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NASA NTRS2012

A Hypothesis on Biological Protection from Space Radiation Through the Use of New Therapeutic Gases as Medical Counter Measures

Radiation exposure to astronauts could be a significant obstacle for long duration manned space exploration because of current uncertainties regarding the extent of biological effects. Furthermore, concepts for protective shielding also pose a technically challenging issue due to the nature of cosmic radiation and current mass and power constraints with modern exploration technology. The concern regarding exposure to cosmic radiation is the biological damage it induces. As damage is associated with increased oxidative stress, it is important and would be enabling to mitigate and/or prevent oxidative stress prior to the development of clinical symptoms and disease. This paper hypothesizes a "systems biology" approach in which a combination of chemical and biological mitigation techniques are used conjunctively. It proposes using new, therapeutic, medical gases as both chemical radioprotectors for radical scavenging and biological signaling molecules for management of the body s response to exposure. From reviewing radiochemistry of water, biological effects of CO, H2, NO, and H2S gas, and mechanisms of radiation biology, it is concluded that this approach may have great therapeutic potential for radiation exposure. Furthermore, it also appears to have similar potential for curtailing the pathogenesis of other diseases in which oxidative stress has been implicated including cardiovascular disease, cancer, chronic inflammatory disease, hypertension, ischemia/reperfusion injury, acute respiratory distress syndrome, Parkinson s and Alzheimer s disease, cataracts, and aging.

Schoenfeld, Michael P.↗

NASA NTRS2011

A Hypothesis on Biological Protection from Space Radiation Through the Use of New Therapeutic Gases

Schoenfeld, Michael P.↗

NASA NTRS2011

A Hypothesis on Biological Protection from Space Radiation Through the Use of New Therapeutic Gases as Medical Counter Measures

Exposure to astronauts could be a significant obstacle for long duration manned space exploration because of current uncertainties regarding the extent of biological effects. Furthermore, concepts for protective shielding also pose a technically challenging issue due to the nature of cosmic radiation and current mass and power constraints with modern exploration technology. As biological damage from exposure is associated with increased oxidative stress, it would be enabling to mitigate and/or prevent stress prior to the development of clinical symptoms and disease. This paper hypothesizes a "systems biology" approach in which a combination of chemical and biological mitigation techniques are used conjunctively. It proposes using new, therapeutic, medical gases as both chemical radioprotectors for radical scavenging and biological promoters for management of the body s response to exposure. From reviewing radiochemistry of water, biological effects of CO, H2, NO, and H2S gas, and mechanisms of radiation biology, it is concluded that this approach may have great therapeutic potential for exposure. Furthermore, it also appears to have potential for curtailing the pathogenesis of other diseases in which oxidative stress has been implicated including cardiovascular disease, cancer, chronic inflammatory disease, hypertension, ischemia/reperfusion injury, acute respiratory distress syndrome, Parkinson s and Alzheimer s disease, cataracts, and aging.

Schoenfeld, Michael P.↗

NASA NTRS2005

Analysis of Effluent Gases During the CCVD Growth of Multi Wall Carbon Nanotubes from Acetylene

Catalytic chemical vapor deposition was used to grow multi-walled carbon nanotubes on a Fe:Co:CaCO3 catalyst from acetylene. The influent and effluent gases were analyzed by gas chromatography and mass spectrometry at different time intervals during the nanotubes growth process in order to better understand and optimize the overall reaction. A large number of byproducts were identified and it was found that the number and the level for some of the carbon byproducts significantly increased over time. The CaCO3 catalytic support thermally decomposed into CaO and CO2 resulting in a mixture of two catalysts for growing the nanotubes, which were found to have outer diameters belonging to two main groups 8 to 35 nm and 40 to 60 nm, respectively.

Schmitt, T. C.↗

NASA NTRS2012

A Group Increment Scheme for Infrared Absorption Intensities of Greenhouse Gases

A molecule's absorption in the atmospheric infrared (IR) window (IRW) is an indicator of its efficiency as a greenhouse gas. A model for estimating the absorption of a fluorinated molecule within the IRW was developed to assess its radiative impact. This model will be useful in comparing different hydrofluorocarbons and hydrofluoroethers contribution to global warming. The absorption of radiation by greenhouse gases, in particular hydrofluoroethers and hydrofluorocarbons, was investigated using ab initio quantum mechanical methods. Least squares regression techniques were used to create a model based on this data. The placement and number of fluorines in the molecule were found to affect the absorption in the IR window and were incorporated into the model. Several group increment models are discussed. An additive model based on one-carbon groups is found to work satisfactorily in predicting the ab initio calculated vibrational intensities.

Kokkila, Sara I.↗

NASA NTRS2014

Noble Gases in the Chelyabinsk Meteorites

The Chelyabinsk meteorite fell in Russia on February 15, 2013 and was classified as LL5 chondrite. The diameter before it entered the atmosphere has been estimated to be about 20 m [1]. Up to now, numerous fragments weighing much greater than 100 kg in total have been collected. In this study, all noble gases were measured for 13 fragments to investigate the exposure history of the Chelyabinsk meteorite and the thermal history of its parent asteroid.

Haba, Makiko K.↗

NASA NTRS2013

The Role of Long-Lived Greenhouse Gases as Principal LW Control Knob that Governs the Global Surface Temperature for Past and Future Climate Change

The climate system of the Earth is endowed with a moderately strong greenhouse effect that is characterized by non-condensing greenhouse gases (GHGs) that provide the core radiative forcing. Of these, the most important is atmospheric CO2. There is a strong feedback contribution to the greenhouse effect by water vapor and clouds that is unique in the solar system, exceeding the core radiative forcing due to the non-condensing GHGs by a factor of three. The significance of the non-condensing GHGs is that once they have been injected into the atmosphere, they remain there virtually indefinitely because they do not condense and precipitate from the atmosphere, their chemical removal time ranging from decades to millennia. Water vapor and clouds have only a short lifespan, with their distribution determined by the locally prevailing meteorological conditions, subject to Clausius-Clapeyron constraint. Although solar irradiance is the ultimate energy source that powers the terrestrial greenhouse effect, there has been no discernible long-term trend in solar irradiance since precise monitoring began in the late 1970s. This leaves atmospheric CO2 as the effective control knob driving the current global warming trend. Over geological time scales, volcanoes are the principal source of atmospheric CO2, and the weathering of rocks is the principal sink, with the biosphere participating as both a source and a sink. The problem at hand is that human industrial activity is causing atmospheric CO2, to increase by 2 ppm per year, whereas the interglacial rate has been 0.005 ppm per year. This is a geologically unprecedented rate to turn the CO2 climate control knob. This is causing the global warming that threatens the global environment.

Greenhouse effect↗

NASA NTRS2015

Quantifying Sources and Sinks of Reactive Gases in the Lower Atmosphere Using Airborne Flux Observations

Atmospheric composition is governed by the interplay of emissions, chemistry, deposition, and transport. Substantial questions surround each of these processes, especially in forested environments with strong biogenic emissions. Utilizing aircraft observations acquired over a forest in the southeast U.S., we calculate eddy covariance fluxes for a suite of reactive gases and apply the synergistic information derived from this analysis to quantify emission and deposition fluxes, oxidant concentrations, aerosol uptake coefficients, and other key parameters. Evaluation of results against state-of-the-science models and parameterizations provides insight into our current understanding of this system and frames future observational priorities. As a near-direct measurement of fundamental process rates, airborne fluxes offer a new tool to improve biogenic and anthropogenic emissions inventories, photochemical mechanisms, and deposition parameterizations.

emission↗

NASA NTRS2015

Spatial Variability of Trace Gases During DISCOVER-AQ: Planning for Geostationary Observations of Atmospheric Composition

Results from an in-depth analysis of trace gas variability in MD indicated that the variability in this region was large enough to be observable by a TEMPO-like instrument. The variability observed in MD is relatively similar to the other three campaigns with a few exceptions: CO variability in CA was much higher than in the other regions; HCHO variability in CA and CO was much lower; MD showed the lowest variability in NO2All model simulations do a reasonable job simulating O3 variability. For CO, the CACO simulations largely under over estimate the variability in the observations. The variability in HCHO is underestimated for every campaign. NO2 variability is slightly overestimated in MD, more so in CO. The TX simulation underestimates the variability in each trace gas. This is most likely due to missing emissions sources (C. Loughner, manuscript in preparation).Future Work: Where reasonable, we will use these model outputs to further explore the resolvability from space of these key trace gases using analyses of tropospheric column amounts relative to satellite precision requirements, similar to Follette-Cook et al. (2015).

trace gas↗

NASA NTRS2015

Interannual Variability of Tropospheric Trace Gases and Aerosols: The Role of Biomass Burning Emissions

Fires are responsible for a range of gaseous and aerosol emissions. However, their influence on the interannual variability of atmospheric trace gases and aerosols has not been systematically investigated from a global perspective. We examine biomass burning emissions as a driver of interannual variability of large-scale abundances of short-lived constituents such as carbon monoxide (CO), hydroxyl radicals (OH), ozone and aerosols using the GISS ModelE composition-climate model and a range of observations, with an emphasis on satellite information. Our model captures the observed variability of the constituents examined in most cases, but with substantial underestimates in boreal regions. The strongest interannual variability on a global scale is found for carbon monoxide (10 for its global annual burden), while the lowest is found for tropospheric ozone (10 for its global annual burden). Regionally, aerosol optical depth shows variability that exceeds 50. Areas of strong variability include the tropical land regions and northern high latitudes, while even regions in the northern midlatitudes experience substantial inteannual variability of aerosols. Ozone variability peaks over Equatorial Asia in boreal autumn, partly due to varying biomass burning emissions, and over the western and central Pacific in the rest of the year, mainly due to meteorological fluctuations. We find that biomass burning emissions are almost entirely responsible for global CO interannual variability, and similarly important for OH variability. The same is true for global and regional aerosol variability, especially when not taking into account dust and sea-salt particles. We show that important implications48 can arise from such interannual influences for regional climate and air quality.

aerosols↗

NASA NTRS2015

Airborne Measurements and Emission Estimates of Greenhouse Gases and Other Trace Constituents From the 2013 California Yosemite Rim Wildfire

This paper presents airborne measurements of multiple atmospheric trace constituents including greenhouse gases (such as CO2, CH4, O3) and biomass burning tracers (such as CO, CH3CN) downwind of an exceptionally large wildfire. In summer 2013, the Rim wildfire, ignited just west of the Yosemite National Park, California, and burned over 250,000 acres of the forest during the 2-month period (17 August to 24 October) before it was extinguished. The Rim wildfire plume was intercepted by flights carried out by the NASA Ames Alpha Jet Atmospheric eXperiment (AJAX) on 29 August and the NASA DC-8, as part of SEAC4RS (Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys), on 26 and 27 August during its intense, primary burning period. AJAX revisited the wildfire on 10 September when the conditions were increasingly smoldering, with slower growth. The more extensive payload of the DC-8 helped to bridge key measurements that were not available as part of AJAX (e. g. CO). Data analyses are presented in terms of emission ratios (ER), emission factors (EF) and combustion efficiency and are compared with previous wildfire studies. ERs were 8.0 ppb CH4/(ppm CO2) on 26 August, 6.5 ppb CH4 (ppm CO2)1 on 29 August and 18.3 ppb CH4 (ppm CO2)1 on 10 September 2013. The increase in CH4 ER from 6.5 to 8.0 ppb CH4/(ppm CO2) during the primary burning period to 18.3 ppb CH4/(ppm CO2) during the fire's slower growth period likely indicates enhanced CH4 emissions from increased smoldering combustion relative to flaming combustion. Given the magnitude of the Rim wildfire, the impacts it had on regional air quality and the limited sampling of wildfire emissions in the western United States to date, this study provides a valuable dataset to support forestry and regional air quality management, including observations of ERs of a wide number of species from the Rim wildfire.

Yates, E. L.↗

NASA NTRS2016

Agricultural Fires in the Southeastern U.S. During SEAC4RS: Emissions of Trace Gases and Particles and Evolution of Ozone, Reactive Nitrogen, and Organic Aerosol

Emissions from 15 agricultural fires in the southeastern U.S. were measured from the NASA DC-8 research aircraft during the summer 2013 Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) campaign. This study reports a detailed set of emission factors (EFs) for 25 trace gases and 6 fine particle species. The chemical evolution of the primary emissions in seven plumes was examined in detail for ~1.2 h. A Lagrangian plume cross-section model was used to simulate the evolution of ozone (O3), reactive nitrogen species, and organic aerosol (OA). Observed EFs are generally consistent with previous measurements of crop residue burning, but the fires studied here emitted high amounts of SO2 and fine particles, especially primary OA and chloride. Filter-based measurements of aerosol light absorption implied that brown carbon (BrC) was ubiquitous in the plumes. In aged plumes, rapid production of O3, peroxyacetyl nitrate (PAN), and nitrate was observed with (Delta)O3/(Delta)CO, (Delta)PAN/(Delta)NOy, and (Delta)nitrate/(Delta)NOy reaching approx. 0.1, approx. 0.3, and approx.0.3. For five selected cases, the model reasonably simulated O3 formation but underestimated PAN formation. No significant evolution of OA mass or BrC absorption was observed. However, a consistent increase in oxygen-to-carbon (O/C) ratios of OA indicated that OA oxidation in the agricultural fire plumes was much faster than in urban and forest fire plumes. Finally, total annual SO2, NOx, and CO emissions from agricultural fires in Arkansas, Louisiana, Mississippi, and Missouri were estimated (within a factor of approx. 2) to be equivalent to approx. 2% SO2 from coal combustion and approx. 1% NOx and approx. 9% CO from mobile sources.

OA mass or BrC absorption↗

NASA NTRS2018

Ozone Sensitivity to Varying Greenhouse Gases and Ozone-Depleting Substances in CCMI-1 Simulations

Ozone fields simulated for the first phase of the Chemistry-Climate Model Initiative (CCMI-1) will be used as forcing data in the 6th Coupled Model Intercomparison Project. Here we assess, using reference and sensitivity simulations produced for CCMI-1, the suitability of CCMI-1 model results for this process, investigating the degree of consistency amongst models regarding their responses to variations in individual forcings. We consider the influences of methane, nitrous oxide, a combination of chlorinated or brominated ozone-depleting substances, and a combination of carbon dioxide and other greenhouse gases. We find varying degrees of consistency in the models' responses in ozone to these individual forcings, including some considerable disagreement. In particular, the response of total-column ozone to these forcings is less consistent across the multi-model ensemble than profile comparisons. We analyse how stratospheric age of air, a commonly used diagnostic of stratospheric transport, responds to the forcings. For this diagnostic we find some salient differences in model behaviour, which may explain some of the findings for ozone. The findings imply that the ozone fields derived from CCMI-1 are subject to considerable uncertainties regarding the impacts of these anthropogenic forcings. We offer some thoughts on how to best approach the problem of generating a consensus ozone database from a multi-model ensemble such as CCMI-1.

CCMI↗

NASA NTRS2018

Profiles of Reactive Trace Gases over Remote Oceans During ATom

The Atmospheric Tomography (ATom) mission deployed an extensive gas and aerosol payload on the NASA DC-8 aircraft on four campaigns spanning each season. ATom systematically sampled the atmosphere from 0.2 to 12 kilometer altitude, from 85 degrees North Latitude to 65 degrees South Latitude, in both the Pacific and the Atlantic to provide detailed profiles of chemical composition over the remote oceans. We will present profiles of reactive trace species, such as O3, NOx, NOy, HOx, HCHO, and several other short-lived source gases. We will combine these measurements with results from a 0-D box model to show their utility in (1) evaluating gradients in latitude/season, (2) identifying contributions of pollution from long-range and convective transport, and (3) evaluating column measurements from remote sensing satellite instruments.

ISAF↗

NASA NTRS2019

The Ability of GeoCarb to Constrain the Interannual Variability of Carbon Gases over the Amazon

We perform a number of idealized assimilation experiments with the GEOS constituent data assimilation system to test the ability of GeoCarb retrievals of CO, CO2, and CH4 to constrain the interannual variability of these gases over the Amazon. Retrievals for instruments on other satellites which observe in similar channels (e.g. MOPITT, GOSAT, and OCO-2) are limited due to persistent cloud coverage. Given its ability to sample the same location multiple times in one day, the expectation is that GeoCarb retrievals will return more soundings than those from previous missions. The goal of the assimilation experiments is to understand which scanning strategies lead to the best sounding densities and thus have the best chance of constraining interannual variability in the carbon species. The experiments each begin by picking a given year at random from a nature run (i.e., a model simulation meant to represent the truth). The model fields are sampled according to a given strategy and then screened to account for cloud coverage. Next, we pick another year at random and assimilate the synthetic GeoCarb samples into the GEOS model for that year. The output of the assimilation, 6-hourly, 3D fields of each constituent, is then directly comparable to the nature run. This comparison allows us to evaluate the ability of GeoCarb measurements to constrain the interannual variability of each gas.

Weir, B.↗

NASA NTRS2019

Five Decades Observing Earth's Atmospheric Trace Gases Using Ultraviolet and Visible Backscatter Solar Radiation from Space

Over the last five decades, Earth’s atmosphere has been extensively monitored from space using different spectral ranges. Early efforts were directed at improving weather forecasts with the first meteorological satellites launched in the 1960s. Soon thereafter, the intersection between weather, climate and atmospheric chemistry led to the observation of atmospheric composition from space. During the 1970s the Nimbus satellite program started regular monitoring of ozone integrated columns and water vapor profiles using the Backscatter Ultraviolet Spectrometer, the Infrared Interferometer Spectrometer and the Satellite Infrared Spectrometer instruments. Five decades after these pioneer efforts, continuous progress in instrument design, and retrieval techniques allow researchers to monitor tropospheric concentrations of a wide range of species with implications for air quality, climate and weather. The time line of historic, present and future space-borne instruments measuring ultraviolet and visible backscattered solar radiation designed to quantify atmospheric trace gases is presented. We describe the instruments technological evolution and the basic concepts of retrieval theory. We include a review of algorithms developed for ozone, nitrogen dioxide, sulfur dioxide, formaldehyde, bromine monoxide, water vapor and glyoxal, a selection of studies using these algorithms, the challenges they face and how these challenges can be addressed. The paper ends by providing insights on the opportunities that new instruments will bring to the atmospheric chemistry, weather and air quality communities and how to address the pressing need for long-term, inter-calibrated data records necessary to monitor the response of the atmosphere to rapidly changing ecosystems.

Infrared Interferometer Spectrometer↗

NASA NTRSDate not supplied

THE DAVINCI+ MISSION TO REVEAL THE MYSTERIES OF VENUS: DEEP ATMOSPHERE VENUS INVESTIGATION OF NOBLE GASES, CHEMISTRY, AND IMAGING PLUS

The Deep Atmosphere Venus Investigation of Noble Gases, Chemistry, and Imaging Plus (DAVINCI+) mission is one of four finalists now in Phase A study as part of the ongoing Discovery Program competition [1-5]. If selected for flight, DAVINCI+ will be the first mission to Venus to incorporate flybys, a descent probe, and an orbital phase into one unified architecture – at the cost of a Discovery mission. The result will be a transformative new understanding of the atmosphere, surface, and evolutionary path of Venus as a once-habitable planet [6] (and model exoplanet) that is now host to a certainly unhabitable surface environment.

S Getty↗

NASA NTRS2022

An Overview of Atmospheric Features Over the Western North Atlantic Ocean and North American East Coast – Part 1: Analysis of Aerosols, Gases, and Wet Deposition Chemistry

The Western North Atlantic Ocean (WNAO) and adjoining East Coast of North America are of great importance for atmospheric research and have been extensively studied for several decades. This broad region exhibits complex meteorological features and a wide range of conditions associated with gas and particulate species from many sources regionally and other continents. As Part 1 of a 2‐part paper series, this work characterizes quantities associated with atmospheric chemistry, including gases, aerosols, and wet deposition, by analyzing available satellite observations, ground‐based data, model simulations, and reanalysis products. Part 2 provides insight into the atmospheric circulation, boundary layer variability, three‐dimensional cloud structure, properties, and precipitation over the WNAO domain. Key results include spatial and seasonal differences in composition along the North American East Coast and over the WNAO associated with varying sources of smoke and dust and meteorological drivers such as temperature, moisture, and precipitation. Spatial and seasonal variations of tropospheric carbon monoxide and ozone highlight different pathways towards the accumulation of these species in the troposphere. Spatial distributions of speciated aerosol optical depth and vertical profiles of aerosol mass mixing ratios show a clear seasonal cycle highlighting the influence of different sources in addition to the impact of intercontinental transport. Analysis of long‐term climate model simulations of aerosol species and satellite observations of carbon monoxide confirm that there has been a significant decline in recent decades among anthropogenic constituents owing to regulatory activities.

ACTIVATE↗