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At least 919 records · Page 51

CO 2 Injectivity, Storage Capacity, Plume Size, and Reservoir and Seal Integrity of the Ordovician St. Peter Sandstone and the Cambrian Potosi Formation in the Illnois Basin

The Cambro-Ordovician strata of the Illinois and Michigan Basins underlie most of the states of Illinois, Indiana, Kentucky, and Michigan. This interval also extends through much of the Midwest of the United States and, for some areas, may be the only available target for geological sequestration of CO 2 . We evaluated the Cambro-Ordovician strata above the basal Mt. Simon Sandstone reservoir for sequestration potential. The two targets were the Cambrian carbonate intervals in the Knox and the Ordovician St. Peter Sandstone. The evaluation of these two formations was accomplished using wireline data, core data, pressure data, and seismic data from the USDOE-funded Illinois Basin Decatur Project being conducted by the Midwest Geological Sequestration Consortium in Macon County, Illinois. Interpretations were completed using log analysis software, a reservoir flow simulator, and a finite element solver that determines rock stress and strain changes resulting from the pressure increase associated with CO 2 injection. Results of this research suggest that both the St. Peter Sandstone and the Potosi Dolomite (a formation of the Knox) reservoirs may be capable of storing up to 2 million tonnes of CO 2 per year for a 20-year period. Reservoir simulation results for the St. Peter indicate good injectivity and a relatively small CO 2 plume. While a single St. Peter well is not likely to achieve the targeted injection rate of 2 million tonnes/year, results of this study indicate that development with three or four appropriately spaced wells may be sufficient. Reservoir simulation of the Potosi suggest that much of the CO 2 flows into and through relatively thin, high permeability intervals, resulting in a large plume diameter compared with the St. Peter.

54 ENVIRONMENTAL SCIENCES↗

Numerical modeling of geomechanical processes related to CO 2 injection within generic reservoirs

In this project generic anticline structures have been used for numerical modeling analyses to study the influence of geometrical parameters, fluid flow boundary conditions, in situ stress regime and inter-bedding friction coefficient on geomechanical risks such as fracture reactivation and fracture generation. The resulting stress states for these structures are also used to determine safe drilling directions and a methodology for wellbore trajection optimization is developed that is applicable for non-Andersonian stress states. The results of the fluid flow simulation show that the type of fluid flow boundary condition is of utmost importance and has significant impact on all injection related parameters. It is recommended that further research is conducted to establish a method to quantify the fluid flow boundary conditions for injection applications. The results of the geomechanical simulation show that in situ stress regime is a crucial, if not the most important, factor determining geomechanical risks. For extension and strike slip stress regimes anticline structures should be favored over horizontally layered basin as they feature higher ΔP c magnitudes. If sedimentary basins are tectonically relaxed and their state of stress is characterized by the uni-axial strain model the basin is in exact frictional equilibrium and fluids should not be injected. The results also show that low inter bedding friction coefficients effectively decouple layers resulting in lower ΔP c magnitudes, especially for the compressional stress regime.

54 ENVIRONMENTAL SCIENCES↗

Electrically Injected UV-Visible Nanowire Lasers

There is strong interest in minimizing the volume of lasers to enable ultracompact, low-power, coherent light sources. Nanowires represent an ideal candidate for such nanolasers as stand-alone optical cavities and gain media, and optically pumped nanowire lasing has been demonstrated in several semiconductor systems. Electrically injected nanowire lasers are needed to realize actual working devices but have been elusive due to limitations of current methods to address the requirement for nanowire device heterostructures with high material quality, controlled doping and geometry, low optical loss, and efficient carrier injection. In this project we proposed to demonstrate electrically injected single nanowire lasers emitting in the important UV to visible wavelengths. Our approach to simultaneously address these challenges is based on high quality III-nitride nanowire device heterostructures with precisely controlled geometries and strong gain and mode confinement to minimize lasing thresholds, enabled by a unique top-down nanowire fabrication technique.

42 ENGINEERING↗

Quantitative Imaging of Turbulent Mixing Dynamics in High-Pressure Fuel Injection to Enable Predictive Simulations of Engine Combustion

In this LDRD project, we developed a capability for quantitative high - speed imaging measurements of high - pressure fuel injection dynamics to advance understanding of turbulent mixing in transcritical flows, ignition, and flame stabilization mechanisms, and to provide e ssential validation data for developing predictive tools for engine combustion simulations. Advanced, fuel - efficient engine technologies rely on fuel injection into a high - pressure, high - temperature environment for mixture preparation and com bustion. Howe ver, the dynamics of fuel injection are not well understood and pose significant experimental and modeling challenges. To address the need for quantitative high - speed measurements, we developed a Nd:YAG laser that provides a 5ms burst of pulses at 100 kHz o n a robust mobile platform . Using this laser, we demonstrated s patially and temporally resolved Rayleigh scattering imaging and particle image velocimetry measurements of turbulent mixing in high - pressure gas - phase flows and vaporizing sprays . Quantitativ e interpretation of high - pressure measurements was advanced by reducing and correcting interferences and imaging artifacts.

33 ADVANCED PROPULSION SYSTEMS↗

A novel injection-locked amplitude-modulated magnetron at 1497 MHz

Thomas Jefferson National Accelerator Facility (JLab) uses low efficiency klystrons in the CEBAF machine. In the older portion they operate at 30% efficiency with a tube mean time between failure (MTBF) of five to six years. A highly efficient source (>55-60%) must provide a high degree of backwards compatibility, both in size and voltage requirements, to replace the klystron presently used at JLab, while providing energy savings. Muons, Inc. is developing a highly reliable, highly efficient RF source based upon a novel injection-locked amplitude modulated (AM) magnetron with a lower total cost of ownership, >80% efficiency, and MTBF of six to seven years. The design of the RF source is based upon a single injection-locked magnetron system at 8 kW capable of operating up to 13 kW, using the magnetron magnetic field to achieve the AM required for backwards compatibility to compensate for microphonics and beam loads. A novel injection-locked 1497 MHz 8 kW AM magnetron with a trim magnetic coil was designed and its operation numerically simulated during the Phase I project. The low-level RF system to control the trim field and magnetron anode voltage was designed and modeled for operation at the modulation frequencies of the microphonics. A plan for constructing a prototype magnetron and control system was developed.

43 PARTICLE ACCELERATORS↗

Mu2e-II Injection from PIP-II

We discuss injection of 800 MeV proton beam from PIP-II into the production target for Mu2e-II, assuming a targeting and μ production scenario similar to mu2e. The incoming beam trajectory must be modified from the mu2e parameters to match the focusing fields. Adding a vertical deflection at injection enables the injected beam to reach the target. Other differences from the mu2e system must be considered, including changes in the target structure, the radiation shielding and beam dump/absorber. H- beam should be stripped to p+. Other variations are discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A novel injection-locked amplitude-modulated magnetron at 1497 MHz

Thomas Jefferson National Accelerator Facility (JLab) uses low efficiency klystrons in the CEBAF machine. In the older portion they operate at 30% efficiency with a tube mean time between failure (MTBF) of five to six years. A highly efficient source (>55-60%) must provide a high degree of backwards compatibility, both in size and voltage requirements, to replace the klystron presently used at JLab, while providing energy savings. Muons, Inc. is developing a highly reliable, highly efficient RF source based upon a novel injection-locked amplitude modulated (AM) magnetron with a lower total cost of ownership, >80% efficiency, and MTBF of six to seven years. The design of the RF source is based upon a single injection-locked magnetron system at 8 kW capable of operating up to 13 kW, using the magnetron magnetic field to achieve the AM required for backwards compatibility to compensate for microphonics and beam loads. A novel injection-locked 1497 MHz 8 kW AM magnetron with a trim magnetic coil was designed and its operation numerically simulated during the Phase I project. The low level RF system to control the trim field and magnetron anode voltage was designed and modeled for operation at the modulation frequencies of the microphonics. A plan for constructing a prototype magnetron and control system was developed.

42 ENGINEERING↗

Biological System Characterization to Address Biofouling of the 200 West Pump-and-Treat Injection Wells

Contaminated groundwater in the 200W Area of the Hanford Site is being treated ex situ by the 200W Pump-and-Treat (P&T) Facility and the subsurface plume is under hydraulic containment. The 200W P&T Facility removes several contaminants of concern from groundwater, as well as nitrate. Facility capacity is constrained by biofouling of injection wells, which limits the ability to efficiently inject treated effluent water in to the subsurface. In a previous report, Thomle et al. provided a comprehensive engineering assessment of biofouling at the 200W P&T Facility. In that report, both operational changes and facility modifications were recommended to help mitigate the symptoms and consequences of biofouling by expanding treatment processes in the plant. The 200W P&T Facility’s fluidized bed reactor (FBR) is a biological treatment system that has been identified as a principal source of biofouling. Carbon and nutrient inputs to the FBR are needed to sustain high rates of activity, but can also be responsible for microbial proliferation in the effluent water distribution pipeline, and loss injection well capacity. The primary objective of this work was to fill critical knowledge gaps associated with the FBR that can be used to optimize the biological system for continuous operation and sustained performance.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of the Change in Uranium Mobility in Sediments from the Hanford 300-FF-5 Stage B Polyphosphate Field Injection

The purpose of this study was to evaluate the change in uranium mobility in the periodically re-wetted zone (PRZ) and upper unconfined aquifer of the Hanford Site’s 300-FF-5 operable unit as a result of Stage B polyphosphate (PO 4 ) injections. These 300 Area sediments are beneath or near the former North Process Pond, which has previously been shown to contain metatorbernite [Cu(UO 2 ) 2 (PO 4 ) 2 •8H 2 O] and uranophane [Ca(UO 2 ) 2 (SiO 3 OH) 2 •5H 2 O], along with aqueous and adsorbed uranium (U), and small amounts of U in calcite as a result of acidic disposal with a significant number of co-contaminants. Previous laboratory-scale studies have identified multiple mechanisms that decrease uranium mobility with polyphosphate injection: (a) precipitation of a low-solubility uranium-phosphate mineral (autunite); (b) precipitation of a Ca-phosphate solid that incorporates U; (c) precipitation of Ca-phosphate mineral (apatite group minerals) that coats existing uranium phases (i.e., U in calcite, U in Fe-oxides), reducing uranium leaching; and (d) aqueous Ca-U-carbonate species adsorption onto apatite. Given the significant amount of apatite precipitation, other U phases such as carbonates could also coprecipitate with apatite. To quantify differences in solubility, leachability, and phases of uranium between pre- and post-PO 4 -treated sediments, different types of analyses were conducted, including analysis of uranium in (a) a carbonate solution extraction from sediment over 1000 h (41.67 days), (b) six sequential liquid extractions from sediment over approximately 1 week, (c) leaching of uranium from sediments in one dimensional (1-D) column experiments over 2 months, and (d) solid phase characterization of select sediments. An additional extraction and solid phase measurements were conducted to evaluate phosphate precipitate formation. Metals were also analyzed in sequential liquid extractions as indicators of (a) amendment injection delivery, (b) co-contaminant movement, and (c) changes in solid phases. Aqueous and solid phase carbonate measurements were also conducted to evaluate changes in carbonates.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Injection considerations for PIP-III Linac to Main Injector

The PIP-III linac produces 8 GeV H- beam for injection into the Recycler or Main Injector (MI). Stripping to H + is needed, in a system that is vulnerable to magnetic stripping of H - in magnetic fields. The High power beam will heat stripping foils, perhaps unacceptably. The injection pulse is much longer than the MI circumference, so multiturn pulses with resulting heating and beam diffusion are required. We discuss design considerations for the injection scenario, the stripper foil and its location, foil heating and related beam loss issues.

43 PARTICLE ACCELERATORS↗

CO2 injection with fracturing in geomechanically protected caprock: Task 6 of LLNL's Research Activities to Support DOE's Carbon Storage Program (FWP-FEW0191) (Final Technical Report)

Conventional principles of the design and operation of geologic carbon storage (GCS) require injecting CO 2 below the caprock fracturing pressure to ensure the integrity of the storage complex. In non-ideal storage reservoirs with relatively low permeability, modest injection rates can lead to pressure buildup and hydraulic fracturing of the reservoir and caprock. While the GCS community has generally viewed hydraulic fractures as a key risk to storage integrity, the actual behavior of a caprock hydraulic fracture, particularly from a geomechanical perspective, has not been thoroughly studied. The prevailing method of treating a hydraulic fracture as a high-permeability wing of the storage reservoir might have resulted in erroneous understanding of caprock hydraulic fracture behavior. Comprehensive analyses of monitoring data from the In Salah project suggested that one or more hydraulic fractures may have been created in the reservoir and lower caprock system during injection operations, but did not cause detectable leakage of CO 2 out of the storage complex. This observation coincides with a well-known phenomenon in the oil and gas industry: sedimentary rock formations have many inherent features that naturally protect the formations from unbounded vertical growth of hydraulic fractures.

58 GEOSCIENCES↗

Assessment of Borehole Gravity (Density) Monitoring for CO 2 Injection into the Dover 33 Reef

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. This report presents the results of BHG surveys conducted in the Lawnichak-Myskier 1-33 well in the Dover 33 reef by Tellus Gravity and Micro-g LaCoste in 2013, 2016, and 2018. A comparison of the data from the three surveys was performed to determine the feasibility of BHG to detect and monitor the location of the injected CO 2 in the reef over time. In addition, modeling was performed to compare the field data with the modeled data. Applying time-lapse BHG monitoring to a carbon sequestration site consists of determining temporal gravity anomalies related to the injection of CO 2 , and exclusively associated to the redistribution of the fluids in the pore space.

01 COAL, LIGNITE, AND PEAT↗

Injection Well Construction Diagrams and Specifications (SECARB Work Product 5.2.1.b)

This report discusses the Anthropogenic Test’s Injection Wells (D-9-7#2 and D-9- 9#2) design and construction specifications. The report includes sections on: Drilling and casing program, Drilling fluids, Coring, Completion program, Logging and testing program, Drilling prognosis, Well closure and post-closure care plans. The injection wells have been designed to meet or exceed the Alabama Department of Environmental Management’s (ADEM) Class V Underground Injection Control (UIC) standards including those designed to protect underground sources of drinking water.

01 COAL, LIGNITE, AND PEAT↗

CO 2 Injection and Recycle (SECARB Phase III Work Product 7.1.b)

During Cranfield Phase II and Phase III, over an elapsed period of more than three years between July 14, 2008, and August 31, 2011, 3,100,340 metric tons of CO 2 were injected and have accumulated (are stored) in the lower Tuscaloosa Formation as a result of injection. Exceeding the planned 1 million ton/year rate for 1½ year was possible because the project is piggy-backed on a commercial EOR project. The stored volume at elevated pressure has allowed the SECARB team to test a variety of monitoring approaches; these are documented in other SECARB reports and publications. The reported mass stored has been corrected so that it does not include methane impurities or double-count CO 2 produced and recycled. The methods of correction and other accounting strategies are reviewed and described based on the data typically available in a commercial EOR project. As a relevant test case, the SECARB accounting protocol has separated the injected, produced and stored volume into the east and west compartments of the field; the techniques demonstrated can be used in many other ways. Evaluation of the distribution of the CO 2 within the field (for example water leg vs. in the oilfield or gas cap or free-phase CO 2 vs. CO 2 dissolved in brine and oil) will be completed via history matching models with monitoring data in future reports. Assessment of conformance data has not identified any out-of zone CO 2 leakage; this evidence will be discussed in other reports. Assessment of surface release to atmosphere from surface infrastructure was outside of the scope of this study; we assume in this accounting that it is negligible, and less than other sources of accounting error. This milestone report also completes the request for an explanation of accounting during recycle.

01 COAL, LIGNITE, AND PEAT↗

H- Injection Simulations for a Multi-MW Upgrade

Fermilab intends to increase its Main Injector (MI) beam power to 2.4 MW in an effort to advance its flagship long-baseline neutrino program. Two scenarios are proposed for this ”PIP-III” upgrade, a 2-8 GeV RCS or an 8 GeV Linac. A Python tracking simulation was developed to model foil injection for these cases. First, the simulation was matched to the well established PIP-II case. From the matched simulation, investigations established that an on-momentum longitudinal injection increases foil traversals in PIP-II. Then the simulation was changed to model the RCS and Linac PIP-III scenarios, for both correlated and anti-correlated beam painting. The results of the PIP-III studies indicate that correlated painting is preferable for both the Linac and RCS scenarios. This research creates a baseline of foil injection performance for PIP-III.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Measured vs. Calculated Dose Rates During Ring Injection Dump Replacement

One of the most irradiated Spallation Neutron Source (SNS) accelerator components is the ring injection dump (RID), which is located downstream of the accumulator ring injection section. The unstripped and only partially stripped H - beam, about 5% of the full SNS beam current, is discarded in the injection into the accumulator ring and is redirected to the RID. According to the accelerator operation plan, the beam stop and the window assemblies of the existing RID are removed and replaced when they have reached their end-of-life owing to radiation exposure. This procedure, which includes multiple steps, took place during a facility maintenance period in March 2023. To support work planning and meet as low as reasonably achievable (ALARA) requirements during removal and exchange of the components, dose rates were calculated for each stage of the exchange operation. During each stage, dose rates were measured before and after work. This comparison shows that measured dose rates are within a factor of 2 of the predicted (calculated) dose rates.

43 PARTICLE ACCELERATORS↗

Study of Particle Loss in Synchrotron Phase Space Injection for ESR Using Weak-Strong Beam-Beam Simulation with Nonlinear Lattice

In this report, we use tracking simulations to investigate synchrotron phase space injection for electron accumulation in the electron storage ring of the Electron Ion Collider. Our simulation model accounts for both beam-beam interactions and lattice nonlinearities. Specifically, we examine how particle loss is influenced by various parameters. Additionally, we conduct a theoretical analysis and derive an analytical formula for the rapid evaluation of particle loss. Our results demon strate the feasibility of synchrotron phase-space injection for the electron storage ring and provide insights to guide parameter selection for the design of the injection line.

43 PARTICLE ACCELERATORS↗

Fracture Network Quantification during CO2 Injection

This is the presentation prepared for the ARMA 2025 (59th US Rock Mechanics/Geomechanics Symposium) Conference held in Santa Fe, New Mexico, June 8-11, 2025. Accurate mapping and quantification of these networks are essential to ensure the integrity of CO2 storage reservoirs, understand and reduce potential leakage, and maintain long-term environmental safety. This study presents a novel machine learning-driven approach, integrated with geomechanical analysis, to quantify fracture networks and assess their spatial distribution during CO2 injection. This paper combines microseismic monitoring data with principles of hydraulic diffusivity and geomechanical analysis to characterize reservoir scale fracture network. The novelty of our approach lies in its capacity to assimilate time-dependent pressure data and microseismicity into a cohesive framework, which not only identifies microseismic triggering fronts but also tracks fracture distribution during active injection. Besides, leveraging image log data and analysis our approach also provides another angle of the insights to solidate the fracture networks understanding and geomechanical impacts. Key results from our study include the detection of over 100 distinct fracture clusters across the injection site, with fracture orientations strongly correlated with the prevailing in-situ stress field.

CO2 storage and sequestration↗