Preparation and Thermoelectric Properties of p- and n-type IrSb(sub 3)
IrSb(sub 3) belongs to a large family of compounds with the skutterudite crystal structure (CoAs(sub 3)).
seebeck coefficient electrical resistivity thermal↗
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Results for “Preparations”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Deep Space One: Preparing for Space Exploration in the 21st Century
This October, NASA will take a revolutionary step with the launch of the New Millennium program's Deep Space One (DS1) mission. DS1 will fly by asteroid 1992KD in July of 1999 and will then be on a trajectory toward comet 19P/Borrelly.
validation↗
Elastic Electron Scattering by Coherently Prepared 138Ba (6s6p1p1) Atoms; Differential Cross
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Elastic Electron Scattering↗
Tunable Infrared Lasers: Preparing for Expanded use in Environmental Monitoring
The literature on the use of tunable infrared lasers, for atmospheric trace gas detection and monitoring is about 25 years of age. However, this field, whith its myriad of potential application areas, has always been driven by the available laser technology. As new or improved laser devices become available, with characteristics which lend themselves to operation in compact, nearly autonomous instruments, their application to atmospheric science and environmental measurements expands.
tunable infrared lasers↗
Thermal testing: the basics of planning, preparation, and implementation
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thermal testing↗
Preparing for the Huygens Probe Mission, Cassini orbit determination results for the first and second targeted Titan encounters
Dynamic modeling of the spacecraft and Saturn system, tracking data, including radio-metric and optical navigation data, and measurement modeling associated with the final trajectory analysis are described. Navigation predictions produced during the operational phase are compared with the final trajectory in order to gain insight into navigation performance and maneuver execution errors. Special attention is given to refinement of the dynamical environment of Saturn, particularly Titan, during the first two orbits.
navigation↗
Methods of preparing polyimides and artifacts composed thereof
Methods of converting essentially unpolymerized precursors into polyimides in which the precursors are exposed to microwave radiation. Preheating, thermal post-curing, and other techniques may be employed to promote the development of optimum properties; and reinforcements can be employed to impart strength and rigidity to the final product. Also disclosed are processes for making various composite artifacts in which non-polymeric precursors are converted to polyimides by using the techniques described above.
Gagliani, John↗
Methods of preparing polyimides and artifacts composed thereof
Methods of converting essentially unpolymerized precursors into polyimides in which the precursors are exposed to microwave radiation. Preheating, thermal post-curing, and other techniques may be employed to promote the development of optimum properties; and reinforcements can be employed to impart strength and rigidity to the final product. Also disclosed are processes for making various composite artifacts in which non-polymeric precursors are converted to polyimides by using the techniques described above.
Gagliani, John↗
Porous article with surface functionality and method for preparing same
Porous organic articles having no surface functionality may be treated by remote plasma discharge to thereby introduce functionality to the surface of the article. The functionality is introduced throughout the article's surface, including the exterior surface and the surfaces of the pores. Little or no degradation of the porous organic article occurs as a result of the functionalization. Amino, hydroxyl, carbonyl and carboxyl groups may be introduced to the article. In this way, an essentially inert hydrophobic porous article, made from, for example, polyethylene, can have its surface modified so that the surface becomes hydrophilic. The remote plasma discharge process causes essentially no change in the bulk properties of the organic article. The remote plasma discharge process is preferably conducted so that no photons, and particularly no ultraviolet radiation, is transmitted from the plasma glow to the porous article. The surface-functionalized article may be used, for example, as a solid support in organic synthesis or in the chromatographic purification of organic or biochemicals.
Koontz, Steven L.↗
Porous article with surface functionality and method for preparing same
Porous organic articles having no surface functionality may be treated by remote plasma discharge to thereby introduce functionality to the surface of the article. The functionality is introduced throughout the article's surface, including the exterior surface and the surfaces of the pores. Little or no degradation of the porous organic article occurs as a result of the functionalization. Amino, hydroxyl, carbonyl and carboxyl groups may be introduced to the article. In this way, an essentially inert hydrophobic porous article, made from, for example, polyethylene, can have its surface modified so that the surface becomes hydrophilic. The remote plasma discharge process causes essentially no change in the bulk properties of the organic article. The remote plasma discharge process is preferably conducted so that no photons, and particularly no ultraviolet radiation, is transmitted from the plasma glow to the porous article. The surface-functionalized article may be used, for example, as a solid support in organic synthesis or in the chromatographic purification of organic or biochemicals.
Koontz, Steven L.↗
Methods of preparing polyimides and artifacts composed thereof
Methods of converting essentially unpolymerized precursors into polyimides in which the precursors are exposed to microwave radiation. Preheating, thermal post-curing, and other techniques may be employed to promote the development of optimum properties; and reinforcements can be employed to impart strength and rigidity to the final product. Also disclosed are processes for making various composite artifacts in which non-polymeric precursors are converted to polyimides by using the techniques described above.
Gagliani, John↗
Phenylated polyimides prepared from 3,6-diarylpyromellitic dianhydride and aromatic diamines
A new class of soluble phenylated polyimides made from 3,6-diarypyromellitic dianhydride and process for the manufacture of the 3,6-diarypyromellitic dianhydride starting material. The polyimides obtained with said dianhydride are readily soluble in appropriate organic solvents and are distinguished by excellent thermal, electrical and/or mechanical properties making the polyimides ideally suited as coating materials for microelectronic apparatii, as membranes for selective molecular separation or permeation or selective gas separation or permeation, or as reinforcing fibers in molecular composites, or as high modulus, high tensile strength fibers.
Harris, Frank W.↗
Preparation of high density heavy metal fluoride glasses with extended ultraviolet and infra red ranges, and such high density heavy metal fluoride glasses
A heavy metal fluoride glass composition range (in mol percent) consisting essentially of: (16-30)BaF.sub.2.(8-26)HfF.sub.4.(6-24)InF.sub.3 or GaF.sub.3.(4-16)CdF.sub.2.(6-24)YbF.sub.3.(4-22)ZnF.sub.2. In an alternative embodiment, a heavy metal fluoride glass composition range (in mol percent) comprises (16-30)BaF.sub.2.(8-26)HfF.sub.4.(6-24) of (0-24)InF.sub.3, (0-24)GaF.sub.3 and (0-19)AlF.sub.3.(1-16)CdF.sub.2.(6-24)YbF.sub.3.(4-26)ZnF.sub.2. A preferred heavy metal fluoride glass produced in accordance with the present invention comprises a composition (in mol %) and comprises about 26BaF.sub.2.18HfF.sub.4.7InF.sub.3.5GaF.sub.3.10CdF.sub.2.18YbF.sub.3. 16ZnF.sub.2. A preferred heavy metal fluoride glass has maximum thickness of most preferably about 3 mm. Another preferred heavy metal fluoride glass comprises a composition (in mol %) and comprises about 26BaF.sub.2.18HfF.sub.4.12AlF.sub.3.10CdF.sub.2.18YbF.sub.3.16ZnF.sub.2.
Martin, Steven W.↗
Material for surface-enhanced Raman spectroscopy, and SER sensors and method for preparing same
Metal-doped sol-gel materials, suitable for use as sensors for surface-enhanced Raman spectroscopic analysis for trace chemical detection, are produced by effecting gelation and solvent removal of a doped sol-gel under mild temperature conditions. At least in certain instances reaction and drying will desirably be effected in an oxygen-starved environment. The metal of the sol-gel material functions, when irradiated, to produce a plasmon field for interaction with molecules of an analyte in contact therewith, increasing by orders of magnitude Raman photons that are generate by excitation radiation, and the method allows matching of the metal and metal particle size to a wavelength of light (or incident radiation, e.g., laser radiation) to generate surface plasmons. The porosity of the sol-gel material dramatically increases the surface area, and thereby the amount of metal exposed for analyte interaction. The sensors provided may be in the form of glass vials, fiber optics, multi-well micro-sample plates, etc., having surface coatings of the doped sol-gel material, to provide sampling systems for use in a Raman instrument.
Farquharson, Stuart↗
High-temperature polyimides prepared from 2,2-bis-[(2-halo-4-aminophenoxy)-phenyl]hexafluoropropane
There are provided the aromatic diamines 2,2-bis-[(2-halo-4-aminophenoxy)-phenyl]hexafluoropropane, where the attached ortho halogen is preferably chlorine, and 4,4'-bis(4-aminophenoxy)biphenyl, as novel monomers for polyimide polymerizations. The former, when reacted with 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, provides a polyimide having exceptional high-temperature performance. The latter diamine is a low-cost monomer for polyimide production.
Jones, Robert J.↗
Phenol-formaldehyde intumescent coating composition and coating prepared therefrom
Intumescent coatings which form a thick, uniform, fine celled, low density foam upon exposure to a high intensity heat flux or flame are disclosed, the invention coatings comprise phenolic resin prepolymer containing a blowing agent and a nucleating agent; in the preferred embodiments the coatings also contains a silicone surfactant, the coatings are useful in thermal and fire protection systems.
Salyer, Ival O.↗
Excavation on the Moon: Regolith Collection for Oxygen Production and Outpost Site Preparation
The development of a robust regolith moving system for lunar and planetary processing and construction is critical to the NASA mission to the Moon and Mars. Oxygen production may require up to 200 metric tons of regolith collection per year; outpost site development may require several times this amount. This paper describes progress in the small vehicle implement development and small excavation system development. Cratos was developed as a platform for the ISRU project to evaluate the performance characteristics of a low center of gravity, small (0.75m x 0.75m x 0.3m), low-power, tracked vehicle performing excavation, load, haul, and dump operations required for lunar ISRU. It was tested on loose sand in a facility capable of producing level and inclined surfaces, and demonstrated the capability to pick up, carry, and dump sand, allowing it to accomplish the delivery of material to a site. Cratos has demonstrated the capability to pick up and deliver simulant to a bury an inflatable habitat, to supply an oxygen production plant, and to build a ramp.
Caruso, John J.↗
New Developments for Physically-based Falling Snow Retrievals over Land in Preparation for GPM
The NASA Global Precipitation Measurement mission (GPM) concept centers on deploying a Core spacecraft carrying a dual-frequency precipitation radar and a microwave radiometric imager with channels from 10 to 183 GHz to serve as a precipitation physics observatory and a calibration reference to unify a constellation of dedicated and operational passive microwave sensors. Because of the extended orbit of the Core (plus or minus 65 deg) and the enhanced dual frequency radar and high frequency radiometer, GPM will be able to sense falling snow precipitation and light rain over land. Accordingly, GPM has partnered with the Canadian CloudSat/CALIPSO Validation Project (C3VP) to obtain observations to provide one of several important ground-based validation data sets around which the falling snow models and retrieval algorithms can be further developed and tested. In this work we compare and correlate the long time series (Nov.'06 - March '07) measurements of precipitation rate from parsivels to the passive (89, 150, 183 plus or minus 1, plus or minus 3, plus or minus 7 GHz) observations of NOAA's AMSU-B radiometer. We separate the comparisons into categories of no precipitation, liquid rain and falling snow precipitation. We found that there are similar TBs (especially at 89 and 150 GHz) for cases with falling snow and for non-precipitating cases. The comparisons indicate that surface emissivity contributions to the satellite observed TB over land can add uncertainty in detecting and estimating falling snow. The newest results show that by computing brightness temperatures based on CARE radiosonde data and a rough estimate of surface emissivity show that the cloud ice scattering signal in the AMSU-B data is detected. That is the differences in computed TB and AMSU-B TB for precipitating and non-precipitating cases are unique such that the precipitating and non-precipitating cases can be identified. These results require that the radiosonde releases are within an hour of the AMSU-B data. Forest fraction, snow cover, and measured emissivities were combined to calculate the surface emissivities.
Jackson, Gail S.↗