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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51

Life Cycle Assessment and Cost Analysis of a Process-Based Sorbent-Based Direct Air Capture with Temperature-Vacuum Swing Adsorption Model

This presentation discusses different aspects of LCA and TEA of sorbent-based case study updates and methodologies utilized for carbon dioxide removal technologies. The combined TEA and LCA approach adopted herein provides insight into trade-offs between environmental performance and cost efficiency under various energy supply scenarios.

carbon dioxide removal↗

Life Cycle Analysis of ONE Future's Supply Chain Methane Emissions

NETL partnered with ONE Future (natural gas industry) to improve operational efficiency and mitigate methane emissions to enhance the nation’s safe and reliable delivery of natural gas. The key findings show that there are industry participants who, through best practices and capital investments, have improved the overall efficiency of their systems. The strategies employed by ONE Future participants are a benchmark that can be followed by other natural gas operators. This collaboration demonstrates how industry and government can work together to improve the understanding of methane emissions and potential reduction strategies that can improve the long-term operational efficiency of the nations’ natural gas production and delivery systems.

03 NATURAL GAS↗

Life Cycle Greenhouse Gas Inventory Sensitivity to Changes in Natural Gas System Parameters [Slides]

This presentation focuses on the greenhouse gases from the extraction, processing, and delivery of natural gas and the key variables that affect the results. It includes eight distinct sources of natural gas and performs a number of sensitivity studies. The production rate of natural gas wells, episodic emission factors and the flaring rate have the most impact on the cradle-to-gate emissions profile, while power plant heat rate or efficiency most affects the cradle-to-grave emissions. New Source Performance Standards have recently focused on the oil and gas sector and could be effective at reducing the upstream emissions from natural gas systems.

03 NATURAL GAS↗

High rate and long cycle life in Li-O 2 batteries with highly efficient catalytic cathode configured with Co 3 O 4 nanoflower

The reaction mechanism of non-aqueous Li-O 2 batteries is based on the deposition and decomposition of Li 2 O 2 . The polarization of Li-O 2 batteries can be rapidly increased by operation under a high rate condition, resulting in the early capacity fade of the cells. Therefore, a well-designed catalyst with a unique structure and excellent catalytic ability is an important way to boost the round-trip performance of Li-O 2 batteries, especially under high current density. In this work, a unique nanoflower structure assembled with Co 3 O 4 nanosheets is synthesized by using 2-methylimidazole (2-MIM) as a structural directing agent. X-ray photoelectron spectroscopy (XPS) and Raman spectra reveal abundant oxygen vacancies on the surface of the Co 3 O 4 nanoflower, which are beneficial for oxygen reduction and evolution reactions and long round-trip lifetime. Density functional theory results demonstrate that Co 3 O 4 catalyst with oxygen vacancies could promote the wetting of Li 2 O 2 on substrate and formation of a Li 2 O 2 nanofilm, thereby boosting the discharge capacity of Li-O 2 batteries. On account of the synergistic effect of abundant oxygen vacancies, the unique structure, and excellent oxygen evolution reaction, Co 3 O 4 nanoflower-based cells could deliver ultralong lifetime of 276 and 248 cycles with a discharge capacity of 1000 mAh g(-1) under charge/discharge current densities of 0.5 A g -1 and 1 A g -1 , respectively. Finally, this study has shed light on a new strategy for catalyst preparation for long lifetime Li-O 2 batteries.

25 ENERGY STORAGE↗

Life Cycle Analysis of Natural Gas Extraction and Power Generation

Natural gas is considered a cleaner burning and more flexible alternative to other fossil fuels today. It is used in residential, commercial, industrial, and transportation applications in addition to having an expanding role in power production. However, the primary component of natural gas is methane, which is also a powerful greenhouse gas (GHG). Methane losses from natural gas extraction vary geographically and by extraction technology. This analysis inventories the GHG emissions from extraction, processing, and transmission of natural gas to large end users, and the combustion of that natural gas to produce electricity. In addition to GHG emissions, this analysis inventories other air emissions, water quality, water use, land use, and resource energy metrics.

03 NATURAL GAS↗

Divergent antiviral effects of bioflavonoids on the hepatitis C virus life cycle

We have previously demonstrated that quercetin, a bioflavonoid, blocks hepatitis C virus (HCV) proliferation by inhibiting NS5A-driven internal ribosomal entry site (IRES)-mediated translation of the viral genome. Here, we investigate the mechanisms of antiviral activity of quercetin and six additional bioflavonoids. We demonstrate that catechin, naringenin, and quercetin possess significant antiviral activity, with no associated cytotoxicity. Infectious virion secretion was not significantly altered by these bioflavonoids. Catechin and naringenin demonstrated stronger inhibition of infectious virion assembly compared to quercetin. Quercetin markedly blocked viral translation whereas catechin and naringenin demonstrated mild activity. Similarly quercetin completely blocked NS5A-augmented IRES-mediated translation in an IRES reporter assay, whereas catechin and naringenin had only a mild effect. Moreover, quercetin differentially inhibited HSP70 induction compared to catechin and naringenin. Thus, the antiviral activity of these bioflavonoids is mediated through different mechanisms. Therefore combination of these bioflavonoids may act synergistically against HCV.

60 APPLIED LIFE SCIENCES↗

Assessing the Impact of Lubrication on Efficiency and Life Cycle Economics of the US Wind Turbine Fleet: Cooperative Research and Development (Final Report)

As with any mechanical system, lubrication plays a key role in the performance of wind turbines used to generate electricity. The lubricant design offers a way to optimize the competing requirements of efficiency, component reliability, and maintenance strategy. This project will estimate the impact of improved lubrication on the levelized cost of energy of the US wind turbine fleet as a means of identifying opportunities for disruptive innovation or system-level optimization. The models developed will provide a clear understanding of the benefits and potential for advanced lubrication of wind turbines. The project will enable identification of high value targets for wind turbine component suppliers and a roadmap that highlights where the greatest return on technology investment can be achieved. This will promote efficient resource allocation in areas of new technology development.

17 WIND ENERGY↗

Using Life Cycle Analysis to Inform Energy Policy [Slides]

NETL uses LCA to understand the environmental burdens of energy systems and to inform policy makers. LCA is well suited for energy analysis, but its answers can change depending on what questions are being asked. NETL approaches all LCAs using a consistent method, which ensures comparability among LCAs. The granularity and flexibility of NETL's models makes it possible to identify key contributors to the environmental burdens of a system, as well as the ability to understand how results can change with changes to a given input parameter. In addition to understanding the attributes of a given energy technology, NETL can also perform consequential modeling that allows an understanding of how a given energy technology can affect the performance of other energy technologies. The effect of enhanced oil recovery (EOR) on conventional crude oil extraction is one example of such consequential analysis.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Embedding Agile Practices within a Plan-Driven Hierarchical Project Life Cycle

Organizations use structured, plan-driven approaches to provide continuity, direction, and control to large, multi-year programs. Projects within these programs vary greatly in size, complexity, level of maturity, technical risk, and clarity of the development objectives. Organizations that perform exploratory research, evolutionary development, and other R&D activities can obtain the benefits of Agile practices without losing the benefits of their program’s overarching plan-driven structure. This paper describes application of Agile development methods on a large plan-driven sensor integration program. While the client employed plan-driven, requirements flow-down methodologies, tight project schedules and complex interfaces called for frequent end-to-end demonstrations to provide feedback during system development. The development process maintained the many benefits of plan-driven project execution with the rapid prototyping, integration, demonstration, and client feedback possible through Agile development methods. This paper also describes some of the tools and implementing mechanisms used to transition between and take advantage of each methodology, and presents lessons learned from the project management, system engineering, and developer’s perspectives.

Agile Development↗

Techno-Economic and Life Cycle Assessment of Chemical Recycling and Upcycling of Mixed Plastics Waste Containing Poly-vinyl-chloride

Developing technologies that completely remove chlorine from plastic waste can allow its chemical recycling and upcycling with catalytic methods. Here, this study compares eight processes involving different dechlorination methods (absorption columns, adsorption in beds of zeolites, catalytic dechlorination, and dissolution in ionic liquids) and chemical conversion technologies (incineration, pyrolysis, hydrogenolysis) to upgrade mixed plastics waste to various products (e.g., electricity, fuels, virgin polymers, and lubricant oil). The analysis determines that the absorption of chlorine in columns with basic aqueous solutions is limited to plastics waste with PVC concentrations below 0.1%. Dissolution in ionic liquids is not cost-competitive. On the contrary, two-step processes with catalytic dechlorination followed by thermochemical catalytic depolymerization, either pyrolysis or hydrogenolysis, significantly improve process economics and emissions. The most economically viable alternative is hydrogenolysis for producing lubricants, while the technology with the lowest global warming potential is chemical recycling via catalytic pyrolysis.

circular economy↗

Comparative life-cycle assessments and techno-economic analysis of renewable natural gas production pathways from biogas

Renewable natural gas (RNG) offers a promising pathway for decarbonizing hard-to-abate sectors. This study shows that, relative to conventional upgrading technologies (i.e., membrane separation and pressure swing adsorption), the catalytic methanation reaction (CMR) at water resource recovery facilities doubles RNG output. When consuming lowcarbon hydrogen, the CMR reduces operational energy use and global warming potential. Techno-economic analysis indicates that the CMR is not yet competitive but will become viable if hydrogen reaches $1/kg. Heat integration and hydrogen cost are key drivers of overall performance.

03 NATURAL GAS↗

Life-cycle assessment of greenhouse gas and air emissions of electric vehicles: A comparison between China and the U.S.

We evaluated the fuel-cycle emissions of greenhouse gases (GHGs) and air pollutants (NOx, SO2, PM10, and PM2.5) of electric vehicles (EVs) in China and the United States (U.S.), two of the largest potential markets for EVs in the world. Six of the most economically developed and populated regions in China and the U.S. were selected. The results showed that EV fuel-cycle emissions depend substantially on the carbon intensity and cleanness of the electricity mix, and vary significantly across the regions studied. In those regions with a low share of coal-based electricity (e.g., California), EVs can reduce GHG and air pollutant emissions (except for PM) significantly compared with conventional vehicles. However, in the Chinese regions and selected U.S. Midwestern states where coal dominates in the generation mix, EVs can reduce GHG emissions but increase the total and urban emissions of air pollutants. In 2025, EVs will offer greater reductions in GHG and air pollutant emissions because emissions from power plants will be better controlled; EVs in the Chinese regions examined, however, may still increase SO2 and PM emissions. Reductions of 60–85% in GHGs and air pollutants could be achieved were EVs charged with 80% renewable electricity or the electricity generated from the best available technologies of coal-fired power plants, which are futuristic power generation scenarios.

Electric vehicles↗

The impact of off-site land use energy intensity on the overall life cycle land use energy intensity for utility-scale solar electricity generation technologies

Estimates of the amount of land used for a defined amount of utility-scale electricity generation in the solar power industry, referred to as solar land use energy intensity (LUEI), are important to decision makers for evaluating the environmental impact of energy technology choices. In general, solar energy tends to have a larger on-site LUEI than that of fossil fuels because the energy generated per square meter of power plant area is much lower. Unfortunately, there are few studies that quantify the off-site LUEI for utility-scale solar energy, and of those that do, they share common methodologies and data sets. As such, in this study, we develop a new method for calculating the off-site LUEI for utility-scale solar energy for three different technologies: silicon photovoltaic (Si-PV), cadmium-telluride (CdTe) PV, and parabolic trough concentrated solar thermal. Our results indicate that the off-site LUEI is most likely 1% or less of the on-site LUEI for each technology. Although our results have some inherent uncertainties, they fall within an order of magnitude of other estimates in the literature.

14 SOLAR ENERGY↗

Core design of long life-cycle fast reactors operating without reactivity margin

In this paper we consider a possibility of designing a fast reactor core that operates without reactivity margin for a long time. This study is based on the physical principle of fast reactor operating in a self-adjustable neutron-nuclear regime (SANNR-1) introduced by L.P. Feoktistov (1988-1993) and improved by V. Ya. Gol'din SANNR-2 (1995). The mathematical modeling of active zones of fast reactors in SANNR modes is held by authors since 1992. The numerical simulation is based on solving the neutron transport equation coupled with quasi-diffusion equations. The calculations have been performed using standard 26 energy groups. We use a hierarchy of spatial models of 1D, 1.5D, 2D, and 3D geometries. The spatial models of higher dimensionality are used for verification of results. The calculations showed that operation of the reactor in this mode increases its efficiency, safety and simplifies management. It is possible to achieve continuous work of the reactor in SANNR-2 during 7-10 years without fuel overloads by means of further optimization of the mode. Small reactivity margin is used only for the reactor start up. After first 10-15 days the reactor in SANNR-2 operates without reactivity margin. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

A Life Cycle Analysis Framework for Point Source Capture Systems

NETL studies the costs and benefits of PSC for electricity, industry, and mobile applications. Mobile point source capture (MPSC) and storage applied to freight modes captures emissions directly from exhaust. This poster presents a framework for conducting LCA of PSC systems applied to heavy-duty trucks, freight trains, and marine vessels. The framework defines a wheels-to-storage (gate-to-grave) boundary, including energy demands (electricity, heat, and cooling requirements), solvent use and cycling, onboard system components, carbon storage in a saline aquifer, and upstream manufacturing impacts for equipment, with a suggested functional unit of 1 tonne-km. Potential data sources for analysis include material, energy, and operational data from Oak Ridge National Laboratory, GREET (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model, and scientific literature. The suggested analytical approach includes comparison to publicly available business-as-usual systems without capture across all modes of transportation, sensitivity to composition of the capture solvent, and sensitivity to capture rate variation, all of which would support a wholistic PSC business case analysis. For future consideration, analysis can be augmented with consideration of different sources of electricity (e.g., nuclear), fuel substitution, deploying supportive infrastructure such as pipeline offloading points, and downstream applications like enhanced oil recovery (EOR).

life cycle analysis (LCA)↗

Comparative Technoeconomic Analysis and Life Cycle Assessment of Emerging Reactive Carbon Capture-to-Methanol Pathways

Our group recently developed dual-function materials (DFMs) and reactive carbon capture (RCC) processes for the selective production of methanol (MeOH) or CO, offering two novel and unique pathways for MeOH production. This study conducted a comparative techno-economic analysis (TEA) of the two RCC pathways from exhaust CO 2 : 1) a “Direct RCC-to-MeOH” pathway and 2) an “Indirect RCC-to-CO” pathway followed by MeOH synthesis. The “Direct RCC-to-MeOH” pathway produced a lower levelized cost of MeOH (LCOM) at $\$$0.78/kg, compared to $\$$0.84/kg for the “Indirect RCC-to-CO” pathway. The key difference is the need to recompress the syngas from RCC before MeOH synthesis in “Indirect RCC-to-CO.” Nonetheless, with reduced catalyst costs and hydrogen requirements for “RCC-to-CO,” this pathway merits further study to produce syngas rather than MeOH. Both pathways are comparable in LCOM to baseline e-MeOH production from CO 2 hydrogenation ($\$$0.72/kg) while having lower carbon intensities (0.45 and 0.51 kg-CO 2 e/kg vs 0.54 kg-CO 2 e/kg).

08 HYDROGEN↗

Life Cycle Analysis of Electrofuels: Fischer–Tropsch Fuel Production from Hydrogen and Corn Ethanol Byproduct CO 2

Electrofuels from renewable H 2 and waste CO 2 streams are of increasing interest because of their CO 2 emissions reduction potentials compared to fossil counterparts. This study evaluated the well-to-wheel (WTW) greenhouse gas (GHG) emissions of Fischer-Tropsch (FT) fuels from various electrolytic H 2 pathways and CO 2 sources, using various process designs (i.e., with and without H 2 recycle) and system boundaries. Two systems with different boundaries were considered: a stand-alone plant (with CO 2 from any source) and an integrated plant with corn ethanol production (supplying CO 2 ). The FT fuel synthesis process was modeled using Aspen Plus, which showed that 45% of the carbon in CO 2 can be fixed in the FT fuel, with a fuel production energy efficiency of 58%. Using nuclear or solar/wind electricity, the stand-alone FT fuel production from various plant designs can reduce WTW GHG emissions by 90-108%, relative to petroleum fuels. When integrating the FT fuel production process with corn ethanol production, the WTW GHG emissions of FT fuels are 57-65% lower compared to petroleum counterparts. This study highlights the sensitivity of the carbon intensity of FT fuels to the system boundary selection (i.e., stand-alone vs integrated), which has different implications under various GHG emission credit frameworks.

08 HYDROGEN↗

What Drives the Life Cycle of Tropical Anvil Clouds?

Abstract The net radiative effects of tropical clouds are determined by the evolution of thick, freshly detrained anvil clouds into thin anvil clouds. Thick anvil clouds reduce Earth's energy balance and cool the climate, while thin anvil clouds warm the climate. To determine role of these clouds in climate change we need to understand how interactions of their microphysical and macrophysical properties control their radiative properties. We explore anvil cloud evolution using a cloud‐resolving model in three‐simulation setups of increasing complexity to disentangle the impacts of the various components of diabatic heating and their interaction with cloud‐scale motions. The first phase of evolution and rapid cloud spreading is dominated by latent heating within convective updrafts. After the convective detrainment stops, most of the spreading and thinning of the anvil cloud is driven by cloud radiative processes and latent heating. The combination of radiative cooling at cloud top, latent cooling due to sublimation at cloud base, latent heating due to deposition and radiative heating in between leads to a sandwich‐like, cooling‐heating‐cooling structure. The heating sandwich promotes the development of two within‐anvil convective layers and a double cell circulation, dominated by strong outflow at 12‐km altitude with inflow above and below. Our study reveals how small‐scale processes including convective, microphysical processes, latent and radiative heating interact within the anvil cloud system. The absence or a different representation of only one component results in a significantly different cloud evolution with large impacts on cloud radiative effects.

54 ENVIRONMENTAL SCIENCES↗