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Phosphate Textural Diversity in CI Chondrites and C-Type Asteroids

Introduction: Apatite, Ca 5 (PO 4 ) 3 (CL/F/OH-), is a ubiquitous phosphate found throughout the solar system, including the most primitive solids, CI-chondrites [1,2] and related samples of carbonaceous asteroids Ryugu [3] and Bennu [4], returned by JAXA’s Hayabusa2 and NASA’s OSIRIS-REx missions, respectively. Apatite in these primitive solids is found as individual grains or mineral clusters and has been inferred to form from the hydrothermal sequence during cooling of their respective parent body or bodies. To better understand the formation history and reworking of these early phosphates we have undertaken a highly coordinated study of phosphate microstructures, geochemistry and U/Pb geochronology from a suite of CI meteorites and carbonaceous asteroid samples. These data have identified novel phosphate microstructures and complex relationships across a suite of apatite grains from the early solar system, indicating multiple episodes of growth and modification on the CI parent body(ies). Methods: Samples of CI chondrites, Alais, Ivuna, Orgueil, Oued Chebeika 002, Yamato (Y) 82162, Y980115, Y980134, and two chips of Hayabusa2 Ryugu particles (A0262 and C0263) have been acquired for analysis. The bulk texture of the samples were first scanned by X-ray Computed Tomography (XCT) using the Nikon XT H 320 within the XFACT facility at NASA JSC or the Xradia 620 Versa at the UTCT facility. Based on the identification of petrofabrics or features of interest from the XCT data, samples were chipped, oriented, potted in epoxy and thick sections were prepared. After anhydrously polishing the samples with silicon carbide and dry diamond powder down to 1 µm, the samples were ion polished using a Hitachi ArBlade. Energy dispersive Xray spectrometry (EDS) maps were collected to ID phosphates of interest using a JEOL 7900F SEM. The internal microstructures of identified phosphates were then mapped by electron backscatter diffraction (EBSD) using the JEOL 7900F. Based on the EDS and EBSD data, domains of interest were targeted for quantitative chemical analyses using a JEOL 8530 EPMA. Subsequently, in situ U-Pb and 207 Pb/ 206 Pb ages will be collected using a Cameca ims1290 secondary ion mass spectrometer at UCLA across a range of microstructures. Results: Apatite grains are ubiquitous throughout the CI chondrites and carbonaceous asteroid materials, found as individual grains, disseminated clusters or grain aggregates. Apatite grains are associated with serpentine, magnet-ite, and/or carbonate. Of particular interest, we have identified individual and aggregate polycrystalline grains ex-hibiting an internal ‘honeycomb’ texture (Fig. 1). Some of these grains appear overprinted by subsequent alteration while others remain unaltered. Apatite halogen sites are dominated by the missing component, assumed to be OH, and F, comparable to published values from Bennu, Ryugu and CM-chondrites [3-5]. However, the Yamato CI-like meteorites show a broader range of Cl values, and one grain from Alais is dominated by CL. Summary: Apatite growth features indicate a protracted and complex growth history, consistent with precipitation from an evolving fluid system. The ‘honeycomb’ texture identified in some CI meteorites is, to the best of our knowledge, the first report of such a microstructure in meteoritic phosphate. The microtextures and zoning will guide subsequent age analyses, to better constrain the formation and reworking of phosphate in CI(-like) materials. Acknowledgments: We thank the National Institute of Polar Research, Japan for samples of Y82162, 980115 and 980134 meteorites, ASU’s Buseck Center for Meteorite Studies for samples of Ivuna and Alais meteorites, and JAXA curation for chips of Ryugu material. This work was funded by NASA ROSES LARS grant 24-LARS24-0014. References: [1] Morlok et al., 2016, GCA 70:5371-5394. [2] Alfin g et al., 2019, Geochemistry 79:125532. [3] Nakamura et al. (2022) Science 379:1-15. [4] Seifert et al. (2026) MAPS 61:504-521. [5] Piralla et al. (2021) MAPS 56:809-828.

CI chondrites↗

NASA NTRS1999

Estimating the Mass of Asteroid 433 Eros During the Near Spacecraft Flyby

The terminal navigation of the Near-Earth Asteroid Rendezvous (NEAR) spacecraft during its flyby of asteroid 433 Eros on December 23, 1998 involved coordinated efforts to determine the heliocentric orbits of the spacecraft and Eros and then to determine the relative trajectory of the spacecraft with respect ot Eros.

Asteroid Near-Earth Asteroid Rendezbous (NEAR) mas↗

NASA NTRS2020

Photometry of Asteroid (101955) Bennu with OVIRS on OSIRIS-REx

NASA’s OSIRIS-REx spacecraft arrived at its sampling target, asteroid (101955) Bennu, in December 2018 and started a series of global observation campaigns. Here we investigate the global photometric properties of Bennu as observed by the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) over the time period December 9, 2018, to September 26, 2019. In this study we used observations obtained over wavelengths ranging from 0.4 to 3.7 μm, with a solar phase angle range of 5.3° to 132.6°. Our aim is to characterize the global average disk-resolved photometric properties of Bennu with multiple models. The best-fit model is a McEwen model with an exponential phase function and an exponential polynomial partition function. We use this model to correct the OVIRS spectra of Bennu to a standard reference viewing and illumination geometry at visible to infrared wavelengths for the purposes of global spectral mapping. We derive a bolometric Bond albedo map in which Bennu’s surface values range from 0.021 to 0.027. We find a phase reddening effect, and our model is effective at removing this phase reddening. Our average model albedo shows a blueish spectrum with a >10% absorption feature centered at 2.74 μm. Of all comparisons with previously visited asteroids and comets, only 28P/Neujmin, 2P/Encke, and (162173) Ryugu are darker than Bennu. We find that Bennu is a few percent brighter than Ryugu in the wavelengths respectively observed by the OSIRIS-REx and Hayabusa2 missions (from 0.48 to 0.86 μm). We also compare our spectroscopic photometry of Bennu with the OSIRIS-REx imaging photometry and with ground-based predictions.

Asteroid Bennu↗

DOE OSTI2022

Mascon distribution techniques for asteroids and comets

The mass-concentration model is an approach that has been used to model the gravitational fields of irregularly shaped bodies such as asteroids and comets. By this approach, the body is treated as a collection of point masses. The method is conceptually simple, easy to program, valid down to the surface, and capable of modeling arbitrary density heterogeneities. How the mass concentrations are distributed as well as how mass is assigned to these concentrations is, however, nontrivial. These aspects significantly affect the accuracy and efficiency of the gravitational model. In this paper, we frame the distribution process in terms of numerical integration applied to finite volume meshes. We describe a new method using unstructured, curvilinear, finite volume meshes to significantly improve the accuracy of the mass-concentration model. We then compare the accuracy and efficiency of several variations of our distribution technique to those from literature using Asteroid Eros and Bennu as example bodies. Our results show that the mascon model can be as accurate as the analytic polyhedral model at the surface using an equivalent number of computational elements—i.e., mascon to surface facets. We report the improvement in the model’s performance can be mainly attributed to the volume mesh topology while mesh curving can provide modest case-dependent improvements.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2019

Options and uncertainties in planetary defense: Impulse-dependent response and the physical properties of asteroids

In this paper we discuss that though rare, asteroid impacts are inevitable, and with the current state of technology, kinetic impactors are the preferred but not the complete solution. If the time to impact is short, or the threatening body too large, nuclear deflection serves as a final option. This work is part of an integrated study by National Aeronautics and Space Administration (NASA) and the National Nuclear Security Administration (NNSA) to better determine the relative efficacy of these complimentary approaches. In particular, we examine the important material properties that affect each approach, to improve critical characterization efforts, and reduce uncertainty in the limits of the impactor technology. Impact speeds for kinetic impactors on Near-Earth Object (NEO) intercept trajectories commonly range from 5 to 20 km/s, resulting in significant crater ejecta and a momentum enhancement above that carried by the impactor. This enhancement depends substantially on the strength and porosity of the asteroid, as well as the impact speed. Here simulations from different codes are presented, along with constraints from experimental measurements. The uncertainties due to ignorance of the strength and porosity of the impact point are significant in determining the limits of impactor sufficiency. The nuclear approach is considered within the context of current capabilities, posing no need to test, as extant and well-understood devices are sufficient for the largest known Potentially Hazardous Objects (PHOs). Results of x-ray sources with realistic spectra as well as blackbody spectra are given, along with some assessment on composition dependence.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2018

Three-dimensional simulations of oblique asteroid impacts into water

Waves generated by impacts into oceans may represent the most significant danger from near-earth asteroids and comets. For impacts near populated shores, the crown splash and subsequent waves, accompanied by sediment lofting and high winds, are more damaging than storm surges from the strongest hurricanes. Asteroids less than 500 m in diameter, impacting deep water far from shores, produce waves that may be detectable over large distances, but are probably not significantly dangerous. Here, we present new three-dimensional simulations of oblique impacts into deep water, with trajectory angles ranging from 27° to 60° (where 90° is vertical). These simulations are performed with the Los Alamos Rage hydrocode, and include atmospheric effects including ablation and airbursts. These oblique impact simulations are specifically performed in order to help determine whether there are additional dangers from the obliquity of impact not covered by previous two-dimensional studies. Water surface elevation profiles, surface pressures, and depth-averaged mass fluxes within the water are prepared for use in propagation studies

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

Incorporation of 16 O-rich anhydrous silicates in the protolith of highly hydrated asteroid Ryugu

The abundant phyllosilicate and carbonate minerals characterizing most of the returned particles from asteroid Ryugu suggest a history of extensive aqueous alteration on its parent body, similar to the rare mineralogically altered, but chemically primitive, CI (Ivuna-type) chondrite meteorites. Particle C0009 differs mineralogically from other Ryugu particles examined so far by containing anhydrous silicates at a level of ~0.5 vol%, and thus can help shed light on the unaltered original materials that constituted Ryugu’s protolith. In situ oxygen isotope measurements of the most Mg-rich olivine and pyroxene in C0009 reveal two populations of Δ 17 O: –25‰ to –15‰ and –8‰ to –3‰. The former and the latter populations correlate well with silicate morphologies similar to those seen in amoeboid olivine aggregates and chondrule phenocrysts, respectively, both of which are abundant in less aqueously altered carbonaceous chondrites. Here, this result also highlights the presence of olivine with Δ 17 O close to the solar value in either a CI chondrite or an asteroid with CI-chondrite characteristics, and provides strong evidence that amoeboid olivine aggregates and Mg-rich chondrules accreted into Ryugu’s protolith. Our data also raise the possibility that the protoliths of CI and other carbonaceous chondrites incorporated similar anhydrous silicates.

58 GEOSCIENCES↗

DOE OSTI2015

A mathematical model of the passage of an asteroid-comet body through the Earth’s atmosphere

In the paper, a mathematical model and a numerical algorithm are proposed for modeling the complex of phenomena which accompany the passage of a friable asteroid-comet body through the Earth’s atmosphere: the material ablation, the dissociation of molecules, and the radiation. The proposed model is constructed on the basis of the Navier-Stokes equations for viscous heat-conducting gas with an additional equation for the motion and propagation of a friable lumpy-dust material in air. The energy equation is modified for the relation between two its kinds: the usual energy of the translation of molecules (which defines the temperature and pressure) and the combined energy of their rotation, oscillation, electronic excitation, dissociation, and radiation. For the mathematical model of atmosphere, the distribution of density, pressure, and temperature in height is taken as for the standard atmosphere. An asteroid-comet body is taken initially as a round body consisting of a friable lumpy-dust material with corresponding density and significant viscosity which far exceed those for the atmosphere gas. A numerical algorithm is proposed for solving the initial-boundary problem for the extended system of Navier-Stokes equations. The algorithm is the combination of the semi-Lagrangian approximation for Lagrange transport derivatives and the conforming finite element method for other terms. The implementation of these approaches is illustrated by a numerical example.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2012

DETECTION OF SEMIMAJOR AXIS DRIFTS IN 54 NEAR-EARTH ASTEROIDS: NEW MEASUREMENTS OF THE YARKOVSKY EFFECT

We have identified and quantified semimajor axis drifts in near-Earth asteroids (NEAs) by performing orbital fits to optical and radar astrometry of all numbered NEAs. We focus on a subset of 54 NEAs that exhibit some of the most reliable and strongest drift rates. Our selection criteria include a Yarkovsky sensitivity metric that quantifies the detectability of semimajor axis drift in any given data set, a signal-to-noise metric, and orbital coverage requirements. In 42 cases, the observed drifts ({approx}10{sup -3} AU Myr{sup -1}) agree well with numerical estimates of Yarkovsky drifts. This agreement suggests that the Yarkovsky effect is the dominant non-gravitational process affecting these orbits, and allows us to derive constraints on asteroid physical properties. In 12 cases, the drifts exceed nominal Yarkovsky predictions, which could be due to inaccuracies in our knowledge of physical properties, faulty astrometry, or modeling errors. If these high rates cannot be ruled out by further observations or improvements in modeling, they would be indicative of the presence of an additional non-gravitational force, such as that resulting from a loss of mass of order a kilogram per second. We define the Yarkovsky efficiency f{sub Y} as the ratio of the change in orbital energy to incident solar radiation energy, and we find that typical Yarkovsky efficiencies are {approx}10{sup -5}.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2015

Near-Earth asteroid satellite spins under spin-orbit coupling

We develop a fourth-order numerical integrator to simulate the coupled spin and orbital motions of two rigid bodies having arbitrary mass distributions under the influence of their mutual gravitational potential. We simulate the dynamics of components in well-characterized binary and triple near-Earth asteroid systems and use surface of section plots to map the possible spin configurations of the satellites. For asynchronous satellites, the analysis reveals large regions of phase space where the spin state of the satellite is chaotic. For synchronous satellites, we show that libration amplitudes can reach detectable values even for moderately elongated shapes. The presence of chaotic regions in the phase space has important consequences for the evolution of binary asteroids. It may substantially increase spin synchronization timescales, explain the observed fraction of asychronous binaries, delay BYORP-type evolution, and extend the lifetime of binaries. The variations in spin rate due to large librations also affect the analysis and interpretation of light curve and radar observations.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2015

Archival observations of active asteroid 313P/GIBBS

We present prediscovery observations of active asteroid 313P/(2014 S4) Gibbs taken in 2003 and 2004. Sloan Digital Sky Survey observations from 2003 establish that, after 133P/Elst–Pizarro and 238P/Read, 313P is only the third main-belt active asteroid to show mass loss in different orbits. This repetitive activity is consistent with mass loss driven by the sublimation of ice. A Finson-Probstein model is used to analyze the morphology of the object, showing that the activity was continuous but declining steadily over two months of observation in 2003. Ejected dust particles are dominated by relatively large sizes with radii from ∼25 to ∼600 μm. We estimate from photometry the dust mass loss rate to be ≲0.2 kg s{sup −1}. In contrast, Subaru telescope observations from 2004 show no evidence for mass loss and suggest a bare nucleus. The color, nucleus size, and the mass loss rates of 313P measured in 2003 are consistent with published values obtained from data taken in 2014. However, the effective cross-section was larger than in 2014 by a factor of ∼2, indicating a decline in the activity between orbits. A new orbital solution gives a 5σ upper limit to the transverse non-gravitational parameter A{sub 2}≲2.45×10{sup −8} AU day{sup −2}.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2015

IMPROVED ALGORITHMS FOR RADAR-BASED RECONSTRUCTION OF ASTEROID SHAPES

We describe our implementation of a global-parameter optimizer and Square Root Information Filter into the asteroid-modeling software shape. We compare the performance of our new optimizer with that of the existing sequential optimizer when operating on various forms of simulated data and actual asteroid radar data. In all cases, the new implementation performs substantially better than its predecessor: it converges faster, produces shape models that are more accurate, and solves for spin axis orientations more reliably. We discuss potential future changes to improve shape's fitting speed and accuracy.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2015

THE EVOLUTION OF ASTEROIDS IN THE JUMPING-JUPITER MIGRATION MODEL

In this work, we investigate the evolution of a primordial belt of asteroids, represented by a large number of massless test particles, under the gravitational effect of migrating Jovian planets in the framework of the jumping-Jupiter model. We perform several simulations considering test particles distributed in the Main Belt, as well as in the Hilda and Trojan groups. The simulations start with Jupiter and Saturn locked in the mutual 3:2 mean motion resonance plus three Neptune-mass planets in a compact orbital configuration. Mutual planetary interactions during migration led one of the Neptunes to be ejected in less than 10 Myr of evolution, causing Jupiter to jump by about 0.3 AU in semimajor axis. This introduces a large-scale instability in the studied populations of small bodies. After the migration phase, the simulations are extended over 4 Gyr, and we compare the final orbital structure of the simulated test particles to the current Main Belt of asteroids with absolute magnitude H < 9.7. The results indicate that, in order to reproduce the present Main Belt, the primordial belt should have had a distribution peaked at ∼10° in inclination and at ∼0.1 in eccentricity. We discuss the implications of this for the Grand Tack model. The results also indicate that neither primordial Hildas, nor Trojans, survive the instability, confirming the idea that such populations must have been implanted from other sources. In particular, we address the possibility of implantation of Hildas and Trojans from the Main Belt population, but find that this contribution should be minor.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2012

TWO EXTRASOLAR ASTEROIDS WITH LOW VOLATILE-ELEMENT MASS FRACTIONS

Using ultraviolet spectra obtained with the Cosmic Origins Spectrograph on the Hubble Space Telescope, we extend our previous ground-based optical determinations of the composition of the extrasolar asteroids accreted onto two white dwarfs, GD 40 and G241-6. Combining optical and ultraviolet spectra of these stars with He-dominated atmospheres, 13 and 12 polluting elements are confidently detected in GD 40 and G241-6, respectively. For the material accreted onto GD 40, the volatile elements C and S are deficient by more than a factor of 10 and N by at least a factor of 5 compared to their mass fractions in primitive CI chondrites and approach what is inferred for bulk Earth. A similar pattern is found for G241-6 except that S is undepleted. We have also newly detected or placed meaningful upper limits for the amount of Cl, Al, P, Ni, and Cu in the accreted matter. Extending results from optical studies, the mass fractions of refractory elements in the accreted parent bodies are similar to what is measured for bulk Earth and chondrites. Thermal processing, perhaps interior to a snow line, appears to be of central importance in determining the elemental compositions of these particular extrasolar asteroids.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2013

DYNAMICS OF LARGE FRAGMENTS IN THE TAIL OF ACTIVE ASTEROID P/2010 A2

We examine the motions of large fragments at the head of the dust tail of the active asteroid P/2010 A2. In previous work, we showed that these fragments were ejected from the primary nucleus in early 2009, either following a hypervelocity impact or by rotationally induced breakup. Here, we follow their positions through a series of Hubble Space Telescope images taken during the first half of 2010. The orbital evolution of each fragment allows us to constrain its velocity relative to the main nucleus after leaving its sphere of gravitational influence. We find that the fragments constituting a prominent X-shaped tail feature were emitted in a direction opposite to the motion of the asteroid and toward the south of its orbital plane. Derived emission velocities of these primary fragments range between 0.02 and 0.3 m s{sup -1}, comparable to the {approx}0.08 m s{sup -1} gravitational escape speed from the nucleus. Their sizes are on the order of decimeters or larger. We obtain the best fits to our data with ejection velocity vectors lying in a plane that includes the nucleus. This may suggest that the cause of the disruption of P/2010 A2 is rotational breakup.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

Formation of the wide asynchronous binary asteroid population

We propose and analyze a new mechanism for the formation of the wide asynchronous binary population. These binary asteroids have wide semimajor axes relative to most near-Earth and main belt asteroid systems. Confirmed members have rapidly rotating primaries and satellites that are not tidally locked. Previously suggested formation mechanisms from impact ejecta, from planetary flybys, and directly from rotational fission events cannot satisfy all of the observations. The newly hypothesized mechanism works as follows: (1) these systems are formed from rotational fission, (2) their satellites are tidally locked, (3) their orbits are expanded by the binary Yarkovsky-O'Keefe-Radzievskii-Paddack (BYORP) effect, (4) their satellites desynchronize as a result of the adiabatic invariance between the libration of the secondary and the mutual orbit, and (5) the secondary avoids resynchronization because of the YORP effect. This seemingly complex chain of events is a natural pathway for binaries with satellites that have particular shapes, which define the BYORP effect torque that acts on the system. After detailing the theory, we analyze each of the wide asynchronous binary members and candidates to assess their most likely formation mechanism. Finally, we suggest possible future observations to check and constrain our hypothesis.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

Analysis of asteroid (216) Kleopatra using dynamical and structural constraints

This paper evaluates a dynamically and structurally stable size for Asteroid (216) Kleopatra. In particular, we investigate two different failure modes: material shedding from the surface and structural failure of the internal body. We construct zero-velocity curves in the vicinity of this asteroid to determine surface shedding, while we utilize a limit analysis to calculate the lower and upper bounds of structural failure under the zero-cohesion assumption. Surface shedding does not occur at the current spin period (5.385 hr) and cannot directly initiate the formation of the satellites. On the other hand, this body may be close to structural failure; in particular, the neck may be situated near a plastic state. In addition, the neck's sensitivity to structural failure changes as the body size varies. We conclude that plastic deformation has probably occurred around the neck part in the past. If the true size of this body is established through additional measurements, this method will provide strong constraints on the current friction angle for the body.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2014

Intermittent dust mass loss from activated asteroid P/2013 P5 (PANSTARRS)

We present observations and models of the dust environment of activated asteroid P/2013 P5 (PANSTARRS). The object displayed a complex morphology during the observations, with the presence of multiple tails. We combined our own observations, all made with instrumentation attached to the 10.4 m Gran Telescopio Canarias on La Palma, with previously published Hubble Space Telescope images to build a model aimed at fitting all the observations. Altogether, the data cover a full three month period of observations which can be explained by intermittent dust loss. The most plausible scenario is that of an asteroid rotating with the spinning axis oriented perpendicular to the orbit plane and losing mass from the equatorial region, consistent with rotational break-up. Assuming that the ejection velocity of the particles (v ∼ 0.02-0.05 m s{sup –1}) corresponds to the escape velocity, the object diameter is constrained to ∼30-130 m for bulk densities 3000-1000 kg m{sup –3}.

79 ASTRONOMY AND ASTROPHYSICS↗