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At least 919 records · Page 51

Comparative study of boron and neon injections on divertor heat fluxes using SOLPS-ITER simulations

Here, based on the EAST equilibrium, the effects of boron (B) and neon (Ne) injected at different locations on the target heat load, and the distributions of B and Ne particles were investigated by transport code SOLPS-ITER. It was found that the B injection was more sensitive to the injection location for heat flux control than impurity Ne. The high electron and ion densities near the inner target in the discharge with impurity B injected from over X-point (R 1 ) led to plasma detachment only at the inner target, and the localized B ions in the cases with injection from outer target location (R 2 ) and upstream location (R 3 ) led to far-SOL detachment at the outer target, but not at the inner target. In contrast, for Ne, the spatial distributions of Ne ions and electrons were found to be similar in all the cases at the three injection locations, and the detached plasma was achieved at the inner target and the electron temperature was reduced at the outer target. For locations R 2 and R 3 , impurity B showed a more pronounced effect on the heat flux at the far-SOL of the outer target. Further analysis indicated that Ne atoms came mainly from the recycling sources, whereas B atoms came mainly from injection, and that their distinct atomic distributions resulted from the difference in the ionization threshold and ionization mean free path. In addition, the radiation proportion of B in the divertor region was larger than that of Ne when the total radiation power was similar, which suggests that B has less influence on the core region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Extension of OpenMC for Fixed Source Transmutation Calculations

This report documents work performed under a Strategic Partnership Project between Argonne National Laboratory (ANL) and the United Kingdom Atomic Energy Authority (UKAEA). The overall goal of this project is to extend OpenMC [1], a community-developed Monte Carlo particle transport code, to be able to perform fixed-source transmutation calculations. In fission and fusion reactors, the high flux of energetic neutrons causes materials within the reactor to “transmute,” or undergo a nuclear reaction that results in the addition/removal of neutrons and protons from the nucleus of an atom. If subjected to these reactions for long enough, the overall composition and physical properties of the material itself begin to change as a result of transmutation. Such a feature is vital for predicting the decrease in tritium production rate within a breeder blanket during the lifetime of a fusion reactor. OpenMC is capable of simulating neutron transport in fission/fusion systems, thereby allowing it to estimate the flux that causes transmutation. It is also capable of solving the transmutation equations, which determine how the composition of a material changes over time due to neutron irradiation and radioactive decay. However, solving the transmutation equations was previously only possible when the source of neutrons came from a fission system. In a fusion system, the source of neutrons is typically determined by a separate code and then given as an input to the particle transport simulation. This is known as a fixed source calculation. Through this project, we have extended OpenMC to solve the transmutation equations for a fixed source calculation. Evaluating the change in material compositions due to transmutation and its effect on physical properties is of key importance to a range of engineering analyses for fission and fusion systems. For example, in a fusion reactor, estimating the dose rate at different physical locations resulting from irradiated materials in the reactor allows designers to ensure that workers are not exposed to doses beyond applicable regulations. In order to properly dispose of irradiated materials, designers also need to estimate the radiotoxicity, which again relies on knowledge of the material composition at some future time. The specific tasks for this project that were agreed to between ANL and UKAEA were as follows: 1. Make changes and additions in the openmc.deplete and related modules in OpenMC to support transmutation calculations following a fixed source transport simulation. 2. Make necessary changes to OpenMC to model transmutation due to an arbitrary set of reactions needed for fusion applications. Use this new capability to generate a depletion chain file based on the TENDL nuclear data library. 3. Improve the openmc.deplete module in OpenMC to keep track of gases produced as a by-product of nuclear reactions during transmutation calculations. 4. Validate the new capabilities by carrying out fixed-source transmutation calculations on a suitable benchmark problem using OpenMC and a comparable Monte Carlo neutron transport code.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

General guide concepts for compact, high-brilliance neutron moderators

The trend in neutron sciences is toward integrating compact, high-brightness moderators into new or upgraded facilities. Transporting neutrons from the source to the sample position with a phase-space distribution tailored to specific requirements is crucial to leverage high source brilliance. Here we have investigated four guide concepts using Monte Carlo ray tracing simulations: Montel beamline with nested Kirkpatrick–Baez mirrors, curved-tapered beamline with a bender and straight sections, straight-elliptical beamline, and curved-elliptical beamline. The straight-elliptical (curved-elliptical) beamline features two half-ellipse guides connected by a straight (non-straight) guide section. The neutron transport efficiency and phase space homogeneity have been quantitatively compared. Our results show that the straight-elliptical beamline performs best because of few neutron bounces on the guide surface with small reflection angles, minimizing flux loss. The Montel beamline provides the best spatial confinement of neutrons within the desired region; however, there is a high thermal-neutron loss due to large reflection angles. The curved-tapered beamline suffers from significant flux loss due to high bounces, and it shows a non-uniform angular distribution related to broad ranges of bounces and reflection angles. The non-straight guide section of the curved-elliptical beamline increases the phase space inhomogeneity, leading to a spatially non-uniform beam profile. The results apply to general neutron instruments that require transporting thermal and cold neutrons from a compact, high-brilliance moderator to the sample location with a moderate phase-space volume.

47 OTHER INSTRUMENTATION↗

A New Shutdown Dose Rate Benchmark Problem for Representative Fusion Applications

Here, this work introduces a new benchmark problem for calculating shutdown dose rates (SDDRs) aimed at fusion reactor applications. The model is designed to represent a simplified version of a typical ITER port plug. The responses of interest include neutron flux, gamma flux, and gamma SDDR at 12 different locations scattered throughout the port. This article outlines the geometry specifications of the problem, provides material definitions for the components, specifies the required responses to be calculated, and presents the source definition information. The need for this benchmark arises from the limited availability of publicly accessible references, with only one benchmark representing the typical dimensions and materials found in fusion systems. This existing benchmark has been cited extensively, reflecting the demand within the scientific community to test both established and novel workflows for SDDR calculations. However, since its presentation at a conference in 2011, the results have become increasingly well known. Moreover, the absence of formal publication and peer review has led to the details of this benchmark being extracted from secondary sources, such as subsequent studies that reference it. As a result, analysts are left with significant flexibility in interpreting the key parameters, which can be adjusted to account for unknown systematic errors, ultimately reproducing the already well-known responses. This new benchmark serves as an updated version of that earlier work, with the aim of providing a more reliable description of the materials and their impurities, which is crucial for assessing activation and subsequent gamma emission. Additionally, it seeks to provide a geometry that more closely represents an ITER port plug. The improvements in the problem definition will lead to a more reproducible benchmark problem, while also presenting the radiation transport community with a completely new challenge. The results will be published in a future article to allow analysts adequate time to analyze this problem independently.

Benchmark↗

Biogeographic patterns in populations of marine Pseudoalteromonas atlantica isolates

Intra-specific genomic diversity is well documented in microbes. The question, however, remains whether natural selection or neutral evolution is the major contributor to this diversity. We undertook this study to estimate genomic diversity in Pseudoalteromonas atlantica populations and whether the diversity, if present, could be attributed to environmental factors or distance effects. Here, we isolated and sequenced twenty-three strains of P. atlantica from three geographically distant deep marine basins and performed comparative genomic analyses to study the genomic diversity of populations among these basins. Average nucleotide identity followed a strictly geographical pattern. In two out of three locations, the strains within the location exhibited >99.5% identity, whereas, among locations, the strains showed <98.11% identity. Phylogenetic and pan-genome analysis also reflected the biogeographical separation of the strains. Strains from the same location shared many accessory genes and clustered closely on the phylogenetic tree. Phenotypic diversity between populations was studied in ten out of twenty-three strains testing carbon and nitrogen source utilization and osmotolerance. A genetic basis for phenotypic diversity could be established in most cases but was apparently not influenced by local environmental conditions. Our study suggests that neutral evolution may have a substantial role in the biodiversity of P. atlantica.

59 BASIC BIOLOGICAL SCIENCES↗

Evaluating radiation impact on transmon qubits in above and underground facilities

Superconducting qubits can be sensitive to energy deposits caused by cosmic rays and ambient radioactivity. While previous studies have explored correlated effects in time and space due to cosmic ray interactions, we present the first direct comparison of a transmon qubit’s performance measured at two distinct sites: the above-ground SQMS facility (Fermilab, US) and the deep-underground Gran Sasso Laboratory (Italy). Despite the stark difference in radiation levels, we observe a similar average qubit relaxation time of approximately 80 microseconds at both locations. To investigate radiation-induced events, we employ a fast decay detection protocol, comparing the relative rates of events between the two environments. Although intrinsic noise remains the dominant source of errors in superconducting qubits, our analysis revealed a significant excess of radiation-induced events for high-coherence transmon qubits operated above-ground. Finally, using γ-ray sources with increasing activity levels, we evaluate the qubit response in a controlled low-background environment.

De Dominicis, Francesco [GSSI, Aquila; INFN, LNS]↗

Measurement results for 60Co Assay baskets H5, H9, H14, H15, A4, and B3 (C003, C001, C005, C022, C021, C020, C032, C033, C038, C035, C036, C039, C053, C054, C055, C065, C066, & C067)

Eighteen cobalt targets (C003, C001, C005, C022, C021, C020, C032, C033, C038, C035, C036, C039, C053, C054, C055, C065, C066, & C067) were assayed on July 28-29, 2020, following irradiation in ATR cycle 168A. The average specific activity of each target was determined by using the cobalt assay system located in the ATR canal following procedure ACMM-3610.

07 ISOTOPE AND RADIATION SOURCES↗

Standoff Detection of Chemical Plumes Using Swept-ECQCL Remote Detection Technology: Results from EMRTC Complex Terrain Dual Tracer Experiment

As part of the Complex Terrain Dual Tracer Experiments performed in support of the LYNM program, a swept-wavelength external cavity quantum cascade laser (swept-ECQCL) remote detection system was deployed to measure chemical plume propagation with high temporal resolution. The swept-ECQCL remote detection technology was initially developed at PNNL, and is now under further development at Opticslah, LLC under SBIR funding from DOE (DOE SBIR Phase I Project DE-SC0019855, Remote Detection Technologies, Program Manager Chris Ramos). The swept-ECQCL technology provides a single-frequency infrared laser source which is rapidly scanned over a large wavelength range to measure the infrared absorption of gases, liquids, or solids. Analysis of the measured infrared absorption spectrum is used to detect, identify, and quantify the chemical species which are present. While most previous laser-based techniques used small wavelength tuning ranges to measure only a few isolated spectral lines of a few species, the swept-ECQCL provides the large tuning range needed to measure multiple species simultaneously, and to detect broad absorption features from large molecules or condensed phase materials. In addition, the swept-ECQCL systems have high enough spectral resolution and sensitivity to measure narrow lines of small molecules and determine isotope ratios. The remote detection system for gas plumes is based on the swept-ECQCL technology, and consists of a swept-ECQCL source, infrared detector, control electronics, and beam transmitting and alignment optics. The remote detection system directs the infrared output of the swept-ECQCL to a target retro reflector typically located at ~10-10,000 m distance. The swept-ECQCL wavelength is varied continuously over a large wavelength range (>1000 nm) at rates up to 1000 Hz. The swept ECQCL light reflected from the remote target is collected and focused onto an infrared photodetector. By measuring the detector signal continuously as the swept-ECQCL wavelength is varied, a time-series of absorption spectra are measured for the gases along the beam line of-sight. Based on analysis and fitting of the measured absorption spectra, the time-dependent chemical concentrations of species are determined. Multiple species and mixtures can be detected simultaneously, for all species with absorption features above the sensor noise floor. The sensor output is thus a continuous, high-speed record of identified chemicals along with their concentrations and isotope ratios of interest. The high-speed operation enables low-noise operation in conditions of atmospheric turbulence and allows tracking of fluctuating concentrations in transient chemical plumes as needed for reliable remote detection applications. All components operate with minimal cooling requirements and no cryogens are needed. In addition, the output infrared light is invisible with an intensity below the maximum permissible exposure (MPE) threshold of 100 mW/cm2 for these infrared wavelengths and thus eye safe. The measurement concept for plume detection using the swept-ECQCL remote detection system is as follows. The ECQCL beam is directed toward a remote retro-reflector, which reflects the beam back to the ECQCL system where it is focused onto an infrared photodetector. The line-of-sight from the ECQCL system to the retro-reflector defines the measurement path. The detected infrared signal is recorded continuously and detects the absorption of molecular species along the measurement path. Before a plume release, the system measures absorption from atmospheric constituents, which in this LWIR band consist primarily of lines from H 2 O and CO 2 , with additional weaker absorption from N 2 O, NH 3 , and O 3 possibly contributing. The system then measures any changes in absorption due to the tracer compounds when they enter the measurement path. The shape of absorption features is used to distinguish and identify the different tracer compounds, and the strength of the absorption is used to determine the path-integrated concentration – also called the column density.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bioenergy Feedstock Library Annual Summary Report 2024

The Bioenergy Feedstock Library (BFL), part of the Biomass Feedstock National User Facility (BFNUF) located at Idaho National Laboratory (INL), is a physical sample repository and a web-accessible electronic database. The BFL stores physical and chemical characteristics of biomass and waste carbon sources for energy use, as well as samples generated from U.S. Department of Energy (DOE) Bioenergy Technologies Office (BETO) and U.S. Department of Agriculture-funded projects. The objective of this Bioenergy Feedstock Library Annual Summary Report for 2024, similar to the 2023 Annual Summary Report , is to focus on the updates to: (1) publicly available analytical data and equipment tracked through the BFNUF, (2) significant increases in the physical samples available for request, (3) sample and data archival progress from recent BETO-funded projects, and (4) publicly available data sets created upon request from BETO, INL projects, or outside entities compared to the previous annual summary reports. This report highlights key statistics and available data and information important for INL, BFL users, academics, and industry.

09 BIOMASS FUELS↗

Observation-Based Constraints on the Condensational Growth of Marine Aerosol Particles to Cloud Condensation Nuclei in the Eastern North Atlantic

This report describes the results from a field project in the Eastern North Atlantic (Aerosol Growth in the Eastern North Atlantic; AGENA) that was designed to determine the source of condensable material that contributes to the growth of Aitken-mode aerosol particles to CCN in the remote marine boundary layer at the ARM Eastern North Atlantic (ENA) location.

54 ENVIRONMENTAL SCIENCES↗

Studying MeV Scale Neutron Interactions in DUNE ND-LAr 2x2 Demonstrator

The Deep Underground Neutrino Experiment (DUNE) is a long-baseline neutrino oscillation experiment designed to make high-precision measurements of neutrino oscillation parameters and probe for new physics using a neutrino beam produced at Fermilab and measured at a near detector complex and a far detector located 1,300 km away at the Sanford Underground Research Facility. Precise neutrino energy reconstruction is essential for these measurements, with neutron production in neutrino–argon interactions representing a significant source of systematic uncertainty, as neutrons can carry away significant energy, making their detection and characterization crucial. DUNE’s near detector complex includes ND-LAr, a Liquid Argon Time Projection Chamber (LArTPC) detector designed to mirror the far detector technology and constrain neutrino–argon interaction systematics. The DUNE 2x2 Demonstrator, a pixelated LArTPC based on the ArgonCube design, serves as a prototype for ND-LAr. During 2x2 operations from October to November 2026, an Americium–Beryllium (AmBe) neutron source was deployed near the detector cryostat to obtain a high-statistics sample of neutron interactions. This poster presents progress in studying MeV-scale neutron interactions in this dataset by identifying de-excitation gammas from neutron capture on argon, providing a method for neutron identification and charge readout system calibration in future DUNE detectors.

Mao, Edgar [Syracuse U.] (ORCID:0009000600893306)↗

Renewable Energy Potential Model: Geothermal Supply Curves

The Renewable Energy Potential (reV) model is a geospatial platform for estimating technical potential and developing renewable energy supply curves, initially developed for wind and solar technologies. The model evaluates deployment constraints, considering land use, environmental, and cultural factors, and estimates the distance to existing grid features to connect future plants (Maclaurin et al., 2021). A pressing deficiency in the reV model, however, is representation of geothermal electricity generation technologies. To address this gap, we developed a novel geothermal generation module for reV that allows for representation and analysis at the same level of detail as other renewable technologies. The included paper describes our process for evaluating data sources for the modeling, and presents five preliminary reV geothermal results. More specifically, we present two sets of resource data that represent upper and lower bounds for geothermal potential. We then present several sensitivity runs using the upper bound resource data; the results are encouraging that levelized cost of electricity (LCOE) can be reduced by optimizing the location and estimated capacity of the spatially diverse geothermal resource while considering the distance to existing grid infrastructure. Our preliminary supply curves and levelized cost of electricity (LCOE) results provided here should be considered with care due to the high uncertainty in geothermal resource potential data. We present median LCOE values for the conterminous U.S. for three scenarios: two hydrothermal (3.5km depth, USGS heat flow & SMU temperatures respectively) and one EGS (4.5km depth, SMU temperatures). The capital and operating costs for each respective technology are modeled. We also compare results using two different resource data sources.

15 GEOTHERMAL ENERGY↗

A biogenic secondary organic aerosol source of cirrus ice nucleating particles

Atmospheric ice nucleating particles (INPs) influence global climate by altering cloud formation, lifetime, and precipitation efficiency. The role of secondary organic aerosol (SOA) material as a source of INPs in the ambient atmosphere has not been well defined. Here, we demonstrate the potential for biogenic SOA to activate as depositional INPs in the upper troposphere by combining field measurements with laboratory experiments. Ambient INPs were measured in a remote mountaintop location at –46°C and an ice supersaturation of 30% with concentrations ranging from 0.1 to 70 L –1 . Concentrations of depositional INPs were positively correlated with the mass fractions and loadings of isoprene-derived secondary organic aerosols. Compositional analysis of ice residuals showed that ambient particles with isoprene-derived SOA material can act as depositional ice nuclei. Laboratory experiments further demonstrated the ability of isoprene-derived SOA to nucleate ice under a range of atmospheric conditions. We further show that ambient concentrations of isoprene-derived SOA can be competitive with other INP sources. This demonstrates that isoprene and potentially other biogenically-derived SOA materials could influence cirrus formation and properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Crowd-based spatial risk assessment of urban flooding: Results from a municipal flood hotline in Detroit, MI

Climate change is increasing the frequency and intensity of extreme precipitation events, raising the risk of urban flood disasters. This study uses a crowd-sourced municipal call database to characterize the spatial distribution of flood risk in Detroit, MI. Call data including dates and addresses were obtained from the City of Detroit Department of Public Works for 2021. Calls were mapped and aggregated to census tract counts and merged with neighborhood-level data. Associations of predictors with flood calls were tested using spatial regression models. Flooding calls were located throughout the city but were concentrated in specific areas. Multivariate models of census tract level call counts indicated that increased poverty and Black, immigrant, and older residents were positively associated with flood calls, while increased elevation was associated with protective effects. Longer distances from waste water interceptors were associated with higher risk for calls. Crowd-sourced flood hotline call data can be used for effective spatial flood risk assessment. Though flooding occurs throughout the city of Detroit, infrastructural, neighborhood, and household factors influence flooding extent. Limitations included the self-reported nature of calls. Future modeling efforts might include input from local stakeholders to improve spatial risk assessment.

54 ENVIRONMENTAL SCIENCES↗

The MolSSI QCArchive project: An open-source platform to compute, organize, and share quantum chemistry data

The Molecular Sciences Software Institute's (MolSSI) Quantum Chemistry Archive (QCArchive) project is an umbrella name that covers both a central server hosted by MolSSI for community data and the Python-based software infrastructure that powers automated computation and storage of quantum chemistry (QC) results. The MolSSI-hosted central server provides the computational molecular sciences community a location to freely access tens of millions of QC computations for machine learning, methodology assessment, force-field fitting, and more through a Python interface. Facile, user-friendly mining of the centrally archived quantum chemical data also can be achieved through web applications found at the website. The software infrastructure can be used as a standalone platform to compute, structure, and distribute hundreds of millions of QC computations for individuals or groups of researchers at any scale. The QCArchiveInfrastructure is open-source (BSD-3C), code repositories can be found at github, and releases can be downloaded via PyPI and Conda. This article is categorized under: Electronic Structure Theory > Ab Initio Electronic Structure Methods Software > Quantum Chemistry Data Science > Computer Algorithms and Programming

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Irrigation Modernization Task 4: Accelerating Energy Solutions (FY2022 Final Report)

This report offers insights on energy solutions for irrigation modernization that serve the needs of farmers as well as residents and industry in the local community. Solutions are found in the irrigation districts where local generation from renewable energy sources – solar, hydro, and wind – can be combined with energy storage and customer loads. These combined resources configured in microgrids can lower costs during peak loads and provide resiliency by maintaining electricity supply during outages. The goal of this project, as stated in the FY2022 AOP, is to promote realization of energy solutions that are tailored to physical location, community, infrastructure, and energy value streams. Further, it is to develop examples of how to increase value of, and overcome barriers to, energy solutions in the context of irrigation modernization. In pursuit of that goal, the project looked at options for: 1) Reducing the cost of energy consumed in irrigation systems, 2) Increasing the revenue from surplus power generation, and 3) Deploying new power generation configured as part of a local microgrid. Potential solutions to reducing energy costs and increasing surplus power revenue revolve around addressing regulatory and legal constraints tied to how power is purchased by and sold to the irrigator or irrigation district. Some headway was made in identifying barriers and ways to push utilities to be more accommodating to distributed energy sources; however, for the most part, real progress hinges on changes at the regulatory and legislative level. Deployment of local, renewable generation systems can be implemented provided the economics of the project and the location are favorable. In concert with Famers Conservation Alliance and Energy Trust of Oregon, a number of approaches were studied in the past year, including off-grid solar powered pumps, grid-tied community solar projects, and in-conduit canal hydropower systems. Ultimately three viable projects were identified: 1) North Unit Irrigation District/City of Redmond, Oregon Critical Facility Microgrid – offers combined in-conduit hydro and solar power generation. 2) Wallowa County/Joseph, Oregon Irrigation System Upgrades – centered on upgrades to a non-powered dam that will add a turbine as well as in-conduit power in canal feeders downstream. 3) Medford, Oregon Wastewater Treatment Plant Biogas Cogeneration System – centered on building out biogas storage and grid upgrades to power the plant, sell excess power, and provide emergency backup power (supplanting a diesel generator). Each of these projects has characteristics that broaden the understanding of the value of microgrids employing renewable energy to achieve resiliency and net-zero carbon goals. The first two projects are centered on new hydropower systems. Although the Medford project is only tangentially tied to an irrigation district, it was selected for study analysis as it was the only one mature enough (with sufficient data) to complete an analysis within this project year. Thus, we chose to move forward developing a case study, in concert with the Community Water-Power Resilience project, to demonstrate a method for evaluating such projects. Essentially, this case study serves as a template for studies to be carried out next year that more directly involve irrigation system hydropower, e.g., the project at the Wallowa County/Joseph, Oregon Irrigation System. Lastly, it is recognized that the locations and case studies in this report are all located in Oregon. We recognize this as a limitation. While the intent is not to ignore other states or regions, this result is driven by the fact that we have cultivated a collaboration with non-profit entities in Oregon that focus on these topics – Farmers Conservation Alliance and Energy Trust of Oregon. These partners were central to identifying projects that may be good fits for this program. A goal in the coming year is to establish collaboration with entities in other states/regions that, similarly, can connect us to potential projects in their geographic area. The potential benefits from the WPTO’s support for demonstration projects as energy solutions in irrigation districts include: (1) Alternative power supplies for communities and farms using renewable, carbon-free energy resources, (2) Cost savings for electricity for communities and farms, (3) Resiliency of power supplies for critical loads when electricity from the grid is not available, (4) Resiliency of power supplies for critical infrastructure in the event of catastrophic events, and (5) Demonstration of irrigation modernization projects that provide resilience and a reduced carbon footprint to irrigation districts and nearby communities. These deployments can serve as vanguards/archetypes spurring similar projects in other districts and states.

13 HYDRO ENERGY↗

A comparison of the power potential for surface- and seabed-deployed tidal turbines in the San Juan Archipelago, Salish Sea, WA

The San Juan archipelago lies along the axis of tidal movement between Straits of Juan de Fuca and Strait of Georgia in the Salish Sea. The amplitude of the tidal exchange produces significant tidal currents between the islands, as well as in Rosario and Haro Straits. These are of interest as a future source of electrical power generation, given the islands’ dependence on electricity supply by a subsea cable from the mainland. Here, we evaluate the tidal current energy potential in this region through a re-analysis of measurements collected by the National Ocean Service (NOS) and a high-resolution numerical model. Given the considerable variations in water depth and vertical velocity profiles across candidate tidal energy sites, we consider the trade-offs between tidal turbines deployed from a floating platform and those anchored to the seabed. Measurement re-analysis indicates several locations that could support tidal current power generation by MW-scale turbines with an acceptable balance between turbine size, rated power, and capacity factor. Even for relatively large (30 m) turbine diameters, surface-deployed turbines would be expected to produce up to 30 % more electricity than the same turbine deployed near the seabed due to vertical shear, with this difference increasing for smaller diameter turbines. A benchmark comparison at the measurement locations with the highest power generation potential shows relatively good model fidelity, though, even with relatively high resolution, time-average power density disagreements of ± 50 % persist throughout the water column. Nonetheless, the simulation identifies several locations with power generation potential more than twice as high as locations in the measurement re-analysis. These sites were either not surveyed by NOS or excluded due to data quality issues. Altogether, these results demonstrate the complimentary of models and measurements for tidal energy site assessment and suggest that tidal currents could be an important source of electricity generation in the San Juan archipelago.

16 TIDAL AND WAVE POWER↗

Ferroelastic Hysteresis in Thin Films of Methylammonium Lead Iodide

Mechanical strain can modify the structural and electronic properties of methylammonium lead iodide MAPbI 3 . The consequences of ferroelastic hysteresis, which involves the retention of structural memory upon cycles of deformation, are reported for polycrystalline thin films of MAPbI 3 . Repeatedly bent films were examined using grazing incidence wide-angle X-ray scattering (GIWAXS) to quantitatively characterize the strains and proportions of twin domains. Approximate locations for the coercive stress and saturation on the ferroelastic stress–strain curve are identified, and changes to the stress–strain curve with cyclic strain are characterized. Notably, an external stress source, such as thermal stress from the substrate or a roll-to-roll printing setup, must apply at least |50| MPa to modify the proportions of different twins. The presence of specific twin domains is found to correlate to previously reported strain and defect heterogeneity in MAPbI 3 films. Domains from differently strained twin sets interact with each other. Long-term stability testing reveals that the domain walls are highly immobile over extended periods. Nucleation of new domain walls occurs for specific mechanical strains and correlates closely with degradation. Furthermore, these results help to explain the behavior of ion migration, degradation rate, and photoluminescence in thin films under compressive and tensile strain.

Defects↗