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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Matrix material in type 3 chondrites - Occurrence, heterogeneity and relationship with chondrules

Variations between mean matrix compositions of individual type 3 ordinary chondrites are nearly fivefold, and partly reflect systematic differences between H, L, and LL matrices. Such variations are probably the result of a nebular separation of feldspathic material and ferromagnesian silicates. While compositions of chondrules and their matrix rims are normally unrelated, rim compositions are correlated with those of matrix lumps inside chondrules. Matrix lumps are as heterogeneous as chondrules, but mean chondrule and matrix compositions differ. Since bulk compositions of matrix lumps and rims have probably not changed significantly since their formation, the present matrix samples cannot represent typical chondrule precursor materials.

Scott, E. R. D.↗
NASA NTRS1985

Geometric effects of global lateral heterogeneity on long-period surface wave propagation

The present investigation has the objective to document examples of anomalous long-period surface wave amplitude behavior and to provide a preliminary appraisal of the effects of global lateral heterogeneity on surface wave propagation from a ray theory perspective. Attention is given to remarkable long-period surface wave anomalies described in literature, an equidistance azimuthal plot centered on the Iranian source region, Rayleigh wave and Love wave spectra for the 256-s period arrivals for the Tabas earthquake, constrained moment tensor and fault model inversion solutions ofr Iranian earthquakes, aspects of surface wave ray tracing, and a table of Rayleigh wave amplitude anomalies for Iranian earthquakes. Surface wave ray-tracing calculations for models of global phase velocity variations proposed by Nakanishi and Anderson (1984) are found to show that large-amplitude anomalies will be observed for Love and Rayleigh waves with periods of 100-250 s.

Lay, T.↗
NASA NTRS1986

Mapping the Structure of Heterogeneous Materials

Image-processing microdensitometer/Fourier analyzer yields statistics of subcomponent distribution. Nondestructive method for studying structure heterogeneous materials uses energy-dispersive X-ray analysis in scanning electron microscope. Scanning microdensitometer/Fourier analyzer (SMFA) is applied to SEM images to obtain statistics about sample structure. Method originally developed for studying effect on combustion of fine structure of composite solid propellants.

Strand, L. D.↗
NASA NTRS1986

Relation between microstructural heterogeneous surface layer and nitrogen pressure during sintering in Si3N4-Ml2O3 ceramics

The effects of N2 pressure (0.1 to 50 MPa) during sintering on the thickness of the microstructurally heterogeneous layer (MHL) formed near the surface of the compact, transverse-rupture strength, were investigated for Si3N4-(10 to 20) mol % MgO-5.5 mol % Al2O3 ceramics. The sintering temperature and time were 1973 K and 3.6 ks, respectively. The N2 gas was introduced into the furnace at about 1273 K. When the compacts were sintered under a certain N2 pressure, for example, about 20 and 7 MPa for 10 and 15 mol% MgO, respectively, the evolutions of N and Si were suppressed. The thickness of the MHL became very small and at the same time the strength of the surface layer of the compact (which was normally less than that of the inside in the case of 0.1 MPa) became nearly the same value as that of the inside. At higher pressure, the strength of both surface layer and the inside decreased considerably. Some discussion was made on these results.

Hayashi, K.↗
NASA NTRS1985

The effect of material heterogeneity and random loading on the mechanics of fatigue crack growth

This paper reviews experimental work on the influence of variable amplitude or random loads on the mechanics and micromechanisms of fatigue crack growth. Implications are discussed in terms of the crack driving force, local plasticity, crack closure, crack blunting, and microstructure. Due to heterogeneity in the material's microstructure, the crack growth rate varies with crack tip position. Using the weakest link theory, an expression for crack growth rate is obtained as the expectation of a random variable. This expression is used to predict the crack growth rates for aluminum alloys, a titanium alloy, and a nickel steel in the mid-range region. It is observed, using the present theory, that the crack growth rate obeys the power law for small stress intensity factor range, and that the power is a function of a material constant.

Srivatsan, T. S.↗
NASA NTRS1986

Finite difference simulations of seismic scattering Implications for the propagation of short-period seismic waves in the crust and models of crustal heterogeneity

Synthetic seismographs that were obtained by the finite difference method are presently applied to the study of elastic and acoustic wave scattering in two-dimensional media with random spatial variations in seismic velocity. The seismograms are analyzed to determine the variation in travel times and waveforms across arrays of receivers. The random media with Gaussian and exponential correlation functions considered differ in the spectral falloff of their velocity fluctuations at wavelengths smaller than 2pi times the correlation distance. It is found that alternative models of crustal heterogeneity can be tested by improved measurements of the frequency dependence of the crustal Q at frequencies greater than about 1 Hz, assuming that scattering is responsible for most of the attenuation at such frequencies.

Frankel, A.↗
NASA NTRS1987

High repetition rate sealed CO2 TEA lasers using heterogeneous catalysts

The significant operational advantages offered by CO2 lasers, operating in the 10.6 micron region of the spectrum, over current solid state lasers, emitting in the near IR region, have prompted increased interest in the development of compact, reliable, rugged CO2 laser sources. Perhaps the most critical aspect associated with achieving a laser compatible with military use is the development of lasers which require no gas replenishment. Sealed, single shot, CO2 TEA lasers have been available for a number of years. Stark et al were first to demonstrate reliable sealed operation in single shot CO2 TEA lasers in 1975 using gas catalysis. GEC Avionics reported the compact, environmentally qualified, MKIII CO2 TEA laser with a pulse life of greater than 10 to the 6th power pulses in 1980. A sealed laser lifetime of greater than 10 to the 6th power pulses is acceptable for single shot cases, such as direct detection rangefinders for tank laser sights. However, in many other applications, such as tracking of fast moving targets, it is essential that a repetition rate of typically 30Hz to 100Hz is employed. In such cases, a pulse lifetime of 10 to the 6th power pulses is no longer sufficient and a minimum pulse lifetime 10 to the 7th power pulses is essential to ensure a useful service life. In 1983 Stark el al described a sealed, 100Hz CO2 TEA laser, with a life of greater than 2.6 x 10 to the 6th power, which employed heterogeneous catalysis. Following this pioneering work, GEC Avionics has been engaged in the development of sealed high repetition rate lasers with a pulse lifetime of 20 million pulses.

Price, H. T.↗
NASA NTRS1985

Heterogeneous distributed query processing: The DAVID system

The objective of the Distributed Access View Integrated Database (DAVID) project is the development of an easy to use computer system with which NASA scientists, engineers and administrators can uniformly access distributed heterogeneous databases. Basically, DAVID will be a database management system that sits alongside already existing database and file management systems. Its function is to enable users to access the data in other languages and file systems without having to learn the data manipulation languages. Given here is an outline of a talk on the DAVID project and several charts.

Jacobs, Barry E.↗
NASA NTRS1986

A kinetics study of the homogeneous and heterogeneous components of the HCl + ClONO2 reaction

The kinetics of the reaction HCl + ClONO2 to Cl2 + HNO3 were investigated at 298 K using a flow reactor with FTIR analysis to assess the importance of this reaction for stratospheric chemistry. The observed reaction was characteristic of a heterogeneous process; an upper limit of 5 x 10 to the -18th cu cm/molecule per s was obtained for the homogeneous gas phase rate constant. From calculations of the first order wall rate constant, estimates were made of the reaction rate on stratospheric aerosols. Because both HCl and ClONO2 need to be adsorbed on the particle surface, the reaction will be of negligible importance under most stratospheric conditions.

Friedl, Randall R.↗
NASA NTRS1986

Mantle heterogeneity and crustal recycling in Archean granite-greenstone belts - Evidence from Nd isotopes and trace elements in the Rainy Lake area, Superior Province, Ontario, Canada

Crustal evolution in the Rainy Lake area, Ontario is studied in terms of geochemical characteristics. The Nd isotope data are examined for heterogeneity of the Archean mantle, and the Sm/Nd depletion of the mantle is analyzed. The Nd isotope systematics of individual rock suites is investigated in order to understand the difference between crust and mantle sources; the precursors and petrogenetic processes are discussed. The correlation between SiO2 content and Nd values is considered. Rapid recycling of crustal components, which were previously derived from depleted mantle sources, is suggested based on the similarity of the initial Nd isotopic composition for both mantle-derived and crustally-derived rocks.

Shirey, Steven B.↗
NASA NTRS1987

Combined homogeneous and heterogeneous crystal nucleation in glasses

The temperature dependence of combined homogeneous and heterogeneous crystal nucleation is examined within the framework of the classical theory. It is demonstrated that nucleation can have a local maximum rate at one or two temperatures. The physical parameters which cause large changes in the structure of the nucleation curve are elucidated. Also, the influence of saturation effects on the structure of nucleation curves is illustrated. The utilization of these results for the interpretation of experiments and for the production of controlled crystal nucleation in glass is considered.

Weinberg, Michael C.↗
NASA NTRS1988

Evaluation and Improvement of Liquid Propellant Rocket Chugging Analysis Techniques. Part 2: a Study of Low Frequency Combustion Instability in Rocket Engine Preburners Using a Heterogeneous Stirred Tank Reactor Model

During the shutdown of the space shuttle main engine, oxygen flow is shut off from the fuel preburner and helium is used to push the residual oxygen into the combustion chamber. During this process a low frequency combustion instability, or chug, occurs. This chug has resulted in damage to the engine's augmented spark igniter due to backflow of the contents of the preburner combustion chamber into the oxidizer feed system. To determine possible causes and fixes for the chug, the fuel preburner was modeled as a heterogeneous stirred tank combustion chamber, a variable mass flow rate oxidizer feed system, a constant mass flow rate fuel feed system and an exit turbine. Within the combustion chamber gases were assumed perfectly mixed. To account for liquid in the combustion chamber, a uniform droplet distribution was assumed to exist in the chamber, with mean droplet diameter determined from an empirical relation. A computer program was written to integrate the resulting differential equations. Because chamber contents were assumed perfectly mixed, the fuel preburner model erroneously predicted that combustion would not take place during shutdown. The combustion rate model was modified to assume that all liquid oxygen that vaporized instantaneously combusted with fuel. Using this combustion model, the effect of engine parameters on chamber pressure oscillations during the SSME shutdown was calculated.

Bartrand, Timothy A.↗
NASA NTRS1987

Thermally induced phase changes, lateral heterogeneity of the mantle, continental roots, and deep slab anomalies

Factors which influence the lateral heterogeneity in density and seismic velocity with depth in the upper earth mantle are discussed. It is emphasized that most of the increases in density and seismic velocity with depth are caused by pressure-induced solid-solid phase changes in the high-density high-velocity phases of mineral assemblage, due to variations in temperature. In particular, the ilmenite form of MgSiO3 and the gamma-spinel form of Mg2SiO4 have broad stability fields in cold mantle and are not stable in hotter mantle. It is emphasized that the density and velocity anomalies associated with temperature-induced phase changes in mineral assemblage must be taken into account in the thermal models of the slabs; when these effects are accounted for, the geoid and seismic anomalies associated with subducted slabs are consistent with slab confinement to the upper mantle and with layered models of mantle convection.

Anderson, Don L.↗
NASA NTRS1988

Laboratory studies of sticking coefficients and heterogeneous reactions important in the Antarctic stratosphere

Laboratory studies of sticking coefficients of H2O, HCl, Cl2, and HNO3 on ice and heterogeneous reactions of ClONO2 with ice or HCl/ice have been performed in a fast flow reactor. A quadrupole mass spectrometer with electron impact ionization was used as a detector. Measured sticking coefficients are: 0.3 (+0.7, -0.1) for H2O, 0.4 (+0.6, -0.2) for HCL, less than 0.0001 for Cl2, and 0.3 (+0.7, -0.1) for HNO3 at 200 K. The reaction probability of ClONO2 on ice was found to be 0.06 (+ or - 0.03) while HOCl was observed as a sole product in the gas phase. With HCl present in ice, the reaction probability of ClONO2 is greatly enhanced, approaching 0.27 (+0.73, -0.13) while molecular chlorine was found to be the major product in the gas phase. Another reaction product was nitric acid which remained in the solid phase. Since the polar stratospheric clouds contain ice particles or possibly HCl/ice particles on the surface, the present results should be a major factor in producing the observed springtime ozone depletion in the Antarctic stratosphere.

Leu, Ming-Taun↗
NASA NTRS1987

Problems related to the determination of land surface parameters and fluxes over heterogeneous media from satellite data

Problems encountered in the definition of relevant parameters which can describe heterogeneous media as a whole are discussed. A procedure to extend the definition of parameters from local to regional scales via inversion of appropriate models is tentatively proposed. The adequacy of these models for describing physical processes at the earth/atmosphere interface as observed with satellite systems is addressed.

Becker, F.↗
NASA NTRS1988

Heterogeneous reactions of N2O5 with H2O and HCl on ice surfaces - Implications for Antarctic ozone depletion

This paper reports on the measurements of reaction probabilities for heterogeneous reaction of N2O5 with H2O and HCl on ice surfaces at 195 K, using a fast-flow reactor coupled with a quadrupole mass spectrometer. The reaction probability for N2O5 on pure-water ice was found to be 0.028 + or - 0.011, with nitric acid in the solid phase as the sole product. In the presence of HCl in ice, the probability of N2O5 reaction was enhanced (to 0.037); the reaction produced, besides solid-phase nitric acid, ClNO2 and ClONO which were released into the gas phase within a few milliseconds. The latter two compounds can be readily photolyzed in the austral spring to form active chlorine which would remove stratospheric ozone. It is suggested that, since the polar stratospheric clouds are believed to contain HCl-ice mixture on the surface, the reactions of N2O5 on H2O/HCl particles is a major factor in the Antarctic springtime ozone depletion.

Leu, Ming-Taun↗
NASA NTRS1988

The use of heterogeneous and epitaxial nucleants to promote the growth of protein crystals

Fifty different mineral samples were tested as potential heterogeneous or epitaxial nucleants for four commonly crystallized proteins. It was found, using conventional protein crystallization techniques, that for each protein there was a set of mineral substrates that promoted nucleation of crystals at lower critical levels of supersaturation than required for spontaneous growth. In at least one case, the growth of lysozyme on the mineral apophyllite, it was shown by lattice analysis and X-ray diffraction that the nucleation and growth of the protein crystal on the mineral was likely to be truly epitaxial.

Mcpherson, Alexander↗
NASA NTRS1988

Estimation of canopy parameters for inhomogeneous vegetation canopies from reflectance data. III - TRIM: A model for radiative transfer in heterogeneous three-dimensional canopies

A model for radiative transfer in heterogeneous three-dimensional canopies such as those found in forests is proposed. Its use in estimating important biophysical variables such as leaf area index and canopy architecture from bidirectional canopy reflectance data is discussed. The model and its use in estimating canopy parameters through its inversion are validated with measured canopy reflectance data for corn canopies.

Goel, Narendra S.↗