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At least 937 records · Page 52

Annual Site Environmental Report, Department of Energy Operations at the Energy Technology Engineering Center – Area IV, Santa Susana Field Laboratory

This Annual Site Environmental Report (ASER) for 2014 describes the environmental conditions related to work performed for the DOE at Area IV of the Santa Susana Field Laboratory (SSFL). The ETEC, a government-owned, company-operated test facility, was located in Area IV. The operations in Area IV included development, fabrication, operation and disassembly of nuclear reactors, reactor fuel, and other radioactive materials. Other activities in the area involved the operation of large-scale liquid metal facilities that were used for testing non-nuclear liquid metal fast breeder reactor components. All nuclear work was terminated in 1988, and all subsequent radiological work has been directed toward environmental restoration and decontamination and decommissioning (D&D) of the former nuclear facilities and their associated sites. Liquid metal research and development ended in 2002. Since May 2007, the D&D operations in Area IV have been suspended by the DOE, but the environmental monitoring and characterization programs have continued. Results of the radiological monitoring program continue to indicate that there are no significant releases of radioactive material from Area IV of SSFL. All potential exposure pathways are sampled and/or monitored, including air, soil, surface water, groundwater, direct radiation, transfer of property (land, structures, waste), and recycling.

Frazee, Brad↗

Site Environmental Report For Calendar Year 2012. DOE Operations at The Boeing Company Santa Susana Field Laboratory, Area IV

This Annual Site Environmental Report (ASER) for 2012 describes the environmental conditions related to work performed for the Department of Energy (DOE) at Area IV of Boeing’s Santa Susana Field Laboratory (SSFL). The Energy Technology Engineering Center (ETEC), a government-owned, company-operated test facility, was located in Area IV. The operations in Area IV included development, fabrication, operation and disassembly of nuclear reactors, reactor fuel, and other radioactive materials. Other activities in the area involved the operation of large-scale liquid metal facilities that were used for testing non-nuclear liquid metal fast breeder reactor components. All nuclear work was terminated in 1988, and all subsequent radiological work has been directed toward environmental restoration and decontamination and decommissioning (D&D) of the former nuclear facilities and their associated sites. Liquid metal research and development ended in 2002. Since May 2007, the D&D operations in Area IV have been suspended by the DOE, but the environmental monitoring and characterization programs have continued. Results of the radiological monitoring program for the calendar year 2012 continue to indicate that there are no significant releases of radioactive material from Area IV of SSFL. All potential exposure pathways are sampled and/or monitored, including air, soil, surface water, groundwater, direct radiation, transfer of property (land, structures, waste), and recycling.

Liu, Ning↗

Site Environmental Report for Calendar Year 2011. DOE Operations at The Boeing Company Santa Susana Field Laboratory, Area IV

This Annual Site Environmental Report (ASER) for 2011 describes the environmental conditions related to work performed for the Department of Energy (DOE) at Area IV of Boeing’s Santa Susana Field Laboratory (SSFL). The Energy Technology Engineering Center (ETEC), a government-owned, company-operated test facility, was located in Area IV. The operations in Area IV included development, fabrication, operation and disassembly of nuclear reactors, reactor fuel, and other radioactive materials. Other activities in the area involved the operation of large-scale liquid metal facilities that were used for testing non-nuclear liquid metal fast breeder reactor components. All nuclear work was terminated in 1988, and all subsequent radiological work has been directed toward environmental restoration and decontamination and decommissioning (D&D) of the former nuclear facilities and their associated sites. Liquid metal research and development ended in 2002. Since May 2007, the D&D operations in Area IV have been suspended by the DOE, but the environmental monitoring and characterization programs have continued. Results of the radiological monitoring program for the calendar year 2011 continue to indicate that there are no significant releases of radioactive material from Area IV of SSFL. All potential exposure pathways are sampled and/or monitored, including air, soil, surface water, groundwater, direct radiation, transfer of property (land, structures, waste), and recycling.

Liu, Ning↗

Site Environmental Report for Calendar Year 2010. DOE Operations at The Boeing Company Santa Susana Field Laboratory, Area IV

This Annual Site Environmental Report (ASER) for 2010 describes the environmental conditions related to work performed for the Department of Energy (DOE) at Area IV of Boeing’s Santa Susana Field Laboratory (SSFL). The Energy Technology Engineering Center (ETEC), a government-owned, company-operated test facility, was located in Area IV. The operations in Area IV included development, fabrication, and disassembly of nuclear reactors, reactor fuel, and other radioactive materials. Other activities in the area involved the operation of large-scale liquid metal facilities that were used for testing non-nuclear liquid metal fast breeder reactor components. All nuclear work was terminated in 1988, and all subsequent radiological work has been directed toward decontamination and decommissioning (D&D) of the former nuclear facilities and their associated sites. Liquid metal research and development ended in 2002. Since May 2007, the D&D operations in Area IV have been suspended by the DOE, but the environmental monitoring and characterization programs have continued. Results of the radiological monitoring program for the calendar year 2010 continue to indicate that there are no significant releases of radioactive material from Area IV of SSFL. All potential exposure pathways are sampled and/or monitored, including air, soil, surface water, groundwater, direct radiation, transfer of property (land, structures, waste), and recycling.

Liu, Ning↗

Evaluation of Runtime Performance for xRage Equations of State Input Settings and Cropped EOS Tables

Using the xRage hydro code with its intrinsic equations of state (EOS) settings does not produce the most accurate representation of the problem due to xRage's internal alterations to the fundamental EOS data. Utilizing EOSPAC with default settings in the hydro code uses the unaltered EOS SESAME data to produce what is considered the most accurate results. However, this setup for the simulation is very computationally inefficient due to xRage's reliance on pressure and temperature as its look-up variables in combination with EOSPAC's use of a rational function interpolator. This report explores the results and performance of running a simulation with the option, within EOSPAC, to invert the table at setup, using a linear or rational interpolator, and using an EOS table cut down to only the region actually sampled in the problem. Air and Deuterium are used as the test materials for the simulations. While using EOS data directly with EOSPAC, the rational interpolator takes about twice as long as the linear one. Additionally, using a windowed EOS table does not show a large increase in performance. An EOS table that has had more energy grid points interpolated and added in by EOSPAC showed more accurate results, suggesting that a more dense EOS table would be more accurate.

97 MATHEMATICS AND COMPUTING↗

Investigation of laser direct energy deposition for production of ODS alloys

Laser blown powder additive manufacturing (AM) was performed to evaluate the feasibility of using the technique to fabricate oxide dispersion strengthened (ODS) alloys. The idea was to utilize an in-situ oxidation reaction to oxidize reactive elements to generate a refined dispersion of the dispersoids with a uniform size distribution. Builds were fabricated using Y added 316L in a reactive atmosphere and an inert atmosphere for comparisons. Detailed characterization was performed to understand the as-fabricated microstructure. Detailed characterization and chemical analysis show that there is significant Y loss during deposition. The loss in Y during processing leads to a reduced volume fraction of precipitates (~2 x 10 18 /m 3 ) with an average size of ~97 nm. Mechanical testing of the samples fabricated in both air and in inert atmosphere were performed at RT, 200 °C, 400 °C and 600 °C. The mechanical properties were then compared with austenitic ODS alloys that were reported in the literature. The results show that while the ultimate tensile strengths were comparable with wrought ODS alloys, the deterioration in yield strength with temperature was more severe in the case of the AM fabricated ODS material. However, the ductility was observed to be higher than all wrought 316L ODS alloys. Future efforts will focus on increasing the percentage of Y in the pre-alloyed powder to refine the dispersoids. In addition, a close control of process parameters and post processing treatments need to be explored to optimize the dispersoids volume fraction.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Crack Growth Rate and Fracture Toughness Tests on Irradiated Ex-Plant Materials

The performance of structural materials is critical for the safe and economic operation of light water reactors. Exposed to neutron irradiation during service, the reactor core internal materials can undergo significant microstructural and microchemical changes, leading to irradiation hardening and embrittlement. To ensure the structural integrity and functionality of nuclear reactor components during long-term operation, material degradation and damage mechanisms must be understood and managed adequately. In this work, irradiated materials harvested from the decommissioned Zorita reactor were studied for their cracking susceptibility and fracture resistance as a function of irradiation dose up to 47 displacement per atom (dpa). The material is a Type 304 stainless steel sectioned from the baffle plates of this pressurized water reactor with 38 years of service. Crack growth rate and fracture toughness J-resistance (J-R) curve tests were performed in low-corrosion-potential environments at ~315°C. All samples behaved similarly under cyclic loading, and no deteriorated corrosion-fatigue behavior was observed in the test environments. Under constant stress intensity factors, most samples did not show elevated crack growth rates, suggesting an adequate stress corrosion cracking resistance in the test environments. However, an unstable cracking behavior was observed in a 47-dpa sample, resulting in significantly higher crack growth rates than expected at high stress intensity factors. Crack instability was also observed in a 0.06-dpa sample but did not lead to a sustained high crack growth rate. The impact of neutron irradiation was more evident in the fracture toughness J-R curve tests. As the dose increased, the J-R curve declined considerably and became very shallow at high doses. A fully intergranular fracture morphology was also observed among the high-dose samples ruptured in an air atmosphere at room temperature. This brittle fracture mode in the absence of high temperature water environment confirmed a high degree of embrittlement of this material resulting from its service exposure to neutron irradiation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Plasmonics-based detection of H 2 and CO: discrimination between reducing gases facilitated by material control

Monitoring emissions in high-temperature-combustion applications is very important for regulating the discharge of gases such as NO 2 and CO as well as unburnt fuel into the environment. This work reports the detection of H 2 and CO gases by employing a metal–metal oxide nanocomposite (gold–yttria stabilized zirconia (Au–YSZ)) film fabricated through layer-by-layer physical vapor deposition (PVD). The change in the peak position of the localized surface plasmon resonance (LSPR) was monitored as a function of time and gas concentration. The responses of the films were preferential towards H 2 , as observed from the results of exposing the films to the gases at temperatures of 500 °C in a background of dry air. Characterization of the samples by XRD and SEM enabled the correlation of material properties with the differences in the CO- and H 2 -induced LSPR peak shifts, including the relative desensitization towards NO 2 . Sensing characteristics of films with varying support thicknesses and metal-particle diameters have been studied, and the results are presented. A comparison has been made to films fabricated through co-sputtered PVD, and the calibration curves of the sensing response show a preferential response towards H 2 . The distinction between H 2 and CO responses is also seen through the use of principal-component analysis (PCA). Such material arrangements, which can be tuned for their selectivity by changing certain parameters such as particle size, support thickness, etc., have direct applications within optical chemical sensors for turbine engines, solid-oxide fuel cells, and other high-temperature applications.

36 MATERIALS SCIENCE↗

Superconductivity in the alkali metal intercalates of molybdenum disulphide

The complete series of alkali metals, lithium through cesium, have been intercalated into molybdenum disulphide, using both the liquid ammonia and vapor techniques. All the intercalates with the exception of lithium yielded full superconducting transitions with onset temperatures of 6 K for AxMoS2(Ax=K,Rb,Cs) and 4 K for BxMoS2(Bx=Li,Na). The superconducting transition for lithium was incomplete down to 1.5 K. Stoichiometries and unit cell parameters have been determined for the intercalation compounds. Both rhombohedral and hexagonal polymorphs of MoS2 have been intercalated and found to exhibit the same superconductivity behavior. The nature of the extraneous superconducting transition of some intercalated samples on exposure to air was elucidated.

Somoano, R. B.↗

Effects of environmental changes on marsh vegetation with special reference to salinity

A literature survey primarily concerned with brackish and salt marshes located along the eastern coast of North America and the Gulf Coast was presented. The review concentrated upon the vegetation of the marshes, particularly in regard to distribution, composition, succession, and productivity. Special efforts were made to include major works concerned with the Louisiana and Mississipi coastal marshes. It appears that spring to early summer (weeks 18-34 of the year; April - mid-July) is the best period of time to categorize the communities. It is during this time of the year that the communities appear most stable in regard to species composition. This allows a strong correlation to be drawn between the salinity of the region and the dominant species of the community. As such, this would seem to be best period in which to sample the marsh via air or land for differences in vegetation and salinity.

Smalley, A. E.↗

Measurement of transpiration in Pinus taeda L. and Liquidambar styraciflua L. in an environmental chamber using tritiated water

Transpiration rates of loblolly pine (Pinus taeda L.) and sweetgum (Liquidambar styraciflua L.) were measured at two different atmospheric water vapor pressure deficits (V.P.D.) in a controlled environment growth chamber using tritiated water as a tracer. The trees were maintained in a sealed plant bed containing a hydroponic nutrient solution into which labeled water (spike) was introduced. Samples of leaves, chamber air, spiked nutrient solution and control water were assayed for ratio-activity using liquid scintillation techniques to determine transpiration rates. The transpiration rate of sweetgum in ml./hr./gm. (4.95) was found to be 5 times greater than that of loblolly pine (1.03) at 1.84 V.P.D. and 8 times greater at 6.74 V.P.D. (15.99 for sweetgum vs. 2.19 for pine). Transpiration (based on measurements of leaf radioactivity) in both species rose with increasing deficit; however sweetgum increased its output by 3 times while pine only doubled its rate. Cyclical changes in transpiration rates were noted in both species; the sweetgum cycle required a 6 hour interval whereas the pine cycle required a 9 hour interval.

Levy, G. F.↗

Automated syringe sampler

Device is designed primarily for remotely collecting field samples of water or air from polluted sources or from tracer gases used to track such sources over long distances.

Purgold, G. C.↗

The Comstar D/3 gain degradation experiment

The results of gain degradation measurements using the Comstar D/3 19.04 GHz beacon are reported. This experiment utilized 0.6 and 5 m aperture antennas aligned along the same propagation path to examine propagation effects which are related to the antenna aperture size. Sample data for clear air, scintillation in clear air, and precipitation fading are presented. Distributions of the received signal levels and variances for both antennas are also presented.

Lee, T. C.↗

The atmospheric inventory of Xenon and noble cases in shales The plastic bag experiment

A novel trapped gas analysis protocol is applied to five shales in which the samples are sealed in air to eliminate the possibility of gas loss in the preanalysis laboratory vacuum exposure of a conventional protocol. The test is aimed at a determination concerning the hypothesis that atmospheric noble gases occur in the same proportion as planetary gases in meteorites, and that the factor-of-23 deficiency of air Xe relative to planetary Xe is made up by Xe stored in shales or other sedimentary rocks. The results obtained do not support the shale hypothesis.

Bernatowicz, T. J.↗

Study of muons near shower cores at sea level using the E594 neutrino detector

The E594 neutrino detector has been used to study the lateral distribution of muons of energy 3 GeV near shower cores. The detector consists of a 340 ton fine grain calorimeter with 400,000 cells of flash chamber and dimensions of 3.7 m x 20 m x 3.7 m (height). The average density in the calorimeter is 1.4 gm/sq cm, and the average Z is 21. The detector was triggered by four 0.6 sq m scintillators placed immediately on the top of the calorimeter. The trigger required at least two of these four counters. The accompanying extensive air showers (EAS) was sampled by 14 scintillation counters located up to 15 m from the calorimeter. Several off line cuts have been applied to the data. Demanding five particles in at least two of the trigger detectors, a total of 20 particles in all of them together, and an arrival angle for the shower 450 deg reduced the data sample to 11053 events. Of these in 4869 cases, a computer algorithm found at least three muons in the calorimeter.

Goodman, J. A.↗

Undercooling and solidification behavior in the InSb-Sb system

Use of the droplet emulsion technique has been successful in studying the undercooling and crystallization behavior of Sb, InSb, and an InSb-Sb eutectic alloy. Both droplet size and imposed cooling rate were influential in controlling the extent of liquid undercooling. The droplet surface coating was of significant importance in determining the resultant solidification product structure through its effect on nucleation kinetics. The maximum undercooling for pure Sb was extended from 0.08 to 0.23 T sub m. While simple crushing techniques provided a dramatic increase in droplet undercooling over the bulk material, emulsification treatments both enhanced this undercooling and allowed successful formation of a metastable simple cubic Sb phase. This phase was stable to temperatures approaching the melting point. The simple cubic phase was detected in droplet samples processed using DTA, air and water quenching, and drop tube processing under a helium gas atmosphere. A deviation in the InSb parent ingot composition limited interpretation of the line compound results, however, emulsification techniques extended the undercooling of this material to 0.17 T sub L and provided a stable, protective surface coating for the droplets. Emulsification of the eutectic alloy was effective at producing various levels of undercooling from 0.1 to 0.2 T sub E. Microstructural examination revealed a normal-type eutectic structure in the undercooled droplets indicating that solidification occurred within the coupled zone and that this zone is somewhat symmetric about the eutectic composition.

Graves, J. A.↗

In situ observations of ClO in the wintertime Northern Hemisphere: ER-2 aircraft results from 21 N to 61 N latitude

Measurements of lower stratospheric ClO taken during a NASA ER-2 flight between Moffett Field, CA (37 N, 122 W) and Great Slave Lake, Canada (61 N, 116 W) on 13 February 1988 are reported. Northbound, the aircraft was flown at about 20 km altitude from 39 N to 56 N, at 18 km from there to 58 N, in a descent to 15 km at 60 N, and in a rise and turn at the northernmost point. The southbound leg was flown in a gradual climb from 20 km to 21.5 km. On this day, the central position of the Arctic polar vortex, as determined by an NMC analysis of heights and temperatures at the 50 mb and 70 mb levels, was approximately 79 N, 100 W. Because the vortex was located on the North American side of the pole, the aircraft was able to reach a point slightly inside the maximum horizontal wind region where wind speeds were 80 to 90 knots. The general pattern for the observed ClO is that it increased with both latitude and altitude, and attained a maximum of about 55 pptv at 61 N latitude and 20.5 km altitude. This value is about 20 times smaller than the maxima observed over Antarctica, but is comparable to those seen just outside the chemical containment vessel located inside the Antarctic Polar vortex. On the other hand, in a comparison with northern midlatitude data taken on this and three other February flights, ClO mixing ratios observed north of 55 N latitude are 2 to 5 times larger at all flight altitudes (15 to 20 km). Possible reasons are discussed for this enhancement over midlatitude and the evidence is considered for whether or not the instruments sampled Arctic polar vortex air. A second feature of the data is the strong positive correlation between ClO and O3 during the entire flight.

Brune, W. H.↗