Measurements of O(1 D) quenching rates in the F-region
In-situ determinations of the quenching of O(1 D) atoms by N2 and O2 molecules were made from observations of 6300 A nightglow intensity enhancements produced by the Platteville 1.6 MW transmitter. The heating of F-region electrons near the point of reflection of the RF wave leads to electron impact excitation of oxygen atoms to the O(1 D) state. It is shown that the resulting region of enhance 6300 A emission is localized to the region of electron energy absorption for heating at the lower altitudes. At 225 km the measured time constants for intensity buildup following transmitter turn-on and for intensity decay following turn-off are identical and equal to (13 plus or minus 1) sec. Time constants varying from 30 to 80 sec are found for the altitude range 260 to 300 km. The inferred quenching coefficient for the whole altitude range, 225 to 300 km, is 4.4 + 2 or - 1 x 10 to the minus 11th power cu cm/sec at 950 K, in good agreement with laboratory data. The quenching frequency obtained at 225 km, when referred to the altitude 120 km, is equal to (21 plus or minus 2)/sec, in agreement with less direct ionospheric determinations.