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At least 937 records · Page 52

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NASA NTRS1985

Effects of tyrosine-26 and tyrosine-64 nitration on the photoreactions of bacteriorhodopsin

The photoreactions of nitrated bacteriorhodopsin (bR) are examined. Flash-induced difference spectra of bR, bR with aminotyrosine in position 26 (bR-N26R) and bR with aminotyrosine in position 64 are analyzed. It is observed that changes in the actinic wavelength (from 520 to 500 or 580 nm) have no affect on the shape of the spectra and the formation and decay kinetics of the O and M intermediates. Nitration of tyrosine-64 decreases the chromophore absorbance, shifts the absorption maximum to 535 nm, and affects photocycle kinetics independent of the pK of its phenolic group. Light-dark adaptation spectra for bR are studied. The kinetics of the M and O intermediates in bR with nitrotyrosine in position 64 (bR-N64) and bR with aminotyrosine in position 64 and bR with nitrotyrosine in position 26 and bR-N26R are described and compared to bR; the pH dependence and M and O decay rates are considered. The deprotonation of bR-N64 during the photoreaction cycle and the effects of nitration on the activity of proton pumping are investigated.

Scherrer, P.↗

NASA NTRS1986

Plasma waves associated with the first AMPTE magnetotail barium release

Plasma waves observed during the March 21, 1985, AMPTE magnetotail barium release are described. Electron plasma oscillations provided local measurements of the plasma density during both the expansion and decay phases. Immediately after the explosion, the electron density reached a peak of about 400,000/cu cm, and then started decreasing approximately as t to the -2.4 as the cloud expanded. About 6 minutes after the explosion, the electron density suddenly began to increase, reached a secondary peak of about 240/cu cm, and then slowly decayed down to the preevent level over a period of about 15 minutes. The density increase is believed to be caused by the collapse of the ion cloud into the diamagnetic cavity created by the initial expansion. The plasma wave intensities observed during the entire event were quite low. In the diamagnetic cavity, electrostatic emissions were observed near the barium ion plasma frequency, and in another band at lower frequencies. A broadband burst of electrostatic noise was also observed at the boundary of the diamagnetic cavity. Except for electron plasma oscillations, no significant wave activity was observed outside of the diamagnetic cavity.

Gurnett, D. A.↗

NASA NTRS1986

Feasibility experiments on time-resolved fluorosensing applied to oil slicks

The introduction of time resolved observations can provide a very penetrating tool in the practice of laser fluorosensing. The investigations have demonstrated a relevance of multispectral, time resolved analysis for oil fingerprinting. By comparative studies on a variety of crude oils and their most significant fractions, it was found that the process of time decay in a composite oil is characterized by a few steps, which are associated with specific components in the medium light range. The average decay times of these pure fractions are markedly differentiated as to absolute values and spectral spread; as a consequence, the corresponding parameters in the resultant crude are quite sensitive to the particular mixture of these components. Measurements of the time response give then a finer discrimination between oil classes, depending on the relative content of certain fractions. Experiments were pursued with an improved fluorosensor facility, in order to test the application of time resolved fluorosensing to remote samples on water.

Camagni, P.↗

NASA NTRS1986

Lidar observations of the decline of the El Chichon stratospheric load

The eruption of the Mexican volcano El Chichon in Apr. 1982 enhanced the stratospheric aerosol load to a level which so far has not been observed by remote sensing techniques. The ruby lidar system at Garmisch-Partenkirchen recorded an increase of about two orders of magnitude above the background level of the years 1977/78. At northern midlatitudes backscattering was peaking in Jan./Feb. 1983, as illustrated. The decline of the El Chichon stratospheric perturbation is discussed. The decay of the El Chichon stratospheric cloud is characterized by an overall 1/e lifetime of about 12 months. The El Chichon decay is further characterized by seasonal variations of the integral backscattering coefficient, which exhibit a winter maximum and a summer minimum. These variations are inversely correlated with the seasonal mean movement of the tropopause height indicating transport processes.

Jaeger, H.↗

NASA NTRS1987

Magnetization of the oceanic crust: TRM or CRM?

A model was proposed in which chemical remanent magnetization (CRM) acquired within the first 20 Ma of crustal evolution may account for 80% of the bulk natural remanent magnetization (NRM) of older basalts. The CRM of the crust is acquired as the original thermoremanent magnetization (TRM) is lost through low temperature alteration. The CRM intensity and direction are controlled by the post-emplacement polarity history. This model explains several independent observations concerning the magnetization of the oceanic crust. The model accounts for amplitude and skewness discrepancies observed in both the intermediate wavelength satellite field and the short wavelength sea surface magnetic anomaly pattern. It also explains the decay of magnetization away from the spreading axis, and the enhanced magnetization of the Cretaceous Quiet Zones while predicting other systematic variations with age in the bulk magnetization of the oceanic crust. The model also explains discrepancies in the anomaly skewness parameter observed for anomalies of Cretaceous age. Further studies indicate varying rates of TRM decay in very young crust which depicts the advance of low temperature alteration through the magnetized layer.

Raymond, C. A.↗

NASA NTRS1987

Two-dimensional nozzle plume characteristics

Future high performance aircraft will likely feature asymmetric or two-dimensional nozzles with or without ejectors. In order to design two-dimensional nozzle/ejector systems of minimum size and weight, the plume decay and spreading characteristics of basic two-dimensional nozzles must first be established. The present work deals with the experimental analyses of these plume characteristics and includes the effects of nozzle aspect ratio and flow conditions (jet Mach number and temperature) on the plume decay and spreading of two-dimensional nozzles. Correlations including these variables are developed in a manner similar to those previously developed successfully for conic and dual-flow plumes.

Vonglahn, Uwe H.↗

NASA NTRS1986

Fast fluctuations of soft X-rays from active regions

A selection of short lived small soft X-ray bursts is studied using data from the Hard X-ray Imaging Spectrometer (HXIS), and the results are compared with the data from the Hard X-Ray Burst Spectrometer (HXRBS) with a view to understanding conditions at the onset of flares. Short-lived events provide an opportunity to study the radiation from the primary energy transfer process without confusion from the slowly-varying thermal X-ray emission which characterizes the decay of a large flare. The fast decay of the soft X-rays, only a few tens of seconds, suggests that they occur in the dense chromosphere. The results indicate that the short events may be signatures of several different phenomena, depending on their characteristics. Some events occur in association with reverse-drift type III bursts and simultaneous flaring elsewhere on the Sun, thus suggesting dumping of particles accelerated at a remote site. Some events have hard X-ray bursts and normal type III bursts associated with them, while others have neither. The latter events place strong constraints on the nonthermal electron population present.

Simnett, G. F.↗

NASA NTRS1987

A prediction model of the depth-of-discharge effect on the cycle life of a storage cell

Cycle life requirements are very high for batteries used in aerospace applications in low Earth orbit. The data base required to establish confidence in a particular cell design is thus both extensive and expensive. Reliable accelerated cycle life testing and performance decay modeling represent attractive alternatives to real-time tests of cycle life. In light of certain long-term cycle life test results, this paper examines a very simple performance decay model developed earlier. Application of that model to available data demonstrates a rigid relationship between a battery's expected cycle life and the depth of discharge of cycling. Further, modeling analysis of the data suggests that a significantly improved cycle life can be obtained with advanced components, materials, and designs; and that cycle life can be reliably predicted from the results of accelerated testing.

Thaller, Lawrence H.↗

NASA NTRS1986

Evolution of lightning flash density and reflectivity structure in a multicell thunderstorm

The radar reflectivity structure and the distribution of lightning in a storm cell was investigated using S-band and UHF-band radar data for six storm cells over Wallops Island. The S-band scans were vertical and continuous, while the UHF data were taken in steps of 2.5 deg elevation. The peak in lightning activity during the study corresponded to a merging of two storm cells. A minimum height of 7 km was found necessary for the appearance of a 40 dBZ core with lightning, which first appears in a multicell thunderstorm at the leading edge of the 50 dBZ core of the cell and between a cell and its decaying neighbor. The lightning moves further into the cell during cell decay and decreases in density. Finally, the lightning is offset horizontally from the precipitation core during cell growth but colocates with the precipitation core as the cell dissipates.

Mazur, V.↗

NASA NTRS1986

A unified N-body and statistical treatment of stellar dynamics. III - Early postcollapse evolution of globular clusters

The period immediately following the core collapse phase in the evolution of a globular cluster is studied using a hybrid N-body/Fokker-Planck stellar dynamical code. Several core oscillations of the type predicted in earlier work are seen. The oscillations are driven by the formation, hardening, and ejection of binaries by three-body processes, and appear to decay on a timescale of about 10 to the 7th yr, for the choice of 'typical' cluster parameters made here. There is no evidence that they are gravothermal in nature. The mechanisms responsible for the decay are discussed in some detail. The distribution of hard binaries produced by the oscillations is compared with theoretical expectations and the longer term evolution of the system is considered.

Mcmillan, S. L. W.↗

NASA NTRS1985

A numerical investigation of the summer 1980 U.S. heat wave

The diagnostic framework being utilized by researchers at NASA-Goddard in a numerical analysis of the draught which occurred in the U.S. in 1980 described, along with preliminary results. Attention is focused on the wave structure at 500 mb and comparisons of this structure with NMC data from 1963-77 to define conditions during the initiation, maintenance and decay of a draught. Attempts are also being made to develop a simple index for the diagnosis of heat patterns using as input data from the 500 mb analysis. Early studies involving the examination of the effects of varying boundary conditions have revealed a positive contribution from the soil moisture fields and a negative contribution from the North Pacific sea surface temperature during the event. Studies are continuing to characterize phenomena during draught initiation and decay.

Wolfson, N.↗

NASA NTRS1986

Rate constant for the reaction SO + BrO yields SO2 + Br

The rate of the radical-radical reaction SO + BrO yields SO2 + Br has been determined at 298 K in a discharge flow system near 1 torr pressure with detection of SO and BrO via collision-free sampling mass spectrometry. The rate constant was determined using two different methods: measuring the decay of SO radicals in the presence of an excess of BrO and measuring the decay of BrO radicals in excess SO. The results from the two methods are in reasonable agreement and the simple mean of the two values gives the recommended rate constant at 298 K, k = (5.7 + or - 2.0) x 10 to the -11th cu cm/s. This represents the first determination of this rate constant and it is consistent with a previously derived lower limit based on SO2 formation. Comparison is made with other radical-radical reactions involving SO or BrO. The reaction SO + BrO yields SO2 + Br is of interest for models of the upper atmosphere of the earth and provides a potential coupling between atmospheric sulfur and bromine chemistry.

Brunning, J.↗

NASA NTRS1986

A polarisation correlation study of the excitation of the H2 d3Piu (v1 = 0, N1 = 1) level by electron impact

Full details are given of an experiment in which the three normalized Stokes' parameters characterizing the decay of the electron impact excited d3Piu (v1 = 0, N1 = 1) rotational level of H2 were determined in an electron-photon coincidence experiment at 25 eV impact energy and over the angular range of 20-60 deg. An analysis shows how these parameters are related to the state multipoles characterizing the excited state. The rather low degree of coherence which was observed is consistent with various depolarizing effects, namely the averaging over magnetic sublevels which occurred in both the excitation and decay channels and also the perturbations due to fine and hyperfine structure relaxations.

Mcconkey, J. W.↗

NASA NTRS1986

Stability of the Io torus

The inherent stability of the coupled neutral-plasma Io torus is investigated. Under the assumptions that the neutrals arise through sputtering by corotating torus ions, and that the ions move radially by centrifugally driven diffusion, it is found that the equilibrium state properties of the Io torus depend on two quantities: the sputtering yield, and Jupiter's ionospheric Pedersen conductance. For fixed values of these quantities, the torus equilibrium state is stable. When the torus neutral and ion densities deviate from the equilibrium state, the perturbations decay without oscillating, with a decay time near 1 day for the neutrals and near 60 days for the ions. The growths of the neutrals and ions from seed populations are computed. The torus evolves directly to its equilibrium state.

Huang, T. S.↗

NASA NTRS1986

Evidence for nonlinear wave-wave interactions in solar type III radio bursts

Evidence is presented that nonlinear wave-wave interactions occur in type III solar radio bursts. Intense, spiky Langmuir waves are observed to be driven by electron beams associated with type III solar radio bursts in the interplanetary medium. Bursts of 30-300 Hz (in the spacecraft frame) waves are often observed coincident in time with the most intense spikes of the Langmuir waves. These low-frequency waves appear to be long-wavelength ion acoustic waves, with wavenumber approximately equal to the beam resonant Langmuir wavenumber. Three possible interpretations of these observations are considered: modulational instability, parametric decay of the parent Langmuir waves to daughter ion acoustic and Langmuir waves, and decay to daughter electromagnetic waves and ion acoustic waves.

Lin, R. P.↗

NASA NTRS1986

Nonradiative relaxation in tunable solid state laser crystals

The characteristics of nonradiative transitions between the 4T2 and 2E excited states of trivalent-chromium-ion-activated ruby (containing 0.04 percent Cr2O3 by weight) and alexandrite (containing 0.4 at. percent chromium ion) laser crystals were studied using the technique described by Gayen et al. (1985). In this technique, a 527-nm pulse excites the 4T2 band of the Cr(3+), and the subsequent population kinetics among excited states is monitored by an IR picosecond probe pulse as a function of pump-probe delay. In ruby, a resolution-limited sharp rise in the excited state population was followed by a long-lifetime decay, leading to an upper limit of 7 ps for the 4T2-state nonradiative lifetime. In alexandrite, a longer rise time was followed by a multicomponent decay. A theoretical model is proposed for explaining the induced absorption and the transition dynamics observed in these crystals.

Gayen, S. K.↗

NASA NTRS1987

Turbulence as a contributor to intermediate energy storage during solar flares

Turbulence is considered as a method for converting the energy observed as mass motions during the impulsive phase into thermal energy observed during the gradual phase of solar flares. The kinetic energy of the large-scale eddies driven by the upflowing material continuously cascades to smaller scale eddies until viscosity is able to convert it into thermal energy. The general properties of steady state, homogeneous, fluid turbulence is a nonmagnetic plasma and the properties of turbulent decay are reviewed. The time-dependent behavior of the velocities and energies observed by the X-Ray Polychromator (XRP) instrument on the SMM during the November 5, 1980 flare are compared with the properties of turbulence. This study indicates that turbulence may play a role in flare energies and may account for a fraction of the total amount of thermal energy observed during the gradual phase. The rate at which the observed flare velocities decrease is consistent with the decay of turbulent energy but may be too rapid to account for the entire time delay between the impulsive and gradual phases.

Bornmann, P. L.↗

NASA NTRS1987

High-energy processes in solar flares

A detailed study of high-energy processes in solar flares is reported, including the production of neutrons and pions, and incorporating isobaric and scaling models and a recent compilation of pion production data (Dermer, 1986). The broad-band gamma-ray spectrum resulting from the decay of neutral pions, the bremsstrahlung of positrons and electrons from the decay of charged pions, and the annihilation in flight of positrons is evaluated. Also evaluated is the 0.511 MeV gamma-ray line resulting from the annihilation of the positrons which survive annihilation in flight. Calculations were based on an isotropic, thick-target model using the best available nuclear data and models. Results are compared with extensive observation of the June 3, 1982 flare (10-120 MeV gamma rays), 0.511 and 2.2 MeV line emission, nuclear line emission, high-energy neutrons, and interplanetary charged particles.

Murphy, R. J.↗