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At least 919 records · Page 51

Atmospheric Gases as Quantitative Indicators of Urbanization Across Land-Use Gradients

The urban heat island (UHI) effect is a significant phenomenon characterized by higher surface temperatures in cities compared to surrounding rural areas. This change in the Earth's energy balance presents considerable challenges for urban populations, increasing heat exposure, straining energy infrastructure, and exacerbating health vulnerabilities. Quantifying UHI intensity is challenging due to blurred distinctions between urban and rural areas as land-use patterns evolve. To address this challenge, the present study builds on the framework established by Salvador et al. (2025) and investigates the use of atmospheric constituents, specifically volatile organic compounds (VOCs) and inorganic gases, as tracers of urbanization levels. A key improvement in this approach is the inclusion of a designated true rural site for comparison. Field measurements were conducted at two locations in the Southeastern United States during the summer of 2025. Inorganic gases were monitored continuously, while VOC samples were collected biweekly and analyzed using a proton transfer reaction time-of-flight mass spectrometer. The urban site exhibited elevated concentrations of anthropogenic inorganic gases, with carbon monoxide and nitrogen dioxide averaging 878 ppb and 17.99 ppb, respectively. In contrast, the rural site showed lower levels of these pollutants, 796 ppb for carbon monoxide and 12.46 ppb for nitrogen dioxide, while displaying higher concentrations of biogenic VOCs, including isoprene and monoterpenes at 1.24 ppb and 0.08 ppb, respectively. Extended mass spectral analyses revealed distinct chemical differences between the two sites, supporting the observed variability of major gases. Overall, these findings are consistent with our previous research and highlight the value of atmospheric constituents as effective indicators of urbanization, thereby improving our understanding of UHI dynamics.

54 ENVIRONMENTAL SCIENCES↗

Regional climate change predictions from the Goddard Institute for Space Studies high resolution GCM

Model simulations of global climate change are seen as an essential component of any program aimed at understanding human impact on the global environment. A major weakness of current general circulation models (GCMs), however, is their inability to predict reliably the regional consequences of a global scale change, and it is these regional scale predictions that are necessary for studies of human/environmental response. This research is directed toward the development of a methodology for the validation of the synoptic scale climatology of GCMs. This is developed with regard to the Goddard Institute for Space Studies (GISS) GCM Model 2, with the specific objective of using the synoptic circulation form a doubles CO2 simulation to estimate regional climate change over North America, south of Hudson Bay. This progress report is specifically concerned with validating the synoptic climatology of the GISS GCM, and developing the transfer function to derive grid-point temperatures from the synoptic circulation. Principal Components Analysis is used to characterize the primary modes of the spatial and temporal variability in the observed and simulated climate, and the model validation is based on correlations between component loadings, and power spectral analysis of the component scores. The results show that the high resolution GISS model does an excellent job of simulating the synoptic circulation over the U.S., and that grid-point temperatures can be predicted with reasonable accuracy from the circulation patterns.

Crane, Robert G.↗

NASA Tech Briefs, October 2007

Topics covered include; Wirelessly Interrogated Position or Displacement Sensors; Ka-Band Radar Terminal Descent Sensor; Metal/Metal Oxide Differential Electrode pH Sensors; Improved Sensing Coils for SQUIDs; Inductive Linear-Position Sensor/Limit-Sensor Units; Hilbert-Curve Fractal Antenna With Radiation- Pattern Diversity; Single-Camera Panoramic-Imaging Systems; Interface Electronic Circuitry for an Electronic Tongue; Inexpensive Clock for Displaying Planetary or Sidereal Time; Efficient Switching Arrangement for (N + 1)/N Redundancy; Lightweight Reflectarray Antenna for 7.115 and 32 GHz; Opto-Electronic Oscillator Using Suppressed Phase Modulation; Alternative Controller for a Fiber-Optic Switch; Strong, Lightweight, Porous Materials; Nanowicks; Lightweight Thermal Protection System for Atmospheric Entry; Rapid and Quiet Drill; Hydrogen Peroxide Concentrator; MMIC Amplifiers for 90 to 130 GHz; Robot Would Climb Steep Terrain; Measuring Dynamic Transfer Functions of Cavitating Pumps; Advanced Resistive Exercise Device; Rapid Engineering of Three-Dimensional, Multicellular Tissues With Polymeric Scaffolds; Resonant Tunneling Spin Pump; Enhancing Spin Filters by Use of Bulk Inversion Asymmetry; Optical Magnetometer Incorporating Photonic Crystals; WGM-Resonator/Tapered-Waveguide White-Light Sensor Optics; Raman-Suppressing Coupling for Optical Parametric Oscillator; CO2-Reduction Primary Cell for Use on Venus; Cold Atom Source Containing Multiple Magneto- Optical Traps; POD Model Reconstruction for Gray-Box Fault Detection; System for Estimating Horizontal Velocity During Descent; Software Framework for Peer Data-Management Services; Autogen Version 2.0; Tracking-Data-Conversion Tool; NASA Enterprise Visual Analysis; Advanced Reference Counting Pointers for Better Performance; C Namelist Facility; and Efficient Mosaicking of Spitzer Space Telescope Images.

Source record↗

Experimental Investigation of Roughness Effects on Transition Onset and Turbulent Heating Augmentation on a Hemisphere at Mach 6 and Mach 10

An experimental investigation of the effects of distributed surface roughness on boundary-layer transition and turbulent heating has been conducted. Hypersonic wind tunnel testing was performed using hemispherical models with surface roughness patterns simulating those produced by heat shield ablation. Global aeroheating and transition onset data were obtained using phosphor thermography at Mach 6 and Mach 10 over a range of roughness heights and free stream Reynolds numbers sufficient to produce laminar, transitional and turbulent flow. Upstream movement of the transition onset location and increasing heating augmentation over predicted smooth-wall levels were observed with both increasing roughness heights and increasing free stream Reynolds numbers. The experimental heating data are presented herein, as are comparisons to smooth-wall heat transfer distributions from computational flow-field simulations. The transition onset data are also tabulated, and correlations of these data are presented.

Hollis, Brian R.↗

NeuroSEM: A hybrid framework for simulating multiphysics problems by coupling PINNs and spectral elements

Multiphysics problems that are characterized by complex interactions among fluid dynamics, heat transfer, structural mechanics, and electromagnetics, are inherently challenging due to their coupled nature. While experimental data on certain state variables may be available, integrating these data with numerical solvers remains a significant challenge. Physics-informed neural networks (PINNs) have shown promising results in various engineering disciplines, particularly in handling noisy data and solving inverse problems in partial differential equations (PDEs). However, their effectiveness in forecasting nonlinear phenomena in multiphysics regimes, particularly involving turbulence, is yet to be fully established. Here, this study introduces NeuroSEM, a hybrid framework integrating PINNs with the highfidelity Spectral Element Method (SEM) solver, Nektar++. NeuroSEM leverages the strengths of both PINNs and SEM, providing robust solutions for multiphysics problems. PINNs are trained to assimilate data and model physical phenomena in specific subdomains, which are then integrated into the Nektar++ solver. We demonstrate the efficiency and accuracy of NeuroSEM for thermal convection in cavity flow and flow past a cylinder. The framework effectively handles data assimilation by addressing those subdomains and state variables where the data is available. We applied NeuroSEM to the Rayleigh-B´enard convection system, including cases with missing thermal boundary conditions and noisy datasets. Finally, we applied the proposed NeuroSEM framework to real particle image velocimetry (PIV) data to capture flow patterns characterized by horseshoe vortical structures. Our results indicate that NeuroSEM accurately models the physical phenomena and assimilates the data within the specified subdomains. The framework’s plug-and-play nature facilitates its extension to other multiphysics or multiscale problems. Furthermore, NeuroSEM is optimized for efficient execution on emerging integrated GPU-CPU architectures. This hybrid approach enhances the accuracy and efficiency of simulations, making it a powerful tool for tackling complex engineering challenges in various scientific domains.

42 ENGINEERING↗

Integration of High-Resolution Mass Spectrometry with Cryogenic Ion Vibrational Spectroscopy

We describe an instrumental configuration for the structural characterization of fragment ions generated by collisional dissociation of peptide ions in the typical MS{sup 2} scheme widely used for peptide sequencing. Structures are determined by comparing the vibrational band patterns displayed by cryogenically cooled ions with calculated spectra for candidate structural isomers. These spectra were obtained in a linear action mode by photodissociation of weakly bound D{sub 2} molecules. This is accomplished by interfacing a Thermo Fisher Scientific Orbitrap Velos Pro to a cryogenic, triple focusing time-of-flight photofragmentation mass spectrometer (the Yale TOF spectrometer). The interface involves replacement of the Orbitrap’s higher-energy collisional dissociation cell with a voltage-gated aperture that maintains the commercial instrument’s standard capabilities while enabling bidirectional transfer of ions between the high-resolution FT analyzer and external ion sources. The performance of this hybrid instrument is demonstrated by its application to the a{sub 1}, y{sub 1} and z{sub 1} fragment ions generated by CID of a prototypical dipeptide precursor, protonated L-phenylalanyl-L-tyrosine (H{sup +}-Phe-Tyr-OH or FY-H{sup +}). The structure of the unusual z{sub 1} ion, nominally formed after NH{sub 3} is ejected from the protonated tyrosine (y{sub 1}) product, is identified as the cyclopropane-based product is tentatively identified as a cyclopropane-based product. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Ion Clusters Reveal the Sources, Impacts, and Drivers of Freshwater Salinization

Population growth, land use change, climate change, and natural resource extraction are driving the salinization of freshwater resources worldwide. Reversing these trends will require data-centric approaches that identify salt sources, environmental drivers, and ecosystem responses. In this study, we applied principal component analysis and hierarchical clustering to identify ion covariance patterns, or “ion clusters,” in Broad Run, an urban stream in the Mid-Atlantic United States. These clusters correspond to distinct hydrologic regimes and reveal specific salinization risks: (1) phosphorus pollution mobilized during summer storms (Cluster 1); (2) elevated concentrations of sulfate and bicarbonate during baseflow (Cluster 2), likely reflecting groundwater discharge; and (3) elevated specific conductance and sodium, chloride, and potassium ion concentrations during snowmelt and rain-on-snow events (Cluster 3), driven by deicer and anti-icer wash-off. These ion fingerprints offer a transferable framework for diagnosing salt sources, assessing ecological risk, and identifying management targets. Our findings underscore the need for next-generation stormwater infrastructure and smart growth policies to protect aquatic life in rapidly urbanizing watersheds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Neural Network Aero Design System for Advanced Turbo-Engines

An inverse design method calculates the blade shape that produces a prescribed input pressure distribution. By controlling this input pressure distribution the aerodynamic design objectives can easily be met. Because of the intrinsic relationship between pressure distribution and airfoil physical properties, a Neural Network can be trained to choose the optimal pressure distribution that would meet a set of physical requirements. Neural network systems have been attempted in the context of direct design methods. From properties ascribed to a set of blades the neural network is trained to infer the properties of an 'interpolated' blade shape. The problem is that, especially in transonic regimes where we deal with intrinsically non linear and ill posed problems, small perturbations of the blade shape can produce very large variations of the flow parameters. It is very unlikely that, under these circumstances, a neural network will be able to find the proper solution. The unique situation in the present method is that the neural network can be trained to extract the required input pressure distribution from a database of pressure distributions while the inverse method will still compute the exact blade shape that corresponds to this 'interpolated' input pressure distribution. In other words, the interpolation process is transferred to a smoother problem, namely, finding what pressure distribution would produce the required flow conditions and, once this is done, the inverse method will compute the exact solution for this problem. The use of neural network is, in this context, highly related to the use of proper optimization techniques. The optimization is used essentially as an automation procedure to force the input pressure distributions to achieve the required aero and structural design parameters. A multilayered feed forward network with back-propagation is used to train the system for pattern association and classification.

Sanz, Jose M.↗

Magnetic contribution of itinerant electrons to neutron diffraction in the topological antiferromagnet CeAlGe

We report a neutron diffraction study of the magnetic structure of CeAlGe, a candidate topological semimetal that hosts a noncollinear, multi-𝐤 magnetic phase. By measuring both low- and high-momentum-transfer magnetic Bragg peaks within a single experimental setup, we refine a magnetic structure model based solely on localized Ce moments. This model, which differs from that obtained using only high-𝑄 data, quantitatively reproduces the observed intensities, including the (000) zeroth-order magnetic satellites that are especially sensitive to subtle components of the modulation. While a contribution from itinerant electrons to the zeroth satellite cannot be definitively excluded, our analysis reveals no unambiguous evidence for such effects within experimental uncertainty. The refined magnetic structures exhibit topologically nontrivial winding patterns, derived from the fitted magnetic parameters, that support localized, particle-like spin textures with half-integer topological charges. These features provide a natural microscopic origin for the observed topological Hall effect, establishing CeAlGe as a model system where magnetism and topology are intimately linked.

Magnetic coupling↗

Solar wind dynamic pressure variations and possible ground signatures of flux transfer events

The effects of a series of solar wind dynamic pressure pulses are followed through the solar wind, across the bow shock and magnetosheath, into the magnetosphere, and down to the dayside ionosphere. Each pressure pulse had an intrinsic solar wind origin, i.e., was not generated by processes occurring at the earth's bow shock. Both upstream and downstream of the earth's bow shock, the pulses were identified by depressed magnetic field strengths and enhanced plasma densities. The pulses compressed the magnetosheath and magnetosphere, causing satellites in the magnetosphere to briefly observe enhanced magnetic field strengths, and/or enter the low-latitude boundary layer or magnetosheath. Satellites already in the magnetosheath observed a brief burst of enhanced magnetosheath flow caused by the relative inward motion of magnetosheath flow patterns. Alfven and fast mode compressional waves propagated rapidly down to the polar ionosphere, where they produced transient ionospheric flows at latitudes equatorward of the convection reversal boundary. The flow patterns moved westward around the auroral oval.

Sibeck, D. G.↗

Numerical simulations of drainage flows on Mars

Data collected by Viking Landers have shown that the meteorology of the near surface Martian environment is analogous to desertlike terrestrial conditions. Geological evidence such as dunes and frost streaks indicate that the surface wind is a potentially important factor in scouring of the martian landscape. In particular, the north polar basin shows erosional features that suggest katabatic wind convergence into broad valleys near the margin of the polar cap. The pattern of katabatic wind drainage off the north polar cap is similar to that observed on Earth over Antarctica or Greenland. The sensitivity is explored of Martian drainage flows to variations in terrain slope and diurnal heating using a numerical modeling approach. The model used is a 2-D sigma coordinate primitive equation system that has been used for simulations of Antarctic drainage flows. Prognostic equations include the flux forms of the horizontal scalar momentum equations, temperature, and continuity. Parameterization of both longwave (terrestrial) and shortwave (solar) radiation is included. Turbulent transfer of heat and momentum in the Martian atmosphere remains uncertain since relevant measurements are essentially nonexistent.

Parish, Thomas R.↗

A circadian rhythm of conidiation in Neurospora crassa (L-12)

Two fungi growth chambers containing six growth tubes each are used in this experiment. One chamber is for the space experiment; the other is for the simultaneous ground control experiment. The hyphae of Neurospora crassa band A mutant are inoculated at one end of each tube. Both the chambers are kept at 3 C plus or minus 1.5 C to stop hyphae growth until the Spacelab is activated. After the activation, each chamber is transferred simultaneously to the Spacelab and a phytotron in KSC and kept in continuous light at the same temperature. After about 24 hours of light exposure, each chamber is inserted into a growth chamber bag to keep it in constant darkness. The circadian rhythm of conidiation is initiated by this light to dark transition. After the dark incubation for 5 days at room temperature, both the growth chambers are kept at 3 C plus or minus 1.5 C to stop growth of the hyphae. After the space shuttle lands, both conidiation patterns are compared and analyzed. It has been known that numerous physiological phenomena show circadian rhythms. They are characterized by the fact that the oscillation can persist under constant conditions of light and temperature. Therefore, it has been accepted by most investigators that the generation mechanism of the circadian rhythm is endogeneous. However, one cannot reject the possibility that these rhythms are caused by some geophysical exogeneous factor having a 24-hour period, such as atmospheric pressure, gravity, or electromagnetic radiation. We use Neurospora crassa band A mutual which shows an obvious circadian rhythm in its spore-forming (conidiation) on the ground, and we intend to attempt the conidation of this mutant in the Spacelab where 24-hour periodicity is severely attenuated and to elucidate the effect of the geophysical exogeneous factor in the generation mechanism of the circadian rhythm.

Miyoshi, Yashuhiro↗

Transients and Dayside Magnetospheric Interactions

Observations at and deep within the Earth’s dayside magnetosphere provide considerable evidence indicating that the solar wind-magnetosphere interaction is often unsteady. Bursty reconnection resulting in the formation of flux transfer events and transient auroral brightenings is common. Fluctuations in solar wind parameters may trigger some bursts of reconnection, while other bursts may result from intrinsic magnetopause instabilities. Large amplitude solitons often travel along the dayside magnetopause. Deeper within the dayside magnetosphere, quasi-periodic transient compressions energize radiation belt electrons and ring current ions. Most of these perturbations occur behind the quasi-parallel bow shock, indicating that they are driven by density structures generated by kinetic processes within the foreshock. This presentation compares and contrasts the amplitudes and occurrence patterns of density and dynamic pressure perturbations intrinsic to the solar wind with those generated within the foreshock, specifies how they move across the magnetosphere, examines recent global MHD simulation results for their interaction with the bow shock, magnetosheath, and magnetopause. It then outlines new paths toward quantifying the significance of bursty reconnection to the overall interaction, via new imaging and analysis techniques.

D. G. Sibeck↗

Computational experiments to characterize bubble formation and movement in waste glass foam layer

Computer simulation experiments are a valuable complement to physical experimentation for systems where there is limited access to quantities of interest. The motivation for this work is to characterize the fluid dynamic and heat transfer processes that affect melt rate of waste slurry during vitrification, which can limit the throughput rate of the melter. Heat transfer to the cold cap from the molten glass below this layer is an important factor determining melt rate. In this study, computational fluid dynamics is used to elucidate the behavior of gas-filled cavities that form underneath the cold cap in a laboratory-scale waste glass melter. The cold cap consists of a reacting feed layer above a foam layer. The cavities are a result of coalesced gases from collapsing primary foam and air from forced convection bubblers. Bubbles in the foam layer move horizontally with the circulation pattern of the melt and escape around the edges of the cold cap to the plenum above. The effects of varying thermophysical properties and foam parameters based on the bounds of high-level waste glass formulations were explored. Using the DAKOTA toolkit, a Latin hypercube space-filling design was used to randomly distribute samples in bins to achieve good coverage over the parameter space with minimal points. Using the results from the set of simulations, a Gaussian process model with a linear trend was used to create response surfaces for several key quantities of interest, including temperatures, temperature gradients, velocities, and foam extent beneath the cold cap.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Validation of Aquarius Measurements Using Radiative Transfer Models at L-Band

Aquarius/SAC-D was launched in June 2011 by NASA and CONAE (Argentine space agency). Aquarius includes three L-band (1.4 GHz) radiometers dedicated to measuring sea surface salinity. We report detailed comparisons of Aquarius measurements with radiative transfer model predictions. These comparisons were used as part ofthe initial assessment of Aquarius data. In particular, they were used successfully to estimate the radiometer calibration bias and stability. Further comparisons are being performed to assess the performance of models in the retrieval algorithm for correcting the effect of sources of geophysical "noise" (e.g. the galactic background, atmospheric attenuation and reflected signal from the Sun). Such corrections are critical in bringing the error in retrieved salinity down to the required 0.2 practical salinity unit (psu) on monthly global maps at 150 km by 150 km resolution. The forward models making up the Aquarius simulator have been very useful for preparatory studies in the years leading to Aquarius' launch. The simulator includes various components to compute effects ofthe following processes on the measured signal: 1) emission from Earth surfaces (ocean, land, ice), 2) atmospheric emission and absorption, 3) emission from the Sun, Moon and celestial Sky (directly through the antenna sidelobes or after reflection/scattering at the Earth surface), 4) Faraday rotation, and 5) convolution of the scene by the antenna gain patterns. Since the Aquarius radiometers tum-on in late July 2011, the simulator has been used to perform a first order validation of the data. This included checking the order of magnitude ofthe signal over ocean, land and ice surfaces, checking the relative amplitude of signal at different polarizations, and checking the variation with incidence angle. The comparisons were also used to assess calibration bias and monitor instruments calibration drift. The simulator is also being used in the salinity retrieval. For example, initial assessments of the salinity retrieved from Aquarius data showed degradation in accuracy at locations where glint from the galactic sky background was important. This was traced to an inaccurate correction for the Sky glint. We present comparisons of the simulator prediction to the Aquarius data in order to assess the performances of the models of various physical processes impacting the measurements, such as the effect of sea surface roughness, the impact of the celestial Sky and the Sun emission scattered at the rough ocean surface. We discuss what components of the simulator appear reliable and which ones need improvements. Improved knowledge on the radiative transfer models at L-band will not only lead to better salinity retrieved from Aquarius data, it will also allow be beneficial for SMOS or the upcoming SMAP mission.

Dinnat, E.↗

Highly Ordered Eutectic Mesostructures via Template‐Directed Solidification within Thermally Engineered Templates

Template-directed self-assembly of solidifying eutectics results in emergence of unique microstructures due to diffusion constraints and thermal gradients imposed by the template. Here, the importance of selecting the template material based on its conductivity to control heat transfer between the template and the solidifying eutectic, and thus the thermal gradients near the solidification front, is demonstrated. Simulations elucidate the relationship between the thermal properties of the eutectic and template and the resultant microstructure. The overarching finding is that templates with low thermal conductivities are generally advantageous for forming highly organized microstructures. When electrochemically porosified silicon pillars (thermal conductivity < 0.3 Wm −1 K −1 ) are used as the template into which an AgCl-KCl eutectic is solidified, 99% of the unit cells in the solidified structure exhibit the same pattern. In contrast, when higher thermal conductivity crystalline silicon pillars (≈100 Wm −1 K −1 ) are utilized, the expected pattern is only present in 50% of the unit cells. The thermally engineered template results in mesostructures with tunable optical properties and reflectances nearly identical to the simulated reflectances of perfect structures, indicating highly ordered patterns are formed over large areas. This work highlights the importance of controlling heat flows in template-directed self-assembly of eutectics.

36 MATERIALS SCIENCE↗

Accurate determination of chemical abundances near a supermassive black hole

The metal abundances in galactic nuclei carry key information on the history of star formation and mass transfer in central regions of galaxies. X-ray fluorescence analysis is a unique tool to reliably measure the abundances of various elements via simple physics. Here we present a new observation of the active nucleus in the Circinus galaxy with the XRISM satellite at unprecedented X-ray energy resolution. The fluorescent iron Kα line profile modified by Compton scattering indicates that the material responsible for its emission is cold and metal rich and is located ≳0.024 pc from the supermassive black hole, consistent with the dusty torus region. The abundance pattern derived from comparing fluorescent line intensities of different metals shows subsolar ratios of argon- and calcium-to-iron and a supersolar ratio of nickel-to-iron. This abundance pattern is best produced by a combination in number fraction of 92$^{+2}_{–4}$% core-collapse supernovae from progenitor stars less massive than 20$^{+3}_{–2}$ M ⊙ and 8$^{+4}_{–2}$% type Ia supernovae. This suggests that gas feeding the supermassive black hole was enriched by recent core-collapse supernovae. Our findings imply that in metal-rich environments stars more massive than about 20 M ⊙ directly collapse into black holes or make faint supernovae without ejecting heavy metals into the space.

Astronomy and AstroPhysics↗