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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

A molecular theory of elastomer deformation and rupture.

The mechanical properties of elastomers, including rupture and its time dependence, can be semiquantitatively predicted from nine molecular parameters which are characteristic for a given species, from the initial molecular weight of a sample before cross-linking and from the effective chain concentration (which must still be determined for each vulcanizate). Only two empirical quantities are involved - the Plazek retardation function for entanglement slippage and a related constant which serves to locate this function on the time scale. The theory leads to a new method of estimating fatigue lifetimes from short-time data.

Landel, R. F.↗
NASA NTRS1973

Reactions of HO2 with carbon monoxide and nitric oxide and of O/1 D/ with water.

Investigation of the reactions of the hydroperoxyl radical with carbon monoxide and nitric oxide in a static system, and reexamination of the reaction of O(1 D) with water. The HO2 radicals were generated by the photolysis of N2O at 2139 A in the presence of excess H2O or H2 and smaller amounts of CO and O2. The O(1 D) atoms produced from the photolysis of N2O react with H2O or with H2 to give OH radicals in the case of H2O or OH radicals and H atoms in the case of H2. With H2O, two OH radicals are produced for each O(1 D) removed at low pressures, but the OH yield drops as the pressure is raised. This drop is attributed to an insertion reaction which removes from 10 to 30% of the O(1 D) atoms at about 650 torr of H2O at 200 F. The OH radicals generated can react with either CO or H2 to produce H atoms, which then add to O2 to produce HO2. In the absence of NO, the HO2 radicals could react by two routes, while with NO present NO2 is produced in a long chain process.

Simonaitis, R.↗
NASA NTRS1973

Rate constants for the reactions of hydroxyl and hydroperoxyl radicals with ozone.

Chain decomposition of ozone by hydroxyl and hydroperoxyl radicals has been observed. The rate constant at 300 K for OH + O3 yielding HO2 + O2 is eight times ten to the -14th power cubic centimeters per second. The rate constant for HO2 + O3 yielding OH + 2O2 is three times ten to the -15th power cubic centimeters per second. These results have implications concerning stratospheric ozone.

Demore, W. B.↗
NASA NTRS1973

Fatty acids of Pinus elliottii tissues.

The total fatty constituents of slash pine (Pinus elliottii) tissue cultures, seeds, and seedlings were examined by GLC and MS. Qualitatively, the fatty acid composition of these tissues was found to be very similar to that reported for other pine species. The fatty acid contents of the tissue cultures resembled that of the seedling tissues. The branched-chain C(sub 17) acid reported for several other Pinus species was confirmed as the anteiso isomer.

Laseter, J. L.↗
NASA NTRS1973

A unified method for analyzing mission reliability for fault tolerant computer systems.

For fault-tolerant computer systems consisting of multiple classes of modules, a unified method for analyzing mission reliability is proposed and evaluated. The analysis proceeds by generalizing the notions of standby and N modular redundancy into a concept called hybrid-degraded redundancy. The probabilistic evaluation of the unified redundancy concept is then developed to yield, for a given modular class, the joint distribution of success and the number of nonfailed modules from that class, at special times. With this information, a Markov chain analysis gives the reliability of an entire sequence of phases (mission profile).

Bricker, J. L.↗
NASA NTRS1974

Statistical analysis of flight times for space shuttle ferry flights

Markov chain and Monte Carlo analysis techniques are applied to the simulated Space Shuttle Orbiter Ferry flights to obtain statistical distributions of flight time duration between Edwards Air Force Base and Kennedy Space Center. The two methods are compared, and are found to be in excellent agreement. The flights are subjected to certain operational and meteorological requirements, or constraints, which cause eastbound and westbound trips to yield different results. Persistence of events theory is applied to the occurrence of inclement conditions to find their effect upon the statistical flight time distribution. In a sensitivity test, some of the constraints are varied to observe the corresponding changes in the results.

Graves, M. E.↗
NASA NTRS1973

The lunar herringbone pattern

Several defined examples of the V shaped components of herringbone patterns observed on Apollo 17 and Apollo 15 metric and panoramic photographs are given along with an explanation on the impact mechanism for forming the V shaped structures. Observations of isolated crater chains having the herringbone patterns but not obviously associated with any primary crater are also included. Preliminary results indicate the lunar herringbone patterns are common to characteristics of secondary cratering and that the pattern results from the collision of material ejected from separated impact points.

Oberbeck, V. R.↗
NASA NTRS1974

Solid state polymerization and crystallography of polyimide precursors

Although the production of crystallinity in a polymeric system has historically led to commerically useful properties, the polyimides, prized for their high temperature characteristics, as customarily synthesized by melt or solution casting, are amorphous. It is shown that polymide containing residual crystallinity can be synthesized by isothermal annealing of crystals of the salt of the diisopropyl ester of pyromellitic acid and phenylene diamine. The reaction is topochemical in that the geometry of the polymer product is dependent upon that of the crystalline precursor. Infrared spectroscopy reveals the presence of imide absorption in the polymer, while powder diffractometry suggests residual crystallinity. Single crystal X-ray analysis of the monomer yields a structure of chains of alternating acid and base suggesting that the monomer is amenable to polymerization with a minimum of geometrical disruption.

Wakelyn, N. T.↗
NASA NTRS1973

Crystal motion measurement by means of satellite techniques

A system for monitoring precursory crustal motions is presented. It involves a set of automated corner reflector stations tracked by means of a laser operating in the Geopause satellite. It is possible to range some three times during every Geopause pass to each of the sites in such an ensemble, weather permitting. One centimeter range data gathered during a quarter of a year can yield position component accuracies of the order of a couple of centimeters. A laser beam of a tenth of a milliradian in diameter would, illuminate a single station in such an array. A broader beam would generate reflections from several sites, yielding overlapping data. A chain or pattern of such overlapping regions can strengthen the solution for site positions. Pressure, temperature and humidity gauges can provide refraction correction data. Turnaround transponders interrogated by the Geopause radio tracking system can furnish corresponding data in excessively cloudy regions.

Siry, J. W.↗
NASA NTRS1974

Cracking and reformation of saturated hydrocarbons by ultrasound in the presence of water

The exposure of saturated hydrocarbons to ultrasound (800 kHz, 6 W/sq cm) in the presence of water results in: (1) cleavage of the carbon chain, producing saturated and unsaturated hydrocarbons with a lower number of carbons than the initial hydrocarbon (cracking); and (2) recombination after cleavage, producing saturated and unsaturated hydrocarbons with a higher number of carbons than the initial hydrocarbon (reformation). The addition of argon facilitates these phenomena. The effects are attributed to a homolytic (radical) mechanism occurring within the cavitation bubbles under the effects of microsparks.

Prudhomme, M. R. O.↗
NASA NTRS1974

Acoustic properties of organic acid mixtures in water

The variation of the rate of propagation of ultrasounds in organic acid mixtures in water points to structural changes caused by interactions that take place under conditions of thermal agitation, at different acid concentrations. At the same time, a difference is found in the changes in velocity as a function of the length of the carbon chain of the acids in the mixture as a result of their effect on the groups of water molecules associated by hydrogen bonds.

Macavei, I.↗
NASA NTRS1974

Management of natural resources through automatic cartographic inventory

The author has identified the following significant results. Significant correspondence codes relating ERTS imagery to ground truth from vegetation and geology maps have been established. The use of color equidensity and color composite methods for selecting zones of equal densitometric value on ERTS imagery was perfected. Primary interest of temporal color composite is stressed. A chain of transfer operations from ERTS imagery to the automatic mapping of natural resources was developed.

Rey, P. A.↗
NASA NTRS1974

Noise and vibration level reduction by covering metal structures with layers of damping materials

One of the most important methods of reducing the noise and vibration level is the damping of the secondary sources, such as metal plates, often used in vehicle structures, by means of covering materials with high internal viscosity. Damping layers are chosen at an optimum thickness corresponding to the frequency and temperature range in which a certain structure works. The structure's response corresponding to various real situations is analyzed by means of a measuring chain including electroacoustical or electromechanical transducers. The experimental results provide the dependence of the loss factor and damping transmission coefficient as a function of the damping layer thickness or of the frequency for various viscoelastic covering materials.

Rugina, I.↗
NASA NTRS1974

Correlations and linkages between the sun and the earth's atmosphere: Needed measurements and observations

A summary of needed measurements and observations is reported to identify the sequence of processes leading from change in solar input to change in tropospheric circulation and weather. Changes in the solar electromagnetic radiation have to be carefully monitored since variations over the solar cycle are small (less than one percent). It is suggested that changes in the ionization at the Pfotzer maximum could influence the formation of thunderstorms by changing the electric potential gradient. This could be checked by measuring the global atmospheric electric field. As an example of spacecraft observations, a worldwide distribution plot of nocturnal thunderstorms compiled from OSO-5 data shown; no obvious correlation with solar data had been found, but the time span of the data is rather limited and more sophisticated observation techniques could be used. Continuous and careful monitoring is recommended of the input of electromagnetic and particle radiation into the earth's atmosphere ozone distributions in the region above 30 km, and wind systems in the mesosphere and lower thermosphere. In addition, special phenomena suspected to be important in the causal chain, such as cirrus cloud formation at high latitudes and thunderstorm activity, should be monitored on a global basis.

Kellogg, W. W.↗
NASA NTRS1974

Interplantetary streams and their interaction with the earth

Plasma and magnetic field observations of interplanetary streams near 1 AU are summarized. Two types of streams have been identified corotating streams and flare-associated, and other flow patterns are present due to interactions among streams. The theory of corotating streams, which attributes them to a high temperature region near the sun, satisfactorily explains many of the effects observed at 1 AU. A correspondingly complete theory of flare-associated streams does not exist. Streams are a key link in the chain that connects solar and geomagnetic activity. The factors that most influence geomagnetic activity are probably related to streams and determined by the dynamics of streams. The evolution of streams on scales of 27 days and 11 years probably determines the corresponding variations of geomagnetic activity.

Burlaga, L. F.↗
NASA NTRS1974

Physiolography of the Hawaiian Islands

Each of the eight principal Hawaiian Islands extending from Kauai on the northwestern end of the chain to Hawaii at the southeastern extremity represents the top of a great basaltic shield volcano that rises 4575 m above the ocean floor. The ages of the islands quite consistently decrease toward the southeast. Kauai is judged to be about 5.3 million years old, whereas Hawaii is less than 750,000 years in age. The ravages of time have had serious effects on the once domelike older volcanoes, so that the traditional shield shape is lost in a fretwork of peaks, ridges, palis, valleys, and plains. Age is not the only determinant of the degree of dissection by running water, waves, and chemical weathering. Another very important factor is the exposure of the particular side of island to excessive rainfall and mercilous trade-wind wave attack. The windward and high lee slopes receive 60 cm or more of rain annually, whereas the lower leeward slopes and coastal areas may receive 4 cm or less annually.

Abbott, A. T.↗
NASA NTRS1974

Origin of the Hawaiian Islands

Recent studies indicate that the Hawaiian volcanic chain is a result of relative motion between the Pacific plate and a melting spot in the earth's mantle.

Dalrymple, G. B.↗