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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

X-ray-imaging spectrometer (XRIS) for studies of residual kinetic energy and low-mode asymmetries in inertial confinement fusion implosions at OMEGA (invited)

A system of x-ray imaging spectrometer (XRIS) has been implemented at the OMEGA Laser Facility and is capable of spatially and spectrally resolving x-ray self-emission from 5 to 40 keV. The system consists of three independent imagers with nearly orthogonal lines of sight for 3D reconstructions of the x-ray emission region. The distinct advantage of the XRIS system is its large dynamic range, which is enabled by the use of tantalum apertures with radii ranging from 50 μm to 1 mm, magnifications of 4 to 35×, and image plates with any filtration level. In addition, XRIS is capable of recording 1–100’s images along a single line of sight, facilitating advanced statistical inference on the detailed structure of the x-ray emitting regions. Properties such as P0 and P2 of an implosion are measured to 1% and 10% precision, respectively. Furthermore, T e can be determined with 5% accuracy.

Adrian, P. J.↗
DOE OSTI2024

Ideal conductor/dielectric model (ICDM): A generalized technique to correct for finite-size effects in molecular simulations of hindered ion transport

Molecular simulations serve as indispensable tools for investigating the kinetics and elucidating the mechanism of hindered ion transport across nanoporous membranes. In particular, recent advancements in advanced sampling techniques have made it possible to access translocation timescales spanning several orders of magnitude. In our prior study [Shoemaker et al., J. Chem. Theory Comput. 18, 7142 (2022)], we identified significant finite size artifacts in simulations of pressure-driven hindered ion transport through nanoporous graphitic membranes. We introduced the ideal conductor model, which effectively corrects for such artifacts by assuming the feed to be an ideal conductor. In the present work, we introduce the ideal conductor dielectric model (Icdm), a generalization of our earlier model, which accounts for the dielectric properties of both the membrane and the filtrate. Using the Icdm model substantially enhances the agreement among corrected free energy profiles obtained from systems of varying sizes, with notable improvements observed in regions proximate to the pore exit. Moreover, the model has the capability to consider secondary ion passage events, including the transport of a co-ion subsequent to the traversal of a counter-ion, a feature that is absent in our original model. We also investigate the sensitivity of the new model to various implementation details. The Icdm model offers a universally applicable framework for addressing finite size artifacts in molecular simulations of ion transport. It stands as a significant advancement in our quest to use molecular simulations to comprehensively understand and manipulate ion transport processes through nanoporous membranes.

Chemistry↗
DOE OSTI2013

Freestanding film structures for laser plasma experiments

The technique is developed for fabricating 5-500-nm-thick freestanding films of various materials and multilayer compositions. Apart from the traditional use in spectral filtration of soft X-ray and extreme ultraviolet radiation, the possibility of using the ultrathin films fabricated by this technique as targets in experiments on laser acceleration of ions is considered. A sample of the target in the form of a 5-nm-thick carbon film on a supporting net is fabricated. (extreme light fields and their applications)

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

Semiconductor laser with a birefringent external cavity for information systems with wavelength division multiplexing

The spectrum of a semiconductor laser with a birefringent external Gires – Tournois cavity is studied. The generation of two main laser modes corresponding to the ordinary and extraordinary wave resonances is found. It is shown that the radiation spectrum is controlled with a high energy efficiency without losses for spectral filtration. The possibility of using two-mode lasing in optical communication systems with wavelength division multiplexing is shown. (control of laser radiation parameters)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Assessing residential PM 2.5 concentrations and infiltration factors with high spatiotemporal resolution using crowdsourced sensors

Building conditions, outdoor climate, and human behavior influence residential concentrations of fine particulate matter (PM 2.5 ). To study PM 2.5 spatiotemporal variability in residences, we acquired paired indoor and outdoor PM 2.5 measurements at 3,977 residences across the United States totaling >10,000 monitor-years of time-resolved data (10-min resolution) from the PurpleAir network. Time-series analysis and statistical modeling apportioned residential PM 2.5 concentrations to outdoor sources (median residential contribution = 52% of total, coefficient of variation = 69%), episodic indoor emission events such as cooking (28%, CV = 210%) and persistent indoor sources (20%, CV = 112%). Residences in the temperate marine climate zone experienced higher infiltration factors, consistent with expectations for more time with open windows in milder climates. Likewise, for all climate zones, infiltration factors were highest in summer and lowest in winter, decreasing by approximately half in most climate zones. Large outdoor–indoor temperature differences were associated with lower infiltration factors, suggesting particle losses from active filtration occurred during heating and cooling. Absolute contributions from both outdoor and indoor sources increased during wildfire events. Infiltration factors decreased during periods of high outdoor PM 2.5 , such as during wildfires, reducing potential exposures from outdoor-origin particles but increasing potential exposures to indoor-origin particles. Time-of-day analysis reveals that episodic emission events are most frequent during mealtimes as well as on holidays (Thanksgiving and Christmas), indicating that cooking-related activities are a strong episodic emission source of indoor PM 2.5 in monitored residences.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Interfacial electroneutrality controls transport of asymmetric salts through charge-patterned mosaic membranes

Membranes that selectively enhance target solute permeation while rejecting competing species are essential for precision separations. This study introduces charge-patterned mosaic membranes (CMMs) that selectively transport divalent asymmetric salts by leveraging a net-neutral membrane–solution interface. This mechanism, dictated by the charge ratio of positive and negative domains on the membrane surface and the balance of cations and anions in the salt, is supported by analytical, numerical, and experimental results. Analytical solutions identified cationic domain coverages (f + ) of 33%, 50%, and 66% as optimal for the selective transport of +2:−1 salts, +1:−1 salts, and +1:−2 salts, respectively, under conditions where the pattern size (L) is significantly larger than the Debye length. Numerical simulations and experiments using CMMs with alternating charged-stripes inkjet-printed onto nanostructure copolymer substrates confirmed these findings. By varying stripe widths to control f + , pressure-driven filtration experiments demonstrated selective enrichment of MgCl 2 and K 2 SO 4 at the predicted f + values, with deviations from these values leading to salt rejection. These results highlight the pivotal role of a net-neutral interface in enabling asymmetric salt enrichment. This study positions CMMs as a versatile platform for tuning ion selectivity, addressing challenges in resource recovery, water treatment, and precision separations.

additive manufacturing↗
DOE OSTI2019

Retractile lysyl-tRNA synthetase-AIMP2 assembly in the human multi-aminoacyl-tRNA synthetase complex

Multi-aminoacyl-tRNA synthetase complex (MSC) is the second largest machinery for protein synthesis in human cells and also regulates multiple nontranslational functions through its components. Prior studies have shown that the MSC can respond to external signals by releasing its components to function outside it. The internal assembly is fundamental to MSC regulation. Here, using crystal structural analyses (at 1.88 Å resolution) along with molecular modeling, gel-filtration chromatography, and co-immunoprecipitation, we report that human lysyl-tRNA synthetase (LysRS) forms a tighter assembly with the scaffold protein aminoacyl-tRNA synthetase complex-interacting multifunctional protein 2 (AIMP2) than previously observed. Wefound that two AIMP2 N-terminal peptides form an antiparallel scaffold and hold two LysRS dimers through four binding motifs and additional interactions. Of note, the four catalytic subunits of LysRS in the tightly assembled complex were all accessible for tRNA recognition. We further noted that two recently reported human disease-associated mutations conflict with this tighter assembly, cause LysRS release from the MSC, and inactivate the enzyme. These findings reveal a previously unknown dimension of MSC subcomplex assembly and suggest that the retractility of this complex may be critical for its physiological functions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Structural and biochemical characterization of 20β-hydroxysteroid dehydrogenase from Bifidobacterium adolescentis strain L2-32

Anaerobic bacteria inhabiting the human gastrointestinal tract have evolved various enzymes that modify host-derived steroids. The bacterial steroid-17,20-desmolase pathway cleaves the cortisol side chain, forming pro-androgens predicted to impact host physiology. Bacterial 20β-hydroxysteroid dehydrogenase (20β-HSDH) regulates cortisol side-chain cleavage by reducing the C-20 carboxyl group on cortisol, yielding 20β-dihydrocortisol. Recently, the gene encoding 20β-HSDH in Butyricicoccus desmolans ATCC 43058 was reported, and a nonredundant protein search yielded a candidate 20 β- HSDH gene in Bifidobacterium adolescentis strain L2-32. B. adolescentis 20β-HSDH could regulate cortisol side-chain cleavage by limiting pro-androgen formation in bacteria such as Clostridium scindens and 21-dehydroxylation by Eggerthella lenta . In this work, the putative B. adolescentis 20β-HSDH was cloned, overexpressed, and purified. 20β-HSDH activity was confirmed through whole-cell and pure enzymatic assays, and it is specific for cortisol. Next, we solved the structures of recombinant 20β-HSDH in both the apo- and holo-forms at 2.0–2.2 Å resolutions, revealing close overlap except for rearrangements near the active site. Interestingly, the structures contain a large, flexible N-terminal region that was investigated by gel-filtration chromatography and CD spectroscopy. This extended N terminus is important for protein stability because deletions of varying lengths caused structural changes and reduced enzymatic activity. A nonconserved extended N terminus was also observed in several short-chain dehydrogenase/reductase family members. B. adolescentis strains capable of 20β-HSDH activity could alter glucocorticoid metabolism in the gut and thereby serve as potential probiotics for the management of androgen-dependent diseases.

20β-hydroxysteroid dehydrogenase↗
DOE OSTI2021

Characterisation of nano-assemblies inside mesopores using neutron scattering

Adsorption of molecular and nanoscale matter in mesoporous materials is important in filtration and chromatography as well as membrane processes. However, the morphology and distribution of self-assembled structures of adsorbate formed within nanoconfined environments is largely unknown. Small Angle Neutron Scattering (SANS) with porous matrix matching the neutron scattering length density of the solvent has the potential to provide detailed information on the self-assemblies formed in pore spaces. However, analysis of such SANS profiles remains a challenge. In this study, we extend the SANS analysis method previously developed by Findenegg and co-workers to include interparticle correlations, providing a qualitative characterisation of the adsorption state of surfactants and nanoparticles in the cylindrical pores of silica nanomaterials. We find that the pore filling fraction and the self-assembled state of the adsorbate governs the scattering profile. We apply the model to two materials namely, triethyleneglycol monohexyl ether (C 6 E 3 ) surfactant and gold nanoparticles adsorbed in SBA-15 mesoporous silica. In contrast to the C 6 E 3 system, Bragg scattering dominates the diffuse scattering in gold nanoparticle system, which we attribute to the immobile internal structure of the nanoparticles. In conclusion, this new SANS analysis method has potential to elucidate structures of soft matter nanoassemblies inside mesopores.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2019

Cesium Ion Exchange Testing Using Crystalline Silicotitanate with Hanford Tank Waste 241-AP-107

Pacific Northwest National Laboratory has been tasked with demonstrating the unit operations for the Low Activity Waste Pretreatment System with actual Hanford tank waste. Crystalline silicotitanate (CST) ion exchange media is planned to be used to remove cesium (137Cs) from the aqueous phases of the tank wastes. Washington River Protection Solutions requested that Hanford tank waste collected from tank 241-AP-107 be processed using conceived pretreatment steps (suspended solids removal by filtration, Cs removal by ion exchange), then vitrified. Removal of Cs from these wastes is an important processing step in preparing the waste for long-term safe storage. Bench-scale ion exchange testing with approximately 9 L of filtered AP-107 supernate was conducted using CST. Column testing was performed using prototypic LAWPS operations in a lead-lag column arrangement using 10-mL CST beds. Feed was processed until the lag column effluent reached the Hanford Tank Waste Treatment and Immobilization Plant waste acceptance criteria (WAC) for receiving supernatant waste for vitrification (a function of the Na and 137Cs concentrations), at which point, a new lag column was needed to continue processing and the original lag column was moved to the lead position. Greater than 99% of the Cs processed through the ion exchange system was collected on the CST in the columns. The AP-107 feed and column processing effluent underwent extensive characterization to better define waste characteristics and assess fractionation to the CST. Selected lead column samples were analyzed to assess particular metal analyte load characteristics. Results of these analyses will be discussed.

cesium exchange, Hanford tank waste, ion exchange↗
DOE OSTI2019

Characterization of a dimer preparation method for nanoscale organic aerosol

Nanoscale dimers have application in studies of aerosol physicochemical properties such as aerosol viscosity. These particle dimers can be synthesized using the dual tandem differential mobility analyzer (DTDMA) technique, wherein oppositely charged particle streams coagulate to form dimers that can be isolated using electrostatic filtration. Although some characterization of the technique has been published, a detailed thesis on the modes and theory of operation has remained outside the scope of prior work. In this paper we present new experimental data characterizing the output DTDMA size distribution and the physical processes underlying its apparent modes. Key experimental limitations for both general applications and for viscosity measurements are identified and quantified in six distinct types of DTDMA experiments. The primary consideration is the production of an adequate number of dimers, which typically requires high mobility-selected number concentration in the range 25,000-100,000 cm -3 . The requisite concentration threshold depends upon the rate of spontaneous monomer decharging, which arises predominately from interactions of the aerosol with ionizing radiation within the coagulation chamber and is instrument location dependent. Lead shielding of the coagulation chamber reduced the first-order decharging constant from ~2.0 x 10 -5 s -1 to ~0.8 x 10 -5 s -1 in our laboratory. Dimer production at monomer diameters less than 40 nm is hindered by low bipolar charging efficiency. Results from the characterization experiments shed light on design considerations for general applications and for characterization of viscous aerosol phase transitions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Nuclear Archaeology for Gaseous Diffusion Enrichment Plants

Gaseous diffusion was historically the most widely used technology for military production of highly enriched uranium. Since June 2013, all gaseous diffusion enrichment plants worldwide are permanently shut down. The experience with decommissioning some of these plants has shown that they contain large amounts of uranium particles deposited in the cascade equipment. This article evaluates the potential of using uranium particle deposition to understand and reconstruct the operating histories of gaseous diffusion enrichment plants. First, a squared-off cascade enrichment model is derived to estimate the enrichment capacity of a reference plant. Then, using a cross-flow filtration model, the mass of solid uranium particles deposited over time in the tubular separation membranes of the stage diffusers is calculated. Lastly, potential techniques to characterize these uranium deposits and help reconstruct the operating history of the plant are assessed.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2025

Impact of ceiling fan and room air cleaner on air mixing and fate of particulate matter in a multiroom residence

We are exposed to airborne particles of health concern in residences, and Room Air Cleaners (RACs) can remove these particles. However, they are often limited to treating local air in the room or near vicinity of the device. RAC performance in multi-room residences may be improved by ceiling fan whole-house air mixing with a minor increase in energy use. Here, this study analyzed air quality and energy efficiency from experimental measurements using combinations of ceiling fan and RAC operation. We measured removal rates of tracer gas and particles from ultrafine to 5 µm after their release in the kitchen area of a multiroom test house. Results show that the air mixing by ceiling fans increased ultrafine and > 1 µm particle removal over the baseline – with no ceiling fans and no RAC – suggesting increased deposition onto the ceiling fan blades and house surfaces. Also, ceiling fan mixing increased particle removal in all size bins over the RAC performance with no ceiling fans. The removal rate with ceiling fans and the RAC was greater than the sum of the rates from each operating alone, indicating that synergistic interactions between the ceiling fans and the RAC increased the RAC filtration rate.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗
DOE OSTI2012

THE MISSING CAVITIES IN THE SEEDS POLARIZED SCATTERED LIGHT IMAGES OF TRANSITIONAL PROTOPLANETARY DISKS: A GENERIC DISK MODEL

Transitional circumstellar disks around young stellar objects have a distinctive infrared deficit around 10 {mu}m in their spectral energy distributions, recently measured by the Spitzer Infrared Spectrograph (IRS), suggesting dust depletion in the inner regions. These disks have been confirmed to have giant central cavities by imaging of the submillimeter continuum emission using the Submillimeter Array (SMA). However, the polarized near-infrared scattered light images for most objects in a systematic IRS/SMA cross sample, obtained by HiCIAO on the Subaru telescope, show no evidence for the cavity, in clear contrast with SMA and Spitzer observations. Radiative transfer modeling indicates that many of these scattered light images are consistent with a smooth spatial distribution for {mu}m-sized grains, with little discontinuity in the surface density of the {mu}m-sized grains at the cavity edge. Here we present a generic disk model that can simultaneously account for the general features in IRS, SMA, and Subaru observations. Particularly, the scattered light images for this model are computed, which agree with the general trend seen in Subaru data. Decoupling between the spatial distributions of the {mu}m-sized dust and mm-sized dust inside the cavity is suggested by the model, which, if confirmed, necessitates a mechanism, such as dust filtration, for differentiating the small and big dust in the cavity clearing process. Our model also suggests an inwardly increasing gas-to-dust ratio in the inner disk, and different spatial distributions for the small dust inside and outside the cavity, echoing the predictions in grain coagulation and growth models.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

SPIRAL ARMS IN THE ASYMMETRICALLY ILLUMINATED DISK OF MWC 758 AND CONSTRAINTS ON GIANT PLANETS

We present the first near-IR scattered light detection of the transitional disk associated with the Herbig Ae star MWC 758 using data obtained as part of the Strategic Exploration of Exoplanets and Disks with Subaru, and 1.1 {mu}m Hubble Space Telescope/NICMOS data. While submillimeter studies suggested there is a dust-depleted cavity with r = 0.''35, we find scattered light as close as 0.''1 (20-28 AU) from the star, with no visible cavity at H, K', or K{sub s} . We find two small-scaled spiral structures that asymmetrically shadow the outer disk. We model one of the spirals using spiral density wave theory, and derive a disk aspect ratio of h {approx} 0.18, indicating a dynamically warm disk. If the spiral pattern is excited by a perturber, we estimate its mass to be 5{sup +3} {sub -4} M{sub J} , in the range where planet filtration models predict accretion continuing onto the star. Using a combination of non-redundant aperture masking data at L' and angular differential imaging with Locally Optimized Combination of Images at K' and K{sub s} , we exclude stellar or massive brown dwarf companions within 300 mas of the Herbig Ae star, and all but planetary mass companions exterior to 0.''5. We reach 5{sigma} contrasts limiting companions to planetary masses, 3-4 M{sub J} at 1.''0 and 2 M{sub J} at 1.''55, using the COND models. Collectively, these data strengthen the case for MWC 758 already being a young planetary system.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

SOLAR RADIATION PRESSURE AND LOCAL INTERSTELLAR MEDIUM FLOW PARAMETERS FROM INTERSTELLAR BOUNDARY EXPLORER LOW ENERGY HYDROGEN MEASUREMENTS

Neutral hydrogen atoms that travel into the heliosphere from the local interstellar medium (LISM) experience strong effects due to charge exchange and radiation pressure from resonant absorption and re-emission of Lyα. The radiation pressure roughly compensates for the solar gravity. As a result, interstellar hydrogen atoms move along trajectories that are quite different than those of heavier interstellar species such as helium and oxygen, which experience relatively weak radiation pressure. Charge exchange leads to the loss of primary neutrals from the LISM and the addition of new secondary neutrals from the heliosheath. IBEX observations show clear effects of radiation pressure in a large longitudinal shift in the peak of interstellar hydrogen compared with that of interstellar helium. Here, we compare results from the Lee et al. interstellar neutral model with IBEX-Lo hydrogen observations to describe the distribution of hydrogen near 1 AU and provide new estimates of the solar radiation pressure. We find over the period analyzed from 2009 to 2011 that radiation pressure divided by the gravitational force (μ) has increased slightly from μ = 0.94 ± 0.04 in 2009 to μ = 1.01 ± 0.05 in 2011. We have also derived the speed, temperature, source longitude, and latitude of the neutral H atoms and find that these parameters are roughly consistent with those of interstellar He, particularly when considering the filtration effects that act on H in the outer heliosheath. Thus, our analysis shows that over the period from 2009 to 2011, we observe signatures of neutral H consistent with the primary distribution of atoms from the LISM and a radiation pressure that increases in the early rise of solar activity.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

THE STRUCTURE OF PRE-TRANSITIONAL PROTOPLANETARY DISKS. II. AZIMUTHAL ASYMMETRIES, DIFFERENT RADIAL DISTRIBUTIONS OF LARGE AND SMALL DUST GRAINS IN PDS 70 {sup ,}

The formation scenario of a gapped disk, i.e., transitional disk, and its asymmetry is still under debate. Proposed scenarios such as disk-planet interaction, photoevaporation, grain growth, anticyclonic vortex, eccentricity, and their combinations would result in different radial distributions of the gas and the small (sub-μm size) and large (millimeter size) dust grains as well as asymmetric structures in a disk. Optical/near-infrared (NIR) imaging observations and (sub-)millimeter interferometry can trace small and large dust grains, respectively; therefore multi-wavelength observations could help elucidate the origin of complicated structures of a disk. Here we report Submillimeter Array observations of the dust continuum at 1.3 mm and {sup 12}CO J = 2 → 1 line emission of the pre-transitional protoplanetary disk around the solar-mass star PDS 70. PDS 70, a weak-lined T Tauri star, exhibits a gap in the scattered light from its disk with a radius of ∼65 AU at NIR wavelengths. However, we found a larger gap in the disk with a radius of ∼80 AU at 1.3 mm. Emission from all three disk components (the gas and the small and large dust grains) in images exhibits a deficit in brightness in the central region of the disk, in particular, the dust disk in small and large dust grains has asymmetric brightness. The contrast ratio of the flux density in the dust continuum between the peak position to the opposite side of the disk reaches 1.4. We suggest the asymmetries and different gap radii of the disk around PDS 70 are potentially formed by several (unseen) accreting planets inducing dust filtration.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

SYMMETRY OF THE IBEX RIBBON OF ENHANCED ENERGETIC NEUTRAL ATOM (ENA) FLUX

The circular ribbon of enhanced energetic neutral atom (ENA) emission observed by the Interstellar Boundary Explorer (IBEX) mission remains a critical signature for understanding the interaction between the heliosphere and the interstellar medium. We study the symmetry of the ribbon flux and find strong, spectrally dependent reflection symmetry throughout the energy range 0.7-4.3 keV. The distribution of ENA flux around the ribbon is predominantly unimodal at 0.7 and 1.1 keV, distinctly bimodal at 2.7 and 4.3 keV, and a mixture of both at 1.7 keV. The bimodal flux distribution consists of partially opposing bilateral flux lobes, located at highest and lowest heliographic latitude extents of the ribbon. The vector between the ribbon center and heliospheric nose (which defines the so-called BV plane) appears to play an organizing role in the spectral dependence of the symmetry axis locations as well as asymmetric contributions to the ribbon flux. The symmetry planes at 2.7 and 4.3 keV, derived by projecting the symmetry axes to a great circle in the sky, are equivalent to tilting the heliographic equatorial plane to the ribbon center, suggesting a global heliospheric ordering. The presence and energy dependence of symmetric unilateral and bilateral flux distributions suggest strong spectral filtration from processes encountered by an ion along its journey from the source plasma to its eventual detection at IBEX.

79 ASTRONOMY AND ASTROPHYSICS↗