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At least 919 records · Page 51

Challenges of Fast Charging for Electric Vehicles and the Role of Red Phosphorous as Anode Material: Review

Electric vehicles (EVs) are being endorsed as the uppermost successor to fuel-powered cars, with timetables for banning the sale of petrol-fueled vehicles announced in many countries. However, the range and charging times of EVs are still considerable concerns. Fast charging could be a solution to consumers’ range anxiety and the acceptance of EVs. Nevertheless, it is a complicated and systematized challenge to realize the fast charging of EVs because it includes the coordinated development of battery cells, including electrode materials, EV battery power systems, charging piles, electric grids, etc. This paper aims to serve as an analysis for the development of fast-charging technology, with a discussion of the current situation, constraints and development direction of EV fast-charging technologies from the macroscale and microscale perspectives of fast-charging challenges. If the problem of fast-charging can be solved, it will satisfy consumers’ demand for 10-min charging and accelerate the development of electric vehicles. This paper summarized the development statuses, issues, and trends of the macro battery technology and micro battery technology. It is emphasized that to essentially solve the problem of fast charging, the development of new battery materials, especially anode materials with improved lithium ion diffusion coefficients, is the key. Finally, it is highlighted that red phosphorus is one of the most promising anodes that can simultaneously satisfy the double standards of high-energy density and fast-charging performance to a maximum degree.

33 ADVANCED PROPULSION SYSTEMS↗

A note on photocurrents in extrinsic semiconductors

The advent of the concept of holes and careful determination of mobilities have made it possible to realize that the potential difference between the contacts of an irradiated semiconductor in the absence of current flow is due to the difference in mobility of electrons and holes. In this paper, a preliminary analysis shows that charge neutrality and zero-current condition are compatible. This situation is clarified and it is found that the equation for the electric field E in the absence of current is not absolutely correct even under low-level injection conditions. In particular, it is shown that fairly large currents can be generated by suitable light sources, currents which are entirely due to the disparity between electron and hole mobilities.

Von Roos, O.↗

Study of relationships of material properties and high efficiency solar cell performance on material composition

The performance improvements obtainable from extending the traditionally thin back-surface-field (BSF) layer deep into the base of silicon solar cells under terrestrial solar illumination (AM1) are analyzed. This extended BSF cell is also known as the back-drift-field cell. About 100 silicon cells were analyzed, each with a different emitter or base dopant impurity distribution whose selection was based on physically anticipated improvements. The four principal performance parameters (the open-circuit voltage, the short-circuit current, the fill factor, and the maximum efficiency) are computed using a FORTRAN program, called Circuit Technique for Semiconductor-device Analysis, CTSA, which numerically solves the six Shockley Equations under AM1 solar illumination at 88.92 mW/cm, at an optimum cell thickness of 50 um. The results show that very significant performance improvements can be realized by extending the BSF layer thickness from 2 um (18% efficiency) to 40 um (20% efficiency).

Sah, C. T.↗

Approximations for column effect in airplane wing spars

The significance attaching to "column effect" in airplane wing spars has been increasingly realized with the passage of time, but exact computations of the corrections to bending moment curves resulting from the existence of end loads are frequently omitted because of the additional labor involved in an analysis by rigorously correct methods. The present report represents an attempt to provide for approximate column effect corrections that can be graphically or otherwise expressed so as to be applied with a minimum of labor. Curves are plotted giving approximate values of the correction factors for single and two bay trusses of varying proportions and with various relationships between axial and lateral loads. It is further shown from an analysis of those curves that rough but useful approximations can be obtained from Perry's formula for corrected bending moment, with the assumed distance between points of inflection arbitrarily modified in accordance with rules given in the report. The discussion of general rules of variation of bending stress with axial load is accompanied by a study of the best distribution of the points of support along a spar for various conditions of loading.

Warner, Edward P↗

Sensitivity of the Tropical Atmosphere Energy Balance to ENSO-Related SST Changes: How Well Can We Quantify Hydrologic and Radiative Responses?

The continuing debate over feedback mechanisms governing tropical sea surface temperatures (SSTs) and tropical climate in general has highlighted the diversity of potential checks and balances within the climate system. Competing feedbacks due to changes in surface evaporation, water vapor, and cloud long- and shortwave radiative properties each may serve critical roles in stabilizing or destabilizing the climate system. It is also intriguing that even those climate variations having origins internal to the climate system-- changes in ocean heat transport for example, apparently require complementary equilibrating effects by changes in atmospheric energy fluxes. Perhaps the best observational evidence of this is the relatively invariant nature of tropically averaged net radiation exiting the top-of-atmosphere (TOA) as measured by broadband satellite sensors over the past two decades. Thus, analyzing how these feedback mechanisms are operating within the context of current interannual variability may offer considerable insight for anticipating future climate change. In this paper we focus on how fresh water and radiative fluxes over the tropical oceans change during ENSO warm and cold events and how these changes affect the tropical energy balance. At present, ENSO remains the most prominent known mode of natural variability at interannual time scales. Although great advances have been made in understanding this phenomenon and realizing prediction skill over the past decade, our ability to document the coupled water and energy changes observationally and to represent them in climate models seems far from settled (Soden, 2000 J Climate). Our analysis makes use a number of data bases, principally those derived from space-based measurements, to explore systematic changes in rainfall, evaporation, and surface and top-of-atmosphere (TOA) radiative fluxes, A reexamination of the Langley 8-Year Surface Radiation Budget data set reveals errors in the surface longwave emission due to use of biased SSTs. Subsequent correction allows subsequent use of this data set along with ERBE TOA fluxes to infer net atmospheric radiative beating. Further analysis of recent rainfall algorithms provides new estimates for precipitation variability in line with interannual evaporation changes inferred from the da Silva, Young, Levitus COADS analysis. The overall results from our analysis suggest an increase (decrease) of the hydrologic cycle during ENSO warm (cold) events at the rate of about 5 Wm-2 per K of SST change. This rate is slightly less than that which would be expected for constant relative humidity over the tropical oceans. Corresponding radiative fluxes seem systematically smaller resulting in a enhanced (suppressed) export of energy from the tropical ocean regions during warm (cold) SST events. Discussion of likely errors due to sampling and measurement strategies are discussed along with their impacts on our conclusions.

Robertson, Franklin R.↗

NASA Strategy for Technology Development

At the National Aeronautics and Space Administration (NASA), foresight is a coordinated, iterative, and continual process for making informed decisions. NASA faces diverse and relatively unique challenges and opportunities as the leading U.S. agency for aeronautics development, cutting-edge scientific discovery, and human space exploration. To address these challenges and leverage opportunities, NASA uses foresight to strategically plan technology development across four mission directorates: Aeronautics Research Mission Directorate, Space Technology Mission Directorate, Science Mission Directorate, and Human Exploration and Operations Mission Directorate (recently separated into the new Exploration Systems Development Mission Directorate and Space Operations Mission Directorate). The mission directorates leverage a broad community of experts and partners to incorporate technology foresight into mission and program planning. Through this process NASA realizes tangible benefits to the agency’s science, technology, and exploration programs. As an independent office, NASA’s Office of Technology, Policy, and Strategy (OTPS) provides strategic advice, supported by independent assessments and rigorous analysis, to inform NASA senior leadership on key areas to align mission and agency-level activities. OTPS serves as a trusted authority to inform technology strategy at the agency to enable future missions. Specifically, OTPS coordinates and uses inputs from a broad community of experts, both internal and external to NASA, to inform decision making for technology plans, investments, and partnerships. OTPS develops and maintains the NASA Technology Taxonomy to standardize communication across the agency’s diverse technology portfolio and the related Strategic Technology Investment Plan that integrates priorities and informs technology investment. Through these efforts, OTPS has refined elements of foresight-informed strategic planning that may be applicable to other technology-driven industries where foresight is essential for resilience. This chapter describes the processes of foresight for technology development at NASA and provides insight into the value the agency derives from these processes. The chapter further describes the role of OTPS as an independent advisory office that supports NASA’s efforts to capitalize on foresight and strategic technology planning. We present these examples with consideration for how organizations in defense, security, and other technology-driven industries can operationalize foresight in their own strategic technology development.

Erica Rodgers↗

DESIGN AND EXPERIMENTAL STUDY OF A HIGH PRESSURE AND SUPERCRITICAL METHANE-OXYGEN BURNER

Directly heated supercritical oxy-fuel power cycles have potential to offer a higher thermal efficiency and lower pollutant emissions compared to existing power cycles. Recent thermodynamic analysis of the cycle performed by several groups including the UTEP-Air Liquide research team show that combustion in the vicinity of 300 bar pressure and 1000-1400 K temperature allows for relatively high system efficiencies while operating within the limit of practical combustor materials. However, the realization of directly heated supercritical power cycle requires combustion systems be designed to operate in supercritical conditions and at temperature far below the blowout limit of conventional flames (above 1500 K), where not only the thermodynamic properties but also the combustion properties and kinetics are unexplored. To minimize these knowledge gaps, some intermediate pressure ranges (up to 20 bar) are experimented and modeled using a CFD simulation tool. The knowledge obtained from the high pressure test will assist in understanding the combustion chamber pressurization mechanism, ignition and flame behavior at the elevated pressure. This is a systematic first step in testing at higher pressures of 100 and 300 bar pressures. The primary objective of this dissertation is to perform qualitative analysis on oxy-methane combustion at high pressure (< 20 bar) and compare to CFD model for future scale up to supercritical condition. For modeling of the system, a commercial computational fluid dynamics simulation tool, ANSYS Fluent, is used. The inlet conditions for the CFD analysis are obtained from the experiments. The geometry used for the study is same as the test apparatus and operates at the same power ratings. The expertise gained from this experimental study is important to accurately and safely design combustors at elevated pressures up to 300bar. A high pressure methane-oxygen fuel burner and combustor have been developed to accommodate oxycombustion environment. A detailed CFD analysis is conducted to understand the flame length and cooling phenomenon inside the combustor first at pressures up to 20 bar to compare to experiments then at supercritical pressure. The first part of the dissertation compares CFD results with high pressure burner experiments at pressures up to 20 bar. The test is conducted for 30 s within 150 kW – 250 kW thermal power inputs. Afterwards, based on the simulation results a cooling system is proposed for steady state high pressure combustion experiments. It is observed from the experimental study that the proposed pressurization mechanism able to pressurize the vessel up to 20 bar. It is also determined that the current combustor can operate up to 20 bar for short term. The steady state CFD simulation demonstrates that a cooling system must be incorporated for continuous operation. Additionally, the study focuses on the ignition delay due to added diluent during the combustion process. It is observed that as the carbon dioxide recirculation ratio increases the ignition delay time increases. Later part of the dissertation provides a preliminary guideline for developing a laboratory scale supercritical oxy combustor. The employment of supercritical fluid in gas turbine is fairly a new concept. Hence, there are many questions that need to be answered. During this dissertation study an investigation is performed to understand the impact of equation of state in the supercritical combustion simulation. Finally, a CFD model for developing supercritical oxy-methane burner and the combustor, incorporating real gas model, is presented. Although Lee-Kesler equation of state provides better accuracy than Peng Robinson, due to the computational time Peng Robinson equation of state is used for the simulation. It is found that existing knowledge is not enough to simulate combustion at supercritical phase. Detailed combustion chemistry at the supercritical condition must be developed and should be incorporated to accurately replicate the combustion phenomenon.

Chowdhury, ASM Arifur Rahim↗

Probing Light Atoms at Subnanometer Resolution: Realization of Scanning Transmission Electron Microscope Holography

Atomic resolution imaging of light elements in electron-transparent materials has long been a challenge. Biomolecular materials, for example, are rapidly altered by incident electrons. We demonstrate a scanning transmission electron microscopy (STEM) technique, called STEM holography, capable of efficient structural analysis of beam-sensitive nanomaterials. STEM holography measures the absolute phase and amplitude of electrons passed through a specimen via interference with a vacuum reference wave. We use an amplitude-dividing nanofabricated grating to prepare multiple beams focused at the sample. We configure the postspecimen microscope imaging system to overlap the beams, forming an interference pattern. We record and analyze the pattern at each 2D-raster-scan-position, reconstructing the complex object wave. As a demonstration, we image gold nanoparticles on an amorphous carbon substrate at 2.4 Å resolution. In conclusion STEM holography offers higher contrast of the carbon while maintaining gold atomic lattice resolution compared to high angle annular dark field STEM.

4D-STEM↗

Structural, thermal and spectroscopic properties of highly Er3+-doped novel oxyfluoride glasses for photonic application

Graphical abstract: - Highlights: • Er{sup 3+}-doped novel oxyfluoride glasses have been prepared by melt quenching technique. • Structural, thermal and spectroscopic properties have been carried out. • SALSFEr glasses exhibit intense green and weak red emissions at 365 nm excitation. • Major laser transition for Er{sup 3+} ion in SALSFEr glasses is {sup 4}I{sub 13/2} → {sup 4}I{sub 15/2} (1.53 μm). • These results suggest the possibility of using SALSFEr glasses as photonic devices. - Abstract: The Er{sup 3+}-doped novel oxyfluoride glasses of composition (43 − x)SiO{sub 2}–10Al{sub 2}O{sub 3}–24LiF–23SrF{sub 2}–xEr{sub 2}O{sub 3}, where x = 1.0, 2.0, 4.0 and 6.0 mol%, have been prepared by conventional melt quenching technique and are characterized through X-ray diffraction (XRD), differential thermal analysis (DTA), Raman, Fourier transform infrared (FT-IR) analysis, optical absorption spectra, visible (vis) and near-infrared (NIR) emission spectra measurements. Judd–Ofelt (JO) intensity parameters (Ω{sub λ}, λ = 2, 4 and 6) have been derived from the absorption spectrum of 1.0 mol% Er{sub 2}O{sub 3} doped glass and are in turn used to calculate radiative properties for the important luminescent levels of Er{sup 3+} ions. The studied glasses show intense green and weak red visible emissions under 365 nm excitation. The decrease in visible emission intensities with concentration of Er{sup 3+} ions has been explained due to energy transfer processes between Er{sup 3+} ions. Upon excitation at 980 nm laser diode, an intense 1.53 μm NIR emission has been observed with the maximum full width at half maximum (FWHM) for Er{sup 3+}-doped oxyfluoride glasses. The higher Er{sup 3+} ion doping capability and relatively high gain and broad emission at 1.5 μm are the most notable features of these glasses to realize efficient short-length optical amplifiers.

36 MATERIALS SCIENCE↗

The BKG/IGGB VLBI Analysis Center

In 2012, the activities of the BKG/IGGB VLBI Analysis Center, as in previous years, consisted of routine computations of Earth orientation parameter (EOP) time series and of a number of research topics in geodetic VLBI. The VLBI group at BKG continued its regular submissions of time series of tropospheric parameters and the generation of daily SINEX (Solution INdependent EXchange format) files. Quarterly updated solutions have been computed to produce terrestrial reference frame (TRF) and celestial reference frame (CRF) realizations. Routine computations of the UT1-UTC Intensive observations include all sessions of the Kokee-Wettzell and Tsukuba-Wettzell baselines and the networks Kokee-Svetloe-Wettzell and Ny-degAlesund-Tsukuba-Wettzell. The VLBI group at BKG developed a procedure to get the most probable station positions of Tsukuba after the earthquake on March 11, 2011 for the epochs of the Intensive sessions. The analysis of the Intensive sessions with station Tsukuba could be resumed in February 2012. At IGGB, the emphasis has been placed on individual research topics.

Thorandt, Volkmar↗

CFD/FEA Co-Simulation Framework for Analysis of the Thermal Barrier Coating Design and Its Impact on the HD Diesel Engine Performance

Thermal barrier coatings (TBCs) have been investigated both experimentally and through simulation for mixing controlled combustion (MCC) concepts as a method for reducing heat transfer losses and increasing cycle efficiency, but it is still a very active research area. Early studies were inconclusive, with different groups discovering obstacles to realizing the theoretical potential. Nuanced papers have shown that coating material properties, thickness, microstructure, and surface morphology/roughness all can impact the efficacy of the thermal barrier coating and must be accounted for. Adding to the complexities, a strong spatial and temporal heat flux inhomogeneity exists for mixing controlled combustion (diesel) imposed onto the surfaces from the impinging flame jets. In support of the United States Department of Energy SuperTruck II program goal to achieve 55% brake thermal efficiency on a heavy-duty diesel engines, this study sought to develop a deeper insight into the inhomogeneous heat flux from mixing controlled combustion on thermal barrier coatings and to infer concrete guidance for designing coatings. To that end, a co-simulation approach was developed that couples high-fidelity computational fluid dynamics (CFD) modeling of in-cylinder processes and combustion, and finite element analysis (FEA) modeling of the thermal barrier-coated and metal engine components to resolve spatial and temporal thermal boundary conditions. The models interface at the surface of the combustion chamber; FEA modeling predicts the spatially resolved surface temperature profile, while CFD develops insights into the effect of the thermal barrier coating on the combustion process and the boundary conditions on the gas side. The paper demonstrates the capability of the framework to estimate cycle impacts of the temperature swing at the surface, as well as identify critical locations on the piston/thermal barrier coating that exhibit the highest charge temperature and highest heat fluxes. In addition, the FEA results include predictions of thermal stresses, thus enabling insight into factors affecting coating durability. An example of the capability of the framework is provided to illustrate its use for investigating novel coatings and provide deeper insights to guide future coating design.

42 ENGINEERING↗

Community Requirements Meta-Analysis: Characterizing Needs and Opportunities for HPDF

This High Performance Data Facility (HPDF) Project is creating a new scientific user facility to provide advanced infrastructure for data-intensive science, supporting the DOE’s Office of Science (SC) community. HPDF’s mission is to enable and accelerate scientific discovery by delivering state-of-the-art data management infrastructure, capabilities, and tools. This meta-analysis examines the needs of the breadth of the SC community, captured in publicly available community reports or mission documents. The meta-analysis identifies and provides initial characterization of fifteen core requirements for the HPDF Project team to consider during the conceptual design phase. The fifteen requirements illustrate how scientific work among SC communities requires modern, seamless user experiences across the ASCR Ecosystem to advance the use of large volumes of heterogeneous data. The scientific community requires support for the missing middle of compute between local and HPC to interactively and collaboratively use growing datasets. Data producers and end users will benefit from enhanced data catalogs and portals that improve data access through advanced search of well curated data. The fifteen requirements are examined here organized across five themes for discussion. Examples in each theme illustrate the array of scientific needs that convey the important role that the fully realized and operational High Performance Data Facility will be able to play as an integral part of the evolving ASCR Ecosystem. Our amalgamated data tables from ESnet reports demonstrate ranges to the volumes of data HPDF must be concerned with, but limitations are inherent to this meta-analysis (see Key Challenges & Limitations). Feedback and validation of these requirements along with additional details and emergent community requirements will be gathered through user research and design activities.

97 MATHEMATICS AND COMPUTING↗

Characterization of the Crab Pulsar's Timing Noise

We present a power spectral analysis of the Crab pulsar's timing noise, mainly using radio measurements from Jodrell Bank taken over the period 1982-1989, an interval bounded by sparse data sampling and a large glitch. The power spectral analysis is complicated by nonuniform data sampling and the presence of a steep red power spectrum that can distort power spectra measurement by causing severe power 'leakage'. We develop a simple windowing method for computing red noise power spectra of uniformly sampled data sets and test it on Monte Carlo generated sample realizations of red power-law noise. We generalize time-domain methods of generating power-law red noise with even integer spectral indices to the case of noninteger spectral indices. The Jodrell Bank pulse phase residuals are dense and smooth enough that an interpolation onto a uniform time series is possible. A windowed power spectrum is computed revealing a periodic or nearly periodic component with a period of 568 +/- 10 days and a l/f(exp 3) power-law noise component in pulse phase with a noise strength S(sub infinity)=(1.24 +/- 0.067) x 10(exp 16) cycles(exp 2)/sec(exp 2) over the analysis frequency range f=0.003- 0.1 cycles/day. This result deviates from past analyses which characterized the pulse phase timing residuals as either l/f(sub 4) power-law noise or a quasiperiodic process. The analysis was checked using the Deeter polynomial method of power spectrum estimation that was developed for the case of nonuniform sampling, but has lower spectral resolution. The timing noise is consistent with a torque noise spectrum rising with analysis frequency as f implying blue torque noise, a result not predicted by current models of pulsar timing noise. If the periodic or nearly periodic component is due to a binary companion, we find a mass function f(M) = (6.8 +/- 2.4) x 10(exp -16) solar mass and a companion mass, M(sub c) is greater than or equal to 3.2 solar mass assuming a Crab pulsar mass of 1.4 solar mass.

Scott, D. M.↗

Chemical design of pH-sensitive nanovalves on the outer surface of mesoporous silicas for controlled storage and release of aromatic amino acid

Mesoporous silicas with hexagonally arranged pore channels were synthesized in water–ethanol-ammonia solution using cetyltrimethylammonium bromide as template. Directed modification of silica surface with N-[N′-(N′-phenyl)-2-aminophenyl]-3-aminopropyl groups was realized by postsynthetic activation of halogenoalkylsilicas, which have surface uniformly or selectively distributed 3-chloropropyl groups, with 2-aminodiphenylamine in the liquid phase. Chemical composition of silica materials was estimated by IR spectroscopy and chemical analysis of the surface products of reactions. Characteristics of porous structure of MCM-41-type silicas were determined from X-ray and low-temperature nitrogen ad-desorption measurements. Release ability of synthesized silica carriers was established on encapsulation of 4-aminobenzoic acid in pore channels and subsequent delivery at pH=6.86 and pH=1.00. It was found that N-[N′-(N′-phenyl)-2-aminophenyl]-3-aminopropyl groups block pore entrances at neutral pH preventing 4-aminobenzoic acid release. At pH=1.00 repulsion of positively charged surface aromatic amino groups localized near pore orifices provides unhindered liberation of aromatic amino acid from mesoporous channels. - Graphical abstract: Blocking of pores with N-[N′-(N′-phenyl)-2-aminophenyl]-3-aminopropyl groups at pH=6.86 for storage of ABA and opening of pore entrances at pH=1.00 for unhindered ABA liberation. - Highlights: • Modification of MCM-41 with N-[N′-(N′-phenyl)-2-aminophenyl]-3-aminopropyl groups. • Study of release ability of synthesized silica carriers in relation to amino acid. • Controlled blocking and opening of pores by amino groups at pH change were performed. • Retention of amino acid at pH=6.86 and its liberation at pH=1.00 was proved.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Phenotypic and functional characterization of corneal endothelial cells during in vitro expansion

The advent of cell culture-based methods for the establishment and expansion of human corneal endothelial cells (CEnC) has provided a source of transplantable corneal endothelium, with a significant potential to challenge the one donor-one recipient paradigm. However, concerns over cell identity remain, and a comprehensive characterization of the cultured CEnC across serial passages has not been performed. To this end, we compared two established CEnC culture methods by assessing the transcriptomic changes that occur during in vitro expansion. In confluent monolayers, low mitogenic culture conditions preserved corneal endothelial cell state identity better than culture in high mitogenic conditions. Expansion by continuous passaging induced replicative cell senescence. Transcriptomic analysis of the senescent phenotype identified a cell senescence signature distinct for CEnC. We identified activation of both classic and new cell signaling pathways that may be targeted to prevent senescence, a significant barrier to realizing the potential clinical utility of in vitro expansion.

59 BASIC BIOLOGICAL SCIENCES↗

Direct observation of charge transfer region at interfaces in graphene devices

Nanoscale spectromicroscopic characterizing technique is indispensable for realization of future high-speed graphene transistors. Highly spatially resolved soft X-ray photoelectron microscopy measurements have been performed using our '3D nano-ESCA' (three-dimensional nanoscale electron spectroscopy for chemical analysis) equipment in order to investigate the local electronic states at interfaces in a graphene device structure. We have succeeded in detecting a charge transfer region at the graphene/metal-electrode interface, which extends over {approx}500 nm with the energy difference of 60 meV. Moreover, a nondestructive depth profiling reveals the chemical properties of the graphene/SiO{sub 2}-substrate interface.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Seismic metamaterials based on isochronous mechanical oscillators

This Letter introduces a seismic metamaterial (SM) composed by a chain of mass-in-mass system able to filter the S-waves of an earthquake. We included the effect of the SM into the mono dimensional model for the soil response analysis. The SM modifies the soil behavior and in presence of an internal damping the amplitude of the soil amplification function is reduced also in a region near the resonance frequency. This SM can be realized by a continuous structure with inside a 3d-matrix of isochronous oscillators based on a sphere rolling over a cycloidal trajectory.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Realizing high-quality ultralarge momentum states and ultrafast topological transitions using semiconductor hyperbolic metamaterials

We employ both the effective medium approximation (EMA) and Bloch theory to compare the dispersion properties of semiconductor hyperbolic metamaterials (SHMs) at mid-infrared frequencies and metallic hyperbolic metamaterials (MHMs) at visible frequencies. This analysis reveals the conditions under which the EMA can be safely applied for both MHMs and SHMs. We find that the combination of precise nanoscale layering and the longer infrared operating wavelengths puts the SHMs well within the effective medium limit and, in contrast to MHMs, allows for the attainment of very high photon momentum states. Additionally, SHMs allow for new phenomena such as ultrafast creation of the hyperbolic manifold through optical pumping. Furthermore, we examine the possibility of achieving ultrafast topological transitions through optical pumping which can photo-dope appropriately designed quantum wells on the femtosecond time scale.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗