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At least 919 records · Page 51

Direct insights into the role of epoxy groups on cobalt sites for acidic H 2 O 2 production

Hydrogen peroxide produced by electrochemical oxygen reduction reaction provides a potentially cost effective and energy efficient alternative to the industrial anthraquinone process. In this study, we demonstrate that by modulating the oxygen functional groups near the atomically dispersed cobalt sites with proper electrochemical/chemical treatments, a highly active and selective oxygen reduction process for hydrogen peroxide production can be obtained in acidic electrolyte, showing a negligible amount of onset overpotential and nearly 100% selectivity within a wide range of applied potentials. Combined spectroscopic results reveal that the exceptionally enhanced performance of hydrogen peroxide generation originates from the presence of epoxy groups near the Co–N 4 centers, which has resulted in the modification of the electronic structure of the cobalt atoms. Computational modeling demonstrates these electronically modified cobalt atoms will enhance the hydrogen peroxide productivity during oxygen reduction reaction in acid, providing insights into the design of electroactive materials for effective peroxide production.<

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Selection of astronauts and cosmonauts

The process by which the U.S. and U.S.S.R. selected astronauts and cosmonauts for early manned space flights is described. Emphasis is placed on medical criteria.

Gurovskiy, N. N.↗

Meteorology, Macrophysics, Microphysics, Microwaves, and Mesoscale Modeling of Mediterranean Mountain Storms: The M8 Laboratory

Comprehensive understanding of the microphysical nature of Mediterranean storms can be accomplished by a combination of in situ meteorological data analysis and radar-passive microwave data analysis, effectively integrated with numerical modeling studies at various scales, from synoptic scale down through the mesoscale, the cloud macrophysical scale, and ultimately the cloud microphysical scale. The microphysical properties of and their controls on severe storms are intrinsically related to meteorological processes under which storms have evolved, processes which eventually select and control the dominant microphysical properties themselves. This involves intense convective development, stratiform decay, orographic lifting, and sloped frontal lifting processes, as well as the associated vertical motions and thermodynamical instabilities governing physical processes that affect details of the size distributions and fall rates of the various types of hydrometeors found within the storm environment. Insofar as hazardous Mediterranean storms, highlighted in this study by three mountain storms producing damaging floods in northern Italy between 1992 and 2000, developing a comprehensive microphysical interpretation requires an understanding of the multiple phases of storm evolution and the heterogeneous nature of precipitation fields within a storm domain. This involves convective development, stratiform transition and decay, orographic lifting, and sloped frontal lifting processes. This also involves vertical motions and thermodynamical instabilities governing physical processes that determine details of the liquid/ice water contents, size disi:ributions, and fall rates of the various modes of hydrometeors found within hazardous storm environments.

Starr, David O.↗

CO2 Acquisition Membrane (CAM) Project

The CO2 Acquisition Membrane (CAM) project was performed to develop, test, and analyze thin film membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The membranes developed in this project are targeted toward In Situ Resource Utilization (ISRU) applications, such as In Situ Propellant Production (ISPP) and In Situ Consumables Production (ISCP). These membrane materials may be used in a variety of ISRU systems, for example as the atmospheric inlet filter for an ISPP process to enhance the concentration of CO2 for use as a reactant gas, to passively separate argon and nitrogen trace gases from CO2 for habitat pressurization, to provide a system for removal of CO2 from breathing gases in a closed environment, or within a process stream to selectively separate CO2 from other gaseous components. The membranes identified and developed for CAM were evaluated for use in candidate ISRU processes and other gas separation applications, and will help to lay the foundation for future unmanned sample return and human space missions. CAM is a cooperative project split among three institutions: Lockheed Martin Astronautics (LMA), the Colorado School of Mines (CSM), and Marshall Space Flight Center (MSFC).

Mason, Larry W.↗

Ultrafast (1‐5 sec) Lamination of Perovskite Solar Cells With Self‐Encapsulation Using Rapid Joule Heating

Perovskite solar cells (PSCs) are traditionally fabricated using sequential layer‐by‐layer deposition, in which each layer of the device is processed on top of the preceding layer. This constrains the processing techniques and selection of transport layer materials that can be used in the solar cell. To overcome these challenges, two half‐cells can be processed independently and then diffusion‐bonded through a lamination process. However, current lamination processes for perovskite solar cells suffer from relatively long process times, which can limit throughput when moving toward high‐volume manufacturing. In this study, a custom platform was designed for rapid‐joule heating of perovskite materials and devices. This enabled more than a 99% reduction in lamination time from 26 min to 1 s. Perovskite samples that were laminated in 1 s exhibited comparable values of percent bonded area, interfacial toughness, grain domain size, and X‐ray diffraction spectra to those laminated in greater than 10 min. As a proof‐of‐concept, 18.3% efficient devices were successfully laminated in 5 s. A transient heat transfer model was developed to describe the relationship between the perovskite temperature and the electrical power supplied to the heaters, establishing a baseline for predicting processing conditions in large‐scale manufacturing systems. Ultra‐fast lamination provides a pathway toward scalable roll‐to‐roll or sheet‐to‐sheet manufacturing of PSCs.

heat transfer↗

Laser Materials Processing for NASA's Aerospace Structural Materials

Lasers are useful for performing operations such as joining, machining, built-up freeform fabrication, and surface treatment. Due to the multifunctional nature of a single tool and the variety of materials that can be processed, these attributes are attractive in order to support long-term missions in space. However, current laser technology also has drawbacks for space-based applications. Specifically, size, power efficiency, lack of robustness, and problems processing highly reflective materials are all concerns. With the advent of recent breakthroughs in solidstate laser (e.g., diode-pumped lasers) and fiber optic technologies, the potential to perform multiple processing techniques in space has increased significantly. A review of the historical development of lasers from their infancy to the present will be used to show how these issues may be addressed. The review will also indicate where further development is necessary to realize a laser-based materials processing capability in space. The broad utility of laser beams in synthesizing various classes of engineering materials will be illustrated using state-of-the art processing maps for select lightweight alloys typically found on spacecraft. Both short- and long-term space missions will benefit from the development of a universal laser-based tool with low power consumption, improved process flexibility, compactness (e.g., miniaturization), robustness, and automation for maximum utility with a minimum of human interaction. The potential advantages of using lasers with suitable wavelength and beam properties for future space missions to the moon, Mars and beyond will be discussed. The laser processing experiments in the present report were performed using a diode pumped, pulsed/continuous wave Nd:YAG laser (50 W max average laser power), with a 1064 nm wavelength. The processed materials included Ti-6AI-4V, Al-2219 and Al-2090. For Phase I of this project, the laser process conditions were varied and optimized to see the effects on melt-quenching, cladding/alloying (using the pre-placed powder technique), and cutting. Key parameters such laser power, pulse repetition frequency, process speed, and shield gas flow and the observed process characteristics such as plasma formation during laser/material interaction, have been reported for all experimental runs. Preliminary materials characterization of select samples was carried out using various microscopy, diffraction, spectroscopy and microhardness test methods, and reported. Select nitridation results of Ti-6AI-4V using nitrogen assist gas indicated the successful formation of hard titanium nitrides with much higher hardness (2180 kg/sq mm). A cost-effective and simple powder delivery system has been successfully fabricated for the further experimentation in Phase H.

Nagarathnam, Karthik↗

Removing imaging systematics from galaxy clustering measurements with Obiwan: application to the SDSS-IV extended Baryon Oscillation Spectroscopic Survey emission-line galaxy sample

This article presents the application of a new tool, Obiwan, which uses image simulations to determine the selection function of a galaxy redshift survey and calculate three-dimensional (3D) clustering statistics. Obiwan relies on a forward model of the process by which images of the night sky are transformed into a 3D large-scale structure catalogue, and offers several advantages over more traditional map-based techniques – such as operating on individual exposures and adopting a maximum likelihood approach. The photometric pipeline automatically detects and models galaxies and then generates a catalogue of such galaxies with detailed information for each one of them, including their location, redshift, and so on. Systematic biases in the imaging data are therefore imparted into the catalogues and must be accounted for in any scientific analysis of their information content. Obiwan simulates this process for samples selected from the Legacy Surveys imaging data. This imaging data will be used to select target samples for the next-generation Dark Energy Spectroscopic Instrument (DESI) experiment. Here, we apply Obiwan to a portion of the SDSS-IV extended Baryon Oscillation Spectroscopic Survey emission-line galaxies (ELGs). Systematic biases in the data are clearly identified and removed. We compare the 3D clustering results to those obtained by the map-based approach applied to the complete eBOSS Data Release 16 (DR16) sample. We find the results are consistent, thereby validating the eBOSS DR16 ELG catalogues, which is used to obtain cosmological results.

79 ASTRONOMY AND ASTROPHYSICS↗

New Millennium EO3

The New Millennium Program (NMP) is a NASA technology program that focuses on the validation of advanced spacecraft and instrumentation technologies in space. This program specifically seeks technologies that could significantly benefit future space and Earth science missions by enabling new science capabilities and reducing life cycle costs. These technologies must also require a validation in space to mitigate risks to the first science users, and provide cross-cutting benefits to both NASA's Earth and Space Science enterprises. The NASA Office of Earth Science (OES) directed the NMP to focus the third Earth Observing mission, E03, on innovative measurement concepts that would facilitate remote sensing observations from orbits beyond conventional low-Earth orbit (LEO). These orbits include geosynchronous orbits, highly elliptical orbits, mid-Earth and high-Earth orbits, and other unique vantage points such as L1 and L2. To maximize the input from the Earth science community, a NASA Research Announcement (NRA) was released to solicit innovative measurement concepts for this NMP flight. Because the NMP is a technology validation program, rather than a conventional science program, the NRA required that these measurement concepts employ revolutionary technologies and/or measurement strategies that will enable future science missions from orbits beyond LEO. Another requirement was that a validation in space was needed to reduce real or perceived risks of this concept to future science users. The proposals submitted in response to this NRA were peer reviewed by the NASA OES. The measurement concepts selected through this process will be summarized in this presentation. The E03 measurement concept NRA did not solicit complete mission concepts or flight hardware. Instead, the selected investigators will join integrated project formulation teams to define the mission for the demonstration of the measurement technique and participate in mission design trades and implementation planning. The teams will define and document the measurement approach, the required technologies, the validation plan, the scalability of the design to future science missions, and the infusion path for the completely validated instrument. During this project formulation phase, the specific technologies required to implement each measurement concept will be solicited through an open technology solicitation, and the technology providers will be added to the integrated teams. Once a complete candidate mission concept has been formulated for each measurement concept, these concepts will be subjected to a comprehensive review. The Associate Administrator of the OES will use the results of this review to select a single concept for the E03 flight opportunity. That mission concept will enter its implementation phase, which is expected to last for less than 36 months before launch. During this phase, and after launch, the implementation team will work with the NMP to document and disseminate the information gathered during the flight qualification testing and operations of the measurement concept and its component technologies. This information will be archived and published, where appropriate, to encourage the rapid infusion of these validated technologies into future space and Earth science missions. I

Li, Fuk K.↗

Experimental Resonance Enhanced Multiphoton Ionization (REMPI) studies of small molecules

Resonance enhanced multiphoton ionization (REMPI) utilizes tunable dye lasers to ionize an atom or molecule by first preparing an excited state by multiphoton absorption and then ionizing that state before it can decay. This process is highly selective with respect to both the initial and resonant intermediate states of the target, and it can be extremely sensitive. In addition, the products of the REMPI process can be detected as needed by analyzing the resulting electrons, ions, fluorescence, or by additional REMPI. This points to a number of exciting opportunities for both basic and applied science. On the applied side, REMPI has great potential as an ultrasensitive, highly selective detector for trace, reactive, or transient species. On the basic side, REMPI affords an unprecedented means of exploring excited state physics and chemistry at the quantum-state-specific level. An overview of current studies of excited molecular states is given to illustrate the principles and prospects of REMPI.

Dehmer, J. L.↗

A Mixed-Method Design Approach for Empirically Based Selection of Unbiased Data Annotators

Implicit bias embedded in the annotated data is by far the greatest impediment in the effectual use of supervised machine learning models in tasks involving race, ethics, and geopolitical polarization. For societal good and demonstrable positive impact on wider society, it is paramount to carefully select data annotators and rigorously validate the annotation process. Current approaches to selecting annotators are not sufficiently grounded in scientific principles and are limited at the policy-guidance level, thereby rendering them unusable for machine learning practitioners. This work proposes a new approach based on the mixed-methods design that is functional, adaptable, and simpler to implement in selecting unbiased annotators for any machine learning problem. By demonstrating it on a real-world geopolitical problem, we also identified and ranked key inane profile characteristics towards an empirically-based selection of unbiased data annotators.

Thakur, Gautam Malviya↗

Produced Water-Economic, Socio, Environmental Simulation Model (PW-ESEim) Model: Proof-of-Concept for Southeastern New Mexico

A proof-of-concept tool, the Produced Water-Economic, Socio, Environmental Simulation model (PW-ESESim), was developed to support ease of analysis. The tool was designed to facilitate head-to-head comparison of alternative produced water source, treatment, and reuse water management strategies. A graphical user interface (GUI) guides the user through the selection and design of alternative produced water treatment and reuse strategies and the associated health and safety risk and economic benefits. At the highest conceptual level, alternative water strategies include the selection of a source water (locally or regionally available produced water), treatment strategy (pre-treatment, physical, chemical, biological, desalination, and post-treatment processes) and product water purpose (e.g., irrigation, industrial processing, environmental). After selection of these details, the PW-ESESim output a number of key economic, societal, environmental, public/ecological health and safety metrics to support user decision-making; specific examples include, cost of treatment, improvements in freshwater availability, human and ecologic health impacts and growth in local jobs and the economy. Through the simulation of different produced water treatment and management strategies, tradeoffs are identified and used to inform fit-for-purpose produced water treatment and reuse management decisions. While the tool was initially designed using Southeastern New Mexico (Permian Basin) as a case study, the general design of the PW-ESESim model can be extended to support other oil and gas regions of the U.S.

54 ENVIRONMENTAL SCIENCES↗

Rare Earth Extraction and Concentration at Pilot-Scale from North Dakota Coal-Related Feedstocks (Final Technical Report)

The objectives of this project were to design, construct, commission, and operate a pilot-scale system utilizing UND's REE extraction technology from lignite, and complete saleability and economic evaluations of products. The process includes a dilute-acid extraction process from low-rank-coals, followed by selective precipitations and further processing to produce mixed rare earth oxide materials. The pilot was successfully constructed to a 1,000 lb/hr nameplate capacity and tested with over 100 tons of >300-ppm lignite-based feedstocks and produced saleable-quality products during operation. The team successfully attained a TRL status of 6 with the completion and testing of the pilot system, and the technology is poised for demonstration at a commercial scale.

01 COAL, LIGNITE, AND PEAT↗

Applications of artificial intelligence to space station: General purpose intelligent sensor interface

This final report describes the accomplishments of the General Purpose Intelligent Sensor Interface task of the Applications of Artificial Intelligence to Space Station grant for the period from October 1, 1987 through September 30, 1988. Portions of the First Biannual Report not revised will not be included but only referenced. The goal is to develop an intelligent sensor system that will simplify the design and development of expert systems using sensors of the physical phenomena as a source of data. This research will concentrate on the integration of image processing sensors and voice processing sensors with a computer designed for expert system development. The result of this research will be the design and documentation of a system in which the user will not need to be an expert in such areas as image processing algorithms, local area networks, image processor hardware selection or interfacing, television camera selection, voice recognition hardware selection, or analog signal processing. The user will be able to access data from video or voice sensors through standard LISP statements without any need to know about the sensor hardware or software.

Mckee, James W.↗

Computer Control For Gas/Tungsten-Arc Welding

Prototype computer-based feedback control system developed for use in gas/tungsten arc welding. Beyond improving welding technician's moment-to-moment general control of welding process, control system designed to assist technician in selecting appropriate welding-process parameters, and provide better automatic voltage control. Modular for ease of reconfiguration and upgrading. Modularity also reflected in software. Includes rack-mounted computer, based on VME bus, containing Intel 80286 and 80386 processors.

Andersen, Kristinn↗

Sustainability in Directed Energy Deposition

Directed energy deposition (DED) additive manufacturing (AM) has been recognized as an efficient and sustainable technology in the field of advanced manufacturing. In the past few years, Considerable discussion has been made by researchers to promote DED AM for better performance in manufacturing. The discussions focus on basic theoretical research, process optimization and control, technology innovation, and industrial applications. However, this technology׳s environmental and economic benefits over traditional manufacturing processes are still to be seen and its sustainability is also a mystery. Here, this chapter presents a critical overview of the environmental sustainability of DED to provide a comprehensive understanding of the effects of materials, processing conditions, and geometric complexities on the energy consumption and environmental impacts of DED and provide a better guide for decision-makers in terms of selecting suitable manufacturing processes. In addition, this chapter proposes a novel framework for DED AM sustainability assessment and improvement based on the Life Cycle Assessment (LCA) method and multi-objective optimization. At last, future perspectives and recommendations for the sustainability of DED AM are put forward.

54 ENVIRONMENTAL SCIENCES↗

An empirical analysis of the distribution of overshoots in a stationary Gaussian stochastic process

The frequency distribution of overshoots in a stationary Gaussian stochastic process is analyzed. The primary processes involved in this analysis are computer simulation and statistical estimation. Computer simulation is used to simulate stationary Gaussian stochastic processes that have selected autocorrelation functions. An analysis of the simulation results reveals a frequency distribution for overshoots with a functional dependence on the mean and variance of the process. Statistical estimation is then used to estimate the mean and variance of a process. It is shown that for an autocorrelation function, the mean and the variance for the number of overshoots, a frequency distribution for overshoots can be estimated.

Carter, M. C.↗

Minimizing Launch Mass for ISRU Processes

The University of Dayton and the Jet Propulsion Laboratory are developing a methodology for estimating the Earth launch mass (ELM) of processes for In-Situ Resource Utilization (ISRU) with a focus on lunar resource recovery. ISRU may be enabling for both an extended presence on the Moon, and for large sample return missions and for a human presence on Mars. To accomplish these exploration goals, the resources recovered by ISRU must offset the ELM for the recovery process. An appropriate figure of merit is the cost of the exploration mission, which is closely related to ELM. For a given production rate and resource concentration, the lowest ELM - and the best ISRU process - is achieved by minimizing capital equipment for both the ISRU process and energy production. ISRU processes incur Carnot limitations and second law losses (irreversibilities) that ultimately determine production rate, material utilization and energy efficiencies. Heat transfer, chemical reaction, and mechanical operations affect the ELM in ways that are best understood by examining the process's detailed energetics. Schemes for chemical and thermal processing that do not incorporate an understanding of second law losses will be incompletely understood. Our team is developing a methodology that will aid design and selection of ISRU processes by identifying the impact of thermodynamic losses on ELM. The methodology includes mechanical, thermal and chemical operations, and, when completed, will provide a procedure and rationale for optimizing their design and minimizing their cost. The technique for optimizing ISRU with respect to ELM draws from work of England and Funk that relates the cost of endothermic processes to their second law efficiencies. Our team joins their approach for recovering resources by chemical processing with analysis of thermal and mechanical operations in space. Commercial firms provide cost inputs for ELM and planetary landing. Additional information is included in the original extended abstract.

England, C.↗

Engine selection for the Space Exploration Initiative

The process used by NASA in the selection of the engine for the Space Exploration Initiative mission is described. The major propulsion requirements of the engine are addressed along with the engine options and key drivers and trades. Special attention is given to the requirements of the propellant feed system and the reaction control system. As a result of the 90-study, four moderate chamber pressure expander-cycle oxygen/hydrogen engines with a thrust level of 20,000 lbf each were selected for the lunar transfer vehicle. The paper also presents results of architecture studies and of advanced engine test bed studies.

Jones, Lee W.↗