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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Quantitative Measurements of Nitric Oxide Concentration in High-Pressure, Swirl-Stabilized Spray Flames

Lean direct-injection (LDI) spray flames offer the possibility of reducing NO(sub x) emissions from gas turbines by rapid mixing of the liquid fuel and air so as to drive the flame structure toward partially-premixed conditions. We consider the technical approaches required to utilize laser-induced fluorescence methods for quantitatively measuring NO concentrations in high-pressure LDI spray flames. In the progression from atmospheric to high-pressure measurements, the LIF method requires a shift from the saturated to the linear regime of fluorescence measurements. As such, we discuss quantitative, spatially resolved laser-saturated fluorescence (LSF), linear laser-induced fluorescence (LIF), and planar laser-induced fluorescence (PLIF) measurements of NO concentration in LDI spray flames. Spatially-resolved LIF measurements of NO concentration (ppm) are reported for preheated, LDI spray flames at pressures of two to five atmospheres. The spray is produced by a hollow-cone, pressure-atomized nozzle supplied with liquid heptane. NO is excited via the Q(sub 2)(26.5) transition of the gamma(0,0) band. Detection is performed in a two nanometer region centered on the gamma(0,1) band. A complete scheme is developed by which quantitative NO concentrations in high-pressure LDI spray flames can be measured by applying linear LIF. NO is doped into the reactants and convected through the flame with no apparent destruction, thus allowing a NO fluorescence calibration to be taken inside the flame environment. The in-situ calibration scheme is validated by comparisons to a reference flame. Quantitative NO profiles are presented and analyzed so as to better understand the operation of lean-direct injectors for gas turbine combustors. Moreover, parametric studies are provided for variations in pressure, air-preheat temperature, and equivalence ratio. Similar parametric studies are performed for lean, premixed-prevaporized flames to permit comparisons to those for LDI flames. Finally, PLIF is expanded to high pressure in an effort to quantify the detected fluorescence image for LDI flames. Success is achieved by correcting the PLIF calibration via a single-point LIF measurement. This procedure removes the influence of any preferential background that occurs in the PLIF detection window. In general, both the LIF and PLIF measurements verify that the LDI strategy could be used to reduce NO(sub x) emissions in future gas turbine combustors.

Cooper, Clayton S.↗
DOE OSTI2016

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber

The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical polymerization (ATRP) from a poly- (vinyl chloride)-co-chlorinated poly(vinyl chloride) (PVC-co-CPVC) fiber. ATRP was employed in the surface graft polymerization of acrylonitrile (AN) and tert-butyl acrylate (tBA), precursors for uranium-interacting functional groups, from PVC-co-CPVC fiber. The [tBA]/[AN] was systematically varied to identify the optimal ratio between hydrophilic groups (from tBA) and uranyl-binding ligands (from AN). The best performing adsorbent fiber, the one with the optimal [tBA]/[AN] ratio and a high degree of grafting (1390%), demonstrated uranium adsorption capacities that are significantly greater than those of the Japan Atomic Energy Agency (JAEA) reference fiber in natural seawater tests (2.42-3.24 g/kg in 42 days of seawater exposure and 5.22 g/kg in 49 days of seawater exposure, versus 1.66 g/kg in 42 days of seawater exposure and 1.71 g/kg in 49 days of seawater exposure for JAEA). Adsorption of other metal ions from seawater and their corresponding kinetics were also studied. The grafting of alternative monomers for the recovery of uranium from seawater is now under development by this versatile technique of ATRP.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2011

EVIDENCE FOR NON-EVOLVING Fe II/Mg II RATIOS IN RAPIDLY ACCRETING z {approx} 6 QSOs

Quasars (QSOs) at the highest known redshift (z {approx} 6) are unique probes of the early growth of supermassive black holes (BHs). Until now, only the most luminous QSOs have been studied, often one object at a time. Here we present the most extensive consistent analysis to date of 4 < z < 6.5 QSOs with observed near-infrared spectra, combining three new z {approx} 6 objects from our ongoing Very Large Telescope-Infrared Spectrometer And Array Camera program with nineteen sources from the literature. The new sources extend the existing Sloan Digital Sky Survey (SDSS) sample toward the faint end of the QSO luminosity function. Using a maximum likelihood fitting routine optimized for our spectral decomposition, we estimate the BH mass (M{sub BH}), the Eddington ratio (defined as L{sub bol}/L{sub Edd}), and the Fe II/Mg II line ratio, a proxy for the chemical abundance, to characterize both the central object and the broad-line region gas. The QSOs in our sample host BHs with masses of {approx}10{sup 9} M{sub sun} that are accreting close to the Eddington luminosity, consistent with earlier results. We find that the distribution of observed Eddington ratios is significantly different than that of a luminosity-matched comparison sample of SDSS QSOs at lower redshift (0.35 < z < 2.25): the average (log (L{sub bol}/L{sub Edd})) = -0.37 (L{sub bol}/L{sub Edd} {approx} 0.43) with a scatter of 0.20 dex for the z > 4 sample and the (log (L{sub bol}/L{sub Edd})) = -0.80 (L{sub bol}/L{sub Edd} {approx} 0.16) with a scatter of 0.24 dex for the 0.35 < z < 2.25 sample. This implies that, at a given luminosity, the M{sub BH} at high-z is typically lower than the average M{sub BH} of the lower-redshift population, i.e., the z > 4 sources are accreting significantly faster than the lower-redshift ones. We show that the derived Fe II/Mg II ratios depend sensitively on the analysis performed: our self-consistent, homogeneous analysis significantly reduces the Fe II/Mg II scatter found in previous studies. The measured Fe II/Mg II line ratios show no sign of evolution with cosmic time in the redshift range 4 < z < 6.5. If the Fe II/Mg II line ratio is used as a secondary proxy of the Fe/Mg abundance ratio, this implies that the QSOs in our sample have undergone a major episode of Fe enrichment in the few 100 Myr preceding the cosmic age at which they are observed.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1976

A correlation polarimeter for noise-like signals

Optimum estimation (tracking) of the polarization plane of a linearly polarized electromagnetic wave is determined when the signal is a narrow-band Gaussian random process with a polarization plane angle which is also a Gaussian random process. This model is compared to previous work and is applicable to space communication. The estimator performs a correlation operation similar to an amplitude-comparison monopulse angle tracker, giving the name correlation polarimeter. Under large signal-to-noise ratio (SNR), the estimator is causal. Performance of the causal correlation polarimeter is evaluated for arbitrary SNR. Optimum precorrelation filtering is determined. With low SNR, the performance of this system is far better than that of previously developed systems. Practical implementation is discussed. A scheme is given to reduce the effect of linearly polarized noise.

Ohlson, J. E.↗
NASA NTRS1982

Spectral discrimination of lithologic facies in the granite of the Pedra Branca Goias using LANDSAT 1 digital imagery

The applicability of LANDSAT MSS imagery for discriminating geobotanical associations observed in zones of cassiterite-rich metasomatic alterations in the granitic body of Serra da Pedra Branca was investigated. Computer compatible tapes of dry and rainy season imagery were analyzed. Image enlargement, corrections, linear contrast stretch, and ratioing of noncorrelated spectral bands were performed using the Image 100 with a grey scale of 256 levels between zero and 255. Only bands 5 and 7 were considered. Band ratioing of noncorrelated channels (5 and 7) of rainy season imagery permits distinction of areas with different vegetation coverage percentage, which corresponds to geobotanial associations in the area studied. The linear contrast stretch of channel 5, especially of the dry season image is very unsatisfactory in this area.

Parada, N. D. J.↗
NASA NTRS1991

Optimal uniform-damping ratio controller for sequential design of multivariable systems

An optimal uniform-damping ratio controller is developed for the sequential design of a multivariable control system so that the designed closed-loop poles of the respective multivariable system and reduced-order observer are exactly placed on the negative real axis and/or the boundaries of desired sectors with constant-damping ratios. The functions in the quadratic performance index to be minimized are chosen as a combination of the weighted outputs, reduced states and inputs. Also, the optimal uniform-damping ratio controller is a combination of optimal output-feedback and optimal reduced-order state-feedback controllers. A numerical example is given to demonstrate the design procedure.

Shieh, Leang G.↗
NASA NTRS1992

Heat transfer performance comparisons of five different rectangular channels with parallel angled ribs

This paper systematically presents the results of heat transfer and friction factor data measured in five short rectangular channels with turbulence promoters. The project investigated the combined effects of the channel aspect ratio, rib angle-of-attack, and flow Reynolds number on heat transfer and pressure drop in rectangular channels with two opposite ribbed walls. The channel aspect ratio (width-to-height, W/H, ribs on side W) varied from 1/4 to 1/2, to 1, 2, and 4, while the corresponding rib angles-of-attack alpha were 90 deg, 60 deg, 45 deg, and 30 deg, respectively. The Reynolds number range was 10,000-60,000. The results suggest that the narrow aspect ratio channels (W/H less than 1) give much better heat transfer performance than the wide aspect ratio channels (W/H greater than 1). For the square channel (W/H = 1), the 60 deg/45 deg angled ribs provide the best heat transfer performance. For the narrow aspect ratio channel (W/H = 1/4 or 1/2), the 45 deg/60 deg angled ribs are recommended, while the 30 deg/45 deg angled ribs are better for wide aspect ratio channels (W/H = 4 or 2).

Park, J. S.↗
NASA NTRS2009

100-lbf LO2/CH4 RCS Thruster Testing and Validation

100 pound thrust liquid Oxygen-Methane thruster sized for RCS (Reaction Control System) applications. Innovative Design Characteristics include: a) Simple compact design with minimal part count; b) Gaseous or Liquid propellant operation; c) Affordable and Reusable; d) Greater flexibility than existing systems; e) Part of NASA'S study of "Green Propellants." Hot-fire testing validated performance and functionality of thruster. Thruster's dependence on mixture ratio has been evaluated. Data has been used to calculate performance parameters such as thrust and Isp. Data has been compared with previous test results to verify reliability and repeatability. Thruster was found to have an Isp of 131 s and 82 lbf thrust at a mixture ratio of 1.62.

Barnes, Frank↗
DOE OSTI2012

Relationship between Particle Size Distribution of Low-Rank Pulverized Coal and Power Plant Performance

The impact of particle size distribution (PSD) of pulverized, low rank high volatile content Alaska coal on combustion related power plant performance was studied in a series of field scale tests. Performance was gauged through efficiency (ratio of megawatt generated to energy consumed as coal), emissions (SO 2 , NO x , CO), and carbon content of ash (fly ash and bottom ash). The study revealed that the tested coal could be burned at a grind as coarse as 50% passing 76 microns, with no deleterious impact on power generation and emissions. The PSD’s tested in this study were in the range of 41 to 81 percent passing 76 microns. There was negligible correlation between PSD and the followings factors: efficiency, SO 2 , NO x , and CO. Additionally, two tests where stack mercury (Hg) data was collected, did not demonstrate any real difference in Hg emissions with PSD. The results from the field tests positively impacts pulverized coal power plants that burn low rank high volatile content coals (such as Powder River Basin coal). These plants can potentially reduce in-plant load by grinding the coal less (without impacting plant performance on emissions and efficiency) and thereby, increasing their marketability.

Ganguli, Rajive↗
NASA NTRS1992

The Use of Subcarriers in Future DSN Missions

The performance of deep space telemetry signals that employ a residual carrier modulation technique is compared in the presence and absence of a subcarrier. When the subcarrier is present, the performance for the resulting pulse-coded modulation/phase-shift keyed/phase-modulated (PCM/PSK/PM) scheme is evaluated for both sine wave and square wave subcarriers and non-return-to zero (NRZ) data. When the subcarrier is absent, the performance for the resulting PCM/PM technique is evaluated for both the NRZ and the bi-phase data format. The comparison is based on telemetry performance as well as bandwidth efficiency. The first criterion is characterized in terms of the symbol error rate (SER) as a function of symbol SNR, loop bandwidth-to-data rate ratio, and modulation index. The bandwidth efficiency is characterized by the occupancy factor. The results of both the analysis and measurements show that when the interference-to-carrier ratio (ICR) is less than -15 dB, the performance degradation in the absence of a subcarrier is negligible. Various combinations of loop bandwidth-to-data rate ratios and modulation indices that achieve this performance are derived and listed. Bandwidth occupancy comparison indicates that PCM/PM/NRZ is the most efficient in this regard. Therefore, by eliminating the subcarrier and using the PCM/PM/NRZ scheme, many advantages can be realized without any sacrifice in performance.

Shihabi, M. M.↗
NASA NTRS1994

A Comparison of Telemetry Signals in the Presence and Absence of a Subcarrier

The performance of deep-space telemetry signals that employ a residual carrier modulation technique is compared in the presence and absence of a subcarrier. When the subcarrier is present, the performance for the resulting pulse-coded modulation/phase-shift keyed/phase-modulated (PCM/PSK/PM) scheme is evaluated for both sine-wave and square-wave subcarriers and Non-Return-to Zero (NRZ) data. When the subcarrier is absent, the performance for the resulting PCM/PM technique is evaluated for both the NRZ and the bi-phase data format. The comparison is based on telemetry performance as well as bandwidth efficiency. The first criterion is characterized in terms of the Symbol Error Rate (SER) as a function of symbol SNR, loop bandwidth-to-data rate ratio, and modulation index. The bandwidth efficiency is characterized by the occupancy factor. The results of both the analysis and measurements show that when the Interference-to-Carrier Ratio (ICR) is less than -20 dB, the performance degradation in the absence of a subcarrier is negligible. Various combinations of loop bandwidth-to-data rate ratios and modulation indices that achieve this performance are derived and listed. Bandwidth occupancy comparison indicates that PCM/PM/NRZ is the most efficient in this regard. Therefore, by eliminating the subcarrier and using the PCM/PM/NRZ scheme, many advantages can be realized without any sacrifice in performance.

Shihabi, Mazen M.↗
NASA NTRS1991

Signal processing considerations for low signal to noise ratio laser Doppler and phase Doppler signals

The relative performance of current methods used for estimating the phase and the frequency in LDV and phase Doppler applications in low signal to noise ratio conditions is analyzed. These methods include the Fourier analysis and the correlation techniques. Three methods that use the correlation function for frequency and phase estimations are evaluated in terms of accuracy and speed of processing. These methods include: (1) the frequency estimation using zero crossings counting of the auto-correlation function, (2) the Blackman-Tukey method, and (3) the AutoRegressive method (AR). The relative performance of these methods is evaluated and compared with the Fourier analysis method which provides the optimum performance in terms of the Maximum Likelihood (ML) criteria.

Ibrahim, K. M.↗
DOE OSTI2015

Computational Fluid Dynamics Simulation of Gasoline Compression Ignition

Gasoline compression ignition (GCI) is a low temperature combustion (LTC) concept that has been gaining increasing interest over the recent years owing to its potential to achieve diesel-like thermal efficiencies with significantly reduced engine-out nitrogen oxides (NOx) and soot emissions compared to diesel engines. In this work, closed-cycle computational fluid dynamics (CFD) simulations are performed of this combustion mode using a sector mesh in an effort to understand effects of model settings on simulation results. One goal of this work is to provide recommendations for grid resolution, combustion model, chemical kinetic mechanism, and turbulence model to accurately capture experimental combustion characteristics. Grid resolutions ranging from 0.7 mm to 0.1 mm minimum cell sizes were evaluated in conjunction with both Reynolds averaged Navier-Stokes (RANS) and Large Eddy Simulation (LES) based turbulence models. Solution of chemical kinetics using the multi-zone approach is evaluated against the detailed approach of solving chemistry in every cell. The relatively small primary reference fuel (PRF) mechanism (48 species) used in this study is also evaluated against a larger 312-species gasoline mechanism. Based on these studies the following model settings are chosen keeping in mind both accuracy and computation costs – 0.175 mm minimum cell size grid, RANS turbulence model, 48-species PRF mechanism, and multi-zone chemistry solution with bin limits of 5 K in temperature and 0.05 in equivalence ratio. With these settings, the performance of the CFD model is evaluated against experimental results corresponding to a low load start of injection (SOI) timing sweep. The model is then exercised to investigate the effect of SOI on combustion phasing with constant intake valve closing (IVC) conditions and fueling over a range of SOI timings to isolate the impact of SOI on charge preparation and ignition. Simulation results indicate that there is an optimum SOI timing, in this case -30?aTDC (after top dead center), which results in the most stable combustion. Advancing injection with respect to this point leads to significant fuel mass burning in the colder squish region, leading to retarded phasing and ultimately misfire for SOI timings earlier than -42?aTDC. On the other hand, retarding injection beyond this optimum timing results in reduced residence time available for gasoline ignition kinetics, and also leads to retarded phasing, with misfire at SOI timings later than -15?aTDC.

Energy conversion↗
DOE OSTI2019

A universal discoidal nanoplatform for the intracellular delivery of PNAs

Peptide nucleic acids (PNAs) have gained considerable attention due to their remarkable potential in gene editing and targeting-based strategies. However, cellular delivery of PNAs remains a challenge in developing their broader therapeutic applications. Here, we investigated a novel complex made of lipid bicelles and PNA-based carriers for the efficient delivery of PNAs. For proof of concept, PNAs targeting microRNA (miR) 210 and 155 were tested. Comprehensive evaluation of positive as well as negative charge-containing bicelles with PNA : lipid ratios of 1 : 100, 1 : 1000, and 1 : 2500 was performed. The negatively charged bicelles with a PNA : lipid molar ratio of 1 : 2500 yielded a discoidal shape with a uniform diameter of ~30 nm and a bilayer thickness of 5 nm, while the positively charged bicellar system contained irregular vesicles after the incorporation of PNA. Small-angle X-ray scattering (SAXS) analysis was performed to provide insight into how the hydrophobic PNAs interact with bicelles. Further, flow cytometry followed by confocal microscopy analyses substantiate the superior transfection efficiency of bicelles containing dyeconjugated antimiR PNAs. Functional analysis also confirmed miR inhibition by PNA oligomers delivered by bicelles. The nanodiscoidal complex opens a new pathway to deliver PNAs, which, on their own, are a great challenge to be endocytosed into cells.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

Heat Transfer Coefficients of Additively Manufactured Tubes with Internal Pin Fins for Supercritical Carbon Dioxide Cycle Recuperators

This paper describes the measurement of convective heat transfer coefficients and friction factors for sCO 2 flowing in additively manufactured tubes with internal pin fins at the US DOE’s National Energy Technology Laboratory in Morgantown, WV. The measurement procedures were validated by conducting benchmark tests with smooth stainless-steel tube and comparing the results with published correlations for Nusselt number (Nu) and friction factor. Over Reynolds numbers (ReD) ranging from 5 × 10 4 to 2.5 × 10 5 , measured Nu was within 5% of the Dittus-Boelter correlation and measured friction factors were within 5% of the McAdams correlation for smooth tube flow. The candidate pin fin patterned pipes were additively manufactured (AM) at the Oak Ridge National Laboratory. The pins were circular or elliptical in cross-section and were printed at a 30⁰ angle relative to the inner wall (to meet AM constraints). The pin arrangement was helical to promote enhanced heat transfer due to swirl flow. Pin length to diameter aspect ratio was 1.33, 2, and 8, while the pin diameter to tube diameter ratio was 0.188, 0.125, and 0.063. Tests were performed for ReD varying from 6.9 × 10 4 to 2.2 × 10 5 and at conditions equivalent to the low pressure (LP) outlet (8.69 MPa, 361 K) and the high pressure (HP) inlet (20.7 MPa, 350 K) of the low temperature recuperator (LTR) in an indirect sCO 2 cycle. The Wilson plot technique was utilized to measure the bulk heat transfer coefficients. For the best performing design (tube A, pin length to tube diameter ratio: 1.33, pin diameter to tube diameter ratio: 0.19), the local heat transfer coefficient increased by 136% relative to the Dittus-Boelter correlation at the LTR low pressure outlet and 194% at the LTR high pressure inlet. These correspond to a 282% and a 271% increase in the product of the heat transfer coefficient and surface area (adjusted for fin efficiency) product, respectively. Large pressure drops across the test articles were observed. For Tube Design A, the average friction factor, across the range of ReD considered, was significantly larger than the McAdams correlation at both the LTR LP outlet and the LTR HP inlet. A thermal performance factor was utilized to express the ratio of material required to build a finned heat exchanger relative to a finless heat exchanger with the same heat duty and pumping power. Tube Design A was estimated to decrease the required heat exchanger material by 13%.

Searle, Matthew↗
DOE OSTI2023

Low thermal inertia thermal barrier coatings for spark ignition engines: An experimental study

Application of thermal barrier coatings in spark ignition engines have historically been avoided due to the knock penalty associated with higher surface temperatures induced by the ceramic layer. However, advances in low thermal inertia coatings (i.e. temperature swing coatings) that combine low thermal conductivity with low volumetric heat capacity can prevent excessively high surface temperatures during the intake stroke and reduce or avoid knock while improving performance and efficiency. In this study, a novel coating material was tested in a low compression ratio spark ignition engine to evaluate the performance of an advanced low thermal inertia coating during steady and cold-start conditions. A total of four pistons with this novel material was tested, with an additional piston coated with gadolinium zirconate. Spark timing sweeps demonstrated a maximum 0.8% relative thermal efficiency gain with a thin coating of the novel material. Here, the novel material coated above 200-microns showed a deterioration in performance and efficiency due to charge heating increasing knock propensity. Cold-start tests demonstrated that charge heating is beneficial for reducing unburned hydrocarbons and particle matter emissions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1986

An evaluation of leading-edge flap performance on delta and double-delta wings at supersonic speeds

The aerodynamic performance of leading-edge flaps on three delta double-delta wing planforms having aspect ratios of 1.75, 2.11, and 2.50, have been investigated experimentally. The wings were mounted on a generic fuselage without an inlet canopy, or a vertical tail. The Mach numbers of the flow over the wings were 1.60, 1.90 and 2.16. A primary set of full-span leading-edge flaps with similar root and tip chords were tested on each wing, and several alternate flap planforms were tested on the aspect ratio 1.75 wings. It is found that all leading edge geometries were effective in reducing drag lifting over the range of wing aspect ratios and Mach numbers tested. Greater flap performance was obtained when primary flaps were applied to the delta planform. In general, the primary flap geometry yielded better performance than the alternative geometries tested. Flow visualization techniques were found to be useful for identifying the beneficial effects of leading-edge flap deflection on flow separation as well as fuselage interference effects. Black and white photographs of the delta and double-delta planforms are provided.

Covell, P. F.↗