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Chemical and biological evolution in space

The formation of organic molecules in interstellar dust grains and the survival of bacterial spores in a space environment are examined, summarizing the results of experimental investigations and theoretical calculations. The interstellar medium is characterized; the production of organic yellow-stuff residues on the mantles of dust grains in molecular clouds by UV radiation is explained; an IR absorption spectrum toward a Galactic-center source is shown to confirm the presence of such residues; and the mass of such abiotically produced complex organic molecules in the Galaxy is estimated as at least 10 to the 7th solar mass, or 0.1 percent of the mass in the Galaxy. This finding is considered significant for the prebiotic chemistry of the earth, since comets containing large amounts of interstellar dust may have impacted the earth many times during comet showers in the early solar system. UV-irradiation experiments on bacterial spores show that initial exposures to solar UV, not interstellar survival, is the main factor rendering theries of panspermia questionable.

Greenberg, J. M.↗

Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance (\rh{}) of $2.37-2.41$ au. These measurements of CO, \ce{CO2}, \ce{H2O}, \ce{CH3OH}, and \ce{CH4} sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the \ce{H2O} ice line --- the region between \rh{} = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and \ce{CO2} begin to control the overall activity. CO was the most abundant molecule, followed by \ce{H2O} and \ce{CO2}, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for \ce{H2O} were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

Nathan X Roth↗

The Formation of Solid Particles from their Gas-Phase Molecular Precursors in Cosmic Environments with NASA Ames' COSmIC Facility

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗

Investigating nearby star-forming galaxies in the ultraviolet with HST/COS spectroscopy. I. Spectral analysis and interstellar abundance determinations

This is the first in a series of three papers describing a project with the Cosmic Origins Spectrograph on the Hubble Space Telescope to measure abundances of the neutral interstellar medium (ISM) in a sample of nine nearby star-forming galaxies. The goal is to assess the (in)homogeneities of the multiphase ISM in galaxies where the bulk of metals can be hidden in the neutral phase, yet the metallicity is inferred from the ionized gas in the H II regions. The sample, spanning a wide range in physical properties, is to date the best suited to investigate the metallicity behavior of the neutral gas at redshift z = 0. ISM absorption lines were detected against the far-ultraviolet spectra of the brightest star-forming region(s) within each galaxy. Here we report on the observations, data reduction, and analysis of these spectra. Column densities were measured by a multicomponent line-profile fitting technique, and neutral-gas abundances were obtained for a wide range of elements. Several caveats were considered, including line saturation, ionization corrections, and dust depletion. Ionization effects were quantified with ad hoc CLOUDY models reproducing the complex photoionization structure of the ionized and neutral gas surrounding the UV-bright sources. An 'average spectrum of a redshift z = 0 star-forming galaxy' was obtained from the average column densities of unsaturated profiles of neutral-gas species. This template can be used as a powerful tool for studies of the neutral ISM at both low and high redshift.

79 ASTRONOMY AND ASTROPHYSICS↗

HERSCHEL/HIFI DISCOVERY OF HCL{sup +} IN THE INTERSTELLAR MEDIUM

The radical ion HCl{sup +}, a key intermediate in the chlorine chemistry of the interstellar gas, has been identified for the first time in the interstellar medium with the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared. The ground-state rotational transition of H{sup 35}Cl{sup +}, {sup 2}{Pi}{sub 3/2} J = 5/2-3/2, showing {Lambda}-doubling and hyperfine structure, is detected in absorption toward the Galactic star-forming regions W31C (G10.6-0.4) and W49N. The complex interstellar absorption features are modeled by convolving in velocity space the opacity profiles of other molecular tracers toward the same sources with the fine and hyperfine structure of HCl{sup +}. This structure is derived from a combined analysis of optical data from the literature and new laboratory measurements of pure rotational transitions, reported in the accompanying Letter by Gupta et al. The models reproduce well the interstellar absorption, and the frequencies inferred from the astronomical observations are in exact agreement with those calculated using spectroscopic constants derived from the laboratory data. The detection of H{sup 37}Cl{sup +} toward W31C, with a column density consistent with the expected {sup 35}Cl/{sup 37}Cl isotopic ratio, provides additional evidence for the identification. A comparison with the chemically related molecules HCl and H{sub 2}Cl{sup +} yields an abundance ratio of unity with both species (HCl{sup +} : H{sub 2}Cl{sup +} : HCl {approx} 1). These observations also yield the unexpected result that HCl{sup +} accounts for 3%-5% of the gas-phase chlorine toward W49N and W31C, values several times larger than the maximum fraction ({approx}1%) predicted by chemical models.

74 ATOMIC AND MOLECULAR PHYSICS↗

StarNAV: An Architecture for Autonomous Spacecraft Navigation by the Relativistic Perturbation of Starlight

Exploration missions to the outer Solar System (e.g., Neptune, Kuiper belt objects) or to the interstellar medium present several challenges for conventional spacecraft designs. One of the greatest challenges is a means for navigation, as Earth-based tracking with the Deep Space Network (DSN) becomes less desirable due to high cost, decreased performance at long ranges, and long light-time delays. Indeed, light time delays at Neptune are over four hours (one way), making control of spacecraft during critical events nearly impossible—and this problem only becomes worse as we move to the Kuiper belt or to interstellar space. The need for autonomous spacecraft navigation is well established and is prominently featured in the 2015 NASA Technology Roadmap (e.g., TA 5.4.2.6 & 5.4.2.8). This has led to investment in various technologies to accomplish this task, with the majority of recent work focusing on optical navigation (OPNAV; TA 5.4.4.1) [1], X-ray pulsar navigation (XNAV; TA 5.6.1) [2], or DSN one-way ranging with the Deep Space Atomic Clock (DSAC; TA 5.4.1.1) [3]. This NIAC study suggests a new (and completely different) way of autonomously navigating a spacecraft anywhere in the Solar System or beyond. We call this new technique StarNAV.

NIAC Phase I↗

On the flux and the energy spectrum of interstellar ions in the solar system

The flux density of ions created by ionization of interstellar neutral particles in the solar system and picked up by the solar wind is calculated as a function of the neutral particles. For atomic hydrogen the flux density is estimated to exceed 10,000/sq cm/sec over the distance range from a few to nearly 100 AU. The velocity space distribution of the interstellar ions is calculated under the assumption of no significant energy diffusion but with inclusion of adiabatic effects as well as a possible strong pitch angle diffusion. The energy spectrum is highly nonthermal and much broader than that of the solar wind ions; interstellar protons are easily distinguishable from solar wind protons by their location in velocity space. If charge exchange is an important contributor to the ionization of hydrogen, the observed local intensity of interstellar protons should exhibit time variations correlated with the density changes of the solar wind stream structure.

Vasyliunas, V. M.↗

Midcourse Space Experiment Spectra of the Orion Nebula and the Implications for Abundances in the Interstellar Medium

Spectra of the Orion Nebula were obtained with the Midcourse Space Experiment Spirit 3 interferometer from 370 to 2000 cm(exp -1) with 2 cm(exp -1) resolution in a 6' x 9' field of view (FOV) in 1996 November. Lines were detected of [S III] 534.4 cm(exp -1), [Ne III] 642.9 cm(exp -1), [Ne II] 780.4 cm(exp -1), [S IV] 951.4 cm(exp -1), [Ar III] 1112.2 cm(exp -1), [Ar II] 1431.6 cm(exp -1), H (7-6) 808.3 cm(exp -1), H (8-6) 1332.9 cm(exp -1), H (6-5) 1340.5 cm(exp -1), H2(S1) 587.0 cm(exp -1), H2(S2) 814.4 cm(exp -1), H2(S3) 1034.7 cm(exp -1), H2(S4) 1246.1 cm(exp -1), and H2(S5) 1447.3 cm(exp -1). The following abundances were determined from these lines: Ne/H = 9.9 +/- 1.1 x 10(exp -5), S/H = 8.1 +/- 1.1 x 10(exp -6), and Ar/H = 2.5 +/- 0.2 x 10(exp -6). These abundances are all less than solar and confirm that the Sun is overabundant in heavy elements without the need for correction for the composition of interstellar dust. The low sulfur abundance compared with solar is an indication that a significant amount of the sulfur in Orion is in dust grains. The FOV-averaged molecular hydrogen column density is approximately 1.6 x 10(exp 20) cm(exp -2) for an excitation temperature of approximately 670 K and an extinction correction corresponding to an optical depth of 1.5 at 9.7 micrometers. The unidentified infrared emission features at 6.2, 7.7, 8.6, 11.3, and 12.7 micrometers, attributable to polycyclic aromatic hydrocarbons, were also detected. A prominent, broad silicate feature centered near 18 micrometer and additional weak features were detected and are discussed.

Simpson, J. P.↗

Engineering planetary lasers for interstellar communication

Transmitting large amounts of data efficiently among neighboring stars will vitally support any eventual contact with extrasolar intelligence, whether alien or human. Laser carriers are particularly suitable for high-quality, targeted links. Space laser transmitter systems designed by this work, based on both demonstrated and imminent advanced space technology, could achieve reliable data transfer rates as high as 1 kb/s to matched receivers as far away as 25 pc, a distance including over 700 approximately solar-type stars. The centerpiece of this demonstration study is a fleet of automated spacecraft incorporating adaptive neural-net optical processing active structures, nuclear electric power plants, annular momentum control devices, and ion propulsion. Together the craft sustain, condition, modulate, and direct to stellar targets an infrared laser beam extracted from the natural mesospheric, solar-pumped, stimulated CO2 emission recently discovered at Venus. For a culture already supported by mature interplanetary industry, the cost of building planetary or high-power space laser systems for interstellar communication would be marginal, making such projects relevant for the next human century. Links using high-power lasers might support data transfer rates as high as optical frequencies could ever allow. A nanotechnological society such as we might become would inevitably use 10 to the 20th power b/yr transmission to promote its own evolutionary expansion out of the galaxy.

Sherwood, Brent↗

FIRST DETECTION OF ULTRAVIOLET EMISSION FROM A DETACHED DUST SHELL: GALAXY EVOLUTION EXPLORER OBSERVATIONS OF THE CARBON ASYMPTOTIC GIANT BRANCH STAR U Hya

We present the discovery of an extended ring of ultraviolet (UV) emission surrounding the asymptotic giant branch (AGB) star U Hya in archival observations performed by the Galaxy Evolution Explorer. This is the third discovery of extended UV emission from a carbon AGB star and the first from an AGB star with a detached shell. From imaging and photometric analysis of the FUV and NUV images, we determined that the UV ring has a radius of ∼110'', thus indicating that the emitting material is likely associated with the detached shell seen in the infrared. We find that scattering of the central point source of NUV and FUV emission by the dust shell is negligible. Moreover, we find that scattering of the interstellar radiation field by the dust shell can contribute at most ∼10% of the FUV flux. Morphological and photometric evidence suggests that shocks caused by the star's motion through space and, possibly, shock-excited H{sub 2} molecules are the most likely origins of the UV flux. In contrast to previous examples of extended UV emission from AGB stars, the extended UV emission from U Hya does not show a bow-shock-like structure, which is consistent with a lower space velocity and lower interstellar medium density. This suggests the detached dust shell is the source of the UV-emitting material and can be used to better understand the formation of detached shells.

79 ASTRONOMY AND ASTROPHYSICS↗

Seven Years of Imaging the Global Heliosphere with IBEX

The Interstellar Boundary Explorer ( IBEX ) has now operated in space for 7 years and returned nearly continuous observations that have led to scientific discoveries and reshaped our entire understanding of the outer heliosphere and its interaction with the local interstellar medium. Here we extend prior work, adding the 2014–2015 data for the first time, and examine, validate, initially analyze, and provide a complete 7-year set of Energetic Neutral Atom (ENA) observations from ∼0.1 to 6 keV. The data, maps, and documentation provided here represent the 10th major release of IBEX data and include improvements to various prior corrections to provide the citable reference for the current version of IBEX data. We are now able to study time variations in the outer heliosphere and interstellar interaction over more than half a solar cycle. We find that the Ribbon has evolved differently than the globally distributed flux (GDF), with a leveling off and partial recovery of ENAs from the GDF, owing to solar wind output flattening and recovery. The Ribbon has now also lost its latitudinal ordering, which reflects the breakdown of solar minimum solar wind conditions and exhibits a greater time delay than for the surrounding GDF. Together, the IBEX observations strongly support a secondary ENA source for the Ribbon, and we suggest that this be adopted as the nominal explanation of the Ribbon going forward.

79 ASTRONOMY AND ASTROPHYSICS↗

Search for Hydrogenated C{sub 60} (Fulleranes) in Circumstellar Envelopes

The recent detection of fullerene (C{sub 60}) in space and the positive assignment of five diffuse interstellar bands to C{sub 60}{sup +} reinforce the notion that fullerene-related compounds can be efficiently formed in circumstellar envelopes and be present in significant quantities in the interstellar medium. Experimental studies have shown that C{sub 60} can be readily hydrogenated, raising the possibility that hydrogenated fullerenes (or fulleranes, C{sub 60}H{sub m}, m = 1–60) may be abundant in space. In this paper, we present theoretical studies of the vibrational modes of isomers of C{sub 60}H{sub m}. Our results show that the four mid-infrared bands from the C{sub 60} skeletal vibrations remain prominent in slightly hydrogenated C{sub 60}, but their strengths diminish in different degrees with increasing hydrogenation. It is therefore possible that the observed infrared bands assigned to C{sub 60} could be due to a mixture of fullerenes and fulleranes. This provides a potential explanation for the observed scatter of the C{sub 60} band ratios. Our calculations suggest that a feature around 15 μm due to the breathing mode of heavily hydrogenated C{sub 60} may be detectable astronomically. A preliminary search for this feature in 35 C{sub 60} sources is reported.

79 ASTRONOMY AND ASTROPHYSICS↗

Physics of the outer heliosphere; Proceedings of the 1st COSPAR Colloquium, Warsaw, Poland, Sept. 19-22, 1989

This volume includes chapters on spectroscopic data on the local interstellar medium and the related XUV radiation background; solar UV backscatter on neutral Galactic gases; entry and dynamics of Galactic and anomalous cosmic rays in the heliosphere; distant solar wind plasma, magnetic field, and solar energetic particles; the interaction of solar wind with the interstellar medium; and deep-space missions. Papers are on the characteristics and the velocity structure of the local interstellar medium, the scattering of solar UV on local neutral gases, solar effects on underground muons at 570 hg/sq cm, and cosmic rays and magnetosonic instabilities of solar wind flow near the heliospheric shock wave. Consideration is also given to the shock heating of the solar wind plasma, solar wind vortex flow in the outer heliosphere, the signature of a viscous interaction at the heliopause, the expected beams of energetic neutral atoms in the outer heliosphere, and the Pioneers 10 and 11 deep-space missions.

Grzedzielski, S.↗