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Silane has been detected in the gas surrounding IRC +10216. Thirteen absorption lines in the nu-4 band around 917/cm were observed at 0.2 km/s resolution. A lower limit to the radial column density is 2 x 10 to the 15th/sq cm, and the relative strengths of the transitions indicate an average rotational temperature of 173 K.
A phenomenological multiple-relaxation theory of the deactivation rate constant for the nu-2 (1 - 0) bending mode of water vapor is presented which incorporates the role not only of the excited monomer but also of the bound molecular complex, in particular the dimer. The deactivation takes place by means of three parallel processes: (1) collisional deexcitation of the excited monomer, (2) a two-step reaction involving association and spontaneous redissociation of an H2O collision complex, and (3) spontaneous dissociation of the stably bound H2O dimer. Oxygen, but not nitrogen or argon, serves as an effective chaperon for the formation of the activated complex. This observation explains the impurity dependence of the self-deactivation rate constant of water vapor. Analysis of an ultrasonic absorption peak based on the third process yields values for the standard entropy and enthalpy of dissociation of the stably bound H2O dimer.
The result of a new calculation of the atmospheric muon and neutrino fluxes and the energy spectrum of muon-neutrinos produced in individual extensive air showers (EAS) initiated by proton and gamma-ray primaries is reported. Also explained is the possibility of detecting atmospheric nu sub mu's due to gamma-rays from these sources.
Line parameters for the nu(5) and 2nu(9) bands and associated hot bands of HNO3 have been calculated and compared with laboratory spectra, and the results are presented. Spectral intervals near 870/cm for which best agreement was obtained are used to quantitatively analyze HNO3 absorption features in 0.02/cm resolution stratospheric solar absorption spectra.
A number of lines belonging to the nu(3) fundamental vibration-rotation band of hydrogen cyanide (HCN) have been identified in atmospheric infrared absorption spectra obtained on high-altitude balloon flights at 32 deg N in 1976 and at 30 deg S in 1977. Quantitative analysis of these spectral features has resulted in the first determination of atmospheric HCN concentrations in the Southern Hemisphere, as well as an independent estimate of stratospheric HCN abundance in the Northern Hemisphere. Within the uncertainties of the present and previous measurements, the Northern Hemisphere result is consistent with those of other investigators, and Southern Hemisphere HCN concentrations appear to be similar to those in the Northern Hemisphere.
A number of prominent Q-branches of the nu-7 band of C2H6 have been identified near 3000/cm in aircraft and ground-based infrared solar absorption spectra. The aircraft spectra provide the column amount above 12 km at various altitudes. The column amount is strongly correlated with tropopause height and can be described by a constant mixing ratio of 0.46 ppbv in the upper troposphere and a mixing ratio scale height of 3.9 km above the tropopause. The ground-based spectra yield a column of 9.0 x 10 to the 15th molecules/sq cm above 2.1 km; combining these results implies a tropospheric mixing ratio of approximately 0.63 ppbv.
The absolute accuracies of infrared calibration standards for the line positions have been investigated using a 0.0056-kayser-resolution (unapodized) Fourier-transform spectrum recorded from 550 to 5000 kayser. The spectrum has been obtained using a multicell arrangement containing the various molecular species. Detailed comoparisons reveal that standards for CO2, CH4, and N2O obtained from laser research and NH3 from Fourier-transform spectrometer research are consistent within the accuracies of the present data (+ or 0.0001 kayser). However, certain N2O, H2O, and CO values in the 1100-to 2300 kayser region are systematically high by 0.0001 to 0.0004 kayser. Correction factors for the H2O and CO standards are obtained to bring these into agreement with the laser values. In addition, corrected values for the 2nu-2 and nu-1 bands of N2O at 9 microns are reported.
The orbital evolution of asteroidal fragments injected into the 3-1 Kirkwood gap resonance at 2.5 AU is investigated on the basis of a Monte Carlo simulation. The diameters of the fragments in the simulation were between 10 cm and 20 km, and it was assumed that the fragments cross the orbital path of the earth every one million years. The effects of close encounter planetary perturbations, the nu dot 6 secular resonance, and the ablative effects of the earth atmosphere were also taken into account. It is found that: (1) the predicted meteorite orbits closely matched the known orbits of ordinary chondrites; and (2) the total flux was in approximate agreement with the observed fall rate of ordinary chondrites. About 90 percent of the predicted impacting bodies were created by fragmentation of larger earth crossing asteroidal fragments, the largest of which were observed in the vicinity of the Apollo-Amor objects. The numerical results are presented in a series of graphs.
The dynamical, chemical, and thermal evolution of zero-metal gas clouds was modeled to study conditions of star formation in the early universe. Numerical results are given for the collapse of spherical clouds of mass 1000 and 50000 solar mass. Cooling by H2 lines and by photons emitted in H + e(-) yields H(-) = h (sup nu) maintains collapse until formation of an equilibrium protostellar core of mass 0.02 solar mass. The cooling by photons produced with H is essential for low mass star formation. If the cloud is fragmented, the evolution of the pieces is similar to that of the parent cloud, but the equilibrium core has larger density and mass.
A nonpolytropic model of a polar coronal hole of 2-5 solar radii constructed. The main assumptions are: (1) the magnetic structure of the sun can be described by a combination of dipole-like and radial fields; (2) in the magnetically dominated region rho(nu sq/2) much less than B sq/8 pi the influence of the outflow on the magnetic structure is negligible. The magnetic and thermodynamic structures are obtained by solving the force balance equation for plasma with the observationally derived electron density. Profiles of velocities in the acceleration regime are presented and the influence of the outflow on the thermodynamic structure of the solar corona above the polar region is discussed.
An analysis of the possible dissociation of metastable oxygen molecules subject ot constraints imposed by selection rules for molecular transitions, airglow observations, and atmospheric chemistry leads to the following conclusions. Dissociation of O2(b1Sigma g +) must produce a negligible number of oxygen atoms at all altitudes in the earth's atmosphere. However, if the dissociation cross section of O2(a1Delta g) has a maximum value in the range 10 to the -20th to 10 to the -19th/sq cm, then the process O2(a1Delta g) + h(nu) yields O2(C3Delta u) yields O(3P) + O(3P) will constitute a significant, and potentially the major, source of odd oxygen in the uppermost stratosphere and mesosphere.
Frederick and Cicerone (1985) have proposed that photodissociation of O2 (a 1 Delta g) by the process O2 (a 1 Delta g) + h-nu + O2 (C 3 Delta u) to O(3 P) + O(3 P) may be a major source of odd oxygen in the upper stratosphere and mesosphere. They argued that, since the process is forbidden only by change in the spin multiplicity, it might have been a cross section intermediate between a fully allowed and a strictly forbidden transition, i.e., 10 to the -20th to 10 to the -19th sq cm near 250 nm. In order to test this proposal, absorption by O2 (a 1 Delta g) has been measured in the 190-290 nm wavelength region. No absorption above the detection limit could be observed for O2 (a 1 Delta g) concentrations of (4-7) x 10 to the 15th/cu cm. An upper limit of 8 x 10 to the -22 sq cm was calculated for the cross section.
Attention is given to the first results of direct, picosec measurements of the Delta-nu(OH) 5 local mode transition of H2O2. These time-resolved studies yield a direct measure of the unimolecular dissociation rate, and furnish a lower limit for the rate of energy redistribution from the OH stretch to the O-O reaction coordinate. The data thus determined may be used to ascertain the domain of validity for statistical unimolecular reaction rate theories.
In the case of an establishment of theoretical models of the hydromagnetic solar wind, the inclusion of the effects of the magnetic field in the solar wind makes it extremely dificult to solve the mathematical problem. This paper has the objective to present a set of particular analytic solutions. The general formulation of Tsinganos (1982) is used to identify a class of analytic solutions to the equations of steady hydromagnetic flows in spherical coordinates. Flow in an open magnetic field are studied, taking into account the problem in dimensionless form, the special case of radial flows with alpha = 0, general radial flows, illustrative examples for flows in which alpha is not equal to 0, a parametric study of nonradial flows in which alpha is not equal to zero, variations in the parameter nu, and variations in the initial speed eta.
Spectral measurements (Delta lambda = 8A) from Spacelab 1 of the O2 atmospheric bands in the dayglow at thermospheric altitudes are reported for a tangent ray height of 150 km. Vibrational levels up to nu-prime = 4 are found in the data, requiring a source in addition to the energy transfer from O(1D) to O2. It is suggested that this source is the collisional deactivation of N(2D) by O2.
The Voyager 2 UV spectrometer was used to scan the Uranus atmosphere at wavelengths from 500-1700 A with a field of view of 0.1 x 0.86 deg. The temperature and composition of the upper atmosphere were determined through occultations of light from gamma Pegasi, nu Geminorum and the sun. The data indicated a substantial gas density (100 million H atoms/cu cm) at about 28,000 km from the Uranus center, suggesting that gas drag plays a significant role in ring evolution. The distributions of CH4 and C2H2 in the lower atmosphere were also estimated. An electroglow emission was detected on the sunlit side, and attributed to emissions from atomic and molecular hydrogen excited by low energy electrons. An auroral glow was also observed, and exhibited evidence of an energy input equal to that of the electroglow. Finally, estimates of the C2H2 mixing ratio and the vertical column abundance of H2 are calculated.
The infrared emission data, obtained on 260 binary systems by the all-sky IRAS survey in wavelengths between 12 and 100 microns, are reported. Of all the 260 sources, which contained compact objects including white dwarfs, neutron stars, or possibly black holes, only 32 contained detectable IR radiation. The X-ray emitting Be-type stars (gamma-Cas and X Per) were found to have their energy flux proportional to frequency in the range of the log nu values of 12.7-14.7. However, the GS304-1 flux distribution is unique, in that its flux rises by several orders of magnitude as the wavelength changes from 4000 A to 60 microns. A static dust cloud was detected, with a radius of about 1 AU, which has formed around the classical nova RR Pic since its 1925 eruption. The post-eruption far-IR light curve of a classical nova provides strong evidence for IR emissions from both dust grains formed during the eruption and dust grains existing from previous eruptions.
The effects of the space environment on the engineering properties and chemistry of a chemically modified T300/934 graphite-epoxy composite system are characterized. The material was subjected to 1.0 x 10 to the 10th power rads of 1.0 MeV electron irradiation under vacuum to simulate 30 years in geosynchronous earth orbit. Monotonic tension tests were performed at room temperature (75 F/24 C) and elevated temperature (250 F/121 C) on 4-ply unidirectional laminates. From these tests, inplane engineering and strength properties (E sub 1, E sub 2, Nu sub 12, G sub 12, X sub T, Y sub T) were determined. Cyclic tests were also performed to characterize energy dissipation changes due to irradiation and elevated temperature. Large diameter graphite fibers were tested to determine the effects of radiation on their stiffness and strength. No significant changes were observed. Dynamic-mechanical analysis demonstrated that the glass transition temperature was reduced by 50 F(28 C) after irradiation. Thermomechanical analysis showed the occurrence of volatile products generated upon heating of the irradiated material. The chemical modification of the epoxy did not aid in producing a material which was more radiation resistant than the standard T300/934 graphite-epoxy system. Irradiation was found to cause crosslinking and chain scission in the polymer. The latter produced low molecular weight products which plasticize the material at elevated temperatures and cause apparent material stiffening at low stresses at room temperature.