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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Assessing geothermal/solar hybridization – Integrating a solar thermal topping cycle into a geothermal bottoming cycle with energy storage

Geothermal and concentrating solar power (CSP) technologies typically use heat at different temperatures in their commercial deployments. This enables a technically viable hybridization of a solar topping cycle and a geothermal bottoming cycle at locations where both resources are available. In this article, an underperforming geothermal power system based at Burley, Idaho is used as a baseline to investigate the technical and economic potential of such a hybrid cycle. A direct thermal energy storage (TES) system is also integrated to overcome the intermittency of the solar resource. Design and off-design behavior of key components are modelled to simulate the annual performance of the hybrid system on an hourly basis. The sizing of the solar field and thermal storage is investigated and is seen to significantly impact the annual electricity generation and efficiency. Various cost scenarios for the solar field and thermal energy storage are investigated. An economic metric - levelized cost of electricity (LCOE) - is used to optimize the solar field sizing and TES capacity. The hybrid plant converts the additional solar heat input into additional work with an efficiency of 32.9%. Retrofitting a geothermal plant with solar and eight hours of energy storage can achieve an LCOE of 0.136 $/kWhe in current cost scenarios and 0.081 $/kWhe in a future cost reduction scenario. Although the hybrid system cannot directly compete with current PV systems without batteries, it has an LCOE 32% lower than that of a PV-battery system. This paper provides insights into the research and development of the future grid with a high renewable energy penetration and encourages further study of energy hybridization for improved efficiencies and economics.

15 GEOTHERMAL ENERGY↗
DOE OSTI2021

Ganged-PV System Evaluation

The following report contains data and data summaries collected for the SkySun LLC elevated Ganged PV arrays. These arrays were fabricated as a series of PV panels in various orientations, suspended by cables, at the National Solar Thermal Test Facility (NSTTF) at Sandia National Laboratories (SNL). Starting in February of 2021, Sandia personnel have collected power and accelerometer data for these arrays to assess design and operational efficacy of varying ganged- PV configurations. The purpose of this power data collection was to see how the various array orientations compare in power collection capability depending on the time of day, year, and the specific daily solar direct normal irradiance (DNI). The power data was collected as a measurement of the power output from the various series strings. The project team measured direct current (DC) voltage and current from the respective arrays. The accelerometer data was collected with the purpose of demonstrating potential destructive mode shapes that could take place with each of the arrays when exposed to high winds. This allowed the team to evaluate whether impacts with respect to specific array orientations using suspended cables is a safe design. All data collection was performed during calendar year 2021.

14 SOLAR ENERGY↗
DOE OSTI2024

Solar Design/Install Labor Quantification (Cooperative Research and Development Final Report)

The goals of this project were to quantify the rate and/or total expected labor expenditure of engineers designing solar arrays and electricians installing solar across a spectrum of project sizes and configurations. Specifically, procuring and analyzing labor data from solar engineering firms relating to the amount of time it takes an engineer to design a solar project, the amount of time it takes an engineer to perform a wiring or stringing design, the amount of time it takes an electrician to install a solar project and the amount of time it takes electricians to install the strings of a solar array. Then these details could be analyzed to evaluate labor intensity for solar design/installation. These goals were unable to be completed because the participant was unable to collect the necessary data for analysis.

14 SOLAR ENERGY↗
DOE OSTI2025

Diagnosis of PV Cell Antireflective Coating Degradation Resulting from Hot-Humid, High Voltage Potential Aging

Corrosion of the antireflective coating on a photovoltaic cell ("ARc corrosion") has previously been observed in studies using hot-humid test conditions with external high-voltage (HV) bias. This study primarily focuses on known vulnerable, legacy aluminum back surface field (Al-BSF) cells in mini-modules (MiMos) put through comparative stepped stress tests. Each cell type had MiMos at +1500 V, -1500 V, or unbiased ("Voc") potential, which were sequentially subjected to test conditions of 60deg C/60% relative humidity (RH) for 96 h, as in International Electrotechnical Commission (IEC) Technical Specification 62804-1; 70 deg C/70% RH for 200 h; and 85 deg C/85% RH for 200 h. Characterizations at each step included visual camera and electroluminescence (EL) imaging, colorimetry, and current-voltage (I-V) curve tracing. Final characterizations included: Suns-Voc; spatial mapping of external quantum efficiency (EQE); high-resolution photoluminescence (PL), EL, and dark lock-in thermography (DLIT) imaging. Forensics were performed on extracted cores, including scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and scanning Auger microscopy (SAM). Forensics were also conducted on MiMos from previous studies that underwent stepped HV aging and separate outdoor aged full-sized modules. ARc corrosion was specifically seen for the glass/encapsulant/cell side of the +1500V (HV+) stressed MiMos and modules. Appearance, color, and reflectance were the most distinguishing characteristics relative to glass corrosion, gridline-corrosion and -delamination as well as other concurrent degradation modes. SEM/EDS and SAM identified conversion of silicon nitride to hydrated silica, hydrous silica, or hydrated amorphous silica, which preferentially occurred at the edges and tips of the pyramidal textured cell surface.

14 SOLAR ENERGY↗
DOE OSTI2024

Quantifying Error in Photovoltaic Installation Metadata: Preprint

In this research, we quantify the level of metadata error for a fleet of 2860 photovoltaic (PV) systems, using metadata values provided by fleet owners. Using satellite imagery and time series analysis techniques available in open-source Python packages Panel-Segmentation and PVAnalytics, respectively, we evaluate the accuracy of PV system metadata such as location, azimuth, tilt, and mounting configuration (fixed tilt vs. tracking). We find that approximately 75% of provided latitude-longitude coordinates are within 190 meters of the actual solar installation. We were unable to link 7.8% of latitude-longitude coordinates to any solar installation via satellite imagery analysis. We evaluate the level of error in owner-provided mounting configuration (fixed tilt vs. single-axis tracking), finding only 8 systems with an incorrect mounting configuration. When evaluating azimuth and tilt parameters, we find that approximately 64% of the data is correct, with data for 860 systems (approximately 30%) not provided by system owners. To illustrate the importance of having correct solar metadata, we evaluate how incorrect metadata affects solar performance estimates by modeling system AC energy output at ground-truth vs. incorrect latitude-longitude coordinates, mounting configurations, and azimuth-tilt configurations. Energy output estimates can vary significantly if incorrect metadata parameters are used, with incorrect mounting configuration leading to the largest discrepancy with over 20% variation in expected energy output.

azimuth↗
DOE OSTI2021

Silver-carbon-nanotube composite metallization for increased durability of silicon solar cells against cell cracks

One of the ways to reduce the cost of solar electricity is to reduce the degradation rate of solar modules and extend their lifetime well beyond 30 years. The extended module lifetime translates to increased bankability of utility-scale PV projects. In this work, we specifically address cell-crack-induced degradation by introducing crack-tolerant metallization. Herein, we make use of low-cost, multi-walled carbon nanotubes embedded in commercial screen-printable silver pastes as a highly integratable engineering solution. When the carbon nanotubes are appropriately functionalized and incorporated into commercial silver pastes, the resulting metal contacts on solar cells, after screen-printing and firing, show exceptional fracture toughness. These composite metal contacts possess increased ductility, electrical gap-bridging capability greater than 50 µm, and “self-healing” to regain electrical continuity even after cycles of complete electrical failure under large strain. While providing crack-tolerant mechanical properties, the composite paste delivers similar beginning-of-life cell performance as the conventional silver paste.

14 SOLAR ENERGY↗
DOE OSTI2021

A Short-Term Solar Forecasting Platform Using a Physics-Based Smart Persistence Model and Data Imputation Method

Electrical energy plays vital role in our socio-economic activity and therefore ensuring the reliability of the electric grid, from the generation, transmission and distribution level is critical. In order to maintain the power system parameter viz., frequency, voltage, etc., optimally, balancing of generation and consumption is very much essential. However, solar energy is infirm power by nature this is due to cloud cover / other local phenomena. Hence, Photovoltaic (PV) power generation brings a significant challenge to the grid operator due to the variability of the solar energy. The complexity of this challenge in terms of planning and dispatch ability of PV resources, aggravates with the high penetration of solar energy into the electric grid. In this setting, reliable solar radiation forecasting models based on accurate and quality input data become essential. In order to develop a suitable model for predicting solar radiation, quality historical / real time measurement is also needed. Under this study NIWE and NREL jointly developed / tested short-term solar forecasting frameworks using a smart persistence and physics-based smart persistence models for intra-hour forecasting of solar radiation (PSPI) and benchmarked 9 different data imputation techniques in 15 Solar Radiation Resource Assessment (SRRA) stations, located at different parts of India. During any measurement campaign, due to various technical reasons, we may miss few observations. However, the missing observation often reduce the performance of any forecasting model. Therefore, suitable data imputation method would assist us to obtain continuous observation of solar radiation. A station-by-station and method-by-method analysis was carried out to understand the performance of each model. Based on our analysis, among all the data imputation methods, the Kalman data imputation method is better for Indian Weather condition. In addition, Kalman StructTS, Linear, Stine and Arima methods yield slightly inferior accuracy compared to Kalman, but outperform the other methods. The extended solar radiation data are used by solar forecasting models to provide the prediction of solar radiation at 15 SRRA stations. As far as short term forecasting model is concerned, the PSPI model outperforms the Smart Persistence model. However, the forecast error is increases with the forecasting horizon.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2023

Multi-Timescale Integrated Dynamics and Scheduling for Solar (MIDAS-Solar) (Final Technical Report)

Solar photovoltaic (PV) installations have experienced unprecedented growth in the United States. PV will become not only an energy producer but also a necessary provider of ancillary services at multiple timescales. Conventional methods to simulate power systems operations - such as long-term production simulation (which typically considers schedules from hours to minutes by using an optimization framework) and short-term transient studies (which simulate dynamics from seconds to sub-seconds using state variables and differential equations) - are not sufficient for studying the multiple-timescale variation of solar generation and its impact on system reliability. Long-term system economics and short-term system dynamics are highly coupled, particularly when the penetration level of renewable generation is extremely high, because the uncertainty and variability of solar generation will impact both power system steady-state and dynamic performance. This project helps meet and exceed the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Solar Energy Technologies Office goal of systems integration by directly addressing this stability and reliability challenge for power grid planning and operation. We have developed a temporally comprehensive, closed-loop simulation model, named Multi-timescale Integrated Dynamics and Scheduling (MIDAS), that seamlessly simulates power system operations from economic scheduling (day-ahead to hours) to dynamic response analysis (seconds to sub-seconds). For schedules with very high levels of inverter-based resources (IBRs), up to and including 100%, the stability of grid controls has been evaluated through electromagnetic transient (EMT) simulations and power-hardware-in-the-loop (PHIL) simulations of key transient events at key schedule points. Specifically, MIDAS provides: 1) a closed-loop simulation framework for simulating timescales from economic scheduling to dynamic stability analysis; 2) machine learning-based stability assessment; 3) EMT modeling and analysis for large-scale power systems; 4) MIDAS PHIL test bed. We worked with Hawaii Electric Companies to apply the MIDAS study framework to a Maui grid study. The entire island's transmission system was modeled in detail - from a yearly scheduling model, to a second-level frequency dynamic model, down to a sub-second-scale EMT model to address critical stability issues. The project demonstrated how MIDAS can help system planners and operators assess system reliability and stability while the power grid is marching toward a high-renewable, high-IBR future. In this Maui grid study, we found that 100% instantaneous IBR operation is achievable in EMT simulation and PHIL testing, and grid planners and operators might need new analysis/simulation tools to assess grid reliability and stability in the scheduling stage. MIDAS will bring Maui and other systems closer to 100% clean and stable energy futures. (In this study, we examined transient stability. Other topics necessary for 100% IBR operation, such as protection and resource adequacy, were not examined.)

100% Renewables↗
DOE OSTI2023

PV module spectral response measurements - Data and Resources

"This dataset includes spectral response curves for 12 commercial silicon module types that are deployed at SNL in Albuquerque. The modules chosen for evaluation were originally purchased by SNL for the PV Lifetime project (renamed to Systems Long-Term Evaluation [SLTE]). The majority of those modules are deployed outdoors for long-term evaluation, but several modules of each type were placed in storage for future comparison purposes. One stored module of each type was sent to NREL for the spectral response measurements. NREL used the recently developed Module Quantum Efficiency (QE) test bed. What makes this system unique is that it scans the entire module automatically, taking one or more measurements on each cell. Using the mean of these measurements at each wavelength leads to improvements in spectral mismatch correction and module power measurements but having the individual measurements also makes it possible to identify outlier cells, which could be useful for investigating underperforming modules. All measurements were performed nominally at 25°C"

14 SOLAR ENERGY↗
DOE OSTI2021

Computational design of passivants for CdTe grain boundaries

CdTe is the second most-widely deployed photovoltaic (PV) material due to its high efficiency and low manufacturing costs. Currently, polycrystalline CdTe (poly-CdTe) has a record efficiency of similar to 22%, which is still well below the theoretical limit (similar to 30%). Polycrystalline CdTe films that have incorporated Cl or Se show higher efficiency, possibly due to the segregation of these ions to the grain boundaries (GBs), where they may passivate the dangling bonds. However, the efficiency enhancement mechanisms of passivants in CdTe GBs, and the feasibility of employing alternative passivants, have not been well explored. Here, we present a systematic computational study of CdTe GBs with potential passivants, namely S, P, As, Se, and Sb on Te sites, and Na, Mg, Al, Sc, Cu, and Zn on Cd sites. Density functional theory (DFT) calculations were performed on GB dislocation core structures derived from scanning transmission electron microscopy (STEM) images of a model GB (bicrystal). We computed the segregation thermodynamics, electronic density of states, and charge variations near doped CdTe GBs. We find that segregation of impurities to GBs is thermodynamically favorable. For a Te-terminated core, Se, S, and P on Te sites effectively reduce midgap states. For both Cd-and Te-terminated dislocation cores, Sc and Al reduce midgap states when substituted for Cd atoms. Overall, the greatest improvement was achieved with co-doping, i.e. simultaneously substituting Te with Se and substituting Cd with Cu or Al. The elimination of midgap states is predicted to increase the photovoltaic efficiency of CdTe by reducing the recombination at grain boundaries.

14 SOLAR ENERGY↗
DOE OSTI2023

Nanopinhole Passivating Contact Si Solar Cells Fabricated with Metal-Assisted Chemical Etching

Monocrystalline Si (c-Si) solar cells with passivating contacts based on doped polycrystalline Si (poly-Si) on ≈2.0 nm silicon oxide (SiO x ) require >1000 °C thermal processing to create conducting pinholes in the SiO x layer. However, this high thermal budget can induce bulk defects in the Czochralski c-Si wafers used as the cell absorber layer. We demonstrate that pinholes can instead be created using metal-assisted chemical etching on planar or textured morphologies, at room temperature. This wet process creates up to 200 nm wide conducting pinholes that are directly observed with transmission electron and atomic force microscopies. High-performance hole-selective poly-Si/SiN y /SiO x and electron-selective poly-Si/SiO x passivating contacts are fabricated and implemented in laboratory-scale solar cells. This process development significantly broadens the range of passivation layer materials, their thicknesses, and surface morphologies, which enables the design of poly-Si contacts with superior passivating quality.

14 SOLAR ENERGY↗
DOE OSTI2021

EMOS (Energy Management Optimization System) [SWR-21-46]

EMOS software performs a real-time hierarchal optimal control for energy systems like multi-port electric vehicles charging site with distributed energy resources (DERs) and energy storage systems (ESSs). It gathers information in real-time from electric vehicles, power grid, and DERs, solves a multi-objective energy management optimization problem, and output setpoint for chargers, ESS converters, DERs converters, and grid converters. The software incorporates a novel integration of two control tasks: a) An Energy Management Optimization (EMO), which is the brain of EMOS controller that gathers information in real-time from EVs [e.g., battery size, state-of-charge (SOC), desired SOC, and charge acceptance curve], grid (e.g., electricity price, allowed feeder capacity, ramp rate limit, and reactive power), and DERs (e.g., prediction for solar generation for PV systems). It solves a control optimization problem in real-time to find optimal setpoint for ESSs power dispatch, EVs charging rate, and grid inverters. The objectives are to (1) minimize the charging cost considering grid energy, demand charges, and battery energy, (2) minimize charging time to meet fast charging criterion, (3) keep high energy level on ESSs at the end of an operating period, while satisfying constraints related to grid, EVs, and power converters. b) Real-Time Energy Management System (RT-EMS) is a rule-based algorithm that has faster response than EMO. It receives optimal setpoint from EMO and actual measurements from the system and modify the setpoint to compensate for any fast disturbance in the system, until a new optimum solution is received. Fast disturbances may include vehicle connect/disconnect, unpredicted variation in DERs profiles, variation in grid voltage, errors in PV generation prediction, and others. In addition, RT-EMS regulates voltage at point of common coupling (PCC) by managing reactive power of grid converters.

Mohamed, Ahmed↗
DOE OSTI2020

The Impact of Behind-the-Meter Heterogeneous Distributed Energy Resources on Distribution Grids: Preprint

The increasing integration of distributed energy resources (DERs) on the electric grid brings new challenges and opportunities for utility grid operations. With the rapid deployment of DERs, there is emerging interest in integrating these controllable devices with utility operations at all levels for monitoring and management. Different types of DERs such as Photovoltaics (PV), energy storage, electric vehicles (EVs), etc. have varying effects on the grid based on how and where they are deployed. Again, the DER deployment and its impact are network-dependent, while the traditional electric grids were not designed to host DERs. To understand the challenges with increasing behind-the-meter (BTM) DERs and to identify the needs in deploying advanced controls, a comprehensive grid impact study is indispensable. This paper investigates the impacts of integrating a mix of DERs in the utility distribution network in Colorado, U.S. Firstly, BTM DERs at the residential scale including distributed PV; battery energy storage systems (BESS); heating, ventilation, and air-conditioning (HVAC) load; electric water heater (EWH) load; and EVs are modeled. The impacts of integrating these resources on the distribution network are evaluated by conducting time-series simulations for different scenarios considering different days to capture the worst-case conditions. Monte Carlo simulations are conducted to generate the realistic EV charging profile. The voltage issues, substation transformer loadings, and critical nodes in the network are identified with the incorporation of uncoordinated EV charging loads and other DER in the network. This analysis helps visualize the DER impact on the grid, identify the challenges, and provides an insight into the new distribution management and control needs to enable reliable and resilient distribution grid operations. Additionally, further analysis is performed to estimate the daily residential electricity cost with the inclusion of DERs under time-of-use tariffs. The result shows the daily residential electricity cost reduced by 20:7% on average with DERs compared to the case without DERs.

27 ARPA - Advanced Research Projects Agency-Energy↗
DOE OSTI2020

Concentrating photovoltaic retrofit for existing parabolic trough solar collectors: Design, experiments, and levelized cost of electricity

Photovoltaics and concentrating solar thermal power are two ways for generating electricity from sunlight, albeit through different methods. Parabolic trough style powerplants represent 3.6 GW of electricity production, but many of these plants are aging and being replaced with photovoltaics. An alternative option that could be employed to leverage the sunk capital cost associated with the primary optics would be the design of a pure photovoltaic retrofit working within the existing plant architecture. Here, a secondary optical concentrator is designed to use the existing primary optics of a parabolic trough type solar thermal powerplant. The design is a v-shaped secondary concentrator resulting in a predicted concentration ratio on a 20 mm wide target of 94. The concentrating photovoltaic receiver for retrofit of an RP-3 based parabolic trough has been constructed using multi-junction concentrator photovoltaic cells and experimentally demonstrated here for the first time. Calculated performance of the cells based on cell specifications should result in 31% efficiency at 85 °C. On-sun efficiencies were measured at an average value of 21% with operational temperatures between 55 and 120 °C. Levelized cost of electricity calculations predict the system to have the potential to be below 7¢/kWh based on predicted efficiencies and 13¢/kWh based on the measured values at cell costs of $5/cm 2 .

14 SOLAR ENERGY↗
DOE OSTI2024

Development and Reliability of Screen-Printable Fire-Through Cu Paste for Passivated Contact Solar Cells

We present the development of copper (Cu) paste which has been screen printed on Selective Emitter-Passivated Emitter Rear Contact (SE-PERC) solar cells. This paste can also be applied to Tunnel Oxide Passivated Contact (TOPCON) solar cells due to its fire-through nature. Champion PERC cells have achieved ....efficiency with ...parameters . Accelerated testing to investigate reliability performance of the SE- PERC mini-modules were carried out in damp heat chamber with 85oC and 85% humidity. The devices were found to be operational even after 1,500 hours. Devices with screen printed Ag contacts on the front side have been studied in parallel to the Cu contacts for comparison.

copper paste↗
DOE OSTI2020

A review of Sb 2 Se 3 photovoltaic absorber materials and thin-film solar cells

Energy generated from environmentally friendly, cost-effective solar cells is a key aspect for developing a clean renewable-energy economy. Non-toxic and Earth-abundant materials with high absorption coefficient (>10 5 cm -1 ) and optimal bandgap (1-1.5 eV) have received great attention as photovoltaic (PV) absorber layers during the last few decades. Among them, antimony selenide (Sb 2 Se 3 ) has been a promising PV absorber, with steadily increasing power-conversion efficiency (PCE) compared to other emerging compounds. Very recent studies showed that high-quality ZnO:Al/ZnO/CdS/TiO 2 /Sb 2 Se 3 /MoSe 2 /Mo devices with PCE of 9.2% can be fabricated using cost-effective novel compounds. Considering these recent advances, this article provides an overview of the material properties of Sb2Se3 thin films and the recent progress made with Sb 2 Se 3 -based solar cells. Furthermore, analysis of Sb 2 Se 3 -based thin-film solar cells has also shown that the devices have relatively good light management due to their suitable bandgap and high absorption coefficient, whereas carrier management, i.e. collection efficiency of photo-generated carriers, needs significant improvement. Overall, this study provides background knowledge on material properties and device performance and suggests main research directions to overcome the limiting factors of solar cell performance.

14 SOLAR ENERGY↗
DOE OSTI2020

A 150-kW 99% Efficient All-Silicon-Carbide Triple-Active-Bridge Converter for Solar-Plus-Storage Systems

Solar-plus-storage systems could effectively mitigate the uncertainties of the photovoltaic (PV) generation and improve system reliability by adding an integrated battery energy storage system. As a three-port bidirectional isolated dc–dc converter with soft-switching capability, the triple-active-bridge (TAB) converter inherently matches the requirements of the solar-plus-storage system. However, challenges still remain in the TAB converter design to further improve system efficiency. In this article, the detailed design, implementation, and demonstration for a silicon carbide (SiC) 150-kW TAB converter are presented. Starting from a brief review of the TAB converter, the modulation scheme, power characteristics, and soft-switching region are analyzed. Then, the detailed design of the H-bridge converter building block is given. Here, to improve the system efficiency, a comprehensive characterization of the SiC gate driver with various external gate resistances is performed to address tradeoffs between switching loss and voltage overshoot during transients, as well as the thermal performance of the H-bridge building block. In addition, the design and characterization of the 20-kHz three-port transformer are also given. Comprehensive experimental studies are conducted on a full-power prototype to verify the proposed design. With a measured 99.1% peak efficiency, the proposed TAB converter can fulfill the requirements for solar-plus-storage applications.

14 SOLAR ENERGY↗
DOE OSTI2021

Real-time Simulation Framework for Hardware-in-the-Loop Testing of Multi-port Autonomous Reconfigurable Solar Power Plant (MARS)

Multiport autonomous reconfigurable solar power plant (MARS) has been proposed for integrated development of photovoltaic (PV) and energy storage system (ESS) that can connect to high-voltage direct current (HVdc) and alternating current (ac) transmission grid. To de-risk the development of this complex integrated system that consists of hundreds to thousands of power electronics modules, a controller hardware-in-the-loop (cHIL) test setup will be extremely beneficial. The cHIL testing can be used for evaluation of modules as well as the hierarchical control system in MARS. With the unique configuration of power electronics modules in MARS, it becomes necessary to develop custom-designed real-time simulation models in the cHIL setup in absence of off-the-shelf models. In this paper, high-fidelity dynamic model of MARS, control algorithms at the lower level, and required communication algorithms are developed and optimized for real-time performance in the cHIL setup. Real-time experimental results from the cHIL are provided.

Dong, Zerui↗