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At least 919 records · Page 51

All sources NASA NTRS DOE OSTI

DOE OSTI2019

Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in polymeric matrix

A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

Vautard, Frederic↗

DOE OSTI2019

Solid composites containing polymeric matrix with carbon fibers embedded therein

A functionalized carbon fiber having covalently bound on its surface a partially cured epoxy or amine-containing sizing agent, wherein at least a portion of epoxide or amine groups in the sizing agent are available as uncrosslinked epoxide or amine groups, which corresponds to a curing degree of epoxide or amine groups of no more than about 0.6. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Shape-preserving polymeric replication of biological matter

The present invention relates to a method of forming silica nanolayers on or within a biological sample, thereby capturing structural details that are present in the sample. The resultant silica composite or silica replica, in turn, can be employed as a template for a replica having those structural details captured in a polymer. Also provided herein are synthetic constructs including a polymeric replica, which can have any useful feature (e.g., oxygen-binding capacity).

36 MATERIALS SCIENCE↗

DOE OSTI2020

Mechanical reticulation of polymeric-based closed cell foams

Polymeric based closed cell foams, such as shape memory polymer foams, contain bubbles. Making these bubbles continuous is called reticulation. Disclosed are embodiments of a device and method to controllably reticulate polymer-based closed cell foams by puncturing the membranes of these polymer-based closed cell foams.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Optically clear photo-polymerization resists for additive manufacturing of radiopaque parts

According to one embodiment, a method includes contacting a triiodobenzoic acid with an oxalyl chloride in a solvent whereby triiodobenzoyl chloride is formed, contacting diethanolamine with triiodobenzoyl chloride where triiodobenzoic diol amine is formed, and forming an acrylate of triiodobenzoic diol amine with acryloyl chloride where an organoiodine compound is formed. According to another embodiment, an optically clear photopolymer resist blend for additive manufacturing includes a radiopaque pre-polymer compound where the compound includes at least one of the following: iodine, bromine, tin, lead, or bismuth. The resist blend also includes a photoinitiator, a polymerization inhibitor, and a base pre-polymer.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Study on Fracture of Fiber-Reinforced Polymeric Composites Using Spiral Notch Torsion Test

Fiber-reinforced polymer-matrix composites have been widely applied in various areas due to their excellent mechanical properties. In this study, carbon fiber-reinforced polymer-matrix composites and glass fiber-reinforced polymer-matrix composites failure tests under quasi static torsion have been demonstrated by using spiral notch torsion test methodology. Three types of cylindrical specimens with different fiber orientations were prepared and tested. For both composites, after increase stage, A type exhibited limited stress variations before the sudden failure, whereas B type showed gradual failure with torque drops. Displacement contours, stress contours and energy release rates were acquired using the anisotropic elastic finite element models. Microscopic characterization exhibited that the failure of A type occurred along interfaces between fibers and matrices, whereas circular cracks in B type propagated alternatively between polymeric matrices and interfaces. Type C failure is similar to type A whereas with a curvature observed on the fracture surface.

Du, Fen↗

DOE OSTI2021

Shape-preserving polymeric replication of biological matter

Kaehr, Bryan James↗

DOE OSTI2021

Perspectives in Scanning Probe Microscopy from the 2021 Joint International Scanning Probe Microscopy and Scanning Probe Microscopy on Soft and Polymeric Materials Conference

In March of 2020 we were well on our way to organizing and hosting one of the premier scanning probe microscopy (SPM) conferences in Breckenridge, Colorado, USA. For the first time, the meeting would synergistically combine International Scanning Probe Microscopy (ISPM) and Scanning Probe Microscopy on Soft and Polymeric Materials (SPMonSPM), to increase the breadth of audience expertise and experience. We coined the joint conference iSPM 3 – a moniker we hope will persist in future events. The plan for 2020 iSPM 3 screeched to a halt in mid-March, amidst the COVID-19 pandemic. Luckily, we were able to regroup and reimagine the conference for 2021 as a virtual experience. The conference took place June 28th to July 2nd with a mix of live and pre-recorded content. Spread throughout the week were 4 live panel discussions, 3 plenary talks, 23 invited talks, 75 contributed talks, 15 posters and 3 social events. The technical program represented much of the latest and most impactful research in the field. The panel discussions sought to step back from specific research findings and assess the state of SPM as it pertains to some of the most pressing opportunities and influential successes. The lively discussions painted a vibrant future for SPM in both breadth and detail, and we hope that similar discussion can be a mainstay of future SPM conferences. In this work, we attempt to distill some of that discussion to motivate researchers across the field of SPM in the coming years.

47 OTHER INSTRUMENTATION↗

DOE OSTI2022

Mechanical reticulation of polymeric-based closed cell foams

Rodriguez, Jennifer N.↗

DOE OSTI2022

In-situ polymerization to protect lithium metal electrodes

An electrode including an electrode active material including lithium (Li) and a polymer layer coating at least a portion of the electrode active material is provided. The polymer layer includes a polymerization product of a monomer having Formula I: where R1 and R2 are independently an aryl or a branched or unbranched C1-C10 alkyl and X1 and X2 are independently chlorine (Cl), bromine (Br), or iodine (I).

Li, Binsong↗

DOE OSTI2023

Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing

Disclosed herein are embodiments of a composition that can be used to make liquid crystalline networks using thiol-ene-based polymerization. In particular embodiments, the liquid crystalline networks can be formed by using the composition embodiments in additive manufacturing methods. The composition comprises a monomer, chain extender compound, and a crosslinker compound and each of these components can be selected so as to influence the thermomechanical and shape memory properties of the liquid crystalline networks and/or objects formed therewith.

Rios, Orlando↗

DOE OSTI2023

Emulsion polymerization of nitriles and other compounds

The present disclosure relates to a method that includes polymerizing a nitrile with an acrylate ester to form a copolymer, in a mixture that includes water and an alcohol (R 2 —OH), according to the following reaction where R 1 includes at least one of a first aliphatic group or hydrogen, R 2 comprises at least one of a second aliphatic group or hydrogen, 100≤m≤4000, and 1≤n≤4000. In some embodiments of the present disclosure, the mixture may be an emulsion.

Meek, Kelly Marie↗

DOE OSTI2023

Use of latent metathesis polymerization systems for photopolymerization-based additive manufacturing

Photolatent olefin metathesis catalysts can be used in combination with metathesis-active monomers or resins for photopolymerization-based additive manufacturing via ring-opening metathesis polymerization (ROMP). A variety of alternative catalysts and photosensitizers are commercially available that allows for tuning of thermomechanical properties, potlifes, activation rates, and irradiation wavelengths. As an example, two optimized catalyst/photosensitizer systems were demonstrated in the rapid stereolithographic printing of complex, multidimensional poly-dicyclopentadiene structures with microscale features under ambient conditions.

Leguizamon, Samuel↗

DOE OSTI2023

Use of latent metathesis polymerization systems for additive manufacturing

The invention is directed to latent metathesis-active resin compositions and additive manufacturing approaches. The latent metathesis-active compositions comprise at least one latent metathesis catalyst, at least one curable metathesis-active monomer, and optional fillers, photosensitizers, and/or a secondary monomer resin system for dual-cure. A method comprises extruding a latent metathesis-active resin from a dispensing apparatus and spatially triggering a ring-opening metathesis polymerization by directed irradiation with light or directed application of a thermal stimuli for direct-ink write printing of objects. Another method uses a latent metathesis-active resin for vat photopolymerization and stereolithographic printing of objects.

Appelhans, Leah↗

DOE OSTI2024