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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Chemical modification of TiO2 surfaces with methylsilanes and characterization by infrared absorption spectroscopy

Infrared absorption spectra of methylsilanes bonded to a TiO2 powder were obtained. The reacting silanes include Me sub (4-n)SiX sub n (n=1-4; X=Cl, OMe) and hexamethyldisilazane (HMDS). Reactions were performed on hydroxylated-but-anhydrous TiO2 surfaces in the gas phase. IR spectra confirm the presence of a bonded silane layer. Terminal surface OH groups are found to react more readily than bridging OH groups. By-products of the modification adsorp tenaciously to the surface. The various silanes show only small differences in their ability to sequester surface OH groups. Following hydrolysis in moist air, Si-OH groups are observed only for the tetrafunctional silanes.

Finklea, H. O.↗
NASA NTRS1981

Chemical modification of semiconductor surfaces

Results of research on the chemical modification of TiO2 powders in the gas phase and the examination of the modified powders by infrared absorption spectroscopy are comprehensively summarized. The range of information obtainable by IR spectroscopy of chemically modified semiconductors, and a definition of the optimum reaction conditions for synthesizing a monolayer of methylsilanes using vapor phase reaction conditions were considered.

Finklea, H. O.↗
NASA NTRS1982

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents on Titan are calculated for solar ultraviolet radiation, the solar wind, Saturn magnetospheric particles, the Saturn co-rotating plasma, and cosmic rays. Laboratory experiments show that a variety of simple gas phase organic molecules and more complex organic solids called tholins are produced by such irradiations of simulated Titanian atmospheres. Except for ultraviolet wavelengths longward of the methane photodissociation continuum, most dissociation events occur between about 3100 and 3600 km altitude, corresponding well to the region of EUV opacity detected by Voyager. For a wide variety of simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at about 2825 km. It is proposed that such condensates, beginning with CH4 at about 2615 km, comprise the principal mass of the Titan clouds. There is a distinct tendency for the atmosphere of Titan to act as a fractional distillation device, molecules of greater complexity condensing out at higher altitudes.

Sagan, C.↗
NASA NTRS1981

Abundances of refractory elements in quasars

A comparison of previous and new observations of iron, silicon, aluminum, magnesium and carbon lines in quasars with theoretical models shows that the gas-phase abundances of these refractory elements cannot be much less than solar, and that they do not show the order-of-magnitude depletions that are found in planetary nebulae and the interstellar medium. In light of this lack of refractory element depletions, it is suggested that the broad emission-line clouds must be devoid of dust.

Gaskell, C. M.↗
NASA NTRS1981

Far-UV, visible, and near-IR reflectance spectra of frosts of H2O, CO2, NH3 and SO2

Measurements in the 0.1-2.5 micron range are presented for the reflectance spectra of the frosts of several volatiles pertinent to the study of comet nuclei. The frost spectra have distinctive features permitting their identification by spectroscopic reflectance remote sensing, notably in the far UV. It is found that: (1) H2O has a minimum at 0.16 microns and a maximum at 0.13 microns; (2) CO2 has minima near 0.21, 0.18 and 0.125 microns, with maxima at 0.19, 0.135 and 0.120 microns; (3) NH3 is bright at wavelengths longer than 0.21 microns, where reflectance drops to a value of only a few per cent at shorter wavelengths; (4) SO2 has a sharp drop at 0.32 microns, with a minimum at 0.18 microns and a maximum at 0.13 microns. The features in the frost spectra largely correspond to absorption line bands in the gas phase.

Hapke, B.↗
NASA NTRS1981

Millimeter-wave experiments for cometary space missions

Predicted brightness temperatures, computed by means of radiative transfer techniques adapted from the modeling of terrestrial ice and snow fields, are given for cometary nucleus models consisting of homogeneous layers of water ice and refractory grain mixtures presented as functions of wavelength. The computed millimeter-wave spectra are sensitive to the values of such physically significant nucleus parameters as (1) crust thickness, (2) subsurface temperature gradient, and (3) sublimating surface boundary temperature. Although antenna beam dilution is a major obstacle for ground-based molecular spectral line radio observations of comets, a millimeter-wave radiometer in the vicinity of the comet would be immune to this effect and able to make observations of several candidate parent molecules in the gas phase.

Hobbs, R. W.↗
NASA NTRS1981

Molecules in interstellar clouds

The physical conditions and chemical compositions of the gas in interstellar clouds are reviewed in light of the importance of interstellar clouds for star formation and the origin of life. The Orion A region is discussed as an example of a giant molecular cloud where massive stars are being formed, and it is pointed out that conditions in the core of the cloud, with a kinetic temperature of about 75 K and a density of 100,000-1,000,000 molecules/cu cm, may support gas phase ion-molecule chemistry. The Taurus Molecular Clouds are then considered as examples of cold, dark, relatively dense interstellar clouds which may be the birthplaces of solar-type stars and which have been found to contain the heaviest interstellar molecules yet discovered. The molecular species identified in each of these regions are tabulated, including such building blocks of biological monomers as H2O, NH3, H2CO, CO, H2S, CH3CN and H2, and more complex species such as HCOOCH3 and CH3CH2CN.

Irvine, W. M.↗
NASA NTRS1982

A new interstellar component in the spectrum of HD 72127A

New high dispersion observations are reported of the very strong, broad interstellar K line of Ca II in the spectrum of HD 72127A, a star located near a filament of the Vela supernova remnant. When compared with similar observations made in 1977, the new data reveal temporal variability of the interstellar absorption, as shown both by the presence of a new, sixth line component and by a 25% increase in the total equivalent width of the K line. All five Ca II components which were seen in both years show very large column-density ratios N(Ca II) /N(Na I) at least equal to 9, probably arising from anomalously large interstellar gas-phase abundances of Ca caused by disruption of interstellar grains. Marked differences in the structure of the K line between the two early-type components of this binary star, which are separated by only 3000 AU, are confirmed.

Hobbs, L. M.↗
NASA NTRS1982

Effect of X-ray flux on polytetrafluoroethylene in X-ray photoelectron spectroscopy

The effect of the X-ray flux in X-ray photoelectron spectroscopy (STAT) on the constitution of the polytetrafluoroethylene (PTFE) surface has been examined. The radiation dose rate for our specimen was about 10 to the 7th rad/s. The structure, magnitude and binding energy of the C(1s) and F(1s) features of the XPS spectrum and the mass spectrum of gaseous species evolved during irradiation are observed. The strong time dependence of these signals over a period of several hours indicated that the surface constitution of PTFE is greatly affected by this level of radiation dose. The results are consistent with the development of a heavily cross-linked or branched structure in the PTFE surface region and the evolution of short chain fragments into the gas phase.

Wheeler, D. R.↗
NASA NTRS1982

The local interstellar medium

Analysis of the velocities of optical interstellar lines shows that the sun is immersed in a coherently moving local interstellar medium whose velocity vector agrees with that of the interstellar wind observed through backscatter of solar H Ly-alpha and He lambda 584 photons. The local interstellar medium consists of both cool clouds and warm intercloud medium gas, has a mass of perhaps approximately 30 solar masses, does not have severe depletion of trace elements from the gas phase, and appears to be material which has been shocked and accelerated by stellar winds and supernovae associated with the Sco-Oph OB association.

Crutcher, R. M.↗
NASA NTRS1981

Interstellar chemistry - Polycyanoacetylene formation

It is argued that interstellar polycyanoacetylenes are formed not on dust grains by catalytic buildup or by dissociation of longer molecules, but rather by gas phase ion-molecule reactions. The primary evidence for this view is the detection of deuterated cyanoacetylene in an interstellar cloud. It is also argued that the relative abundance of successive homologs of polycyanoacetylenes rules out the grain catalysis theory.

Langer, W. D.↗
NASA NTRS1982

Origin of rims on coarse-grained inclusions in the Allende meteorite

Coarse-grained, calcium-rich inclusions in the Allende meteorite are enclosed by sequences of very thin, mineralogically distinct rim layers. A number of questions arise in connection with the presence of rims. The present investigation presents new observations bearing on all these questions and provides a model for the formation of rims. A zoned alteration vein is considered along with a sinuous inclusion, a spinel-perovskite-melilite band (SP), layers overlying the melilite-rich side of SP, a layer overlying the spinel-rich side of SP, and aspects of rim composition and the degree of alteration in coarse-grained inclusions. It is proposed that rims on coarse-grained inclusions formed in a nonequilibrium process involving those reactions between coarse-grained melilite and spinel and a nebular gas phase which also produced the secondary alteration products in the interiors of these inclusions.

Macpherson, G. J.↗
NASA NTRS1982

Recent theoretical chemical dynamics at Rochester in the paths of Joseph O. Hirschfelder

A review of recent theoretical studies of gas-phase molecular rate processes, including various effects of laser radiation, is presented in the context of the extensive and influential work of Joseph O. Hirschfelder during the past half-century. The topics addressed are energy transfer, chemical reactions, unimolecular dissociation, transition states, and bound-continuum interactions.

George, T. F.↗
NASA NTRS1982

Theory of metal atom-water interactions and alkali halide dimers

Theoretical studies of the interactions of metal atoms with water and some of its isoelectronic analogs, and of the properties of alkali halides and their aggregates are discussed. Results are presented of ab initio calculations of the heats of reaction of the metal-water adducts and hydroxyhydrides of Li, Be, B, Na, Mg, and Al, and of the bond lengths and angles an; the heats of reaction for the insertion of Al into HF, H2O, NH3, H2S and CH3OH, and Be and Mg into H2O. Calculations of the electron affinities and dipole moments and polarizabilities of selected gas phase alkali halide monomers and dimers are discussed, with particular attention given to results of calculations of the polarizability of LiF taking into account electron correlation effects, and the polarizability of the dimer (LiF)2.

Jordan, K. D.↗
NASA NTRS1982

Sulfur chemistry in dense interstellar clouds

A model is presented for the gas phase chemistry of molecules containing sulfur in dense interstellar clouds. The sulfur chemistry is different from that used in previous models as a result of an extensive search of the recent literature and the availability of new laboratory data. The changes have a significant effect on the calculated abundance of sulfur compounds. The linked chemistry of sulfur and oxygen in the present model requires a severe depletion of sulfur and low fractional abundances of both O and O2 in the dense clouds. In contrast, the high abundance of SO and the low abundance of CS relative to SO in the HVS in the KL may indicate an oxygen-rich, high temperature environment compared to OMC-1. The formation of S-H bonds is slow because of the absence of radiative association between S(+) and H2. The present model underestimates the abundance of H2S unless a radiative association reaction between HS(+) and H2 is postulated.

Prasad, S. S.↗
NASA NTRS1982

Airborne aerosol measurements in the quiescent plume of Mount Saint Helens September, 1980

A study of the emissions from the Mt. St. Helens volcano was conducted to obtain data for an assessment of the importance of volcanoes as a global source of volatile trace elements to the atmosphere and to the global biochemical cycles of these elements. Sampling was done on board an Orion P-3 turboprop aircraft modified for tropospheric aerosol and gas sampling. Two filter collection systems were used. Samples were collected on a single flight on September 22, 1980, at which time the volcano was emitting a stable plume to an altitude of between 2 and 3 km. The results regarding the concentrations of aerosols obtained for this mission are presented in a table. Attention is also given to data concerning particulate vs. gas phase sulfur in the Mt. Saint Helens plume, and the estimated volcanic particle flux of selected volatile elements.

Phelan, J. M.↗
NASA NTRS1982

Analytical modeling of operating characteristics of premixing-prevaporizing fuel-air mixing passages. Volume 1: Analysis and results

A model for predicting the distribution of liquid fuel droplets and fuel vapor in premixing-prevaporizing fuel-air mixing passages of the direct injection type is reported. This model consists of three computer programs; a calculation of the two dimensional or axisymmetric air flow field neglecting the effects of fuel; a calculation of the three dimensional fuel droplet trajectories and evaporation rates in a known, moving air flow; a calculation of fuel vapor diffusing into a moving three dimensional air flow with source terms dependent on the droplet evaporation rates. The fuel droplets are treated as individual particle classes each satisfying Newton's law, a heat transfer, and a mass transfer equation. This fuel droplet model treats multicomponent fuels and incorporates the physics required for the treatment of elastic droplet collisions, droplet shattering, droplet coalescence and droplet wall interactions. The vapor diffusion calculation treats three dimensional, gas phase, turbulent diffusion processes. The analysis includes a model for the autoignition of the fuel air mixture based upon the rate of formation of an important intermediate chemical species during the preignition period.

Anderson, O. L.↗
NASA NTRS1983

CARS temperature measurements in the fuel preburner of the Space Shuttle main engine: A feasibility study

This report discusses the feasibility of making temperature profile measurements in the fuel preburner of the main engine of the space shuttle (SSME) using coherent anti-Stokes Raman spectroscopy (CARS). The principal thrust of the work is to identify problems associated with making CARS measurements in high temperature gas phase hydrogen at very high pressures (approx 400 atmospheres). To this end a theoretical study was made of the characteristics of the CAR spectra of H2 as a function of temperature and pressure and the accuracy with which temperatures can be extracted from this spectra. In addition the experimental problems associated with carrying out these measurements on a SSME at NSTL were identified. A conceptual design of a CARS system suitable for this work is included. Many of the results of the calculations made in this report are plotted as a function of temperature. In the course of presenting these results, it was necessary to decide whether the number of density or the pressure should be treated as a fixed parameter.

Beiting, E. J.↗