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At least 937 records · Page 52

Thermal reactive ion etching technique involving use of self-heated cathode

In this work, the thermal reactive ion etching (TRIE) technique for etching hard-to-etch materials is presented. The TRIE technique employs a self-heated cathode and a thermally insulated aluminum plate is placed on the cathode of a regular reactive ion etching (RIE) system. By optimizing the beam size to support the sample stage, the temperature of the stage can be increased to a desired temperature without a cathode heater. The technique was used to etch a bulk titanium plate. An etch rate of 0.6 μm/min and an etch selectivity to nickel of 100 were achieved with SF{sub 6} plasma. The proposed technique makes a regular RIE system a more powerful etcher without the use of chlorine gas, a cathode heater, and an inductively coupled plasma source.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Electronic structure of the polymer-cathode interface of an organic electroluminescent device investigated using operando hard x-ray photoelectron spectroscopy

The electronic structure of a polymer-cathode interface of an operating organic light-emitting diode (OLED) was directly investigated using hard X-ray photoelectron spectroscopy (HAXPES). The potential distribution profile of the light-emitting copolymer layer as a function of the depth under the Al/Ba cathode layer in the OLED depended on the bias voltage. We found that band bending occurred in the copolymer of 9,9-dioctylfluorene (50%) and N-(4-(2-butyl)-phenyl)diphenylamine (F8-PFB) layer near the cathode at 0 V bias, while a linear potential distribution formed in the F8-PFB when a bias voltage was applied to the OLED. Direct observation of the built-in potential and that band bending formed in the F8-PFB layer in the operating OLED suggested that charges moved in the F8-PFB layer before electron injection from the cathode.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Operating modes of a hydrogen ion source based on a hollow-cathode pulsed Penning discharge

An ion source based on a hollow-cathode Penning discharge was switched to a high-current pulsed mode (tens of amperes and tens of microseconds) to produce an intense hydrogen ion beam. With molecular hydrogen (H{sub 2}), the ion beam contained three species: H{sup +}, H{sub 2}{sup +}, and H{sub 3}{sup +}. For all experimental conditions, the fraction of H{sub 2}{sup +} ions in the beam was about 10 ÷ 15% of the total ion beam current and varied little with ion source parameters. At the same time, the ratio of H{sup +} and H{sub 3}{sup +} depended strongly on the discharge current, particularly on its distribution in the gap between the hollow and planar cathodes. Increasing the discharge current increased the H{sup +} fraction in ion beam. The maximum fraction of H{sup +} reached 80% of the total ion beam current. Forced redistribution of the discharge current in the cathode gap for increasing the hollow cathode current could greatly increase the H{sub 3}{sup +} fraction in the beam. At optimum parameters, the fraction of H{sub 3}{sup +} ions reached 60% of the total ion beam current.

43 PARTICLE ACCELERATORS↗

Particle-in-cell based parameter study of 12-cavity, 12-cathode rising-sun relativistic magnetrons for improved performance

Particle-in-cell simulations are performed to analyze the efficiency, output power and leakage currents in a 12-Cavity, 12-Cathode rising-sun magnetron with diffraction output (MDO). The central goal is to conduct a parameter study of a rising-sun magnetron that comprehensively incorporates performance enhancing features such as transparent cathodes, axial extraction, the use of endcaps, and cathode extensions. Our optimum results demonstrate peak output power of about 2.1 GW, with efficiencies of ∼70% and low leakage currents at a magnetic field of 0.45 Tesla, a 400 kV bias with a single endcap, for a range of cathode extensions between 3 and 6 centimeters.

36 MATERIALS SCIENCE↗

Transparent ITO/Ag-Pd-Cu/ITO multilayer cathode use in inverted organic solar cells

The characteristics of transparent ITO/Ag-Pd-Cu (APC)/ITO multilayer cathodes were investigated for use in inverted organic solar cells (IOSCs). The insertion of an APC interlayer into the ITO film effectively led to crystallization of the top ITO layer, unlike that in the Ag interlayer, and resulted in a low sheet resistance of 6.55 Ohm/square and a high optical transmittance of 84.14% without post annealing. In addition, the alloying of the Pd and Cu elements into Ag prevented agglomeration and oxidization of the metal interlayer and led to more stable ITO/APC/ITO films under ambient conditions. The microstructure and interfacial structure of the transparent ITO/APC/ITO cathode in the IOSCs were examined in detail by synchrotron X-ray scattering and high resolution transmission electron microscopy. Furthermore, we suggested a possible mechanism to explain the lower PCE of the IOSCs with an ITO/APC/ITO cathode than that of a reference IOSC with a crystalline ITO cathode using the external quantum efficiency of the IOSCs.

36 MATERIALS SCIENCE↗

Magnetically insulated coaxial vacuum diode with partial space-charge-limited explosive emission from edge-type cathode

The vacuum current associated with any type of electron emission for arbitrary configuration of the diode depends on the combination of the applied electric field and vacuum space charge (VSC) field created by the current. Such fundamental statement should give very close links between the diode current and the normalized cathode field θ which has been introduced by Forbes in 2008 for planar diodes as a reduction in the cathode surface field: θ = field-with/field-without VSC. This article reports the universal approximation of the type of cos(πθ/2) that is the ratio of the actual current and the fully space-charge-limited current. Also, the theoretical treatment and the experimental method of determination of the dynamic emissive characteristics of the macroscopic explosive emission from edge-type cathodes in the coaxial diode are developed. The experimental results obtained with a picosecond time reference between the cathode voltage and the onset of the high-current electron beam exhibit a good coincidence with the theoretical predictions. The presented methods enable the analysis of a real-time-resolved dynamics associated with the dense, magnetized electron beam formation, acceleration and drift motion, including kinematic effects and the phase-stable excitation of high-power microwave oscillators.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Barium depletion in hollow cathode emitters

Dispenser hollow cathodes rely on a consumable supply of Ba released by BaO-CaO-Al{sub 2}O{sub 3} source material in the pores of a tungsten matrix to maintain a low work function surface. The examination of cathode emitters from long duration tests shows deposits of tungsten at the downstream end that appear to block the flow of Ba from the interior. In addition, a numerical model of Ba transport in the cathode plasma indicates that the Ba partial pressure in the insert may exceed the equilibrium vapor pressure of the dominant Ba-producing reaction, and it was postulated previously that this would suppress Ba loss in the upstream part of the emitter. New measurements of the Ba depletion depth from a cathode insert operated for 8200 h reveal that Ba loss is confined to a narrow region near the downstream end, confirming this hypothesis. The Ba transport model was modified to predict the depletion depth with time. A comparison of the calculated and measured depletion depths gives excellent qualitative agreement, and quantitative agreement was obtained assuming an insert temperature 70 °C lower than measured beginning-of-life values.

36 MATERIALS SCIENCE↗

Efficient polymer light-emitting diode with air-stable aluminum cathode

The fast degradation of polymer light-emitting diodes (PLEDs) in ambient conditions is primarily due to the oxidation of highly reactive metals, such as barium or calcium, which are used as cathode materials. Here, we report the fabrication of PLEDs using an air-stable partially oxidized aluminum (AlO{sub x}) cathode. Usually, the high work function of aluminum (4.2 eV) imposes a high barrier for injecting electrons into the lowest unoccupied molecular orbital (LUMO) of the emissive polymer (2.9 eV below the vacuum level). By partially oxidizing aluminum, its work function is decreased, but not sufficiently low for efficient electron injection. Efficient injection is obtained by inserting an electron transport layer of poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3] thiadiazol-4,8-diyl)] (F8BT), which has its LUMO at 3.3 eV below vacuum, between the AlO{sub x} cathode and the emissive polymer. The intermediate F8BT layer not only serves as a hole-blocking layer but also provides an energetic staircase for electron injection from AlO{sub x} into the emissive layer. PLEDs with an AlO{sub x} cathode and F8BT interlayer exhibit a doubling of the efficiency as compared to conventional Ba/Al PLEDs, and still operate even after being kept in ambient atmosphere for one month without encapsulation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Repetitive operation of an L-band magnetically insulated transmission line oscillator with metal array cathode

We present the repetitive operation research results of an L-band magnetically insulated transmission line oscillator with metal array cathode (MAC-MILO) in this paper. To ensure a more uniform emission of electrons emitted from the cathode, metal plates with different outer radii and thicknesses are periodically arranged in longitudinal direction on the cathode substrate to act as emitters. The higher order mode depressed MILO (HDMILO) structure is applied to ensure stability of the tube. Comparison experiments are carried out between velvet cathode and MAC MILO driven by a 20 GW/40 Ω/40 ns/20 Hz pulse power system. Experimental results reveal that the MAC has much lower outgassing rate, much longer life time, and higher repetitive stability. The MAC-MILO could work stably with a rep-rate up to 20 Hz at a power level of 550 MW when employing a 350 kV/35 kA electric pulse. The TE{sub 11} mode radiation pattern in the farfield region reveals the tube works steadily on the dominant mode. More than 2000 shots have been tested in repetitive mode without any obvious degradation of the detected microwave parameters.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Verification of high efficient broad beam cold cathode ion source

An improved form of cold cathode ion source has been designed and constructed. It consists of stainless steel hollow cylinder anode and stainless steel cathode disc, which are separated by a Teflon flange. The electrical discharge and output characteristics have been measured at different pressures using argon, nitrogen, and oxygen gases. The ion exit aperture shape and optimum distance between ion collector plate and cathode disc are studied. The stable discharge current and maximum output ion beam current have been obtained using grid exit aperture. It was found that the optimum distance between ion collector plate and ion exit aperture is equal to 6.25 cm. The cold cathode ion source is used to deposit aluminum coating layer on AZ31 magnesium alloy using argon ion beam current which equals 600 μA. Scanning electron microscope and X-ray diffraction techniques used for characterizing samples before and after aluminum deposition.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Vacuum arc cathode spot motion in oblique magnetic fields: An interpretation of the Robson experiment

A model was developed of vacuum arc cathode spot motion in a magnetic field that obliquely intercepts the cathode surface. The model takes into account a force under an electric field caused by retrograde spot motion across the normal component of the magnetic field, producing a drift velocity component in the direction of the acute angle between the magnetic field and the cathode surface. The relationship between velocity of the retrograde direction and drift velocity of the cathode spot motion to the acute angle was developed. The dependencies of the drift angle θ on the acute angle φ, magnetic field strength B, and arc current I were calculated. It was found that the calculated θ increased with φ, B, and I in accordance with Robson's measurements.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Electrical and thermal characteristics of LaB6 thermionic hollow cathodes operating in He, D2, Ar, and Xe at 4–200 Pa and 0.25–5 A cm−2

We report characteristics of lanthanum hexaboride (LaB6) cathodes for conditions relevant to a high-voltage, high-current switching device. LaB6 is selected because of its relatively low work function, stability in the presence of many common gas impurities, and a low evaporation rate (long life) at operating temperatures. We have investigated the effect of cathode geometry, gas type, pressure, and current on a LaB6 hollow cathode in a diode configuration with an opposing planar anode. The gas is stagnant at a relatively low pressure of 4–200 Pa (0.03–1.5 Torr) because of device high-voltage standoff requirements. In all cases, the plasma voltage decreases to a plateau value with increasing current where a practical device would operate. The plateau voltage aligns with the fill gas excitation or ionization voltage, depending on conditions. At high current, the cathode temperature exceeds that required for thermionic emission to supply the total current, a behavior that is understood by accounting for back-diffusing bulk electrons.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Correlation between microstructure and thermionic electron emission from Os-Ru thin films on dispenser cathodes

Osmium-ruthenium films with different microstructures were deposited onto dispenser cathodes and subjected to 1000 h of close-spaced diode testing. Tailored microstructures were achieved by applying substrate biasing during deposition, and these were evaluated with scanning electron microscopy, x-ray diffraction, and energy dispersive x-ray spectroscopy before and after close-spaced diode testing. Knee temperatures determined from the close-spaced diode test data were used to evaluate cathode performance. Cathodes with a large (10-11) Os-Ru film texture possessed comparatively low knee temperatures. Furthermore, a low knee temperature correlated with a low effective work function as calculated from the close-spaced diode data. It is proposed that the formation of strong (10-11) texture is responsible for the superior performance of the cathode with a multilayered Os-Ru coating.

36 MATERIALS SCIENCE↗

Activity and Stability of (Pr 1-x Nd x ) 2 NiO 4 as Cathodes for Solid Oxide Fuel Cells: II. Electrochemical Performance and Performance Durability

Single phase (Pr 1-x Nd x ) 2 NiO 4 cathode powders (x = 0, 0.25, 0.50, 0.75, and 1.0) were synthesized via a glycine-nitrate combustion and high temperature calcination. Anode supported cells were used to investigate the cathode property. A reproducible performance, within 9% for each cathode composition, was observed providing a wealth of data for quantitative studies. Area specific resistance analysis and i-V measurements between 650 and 850°C showed a decrease in the cell performance with increasing Nd content. Impedance spectrum analysis suggests that the decline in performance results from an increase in electrode polarization. While Pr 2 NiO 4 cells showed significant performance degradation of 6.40%/1,000 hours, the degradation rate for (Pr 0.75 Nd 0.25 ) 2 NiO 4 cells was reduced by an order of magnitude (0.56%/1,000 hours) with a 7% lower power output. Furthermore, the cathodes with a higher Nd content showed further improvement in performance stability with a marginal degradation rate of 0.06%/1,000 hours.

25 ENERGY STORAGE↗

A High-Performance Sodium-Ion Full Cell with a Layered Oxide Cathode and a Phosphorous-Based Composite Anode

A low-cost sodium-ion full cell with a O3-type layered Na[Cu 0.2 (Fe 1/3 Mn2/3) 0.8 ]O 2 cathode and an alloy-type P-TiP2-C anode is presented. The cathode is synthesized by an oxalate coprecipitation method and optimized cathodes shows a high specific capacity of 135 mAh g -1 at 0.1C rate with a high rate capability of 90 mAh g-1 at 1C rate and 70 mAh g -1 at 2C rate with good cyclability. The full cell exhibits better capacity retention than the half cell with the cathode due to the elimination of the degradation caused by sodium-metal anode. The dramatically enhanced electrochemical performance of the Na[Cu 0.2 (Fe 1/3 Mn 2/3 ) 0.8 ]O 2 / P-TiP 2 -C full cell compared to that of the sample with no Cu is attributed to the structural stabilization imparted by Cu by suppressing the phase change from the O3 structure to the P3 structure during cycling.

25 ENERGY STORAGE↗

A Finite Length Cylinder Model for Mixed Oxide-Ion and Electron Conducting Cathodes Suited for Intermediate-Temperature Solid Oxide Fuel Cells

A physics-based model is presented to simulate the electrochemical behavior of mixed ion and electron conducting (MIEC) cathodes for intermediate-temperature solid oxide fuel cells. Analytic solutions for both transient and impedance models based on a finite length cylinder are derived. These solutions are compared to their infinite length counterparts. The impedance solution is also compared to experimental electrochemical impedance spectroscopy data obtained from both a traditional well-established La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF) cathode and a new SrCo 0.9 Nb 0.1 O 3-δ (SCN) porous cathode. Lastly, the impedance simulations agree well with the experimental values, demonstrating that the new models can be used to extract electro-kinetic parameters of MIEC SOFC cathodes.

25 ENERGY STORAGE↗

Direct Recycling of End-of-Life Cathode Material Through Redox Chemistry Mediators

Lithium-ion batteries (LIBs) are ideal for electric vehicles and electronic devices because of their high-power density and outstanding cycle life. The need for recycled LIBs material is pivotal for the sustainability of the renewable energy industry. The recycling process needs to be both economically and environmentally conscious. Direct recycling is cheaper and generates the least amount of waste compared to pyrometallurgical and hydrometallurgical processes. Direct recycling explored in this work is useful for reclaiming precious minerals from the End-of-Life (EOL) LIBs material. The EOL material has varying lithium deficiency, hence, redox mediator relithiation restores the lithium content rapidly and at low cost. The redox mechanism relithiate EOL cathode material by shuttling charges very fast between lithium metal and EOL cathode material. The redox mediator is oxidized to create lithium rich solvent and reduced to relithiate EOL cathode material. However, the process is sensitive to pH changes. The redox reaction creates acidic solvent, which may cause lithium leaching. Therefore, use of lithium hydroxide (LiOH) to remove impurities on the surface of the EOL material and as a lithium source creates a basic solution to prevent lithium leaching and relithiate EOL material. This approach will potentially pave way for fast quality cathode material recovery at a low cost.

cathode material↗

Scalable and Cost-Effective Barrier Layer Coating to Improve Stability and Performance of SOFC Cathode

During this project, a dense GDC barrier layer was deposited on YSZ substrate to prevent chemical reaction between LSCF and YSZ by a cost-effective EPD method. PPy was used as the agent to make YSZ conductive. Highly compact GDC green layer was obtained by the EPD process in an ethanol-based suspension. The deposition rate on PPy coated YSZ is slower than that on graphite because the charge transfer process is the rate-determining step. The main resistance is from the ion accumulation/depletion zone. The H + ions reduced at the cathode consist of free H + ions and absorbed H + ions corresponding to the unavoidable electrochemical reaction and deposition, respectively. A factor f was introduced to reflects EPD efficiency and describe the competitive relationship between deposition and electrochemical reaction during EPD process. f is in the range from 0 to 0.5 which is determined by the amount ration between free H + ions and absorbed H + ions at the suspension/deposit interface and the conductivity of the cathode. f decreases with the increase of current density or applied voltage and the conductivity of the cathode. GDC thin layers formed by DC-EPD in a thickness range of 5-8 µm were successfully densified at as low as 1300 °C and the adhesion between GDC and YSZ was good. The densification temperature can be further reduced to 1250 °C when AC-EPD was used to replace DC-EPD. The deposition rate increases with the increase of duty cycle and voltage ratio. The deposition rate increases with the increase of frequency from 10 Hz to 500 Hz, while decrease when the frequency increases from 500 Hz to 5000 Hz. Desorption of absorbed charge carrier is easy and irreversible. The deposition rate is independent on the conductivity of the cathode when the electrochemical reaction can be ignored with a high frequency. Inter-diffusion of cation ions between the electrolyte and barrier layer has been systematically characterized via 3-D atom probe, TEM, and other techniques. No measurable Sr transport occurs across the GDC layer with a thickness of 1.5 – 6 μm at a LSCF processing temperature of 1000 °C. However, Sr transport does occur across GDC layer with a thickness of 1.5 or 3 μm at a higher LSCF sintering temperature (1000 °C or 1200 °C). The primary pathway are open pores or grain boundaries in the GDC. The observed zirconate layer is discontinuous even for the most extreme conditions (1.5 μm GDC, 1200 °C LSCF sintering temperature). Increasing the thickness of GDC to 4.5 μm can effectively suppress any zirconate formation measurable by SEM-EDX. Cobalt is observed at grain boundaries within the GDC, suggesting some depletion of Co from the LSCF layer that may ultimately impact electrode performance.

08 HYDROGEN↗