Reactions of fragment ions in methane - Ion-molecule reactions in methane and helium-methane mixtures
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Basalt and single-mineral particles, ranging from 150 to 425 microns, from the Luna-16 sample are studied by electron microanalysis, X-ray fluorescence analysis, and petrographic techniques. Three basalt species of different structure are identified. The structure and composition of the individual minerals (in particular of pyroxenes) indicate that the basalts have crystallized under conditions similar to those established for Apollo-11 samples.
Mineralogical, petrological, and chemical analyses, along with Rb-Sr age and Ar-40/Ar-39 measurements, were carried out with the B-1 sample returned from the Luna 16 mission. The sample, weighing 62 mg, is a fine-grain basalt of ophitic structure. It differs from the Apollo samples in that the pyroxene and plagioclass contents are almost identical, and the ilmenite content (7%) lies between those of the Apollo-11 and Apollo-12 samples. Chemically, it is characterized by a high Sr content and a high K/U ratio.
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A volumetric adsorption system incorporating a pressure gauge was employed to determine nitrogen adsorption and evaluate surface areas. The water adsorption of the lunar samples was measured with the aid of a gravimetric adsorption system including a microbalance. The results obtained in the investigation for the three samples are discussed in detail, giving attention to aspects of dehydroxylation and rehydroxylation.
Production of hydrogen and carbon atoms in metastable and high-lying Rydberg states by electron-impact dissociation of methane and deuterated methane is investigated for incident electron energies ranging from threshold values to 300 eV. Threshold energies for five different processes resulting in metastable hydrogen and carbon atoms are determined in the energy range from 20 to 70 eV, and it is shown that metastable hydrogen atoms are produced in four of these collisional processes while metastable carbon atoms are produced in the other. The nature of each collisional process is described, differential cross sections are derived for the dissociative excitation of both types of atoms to metastable and high-Rydberg states at 100 eV, and the onset energy for UV photon production is measured. Much of the data is interpreted in terms of the ion core model suggested by Kupriyanov (1968) and developed by Freund (1971).
Technology needed to predict damage and hazards from explosions of propellant tanks and bursts of pressure vessels, both near and far from these explosions is introduced. Data are summarized in graphs, tables, and nomographs.
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The delta Z is greater than or equal to 1 reaction cross section for 1.8 GeV/n Ar-40 have been measured on targets ranging from H to Pb. Comparing these cross sections with H-1, C-12, and O-16 reaction cross sections at relativistic energies yields a formula for nucleus-nucleus reaction cross sections.
(For abstract see issue 11, p. 1731, Accession no. A76-27209)
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Specific characteristics of the media including density, excitation rates, wavelength, kinetics, fissile material, scale size, and medium uniformity are assessed. The use of epithermal neutrons, homogeneously mixed fissile material, and special high cross section nuclear isotopes to optimize coupling of the energy to the medium are shown to be important considerations maximizing the scale size, energy deposition, and medium uniformity. It is demonstrated that e-beam excitation can be used to simulate nuclear pumping conditions to facilitate the search for candidate media.
Moderate dilution of the CO with Ar lowers the reactor excitation threshold for lasing. Fission coatings on ceramic substrates have been developed which minimize fouling of laser mirrors. A new laser apparatus was constructed which more closely resembles large electrically excited CO lasers. Measurements of the energy emerging from the foils indicate that excitation of the gas is still below optimum values. Laser action at room temperature has also been observed.
Rocks from an ophiolite suite once on the seafloor were analyzed for rare earth elements (REE), Sc, Co, Na2O, Cr, Zn and FeO. Strontium isotope exchange noted in some of the lavas is attributed to basalt-seawater interaction; the Ce abundance in smectite- and zeolite-bearing lavas may also be due to prolonged exposure to seawater. The higher grades of metamorphic rock, however, show no variation from the usual flat or slightly light REE depleted profiles. Plutonic igneous rock, all light REE depleted, have total REE abundances varying by a factor of 100 between the dunites and diorites. In order of decreasing REE abundance are hornblende, clinopyroxene, plagioclase, orthopyroxene and olivine. Calculations of REE contents of liquids in equilibrium with early cumulative clinopyroxenes suggest that the parent to the stratiform sequence was more depleted in light REE than the parent to the lava pile.