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At least 937 records · Page 52

Blends of an ethynyl terminated imidothioether with ethynyl terminated arylene ether oligomers

An evaluation has been undertaken of blends of a novel ethynyl-terminated imidothioether with Udel P1700 polysulfone and ethynyl-terminated arylene ether oligomers. Good to excellent processability was obtained with these blends using compression molding; the cured blends displayed poor-to-good resistance to chloroform and low-to-moderately high fracture toughness, depending on the blends' crosslink density. The flexural strength and modulus of unidirectional carbon graphite laminates prepared with the blended resins were good.

Connell, J. W.↗

Polyenamines from aromatic diacetylenic diketones and diamines

The synthesis and characterization of several ployenamine ketones are discussed wherein conjugated diacetylenic diketones and aromatic diamines are used as a route to the formation of high molecular weight polyenamine ketones which exhibit good mechanical properties and can be cast into creasible films. Typical polymerization conditions involved the reaction of stoichiometric amounts of 1,4- or 1,3-PPPO and a diamine at 60°-130° C. in m-cresol at (w/w) solids content of 8-26% for a specified period of time under a nitrogen atmosphere. Novel polyenamine ketones were prepared with inherent viscosities as high as 1.99 dl/g and tough, clear amber films with tensile strengths of 12,400 psi and tensile moduli of 397,000 psi were cast from solutions of the polymers in chloroform. The polymers exhibited T g s as high as 235° C. and weight losses of 14% after aging at 232° C. in circulating air for sixty hours. The specific conditions for the preparation of the various polyenamine ketones are presented in Table I. In most cases, the elemental analyses for the polyenamine ketones, shown in Table II, agree within ±0.3% of the theoretical values.

Paul M Hergenrother↗

Paradigmatic error calculations for adaptive finite element approximations of convection dominated flows

New error estimation techniques are described for two-dimensional convection-dominated flows. Examples of applications to linear convection problems are given. The methods are based on discontinuous finite-element techniques. Results show that conventional interpolation methods may lead to gross underestimates of actual error and be inadequate for use in adaptive methods.

Oden, J. T.↗

Ethynyl-Terminated Imidothioethers And Derived Resins

New toughened epoxies exhibit excellent properties, but temperatures at which used limited. Bismaleimide resins some of base materials being formulated to develop materials used at moderate temperatures. Work conducted on use of acetylenic (ethynyl) group to cross-link and extend chains of oligomers and polymers to obtain materials that perform at high temperatures. Work extended to ethynyl-terminated imidothioethers (ETI's). Tested primarily as adhesives and composite matrices and found to have useful properties in terms of processing, resistance to high temperature, fracture toughness, and resistance to solvents. Also have desirable mechanical properties. Potentially useful for aerospace and nonaerospace applications.

Hergenrother, Paul M.↗

Second order tensor finite element

The results of a research and software development effort are presented for the finite element modeling of the static and dynamic behavior of anisotropic materials, with emphasis on single crystal alloys. Various versions of two dimensional and three dimensional hybrid finite elements were implemented and compared with displacement-based elements. Both static and dynamic cases are considered. The hybrid elements developed in the project were incorporated into the SPAR finite element code. In an extension of the first phase of the project, optimization of experimental tests for anisotropic materials was addressed. In particular, the problem of calculating material properties from tensile tests and of calculating stresses from strain measurements were considered. For both cases, numerical procedures and software for the optimization of strain gauge and material axes orientation were developed.

Oden, J. Tinsley↗

Mission design applications of QUICK

An overview of an interactive software environment for space mission design termed QUICK is presented. This stand-alone program provides a programmable FORTRAN-like calculator interface to a wide range of both built-in and user defined functions. QUICK has evolved into a general-purpose software environment that can be intrinsically and dynamically customized for a wide range of mission design applications. Specific applications are described for some space programs, e.g., the earth-Venus-Mars mission, the Cassini mission to Saturn, the Mars Observer, the Galileo Project, and the Magellan Spacecraft.

Skinner, David L.↗

Crystalline Imide/Arylene Ether Copolymers

Series of imide/arylene ether block copolymers prepared by using arylene ether blocks to impart low melt viscosity, and imide blocks to provide high strength and other desirable mechanical properties. Work represents extension of LAR-14159 on imide/arylene ether copolymers in form of films, moldings, adhesives, and composite matrices. Copolymers potentially useful in variety of high-temperature aerospace and microelectronic applications.

Jensen, Brian J.↗

Imide/Arylene Ether Copolymers

New imide/arylene ether copolymers prepared by reacting anhydride-terminated poly(amic acids) with amine-terminated poly(arylene ethers) in polar aprotic solvents. Each resulting copolymer may have one glass-transition temperature or two, depending on chemical structure and/or compatibility of block units. Most of copolymers form tough, solvent-resistant films with high tensile properties. Films cast from solution tough and flexible, and exhibit useful thermal and mechanical properties. Potentially useful as moldings, adhesives, or composite matrices. Because of flexible arylene ether blocks, these copolymers easier to process than polyimides.

Jensen, Brian J.↗

Scattering of sound by atmospheric turbulence predictions in a refractive shadow zone

According to ray theory, regions exist in an upward refracting atmosphere where no sound should be present. Experiments show, however, that appreciable sound levels penetrate these so-called shadow zones. Two mechanisms contribute to sound in the shadow zone: diffraction and turbulent scattering of sound. Diffractive effects can be pronounced at lower frequencies but are small at high frequencies. In the short wavelength limit, then, scattering due to turbulence should be the predominant mechanism involved in producing the sound levels measured in shadow zones. No existing analytical method includes turbulence effects in the prediction of sound pressure levels in upward refractive shadow zones. In order to obtain quantitative average sound pressure level predictions, a numerical simulation of the effect of atmospheric turbulence on sound propagation is performed. The simulation is based on scattering from randomly distributed scattering centers ('turbules'). Sound pressure levels are computed for many realizations of a turbulent atmosphere. Predictions from the numerical simulation are compared with existing theories and experimental data.

Mcbride, Walton E.↗

Effects of large-scale wind driven turbulence on sound propagation

Acoustic measurements made in the atmosphere have shown significant fluctuations in amplitude and phase resulting from the interaction with time varying meteorological conditions. The observed variations appear to have short term and long term (1 to 5 minutes) variations at least in the phase of the acoustic signal. One possible way to account for this long term variation is the use of a large scale wind driven turbulence model. From a Fourier analysis of the phase variations, the outer scales for the large scale turbulence is 200 meters and greater, which corresponds to turbulence in the energy-containing subrange. The large scale turbulence is assumed to be elongated longitudinal vortex pairs roughly aligned with the mean wind. Due to the size of the vortex pair compared to the scale of the present experiment, the effect of the vortex pair on the acoustic field can be modeled as the sound speed of the atmosphere varying with time. The model provides results with the same trends and variations in phase observed experimentally.

Noble, John M.↗

Synthesis of imide/arylene ether copolymers for adhesives and composite matrices

A series of imide/arylene ether copolymers were prepared from the reaction of an amorphous arylene ether oligomer and a semi-crystalline imide oligomer. These copolymers were thermally characterized and mechanical properties were measured. One block copolymer was endcapped and the molecular weight was controlled to provide a material that displayed good compression moldability and attractive adhesion and composite properties.

Jensen, B. J.↗

Imide/arylene ether block copolymers

Two series of imide/arylene either block copolymers were prepared using an arylene ether block and either an amorphous or semi-crystalline imide block. The resulting copolymers were characterized and selected physical and mechanical properties were determined. These results, as well as comparisons to the homopolymer properties, are discussed.

Jensen, B. J.↗

Spillover, nonlinearity, and flexible structures

Many systems whose evolution in time is governed by Partial Differential Equations (PDEs) are linearized around a known equilibrium before Computer Aided Control Engineering (CACE) is considered. In this case, there are infinitely many independent vibrational modes, and it is intuitively evident on physical grounds that infinitely many actuators would be needed in order to control all modes. A more precise, general formulation of this grave difficulty (spillover problem) is due to A.V. Balakrishnan. A possible route to circumvention of this difficulty lies in leaving the PDE in its original nonlinear form, and adding the essentially finite dimensional control action prior to linearization. One possibly applicable technique is the Liapunov Schmidt rigorous reduction of singular infinite dimensional implicit function problems to finite dimensional implicit function problems. Omitting details of Banach space rigor, the formalities of this approach are given.

Bass, Robert W.↗

Ethynyl terminated imidothioethers and resins therefrom

Ethynyl terminated imidothioethers (ETIs) are prepared by the reaction of a dimercaptan, such as 4,4'-dimercaptodiphenyl ether, and an ethynyl containing maleimide, such as N-(3-ethynylphenyl)maleimide. Blends of these ETIs and ethynyl terminated polymeric materials, such as ethynyl terminated sulfones and ethynyl terminated arylene ethers, are also prepared. These resin blends exhibit excellent processability, and the cured blends show excellent fracture toughness and solvent resistance, as well as excellent adhesive and composite properties.

Hergenrother, Paul M.↗

Comparison of shock wave rise time prediction techniques

Two techniques for predicting sonic-boom rise times are described, and the values of the rise time (defined as the time required for the shock front to go from 10 percent to 90 percent of the maximum overpressure) predicted when using the two approaches are compared. The results are applied to the prediction of the rise time from two hypothetical supersonic transport aircraft. In both cases, the rise time predicted at the ground was much greater than that predicted for a conventional SST.

Raspet, Richard↗

Validation of a flight simulation model of the AH-64 Apache attack helicopter against flight test data

The FLYRT simulation model of the U.S. Army/McDonnell Douglas AH-64 Apache attack helicopter is validated against flight test data. The approach used for validation involves matching static trim attitudes and control positions and driving the model with measured control time histories to compare dynamic responses such as angular rates and normal acceleration. Flight test data is processed to determine kinematic consistency in the angular degrees of freedom. Modeling problems associated with aerodynamic interaction of the main rotor wake on the horizontal stabilator and engine response timing are identified. Appropriate model updates are made which result in good overall model correlation throughout the flight regime investigated.

Harding, J. W.↗