for Wendelstein 7-X

Abstract We present the first validated synthetic diagnostic for fast ion loss detectors (FILDs) in the Wendelstein 7-X (W7-X) stellarator. This model has been developed on, and validated against experimental data from, a FILD provided by the National Institute for Fusion Science (NIFS-FILD), with potential future applicability to the existing Faraday Cup FILD (FC-FILD) on W7-X as well as the scintillating FILD (S-FILD) currently under development. A workflow combining Monte Carlo codes BEAMS3D and ASCOT5 is used to track fast ions produced by neutral beam injection from the moment of ionization until they are thermalized or lost from the last closed flux surface, and from there to a virtual plane which serves as a projection of the entrance aperture to the FILD. Simulations in ASCOT5 are analyzed via a geometric method to determine the probability of transmission through the FILD aperture and onto the detector as a function of normalized momentum, pitch angle, gyrophase, and position at the virtual plane. This probability is then applied to the simulated ions arriving from the plasma, producing a simulated signal from a computationally tractable number of simulated fast ions. Simulated signals are presented for two W7-X experiments with neutral beam injection and quantitatively compared with experimental measurements from the NIFS-FILD diagnostic. An estimate of the frequency of charge-exchange with neutral particles in the edge is performed, and it is found that this process may have a significant impact on the measured signals.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1993

Isotopic fractionation of hydrogen in planetary exospheres due to ionosphere-exosphere coupling - Implications for Venus

The paper considers isotopic hydrogen fractionation processes in the Venusian exosphere due to ionosphere-exosphere coupling by addressing two deficiencies in the present theory of differential escape. First, a set of D/H isotopic fractionation curves is derived for the ion-neutral interactions of charge and collisional momentum transfer, and these are compared with the results of Gurwell and Yung (1993) for hot O collisional ejection. Then, the question of the relative importance of collisional ejection in atmospheric escape is reexamined using two simple exosphere models. It is shown that O-O collisions suppress the high energy component of the hot O distribution by more than a factor of 10. Moreover, the ballistic trajectories of fast O atoms that reach the nighttime reservoir of exospheric hydrogen favor downward scatter of D and H rather than their escape. It is concluded that, due to severe limits placed on the effectiveness of collisional ejection, the differential escape of D and H from Venus is determined by charge exchange interactions rather than the collisional ejection.

Hodges, R. R., Jr.↗
NASA NTRS1996

Fast Neural Solution Of A Nonlinear Wave Equation

Neural algorithm for simulation of class of nonlinear wave phenomena devised. Numerically solves special one-dimensional case of Korteweg-deVries equation. Intended to be executed rapidly by neural network implemented as charge-coupled-device/charge-injection device, very-large-scale integrated-circuit analog data processor of type described in "CCD/CID Processors Would Offer Greater Precision" (NPO-18972).

Barhen, Jacob↗
DOE OSTI2023

Disrupting EV Charging Sessions and Gaining Remote Code Execution with DoS, MITM, and Code Injection Exploits using OCPP 1.6

Open Charge Point Protocol (OCPP) 1.6 is widely used in the electric vehicle (EV) charging industry to communicate between Charging System Management Services (CSMSs) and Electric Vehicle Supply Equipment (EVSE). Unlike OCPP 2.0.1, OCPP 1.6 uses unencrypted websocket communications to exchange information between EVSE devices and an onpremise or cloud-based CSMS. In this work, we demonstrate two machine-in-the-middle (MITM) attacks on OCPP sessions to terminate charging sessions and gain root access to the EVSE equipment via remote code execution (RCE). Second, we demonstrate a malicious firmware update with a code injection payload to compromise an EVSE. Lastly, we demonstrate two methods to prevent availability of the EVSE or CSMS. One of these, originally reported by SaiFlow, prevents traffic to legitimate EVSE equipment using a DoS-like attack on CSMSs by repeatedly connecting and authenticating several CPs with the same identities as the legitimate CP. These vulnerabilities were demonstrated with proof-of-concept exploits in a virtualized Cyber Range at Wright State University and/or with a 350 kW Direct Current Fast Charger (DCFC) at Idaho National Laboratory. The team found that OCPP 1.6 could be protected from these attacks by adding secure shell (SSH) tunnels to the protocol, if upgrading to OCPP 2.0.1 was not an option. Index Terms—Electric vehicle charging, cybersecurity, OCPP, cyberattack, cyber-resilience. INSPEC Accession Number: 23981565

99 GENERAL AND MISCELLANEOUS↗