Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Construction”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 937 records · Page 52
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Construction of MoS 2 /NiS 2 heterostructure with fast interfacial reaction kinetics for ultrafast sodium storage

Constructing heterostructure is a valid method to reinforcing sodium storage performance of transition metal chalcogenides materials. Herein, a simple, safe and controllable one step hydrothermal method is proposed to synthesize MoS 2 /NiS 2 heterostructure. Due to the difference in band gaps and work functions of MoS 2 and NiS 2 , the charges are redistributed at the MoS 2 /NiS 2 heterointerfaces, thereby accelerating the migration of electrons and Na + . The heterointerfaces provide extra active sites for storing Na + , thus increasing the sodium storage capacity of the heterostructure. Furthermore, the distinct redox potentials of NiS 2 and MoS 2 promote the structural stability of MoS 2 /NiS 2 heterostructure during the electrochemical reaction processes. Consequently, the obtained MoS 2 /NiS 2 heterostructure exhibits superior rate properties (339.4 mAh g –1 at 10 A g –1 ) and ultra-stable cycling stability (480.5 mAh g –1 after 350 cycles at 1 A g –1 ). Finally, this paper presents a valid strategy for creating heterostructure anodes with excellent sodium storage properties.

25 ENERGY STORAGE↗
DOE OSTI2017

Design and construction of a high-energy photon polarimeter

Here, we report on the design and construction of a high-energy photon polarimeter for measuring the degree of polarization of a linearly-polarized photon beam. The photon polarimeter uses the process of pair production on an atomic electron (triplet production). The azimuthal distribution of scattered atomic electrons following triplet production yields information regarding the degree of linear polarization of the incident photon beam. Furthermore, the polarimeter, operated in conjunction with a pair spectrometer, uses a silicon strip detector to measure the recoil electron distribution resulting from triplet photoproduction in a beryllium target foil. The analyzing power Σ A for the device using a 75 μm beryllium converter foil is about 0.2, with a relative systematic uncertainty in Σ A of 1.5%.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2017

The ALICE Transition Radiation Detector: Construction, operation, and performance

The Transition Radiation Detector (TRD) was designed and built to enhance the capabilities of the ALICE detector at the Large Hadron Collider (LHC). While aimed at providing electron identification and triggering, the TRD also contributes significantly to the track reconstruction and calibration in the central barrel of ALICE. In this article, the design, construction, operation, and performance of this detector are discussed. A pion rejection factor of up to 410 is achieved at a momentum of 1 GeV/c in p-Pb collisions and the resolution at high transverse momentum improves by about 40% when including the TRD information in track reconstruction. The triggering capability is demonstrated both for jet, light nuclei, and electron selection.

43 PARTICLE ACCELERATORS↗
DOE OSTI2018

Construction and response of a highly granular scintillator-based electromagnetic calorimeter

Here, a highly granular electromagnetic calorimeter with scintillator strip readout is being developed for future linear collider experiments. A prototype of 21.5 X 0 depth and 180 × 180 mm 2 transverse dimensions was constructed, consisting of 2160 individually read out 10 × 45 × 3 mm 3 scintillator strips. This prototype was tested using electrons of 2–32 Ge V at the Fermilab Test Beam Facility in 2009. Deviations from linear energy response were less than 1.1%, and the intrinsic energy resolution was determined to be ( 12 . 5 ± 0 . 1 ( stat. ) ± 0 . 4 ( syst. ) ) % / E [ Ge V ] ⊕ ( 1 . 2 ± 0 . 1 ( stat. ) - 0 . 7 + 0 . 6 ( syst. ) ) % , where the uncertainties correspond to statistical and systematic sources, respectively.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Construction and performance of the barrel electromagnetic calorimeter for the Gluex experiment

The barrel calorimeter is part of the new spectrometer installed in Hall D at Jefferson Lab for the GlueX experiment. The calorimeter was installed in 2013, commissioned in 2014 and has been operating routinely since early 2015. The detector configuration, associated Monte Carlo simulations, calibration and operational performance are described in this paper. The calorimeter records the time and energy deposited by charged and neutral particles created by a multi-GeV photon beam. It is constructed as a lead and scintillating-fiber calorimeter and read out with 3840 large-area silicon photomultiplier arrays. Particles impinge on the detector over a wide range of angles, from normal incidence at 90 degrees down to 11.5 degrees, which defines a geometry that is fairly unique among calorimeters. The response of the calorimeter has been measured during a running experiment and performs as expected for electromagnetic showers below 2.5 GeV. Finally, we characterize the performance of the BCAL using the energy resolution integrated over typical angular distributions for π 0 and η production of σ E / E = 5 . 2 % / E ( GeV ) ⊕ 3 . 6 % and a timing resolution of σ = 150 ps at 1 GeV.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

The design and construction of the Chips water Cherenkov neutrino detector

Chips (CHerenkov detectors In mine PitS) was a prototype large-scale water Cherenkov detector located in northern Minnesota. The main aim of the R&D project was to demonstrate that construction costs of neutrino oscillation detectors could be reduced by at least an order of magnitude compared to other equivalent experiments. This article presents design features of the Chips detector along with details of the implementation and deployment of the prototype. While issues during and after the deployment of the detector prevented data taking, a number of key concepts and designs were successfully demonstrated.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

A simple procedure for construction of the orthonormal basis vectors of irreducible representations of O(5) in the O T ( 3 ) Ⓧ O N ( 2 ) basis

We report a simple and effective algebraic isospin projection procedure for constructing orthonormal basis vectors of irreducible representations of O(5) ⊃ OT(3) Ⓧ O$_\mathscr{N}$ (2) from those in the canonical O(5) ⊃ SU Λ (2) Ⓧ SU I (2) basis is outlined. The expansion coefficients are components of null space vectors of the projection matrix with four nonzero elements in each row in general. Explicit formulae for evaluating O T (3)-reduced matrix elements of O(5) generators are derived.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

A call to standardize metrics for monitoring baleen whales near marine construction activities

Effective monitoring is necessary to protect marine mammal species during the construction of offshore infrastructure. The tools for detecting or monitoring marine mammals span traditional (e.g., visual observers, optical cameras), to newer (e.g., passive acoustic monitoring, infrared cameras, tags), and emerging (e.g., satellite imagery, environmental DNA, dimethyl sulfide concentration) technologies. Some are better suited for use during offshore development; however, peer-reviewed literature does not typically evaluate and report on the performance of these various technologies. We define a minimum set of metrics related to efficacy (i.e., confusion matrix, precision and recall, probability of missed mitigation), detection range (i.e., maximum and reliable detection range, spatial resolution), and data delivery (i.e., detection latency, system reliability, temporal resolution) that we recommend are needed to assess the utility of monitoring technologies for this purpose. Following a literature review of relevant studies, we highlight which publications reported these metrics and used multiple technologies to compare relative performance. We also emphasize the benefits of multi-modal approaches and recommend performance assessments through modeling or large-scale collaborative field testing. These metrics will standardize data collection, reporting, and analysis; promote consistent and comparable results; and foster collaboration among developers, regulatory agencies, and scientists. This may lead to the co-development of technology that achieves multiple goals, has greater application, and can answer research questions while collecting data to fulfill permitting requirements. These metrics may also inform decisions on what systems regulatory agencies might consider using and reduce monitoring costs, which is critical to support the marine sector's rapid growth alongside marine mammal conservation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Constructing a spatiotemporally coherent long-term PM2.5 concentration dataset over China during 1980–2019 using a machine learning approach

The lack of long-term observations and satellite retrievals of health-damaging fine particulate matter in China has demanded the estimates of historical PM 2.5 (particulate matter less than 2.5 µm in diameter) concentrations. This study constructs a gridded near-surface PM 2.5 concentration dataset across China covering 1980–2019 using the space-time random forest model with atmospheric visibility observations and other auxiliary data. The modeled daily PM2.5 concentrations are in excellent agreement with ground measurements during 2015–2019, with a coefficient of determination of 0.95 and mean relative error of 12%. Besides the atmospheric visibility which explains 30% of total importance of variables in the model, both emissions and meteorological conditions are also essential factors affecting PM2.5 predictions. From 1980 to 2014, the model-predicted PM2.5 concentrations increased constantly with the maximum growth rate of 5–10 µg/m3/decade over eastern China. Due to the clean air actions, PM 2.5 concentrations have decreased effectively at a rate over 50 µg/m 3 /decade in the North China Plain and 20–50 µg/m 3 /decade over eastern China during 2014–2019. The newly generated dataset of 1-degree gridded PM 2.5 concentrations for the past 40 years across China provides a useful means for investigating interannual and decadal environmental and climate impacts related to aerosols.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Removal, distribution and retention of metals in a constructed wetland over 20 years

The A-01 wetland treatment system (WTS) was designed to remove metals (primarily copper) from the effluent at the A-01 National Pollution Discharge Elimination System (NPDES) outfall at the Savannah River Site, Aiken, SC. This research investigated metal removal, distribution and retention in the A-01 WTS over a period of 20 years. The findings are important for ensuring continued metal sequestration in the A-01 WTSs over time, providing management guidance for constructed wetlands, and investigating changes in metal remediation effectiveness as a wetland ages. During 20 years of operation, systematic water and sediment sampling validated the wetlands' performance. After passage through the treatment cells, Cu concentrations were well below permit limits during all years of operation, often falling below 10 μg L -1 . Cu removal has been consistent over time, averaging about 80% despite large changes in influent Cu concentrations. Most divalent metals were rapidly removed from the water and held in the sediments shortly after the water entered the treatment wetland. Average removal of Pb from water by the wetland system was 67 and 74% in 2004 and 2020, respectively. Comparable values for Zn were 52 and 65%, respectively. Generally, the highest concentrations of Cu, Pb, and Zn were found in the sediment from the first cell in each pair of cells suggesting that most of the Cu, Pb, and Zn in the A-01 effluent was bound to the sediment quickly. Diffusive gradients in thin films (DGT) measurements of Cu and Zn in the sediments were much lower than bulk sediment concentrations. These results suggest that most of the Cu and Zn in the A-01 WTS sediments was not bioavailable, hence not toxic to aquatic organisms, as a likely consequence of adsorption to sediment particles and complexation with organic and inorganic substances.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Vacuum system design, construction, and operation for the Cornell High Energy Synchrotron Source upgrade

During the summer and fall 2018, the Cornell High Energy Synchrotron Source (CHESS), underwent an upgrade that recast the facility as primarily a low emittance X-ray source. The upgrade replaced one sixth of the Cornell Electron Storage Ring (CESR) with six double-bend achromats, featuring four novel CHESS Compact Undulator (CCU) insertion devices, and switched CESR to single particle beam operation. At the time of this writing, the upgraded storage ring has achieved the CHESS-U design goal of operating with 200 mA of positron current at 6.0 GeV beam energy. Additionally, seven out of eleven CHESS-U beamlines are currently in X-ray user operation. The construction and the commissioning of the new section of the CESR accelerator required novel solutions to design, fabrication, and vacuum system operations. Significant design considerations and efforts were made to minimize X-ray ‘dark-time’, returning to operation less than 1 year. This paper describes the important milestones of the process, the solutions implemented, and the present status of CHESS-U.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Chromosomal integration of complex DNA constructs using CRAGE and CRAGE-Duet systems

Our recent development of the CRAGE (chassis-independent recombinase-assisted genome engineering) system enables single-step integration of large, complex DNA constructs directly into bacteria genomes across multiple phyla. This protocol describes the details of the experimental design and procedures of CRAGE and extended CRAGE-Duet systems. It also describes a strategy that combines CRISPR with CRAGE, which allows implementation of CRISPR-Cas9, CRISPRa, and CRISPRi in diverse bacteria, overcoming major limitations to broaden the application of CRISPR in non-model bacterial genome engineering. For complete details on the use and execution of this protocol, please refer to Wang et al. (2019), Wang et al. (2020), and Liu et al. (2020).

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Construction of extracellular matrix-based 3D hydrogel and its effects on cardiomyocytes

Highlights: • SOD and Triton X-100 could efficiently decellularize cells to get cardiac ECM. • Main proteins of cECM were fibronectin, collagen, elastin, fibrillin, laminin, etc. • 75% cECM-containing 3D hydrogel promoted cell proliferation and anti-apoptosis. • cECM3DH facilitated the differentiation of ESCs into CMs. • APcECM3DH was more conducive to NCM and ESC-derived CM maturation. Some discoveries resulted from 2-dimensional (2D) cultured cardiac cells have been disqualified in animal testing and later clinical trials. Extracellular matrix (ECM) plays a vital role in cardiac homeostasis, cardiac ECM (cECM)-based 3D cell cultures can mimics the physiological and pathological conditions in vivo closely, it is hopeful of addressing this challenge. Construction of cECM-based 3-dimensional (3D) hydrogel (cECM3DH) and its effects on cell behaviors were studied here. The results indicated that cellular compartments could be efficiently removed from heart tissue via sodium dodecyl sulfonate (SDS)- and Triton X-100-mediated decellularization, remaining the natural fibrous network structure and major proteins. 3D hydrogel consisted of 1 × 10{sup 7} cells/mL cells and 75% cECM could promote the proliferation and anti-apoptosis ability of human embryonic kidney (HEK)-293T cells. 0.25% trypsin or 0.20% collagenase was suitable to retrieve these cells from 3D hydrogel for further researches. Compared with 2D culture system, cECM3DH could significantly increase the proportion of GATA 4{sup +} cardiomyocytes (CMs) derived from heart tissue of neonatal mouse or induced differentiation of embryonic stem cells (ESCs) (P < 0.05) The expression levels of mature genes including cTnT, JCN, CaV1.2, MYL2, CASQ2, NCX1, and Cx43 of these CMs in adult pig cECM-based 3D hydrogel (APcECM3DH) were significantly higher than that in 2D culture system and in newborn piglet cECM-based 3D hydrogel (NPcECM3DH), respectively (P < 0.05). Therefore, cECM3DH supports the generation of primary CMs and ESC-derived CMs, APcECM3DH was more conducive to promoting CM maturation, which contributes to building 3D model for pathogenesis exploration, drug screening, and regenerative medicine of heart diseases.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Direct construction of optimized stellarator shapes. Part 1. Theory in cylindrical coordinates

The confinement of the guiding-centre trajectories in a stellarator is determined by the variation of the magnetic field strength $B$ in Boozer coordinates $(r,\unicode[STIX]{x1D703},\unicode[STIX]{x1D711})$ , but $B(r,\unicode[STIX]{x1D703},\unicode[STIX]{x1D711})$ depends on the flux surface shape in a complicated way. Here we derive equations relating $B(r,\unicode[STIX]{x1D703},\unicode[STIX]{x1D711})$ in Boozer coordinates and the rotational transform to the shape of flux surfaces in cylindrical coordinates, using an expansion in distance from the magnetic axis. A related expansion was done by Garren and Boozer ( Phys. Fluids B, vol. 3, 1991 a , 2805) based on the Frenet–Serret frame, which can be discontinuous anywhere the magnetic axis is straight, a situation that occurs in the interesting case of omnigenity with poloidally closed $B$ contours. Our calculation in contrast does not use the Frenet–Serret frame. The transformation between the Garren–Boozer approach and cylindrical coordinates is derived, and the two approaches are shown to be equivalent if the axis curvature does not vanish. The expressions derived here help enable optimized plasma shapes to be constructed that can be provided as input to VMEC and other stellarator codes, or to generate initial configurations for conventional stellarator optimization.

Physics↗
DOE OSTI2019

Constructing stellarators with quasisymmetry to high order

Here, a method is given to rapidly compute quasisymmetric stellarator magnetic fields for plasma confinement, without the need to call a three-dimensional magnetohydrodynamic equilibrium code inside an optimization iteration. The method is based on direct solution of the equations of magnetohydrodynamic equilibrium and quasisymmetry using Garren & Boozer’s expansion about the magnetic axis ( Phys Fluids B, vol. 3, 1991, p. 2805), and it is several orders of magnitude faster than the conventional optimization approach. The work here extends the method of Landreman et al. ( J. Plasma Phys. , vol. 85, 2019, 905850103), which was limited to flux surfaces with elliptical cross-section, to higher order in the aspect-ratio expansion. As a result, configurations can be generated with strong shaping that achieve quasisymmetry to high accuracy. Using this construction, we give the first numerical demonstrations of Garren and Boozer’s ideal scaling of quasisymmetry breaking with the cube of the inverse aspect ratio. We also demonstrate a strongly non-axisymmetric configuration (vacuum rotational transform $\unicode[STIX]{x1D704} >0.4$ ) in which symmetry-breaking mode amplitudes throughout a finite volume are ${<}2\times 10^{-7}$ , the smallest ever reported. To generate boundary shapes of finite-minor-radius configurations, a careful analysis is given of the effect of substituting a finite minor radius into the near-axis expansion. In conclusion, the approach here can provide analytic insight into the space of possible quasisymmetric stellarator configurations, and it can be used to generate good initial conditions for conventional stellarator optimization.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Constructing Self-Labeled Materials Imaging Datasets from Open Access Scientific Journals with EXSCLAIM!

Due to recent improvements in image resolution and acquisition speeds, materials microscopy is experiencing an explosion in imaging data. Yet, despite the volume of images generated, the overall accessibility landscape is highly fragmented, as researchers who do release images to the public, often only do so as snapshots of their larger private dataset in context of scientific journal publications. The effort to automatically consolidate images and descriptive information from web-based platforms has garnered broad attention from the computer vision, language technologies, and chemistry/materials informatics communities. However, these methods are problematic for scientific figures because over 30% of figures are compound in nature, and it is the individual images themselves, paired with relevant context, that are necessary for construction a proper labeled dataset. To this end, we outline in this paper the design of a software pipeline for the automatic EXtraction, Separation, and Caption-based natural Language Annotation of IMages from scientific figures (EXSCLAIM!). Successful consolidation of materials imaging across literature sources will enhance navigation and searchability of materials microscopy images for both novice and experienced researchers, as well as establish the framework necessary for users to search by images, text, or some combination of both.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Covalent Triazine Framework-Derived Membranes: Engineered Sol–Gel Construction and Gas Separation Application

Covalent triazine frameworks (CTFs) represent one of the most extensively studied organic networks characterized by graphitic π-conjugated structures linked by aza-fused rings, possessing unique features such as compositions of light elements (e.g., C, H, and N), porous architectures abundant heteroatom involvement, and extensively conjugated structures. In addition, the textural and chemical structures of CTFs could be engineered via synthesis control to accommodate diverse applications. CTF materials with notable characteristics, including plentiful (ultra-)micropores, high surface areas, and the presence of CO 2 -philic functional groups involving nitrogen (N), oxygen (O), and fluorine (F), hold great promise as potential candidates for anthropogenic CO 2 capture and sequestration (CCS) applications. However, the conventional high-temperature involved ionothermal procedures and the solution-based coupling pathway only afforded CTF materials in powder form, which is difficult to be processed toward membrane formation. Successful fabrication of CTF-derived membranes will rely on the development of alternative polymerization approaches as well as structural engineering to afford membrane architectures with controllable porosity distribution and active interaction sites with CO 2 benefiting the CO 2 separation procedure. In this Account, a demonstration of the latest progress in the development of CTF-derived membranes was provided. The CTF membranes were mainly synthesized via a superacid (e.g., CF 3 SO 3 H)-promoted sol–gel approach involving the polymerization of aromatic nitrile monomers. The formation of the triazine unit through the trimerization of cyano groups served as the cross-linkers, resulting in the creation of π-conjugated networks alongside the arenes present in the starting materials. The aromatic nitrile monomers with rigid and sterically hindered structures were required to afford CTF membranes with nanoporous architectures. The acidity of the superacid and reactivity of the aromatic monomers played critical roles in the polymerization efficiency. The monomer diversity and synthesis tunability endowed the introduction of CO 2 -philic functionalities (e.g., pyrazole and fluorine) within the CTF skeletons, and integration of ionic moieties was achieved by adopting FSO 3 H with stronger acidity as the catalyst and aromatic nitrile monomers with pyrazine structures. To ensure the successful construction of fluorinated CTF membranes, it is important to avoid any fluorines on the ortho-position of the cyano groups on the benzene ring. Through control over the monomers and reaction conditions, flexible, transparent, and insoluble CTF membranes could be fabricated. The sol–gel method could be further expanded to membrane fabrication through acetyl-to-benzene transformation through synthesis control. The mild oxidation-exfoliation-filtration method was also demonstrated to fabricate substrate-supported CTF membranes. The as-afforded membranes are well characterized to determine the structural features and provide information to study the structure-performance relationship. Here, the application of CTF membranes in CO 2 separation was summarized, focusing on the approaches being developed to enhance CO 2 uptake and separation performance. In addition to utilizing the pristine CTF membranes for gas separation, functionalized carbon molecular sieve membranes could be obtained from the pyrolysis of thermally stable CTF membrane precursors toward efficient CO 2 separation, benefiting from the abundant ultramicropores being created during the pyrolysis/decomposition procedure and involvement of CO 2 -philic functionalities such as fluorine and nitrogen-containing moieties. Based on these achievements, unsolved issues in CTF membrane-related fabrication and applications, including the potential solution approaches, have been proposed to advance the application of CTF membranes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Soft Materials Constructed Using Calix[4]pyrrole- and “Texas-Sized” Box-Based Anion Receptors

We present that soft materials have received considerable attention from supramolecular chemists and material scientists alike. This interest reflects the advantages provided by their soft, flexible nature and the convenience of the molecular self-assembly that underlies their preparation. Common soft supramolecular materials include polymeric gels, supramolecular polymers, nanoaggregates, and membranes. Polymeric gels are solidlike networks of cross-linked polymer chains. Supramolecular polymers contain repeat units connected through reversible non-covalent bonds. Nanoaggregates are formed as a result of hydrophobic interactions involving amphiphilic building blocks. Because of the presence of non-covalent interactions, supramolecular soft materials typically display stimuli-responsive or adaptive features. Various macrocyclic hosts, such as cyclodextrins, crown ethers, calixarenes, cucurbiturils, and pillararenes, and many classic non-covalent interactions have been harnessed to construct supramolecular soft materials. Only recently has anion binding been used as the underlying recognition motif. Anions are ubiquitous in the natural world. Their importance has inspired efforts to achieve good anion binding and to exploit anion recognition in a number of fields, including extraction, transport, sensing, and catalysis. Most of this effort has involved the use of stand-alone anion receptors. On the other hand, soft materials with anion recognition features could lead to new macromolecular systems of interest in the context of many application areas. In this Account, we summarize the latest efforts from our laboratory to prepare supramolecular soft materials, including polymeric gels, supramolecular polymers, and nanoaggregates, with bona fide anion recognition features. Two anion receptor systems, namely, calix[4]pyrroles (C4Ps) and a tetraimidazolium macrocycle known as the “Texas-sized” molecular box (TxSB), have been used for this purpose. To date, TxSB-based hydrogels have been utilized to capture anions from water and for coded information applications; C4P-based organic polymeric gels have been used to extract dianions from aqueous source phases and for the on-site detection of chloride anions. Polymers containing C4P and TxSB anion recognition subunits typically display responsive features and can be modified through application of appropriately chosen external stimuli. For instance, nanoaggregates may be formed as a result of the hydrophobic interactions of C4P- and TxSB-based amphiphiles. The resulting aggregates were found to mimic the structural evolution of organelles and could be used as effective anion and ion pair extractants. This Account summarizes progress to date while underscoring potential opportunities associated with combining anion recognition and soft materials chemistry. Finally, the hope is to stimulate further advances in broad areas, including polymer science, supramolecular chemistry, biology, materials research, and information storage.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗