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At least 937 records · Page 52

Pulsed-field magnetization of frustrated S = 1/2 Cu(pyrimidine) 1.5 (H 2 O)(BF 4 ) 2

Cu(pym) 1.5 (H 2 O)(BF 4 ) 2 (pym = pyrimidine) was synthesized and its structure determined by synchrotron single crystal X-ray diffraction. The compound contains S = 1/2 Cu(II) ions arranged in a distorted triangular array (Fig. 1). Each Cu(II) ion is coordinated to three pym ligands, two weakly held BF 4 - anions and one H 2 O. To get a sense to the extent (i.e., strength) of possible frustrated exchange interactions in this new compound we measured the magnetization of Cu(pym) 1.5 (H 2 O)(BF 4 ) 2 in pulsed magnetic fields up to 60 T.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Determining single-ion and spatial exchange anisotropies by pulsed-field magnetometry

The magnetic ground-state of the Q1D S = 1 antiferromagnetic (AFM) chain is sensitive to the single-ion anisotropy (D) and the relative strength of intra- (J) and interchain (J’) exchange interactions. The ratios D/J and J’/J dictate the material’s placement on the phase diagram for which three competing phases are known to theoretically exist: Haldane, XY and quantum paramagnetic. We identified [Ni(HF 2 )(pyz) 2 ]SbF 6 (pyz = pyrazine) as a candidate in which to explore proximity to these phases.

36 MATERIALS SCIENCE↗

High-field magnetotransport in microstructures of the frustrated antiferromagnet Yb 2 Pt 2 Pb

Frustrated quantum magnets exhibit a rich variety of non-trivial quantum ground states due to their remnant entropy at zero temperature. Most studied materials are insulators, with magnetic coupling of localized spins mediated by exchange interactions. Yb 2 Pt 2 Pb (YPP) is a rare example of a metallic frustrated quantum magnet, where Yb 3+ J=7/2 moments are arranged in dimers forming a Shastry-Sutherland lattice. In addition, the itinerant charge carriers of the metal provide gapless excitations able to mediate magnetic interactions (RKKY) as well as hybridize with the 4f-states, which has been proposed to lead to a novel charge-orbital separation. YPP orders antiferromagnetically (AFM) below TN = 2.1 K, and strong g-factor anisotropy confines the spins into the ab planes. Accordingly, fields aligned parallel to the planes suppress the AFM order already below 4 T, while fields of up to 65 T along the c direction do not lead to saturation in the magnetization and step-like features even at B ~ 25 T were observed [4]. Here we probe the electronic structure of YPP by quantum oscillation and conductivity measurements in high fields, which tune the energy balance of the 4f states and thus the degree of charge-orbital separation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

High magnetic field magnetization of a new triangular lattice antiferromagnet

In CsV(MoO 4 ) 2 , the magnetic V 3+ ions with octahedral oxygen-coordination form a geometrically frustrated triangular lattice. So fare, there is no magnetic properties reported on it. Recently, we successfully grew single crystals of CsV(MoO 4 ) 2 by using flux method. The susceptibility shows a sharp drop around 24 K, representing a long range magnetic ordering. To understand the physical properties of this new triangular lattice antiferromagnet (TLAF), we pursued high field magnetization measurements to answer two questions: (i) what is the saturation field, which will be very useful to calculate the exchange interaction of the system? (ii) Will it exhibit spin state transition, such as the up up down phase with 1/3-saturation moment as other TLAFs? Recently, we performed VSM measurements in Cell 8, Tallahassee, NHMFL, the results show that the magnetization reaches 0.38 MuB at 34 T, which is just 19% of the full moment of 2 MuB for V 3+ (3d 2 ) ions. Apparently we need higher field to reach 1/3 value or full moment.

36 MATERIALS SCIENCE↗

Nucleon properties from basis light front quantization

We investigate the electromagnetic properties of the nucleon using the framework of basis light front quantization. We consider the light front wave functions obtained by diagonalizing an effective Hamiltonian consisting of the holographic quantum chromodynamics confinement potential, a longitudinal confinement and a one-gluon exchange interaction with fixed coupling. The electromagnetic radii of the nucleon are also evaluated.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Investigation of spin and magnetism in two dimensional materials with atomic-scale spatial resolution (Final Technical Report)

Spintronics is an approach to energy-efficient electronics beyond silicon CMOS that utilizes the electron’s spin degree of freedom for memory and logic. The record spin diffusion length in graphene has generated considerable interest in two dimensional (2D) materials (i.e. graphene and beyond) as a platform for spintronics. Magnetism in 2D van der Waals materials may offer additional opportunities for tunability via strain, external fields, and layer-dependent quantum effects. The inherently atomic-scale nature of exchange interactions and the inherently all-surface nature of 2D sheets motivate an integrated approach combining atomic-scale magnetic characterization, epitaxial growth, and nanodevice fabrication. The mission of the research is to develop and utilize atomic-scale imaging of spin and magnetism via spin-polarized scanning tunneling microscopy (STM) in conjunction with atom-by-atom materials growth via molecular beam epitaxy (MBE) and nanoscale device fabrication to explore new frontiers of spintronics and quantum science in 2D materials. The PIs are particularly motivated by understanding how the magnetic and spin-dependent properties at the atomic scale lead to interesting and potentially useful phenomena in spintronic devices at the macroscopic scale.

36 MATERIALS SCIENCE↗

Carbon-Based Quantum Information Science with Symmetry Protected Topological States (Final Report, DOE-BES award DE-SC0023105)

This research program established the scientific foundation for the rational, bottom-up design, synthesis, isolation, and investigation of symmetry-protected topological (SPT) electron spin qubits embedded in graphene nanoribbons (GNRs). The work focused on integrating atomically precise low-dimensional carbon nanostructures with emerging quantum logic architectures, providing a pathway toward scalable quantum materials for next-generation computing and sensing technologies. A central component of the program was the elucidation of fundamental relationships between real-space molecular architecture, local spin density distributions, electronic band dispersion, and energy level alignment in atomically precise GNR systems. These correlations define key operational parameters of SPT qubits and were systematically investigated to establish quantitative benchmarks against established molecular and solid-state spin qubit platforms. Attention was given to properties critical for quantum device performance, e.g. decoherence times, spectral sharpness of energy transitions, and tunable exchange interactions between spin states. The research demonstrated that these parameters can be engineered with atomic precision through scalable bottom-up synthetic strategies. Theory-guided design played a central role in identifying candidate structures hosting topologically protected spin states. Experimental validation was performed using both ensemble measurements and single-molecule characterization. In addition to advances in quantum materials synthesis, the program developed and applied spin-sensitive scanning probe microscopy techniques capable of directly probing quantum states and dynamic processes with atomic-scale spatial resolution. These capabilities enabled direct observation and characterization of quantum structures at the single-atom level. While the research activities were primarily hypothesis-driven fundamental investigations, the program adopted a comprehensive materials-by-design framework aimed at translating scientific discoveries into technological concepts compatible with scalable and intelligent manufacturing approaches.

36 MATERIALS SCIENCE↗

Basis light-front quantization approach to nucleon

We obtain the light-front wavefunctions for the nucleon in the valence quark Fock space from an effective Hamiltonian, which includes the transverse and longitudinal confinement and the one gluon exchange interaction with fixed coupling. The wavefunctions are generated by solving the eigenvalue equation in a basis light front quantization. Fitting the model parameters, the wavefunctions lead to good simultaneous description of electromagnetic form factors, radii, and parton distribution functions for the proton.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Effect of Controlled Artificial Disorder on the Magnetic Properties of EuFe 2 (As 1– x P x ) 2 Ferromagnetic Superconductor

Static (DC) and dynamic (AC, at 14 MHz and 8 GHz) magnetic susceptibilities of single crystals of a ferromagnetic superconductor, EuFe 2 ( As 1 – x P x ) 2 ( x = 0.23), were measured in pristine state and after different doses of 2.5 MeV electron or 3.5 MeV proton irradiation. The superconducting transition temperature, T c ( H ) , shows an extraordinarily large decrease. It starts at T c ( H = 0 ) ≈ 24 K in the pristine sample for both AC and DC measurements, but moves to almost half of that value after moderate irradiation dose. Remarkably, after the irradiation not only T c moves significantly below the FM transition, its values differ drastically for measurements at different frequencies, ≈16 K in AC measurements and ≈12 K in a DC regime. We attribute such a large difference in T c to the appearance of the spontaneous internal magnetic field below the FM transition, so that the superconductivity develops directly into the mixed spontaneous vortex-antivortex state where the onset of diamagnetism is known to be frequency-dependent. We also examined the response to the applied DC magnetic fields and studied the annealing of irradiated samples, which almost completely restores the superconducting transition. Overall, our results suggest that in EuFe 2 ( As 1 – x P x ) 2 superconductivity is affected by local-moment ferromagnetism mostly via the spontaneous internal magnetic fields induced by the FM subsystem. Another mechanism is revealed upon irradiation where magnetic defects created in ordered Eu 2 + lattice act as efficient pairbreakers leading to a significant T c reduction upon irradiation compared to other 122 compounds. On the other hand, the exchange interactions seem to be weakly screened by the superconducting phase leading to a modest increase of T m (less than 1 K) after the irradiation drives T c to below T m . Our results suggest that FM and SC phases coexist microscopically in the same volume.

36 MATERIALS SCIENCE↗

Intrinsic and Extrinsic Exciton Recombination Pathways in AgInS 2 Colloidal Nanocrystals

Ternary I-III-VI 2 nanocrystals (NCs), such as AgInS 2 and CuInS 2 , are garnering interest as heavy-metal-free materials for photovoltaics, luminescent solar concentrators, LEDs, and bioimaging. The origin of the emission and absorption properties in this class of NCs is still a subject of debate. Recent theoretical and experimental studies revealed that the characteristic Stokes-shifted and long-lived luminescence of stoichiometric CuInS 2 NCs arises from the detailed structure of the valence band featuring two sublevels with different parity. The same valence band substructure is predicted to occur in AgInS 2 NCs, yet no experimental confirmation is available to date. Here, we use complementary spectroscopic, spectro-electrochemical, and magneto-optical investigations as a function of temperature to investigate the band structure and the excitonic recombination mechanisms in stoichiometric AgInS 2 NCs. Transient transmission measurements reveal the signatures of two subbands with opposite parity, and photoluminescence studies at cryogenic temperatures evidence a dark state emission due to enhanced exchange interaction, consistent with the behavior of stoichiometric CuInS 2 NCs. Lowering the temperature as well as applying reducing electrochemical potentials further suppress electron trapping, which represents the main nonradiative channel for exciton decay, leading to nearly 100% emission efficiency.

36 MATERIALS SCIENCE↗

Increased Ly α Opacity in White Dwarf Photospheres from Transient H − Resonances

The structure and emergent flux of hydrogen atmosphere white dwarfs depend on the opacity of the Lyα and Lyβ spectral lines. The opacity here is set by the strength and broadening of these lines; the latter is dictated by the far line wing, which is in the “quasi-static” limit of electron broadening, placing it in the incomplete collision regime, and describes the transient parts of electron and ion collisions. These transient stages of the collision form resonances: In the case of ions, they manifest as molecular resonances, while for electrons they are H − resonances, both of which can only be captured quantum-mechanically. Quantum-mechanical calculations have historically preserved only a handful of broadening terms that are most important near the center of the line. However, in the wings of the line, the previously neglected terms that describe the transient stages of the collision need to be included. This requirement arises because, in the line wings, the broadening from the 1s ground state, which is generally assumed to be extremely small compared to the broadening of the upper state, is no longer negligible within a quantum-mechanical model that takes into account exchange interactions. The inclusion of all the transient terms results in asymmetries and extra broadening. The increased broadening of Lyα increases the opacity at the energy where most of the flux leaves the star. The broader Lyα lines also impact the visible flux, raising it by an amount that exceeds previously estimated errors.

74 ATOMIC AND MOLECULAR PHYSICS↗

Influence of Electron Doping on Magnetic Order in CeRu 2 Al 10

The effect of electron doping by the substitution of Rh for Ru on unconventional magnetic order in CeRu 2 Al 10 was investigated via neutron powder diffraction. In Ce(Ru 1-x Rh x ) 2 Al 10 with x = 0.05, 0.12, and 0.2, reorientation of the ordered moment from the c- to the a-axis takes place in all samples, while the ordering vector q=(0 1 0) remains unchanged within this concentration range. The moment reorientation is accompanied by an enhancement in its size by a factor of ~2.4, from μ=0.43 μ B at x=0 to μ =1.06, 1.04, and 1.02 μ B for x=0.05, 0.12 and 0.2, respectively. The continuous decrease in N´eel temperature T 0 (T N ), despite an abrupt increase in μ , underlines the strong anisotropy in the exchange interaction in CeRu 2 Al 10 , and the fact that this anisotropy is easily suppressed by electron doping.

36 MATERIALS SCIENCE↗

Locating the magnetospheric ring current

Protons are studied in the global depression of the earth's horizontal magnetic field. It is shown that 10 to 100 keV protons dominate ring current energetics in two preferred regions of cyclotron instability, which serve as stable trapping boundaries for ring current protons. The only apparent means of removing this stably trapped belt of particles are considered to be by charge exchange interactions, or by outward expansion of the plasmapause to erode the ring current. Both of these processes require about two days, which is the characteristic decay period of the main phase depression. Questions whose answers are necessary to formulate a quantitative theory of geomagnetic storms which relates main phase depression to solar wind parameters are included.

Thorne, R. M.↗

Theory of disordered Heisenberg ferromagnets

A Green's function technique is used to calculate the magnetic properties of Heisenberg ferromagnets in which the exchange interactions deviate randomly in strength from the mean interaction. Systems of sc, bcc, and fcc topologies and of general spin values are treated. Disorder produces marked effects in the density of spin wave states, in the form of enhancement of the low-energy density and extension of the energy band to higher values. The spontaneous magnetization and the Curie temperature decrease with increasing disorder. The effects of disorder are shown to be more pronounced in the ferromagnetic than in the paramagnetic phase.

Stubbs, R. M.↗

Low-energy electron scattering from CO

The scattering of electrons from carbon monoxide has been studied in the framework of a previously proposed pseudopotential method. It is found that the single-center expansion of the continuum electron orbital about the center of mass of the molecule is very well converged when the two noncoincident nuclear singularities and the nonlocal exchange interactions are properly taken into account in the scattering equations. An analytical proof has been given to show that unlike the total cross section, the momentum-transfer cross section in the fixed-nuclei approximation is finite even for polar molecules. The calculated results of the momentum-transfer cross section for e(-)-CO scattering in the energy range between 0.1 and 10.0 eV are in good accord with the experimental measurements.

Chandra, N.↗