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At least 937 records · Page 52

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NASA NTRS1984

Test bed ion engine development

A test bed ion (TBI) engine was developed to serve as a tool in exploring the limits of electrostatic ion thruster performance. A description of three key ion engine components, the decoupled extraction and amplified current (DE-AC) accelerator system, field enhanced refractory metal (FERM) hollow cathode and divergent line cusp (DLC) discharge chamber, whose designs and operating philosophies differ markedly from conventional thruster technology is given. Significant program achievements were: (1) high current density DE-AC accelerator system operation at low electric field stress with indicated feasibility of a 60 mA/sq cm argon ion beam; (2) reliable FERM cathode start up times of 1 to 2 secs. and demonstrated 35 ampere emission levels; (3) DLC discharge chamber plasma potentials negative of anode potential; and (4) identification of an efficient high plasma density engine operating mode. Using the performance projections of this program and reasonable estimates of other parameter values, a 1.0 Newton thrust ion engine is identified as a realizable technology goal. Calculations show that such an engine, comparable in beam area to a J series 30 cm thruster, could, operating on Xe or Hg, have thruster efficiencies as high as 0.76 and 0.78 respectively, with a 100 eV/ion discharge loss.

Aston, G.↗

NASA NTRS1983

Cathode degradation and erosion in high pressure arc discharges

The various processes which control cathode erosion and degradation were identified and evaluated. A direct current arc discharge was established between electrodes in a pressure-controlled gas flow environment. The cathode holder was designed for easy testing of various cathode materials. The anode was a water cooled copper collector electrode. The arc was powered by a dc power supply with current and voltage regulated cross-over control. Nitrogen and argon were used as propellants and the materials used were two percent thoriated tungsten, barium oxide impregnated porous tungsten, pure tungsten and lanthanum hexaboride. The configurations used were cylindrical solid rods, wire bundles supported by hollow molybdenum tubes, cylindrical hollow tubes, and hollow cathodes of the type used in ion thrusters. The results of the mass loss tests in nitrogen indicated that pure tungsten eroded at a rate more than 10 times faster than the rates of the impregnated tungsten materials. It was found that oxygen impurities of less than 0.5 percent in the nitrogen increased the mass loss rate by a factor of 4 over high purity nitrogen. At power levels less than 1 kW, cathode size and current level did not significantly affect the mass loss rate. The hollow cathode was found to be operable in argon and in nitrogen only at pressures below 400 and 200 torr, respectively.

Hardy, T. L.↗

NASA NTRS1984

Status of Understanding for Gear Materials

Today's gear designer has a large selection of possible gear materials to choose from. The choice of which material to use should be based on the requirements of the application and will include the operating conditions of load, speed, and temperature in addition to reliability, weight, noise limitation, accuracy, and cost. The plastic materials are generally low in cost with low strength capabilities and are suitable for many light-duty applications. Die-cast alloy and sintered powder-metal gears are also fairly inexpensive and will operate at higher loads and temperatures than plastic gears. The three types of cast iron offer a medium-strength gear at a cost that varies with the accuracy of machining requirements. Gears can be manufactured from several aluminum alloys for lightweight and medium cost and may be anodized for improved load capacity. The copper alloys, bronze and brass, are more costly but have good sliding and wear properties that are useful for worm gear applications. The hot-forged powder-metal gears have the advantage of medium cost with good accuracy and high strength. Several low- to medium alloy steels are available for gear design and most can be heat treated for added strength. The medium-alloy gear materials offer high strength when case hardened and will satisfy most high-load medium-temperature applications. For more severe load, speed, and temperature requirements the advanced high temperature alloys must be used. These include EX-53, CBS 600, Vasco X-2, Super Nitralloy (5Ni-2Al), and forged AISI M-50. As the requirements become more stringent, the cost will also increase. It is necessary that the gear designer have a working knowledge of the various gear materials in order to match the most economical material with the design requirements.

Dennis P Townsend↗

NASA NTRS1984

An extreme ultraviolet spectrometer experiment for the Shuttle Get Away Special Program

An extreme ultraviolet (EUV) spectrometer experiment operated successfully during the STS-7 mission in an experiment to measure the global and diurnal variation of the EUV airglow. The spectrometer is an F 3.5 Wadsworth mount with mechanical collimator, a 75 x 75 mm grating, and a bare microchannel plate detector providing a spectral resolution of 7 X FWHM. Read-out of the signal is through discrete channels or resistive anode techniques. The experiment includes a microcomputer, 20 Mbit tape recorder, and a 28V, 40 Ahr silver-zinc battery. It is the first GAS payload to use an opening door. The spectrometer's 0.1 x 4.2 deg field of view is pointed vertically out of the shuttle bay. During the STS-7 flight data were acquired continuously for a period of 5 hours and 37 minutes, providing spectra of the 570 A to 850 A wavelength region of the airglow. Five diurnal cycles of the 584 A emission of neutral helium and the 834 A emission of ionized atomic oxygen were recorded. The experiment also recorded ion events and pressure pulses associated with thruster firings. The experiment is to fly again on Mission 41-F.

Conway, R. R.↗

NASA NTRS1983

Ion sputter textured graphite electrode plates

A specially textured surface of pyrolytic graphite exhibits extremely low yields of secondary electrons and reduced numbers of reflected primary electrons after impingement of high energy primary electrons. Electrode plates of this material are used in multistage depressed collectors. An ion flux having an energy between 500 iV and 1000 iV and a current density between 1.0 mA/sq cm and 6.0 mA/sq cm produces surface roughening or texturing which is in the form of needles or spires. Such textured surfaces are especially useful as anode collector plates in high tube devices.

Curren, A. N.↗

NASA NTRS1984

A High-speed Characterization Technique for Solar Silicon

High-speed crystal growth techniques demand high-speed characterization techniques to allow a timely feed-back of information to the crystal growers. The unique properties of the Si electrolyte-contact (SEC) provide for an extremely fast and simple measurement of the light-induced photo-current for any piece of Si without lengthy preparation of the specimen. Electropolishing at high anodic current densities allows for insitu generation of fresh surfaces whereas preferential etching of defects in various modes is possible at low current densities. In n-type Si a simple estimation of the minority-carrier diffusion length is possible in many cases. Laser-scanning enables local probing of the photocurrent and provides data about the homogeneity of a sample. The experimental realization of the method is described in detail and examples are given and discussed.

Lehmann, V.↗

NASA NTRS1984

Energy Conversion and Utilization Technologies Program (ECUT) electrocatalysis research

The general field of electrocatalysis, from both the technical and business standpoints is accessed and research areas and approaches most likely to lead to substantial energy/cost savings are identified. The overall approach was to compile and evaluate available information, relying heavily on inputs/recommendations of research managers and technical personnel in responsible positions in industry and at universities. Some promising approaches identified to date include the use of transition metal compounds as electrocatalysts and the use of the new electrochemical photocapacitance spectroscopy (EPS) technique for electrocatalyst characterization/development. For the first time, an oxygen electrocatalyst based on the K2NiF4 structure was synthesized, investigated and compared with a perovskite analog. Results show that this class of materials, based on Ni(3+), forms very efficient and stable O2 anodes in basic solution and suggest that other structure-types be examined in this regard. The very difficult problem of dinitrogen and carbon dioxide electroreductions is addressed through the use of biological model systems which can mimic the enzyme processes in nature.

Warren, L. F.↗

NASA NTRS1984

Shunt Diode Designs in Li/cf Shuttle Batteries

Although Li/CF cells and batteries have an excellent safety record, they are included with other battery systems that require additional safety precautions. One precaution suggested is the inclusion of shunt diodes into these batteries. The benefits of this addition are examined. All cells tested at elevated temperatures vent regardless of length of time between being fully discharged and reversed or inclusion of the diode in the system. Cells discharged at ambient temperatures all show a relatively quick reversal, but stabilize at voltages that are high enough that the diodes are not functioning. Cells tested at depressed temperatures reverse the deepest of all cells tested, with the deepest reversal occurring very early in the test and voltages recovering to above -0.60 volts near the end of the tests. Anode limited cells will eliminate the venting during hot reversal.

Miller, D.↗

NASA NTRS1983

Image plane detector for the dynamics explorer Fabry-Perot interferometer

A compact twelve-channel photon-counting device based on existing Generation II imaging technology has been developed for use as the image-plane detector of the Dynamics Explorer Fabry-Perot interferometer. The device has an S-20 photocathode, three-microchannel plate electron multiplication stages, and an equal-area concentric-ring segmented anode whose geometry mimics that of the interference ring pattern produced by a plane etalon. The twelve channels sample equal and contiguous intervals in the spectrum. The purpose of the delopment has been to utilize the signal multiplex advantage of a multichannel detector in the measurement of Doppler shifts and line-broadening effects for naturally occurring atmospheric emission features of low intensity. The design, testing, calibration, and flight performance of the novel detector system are presented. In addition, measured emission line profiles at high resolution from the satellite instrument are presented to illustrate the operation of the device.

Killeen, T. L.↗

NASA NTRS1983

A basic design fault in ceramic flat packs

Drotman, B.↗

NASA NTRS1983

A basic design fault in ceramic flat packs

Recent moisture resistance tests of various multilayer top brazed ceramic flat packs and leaded and unleaded chip carriers has revealed a serious design defect. These packages, which utilize a tungsten interconnect system, in the presence of high humidity, suffer a galvanic corrosion which anodically consumes the tungsten. This process can continue until the package suffers an open circuit. The test results indicate that the lead plating system does not adequately seal off the interface area where the tungsten stripe egresses from the inside of the package. Leaded and leadless chip carrier packages were also subjected to the moisture resistance test. The familiar red and green corrosion products were visible after the test was completed. Careful sectioning of the chip carriers has revealed that the tungsten interconnect stripe instead of exiting under the castellations, exits at the top of the castellation and is thus vulnerable to the attack of moisture. These basic design faults severely impact the reliability of these packages.

Drotman, B.↗

NASA NTRS1984

Efficient AlGaAs shallow-homojunction solar cells

Shallow-homojunction n+/p/p+ solar cells with one-sun, AM1 conversion efficiencies as high as 12.9 percent have been fabricated in Al0.2Ga0.8As epitaxial layers grown by organometallic chemical vapor deposition on single-crystal GaAs substrates. For these cells, which have n+ layers thinned by anodic oxidation to about 500 A, the quantum efficiencies in the short-wavelength portion of the spectrum are as high as the best reported for AlGaAs cells with high band-gap window layers.

Gale, R. P.↗

NASA NTRS1984

A mathematical model for the iron/chromium redox battery

A mathematical model has been developed to describe the isothermal operation of a single anode-separator-cathode unit cell in a redox-flow battery and has been applied to the NASA iron/chromium system. The model, based on porous electrode theory, incorporates redox kinetics, mass transfer, and ohmic effects as well as the parasitic hydrogen reaction which occurs in the chromium electrode. A numerical parameter study was carried out to predict cell performance to aid in the rational design, scale-up, and operation of the flow battery. The calculations demonstrate: (1) an optimum electrode thickness and electrolyte flow rate exist; (2) the amount of hydrogen evolved and, hence, cycle faradaic efficiency, can be affected by cell geometry, flow rate, and charging procedure; (3) countercurrent flow results in enhanced cell performance over cocurrent flow; and (4) elevated temperature operation enhances cell performance.

Fedkiw, P. S.↗

NASA NTRS1983

Single cell performance studies on the FE/CR Redox Energy Storage System using mixed reactant solutions at elevated temperature

Experimental studies in a 14.5 sq cm single cell system using mixed reactant solutions at 65 C are described. Systems were tested under isothermal conditions, i.e., reactants and the cell were at the same temperature. Charging and discharging performance were evaluated by measuring watt-hour and coulombic efficiencies, voltage-current relationships, hydrogen evolution and membrane resistivity. Watt-hour efficiencies ranged from 86 percent at 43 ma/sq cm to 75 percent at 129 ma/sq cm with corresponding coulombic efficiencies of 92 percent and 97 percent, respectively. Hydrogen evolution was less than 1 percent of the charge coulumbic capacity during charge-discharge cycling. Bismuth amd bismuth-lead catalyzed chromium electrodes maintained reversible performance and low hydrogen evolution under normal and adverse cycling conditions. Reblending of the anode and cathode solutions was successfully demonstrated to compensate for osmotic volume changes. Improved performance was obtained with mixed reactant systems in comparison to the unmixed reactant systems. Previously announced in STAR as N83-25042

Gahn, R. F.↗

NASA NTRS1984

Atmospheric emissions photometric imaging experiment

The atmospheric emissions photometric imaging experiment was flown on Spacelab 1 to study faint natural and artificial atmospheric emission phenomena. The instrument imaged optical emission in the region 2000 to 7500 angstroms with a television system consisting of two optical channels, one wide-angle and one telephoto. A third optical channel imaged onto the photocathode of a microchannel plate photomultiplier tube that has 100 discrete anodes. A hand-held image intensifier camera with an objective grating permitted spectral analysis of the earth's airglow and the Shuttle glow. Preliminary data show magnesium ion emission features in the lower ionosphere as well as the spacecraft glow spectrum.

Mende, S. B.↗

NASA NTRS1985

Methanol Fuel Cell

In proposed fuel-cell system, methanol converted to hydrogen in two places. External fuel processor converts only part of methanol. Remaining methanol converted in fuel cell itself, in reaction at anode. As result, size of fuel processor reduced, system efficiency increased, and cost lowered.

Voecks, G. E.↗

NASA NTRS1986

Accelerating Corrosion in Solar-Cell Tests

In simple electrochemical cell, two silicon solar cells serve as anode and cathode, respectively. Electrolytic medium and voltage between them accelerate corrosion and migration interactions between cell metal contacts and plastic encapsulant. Degradation of metal contacts becomes evident in few hours. Although developed specifically for cells with Ti/Pd/Ag contacts, technique readily adapted to other metal combinations.

Shalaby, H. M.↗

NASA NTRS1984

Experiments with phase transitions at very high pressure

A diamond anvil cell is described which was developed for studying hydrogen and other materials to pressure above 100 PGa, including measurements at low temperature. The benefits of X-ray diffraction using synchrotron radiation and using a fixed anode source are examined as well as the optimization of X-ray diffraction at low temperature. A Ge diode detector was incorporated into apparatus for measuring optical absorption, reflectance, and fluorescence in order to enable luminescence studies and Raman spectra were obtained. Results of experiments on Si, Ge, GaP, InAs, hydrogen, benzene, nitrogen, graphite, and the superconductor CeCu2Si2 are given.

Spain, I. L.↗