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At least 919 records · Page 51

Boride Based Electrode Materials with Enhanced Stability Under Extreme Conditions for MHD Direct Power Extraction. Final Scientific Report

Coal power currently makes up almost 40% of global electricity production. This method of extracting energy from coal can be added to any coal plant, improving its energy output. Not only would this prepare us to keep up with the ever-increasing energy demands but it could also allow us to significantly cut the greenhouse gas emissions for the coal power industry. Hafnium diboride (HfB 2 ), Zirconium diboride (ZrB 2 ), and their solid solution mixtures were studied, primarily for electrode coating applications in coal-fired magnetohydrodynamic (MHD) direct power extraction plants. MHD works by directly extracting current from superheated plasma flame (2725 °C) seeded with potassium salts. Obviously, the electrodes near this flame are subject to extreme temperatures and corrosive environments. The coating material needs to protect the electrodes from salt corrosion, oxidation, and melting, while still providing electrical conductivity. Transition metal diborides have many of the desired properties but need improvement for oxidation resistance above 1200 °C. Two main methods of oxidation resistance improvements were investigated during this research. The first was through electrochemical anodization, a process where a thin protective oxide layer is grown on the surface to prevent further detrimental oxidation at high temperatures. Several solutions, voltages, and methods were used to find an oxide layer that would protect at high temperatures. The second method was to use various additives and mixture ratios to improve densification and oxidation resistance. Ratios of HfB 2 and ZrB 2 tested were 1:4, 1:1, 4:1 and 1:1 with additives of Ta, Hf, and Zr metals, bringing the boron to metal ratio down to 1.86. Additionally, 1.8 mol% Gd 2 O 3 and LaB 6 were added to the 1:1 ratio HfB 2 -ZrB 2 . Hydrogen evolution reaction kinetics were also investigated to shed some light on the ability of these materials to resist corrosion. Aqueous corrosion tests were also performed in several solutions of different pH. The 1:1 ratio solution added with LaB 6 gave the best overall results both in high temperature and room temperature aqueous experiments. Further work will be needed to evaluate the efficacy of these materials for such applications.

01 COAL, LIGNITE, AND PEAT↗

Detecting Outliers in Network Transfers with Feature Extraction

Reliable file transfers are essential for successful science computations and experiments that need large complex data files to be moved across long distances. Networks use protocols such as TCP and UDP to support file transfers, and their performance degrades under packet losses and duplications, thereby adversely affecting science applications. Hence, scientists and engineers often monitor network statistics to find and repair network problems that cause such degradations.Outliers or anomalies can be detected using statistical and machine learning methods that highlight abnormal behaviors. However, without knowing what is normal, it is very difficult and subjective to determine the anomalies. In this paper, we investigate statistical and machine learning approaches to extract unknown or unsupervised features from TCP and perfSONAR data sets, with the aim to identify anomalies such as packet loss, duplication and retransmission sequencing that affect file transfer performance. Simple statistical and feature extraction methods (e.g. PCA) have shown that detecting anomalies is simpler if labeled data sets of normal behavior are available. While perfSONAR logs record losses,they do not detect duplications and reordering. We show that PCA applied to TCP statistics is able to determine abnormal behavior in the above cases. In particular, our results show that simple feature extraction techniques provide building blocks for more advanced network monitoring tools that can quickly flag anomalies using simple measurements, thereby helping to build confidence in file transfer reliability.

Rao, Nageswara S.↗

Process for increasing liquid extraction from fabrics

The present invention relates to a process of increasing liquid extraction from fabrics having a first liquid content through the use of a mechanical extraction means and a liquid extraction agent.

Zhang, Shulin Larry↗

Recovery of rare earth elements by liquid-liquid extraction from fresh water to hypersaline solutions

The disclosure describes a method of extraction for optimal recovery of rare earth elements (REE). This includes the optimization of a liquid-liquid extraction technique for economic extraction of REE from chemically complex brines. Through the use of a model, operating conditions are altered to increase separation efficiency. The technique achieves >98% recovery of all rare earth elements in one fraction, while using small volumes of sample and reagents. The method of the present invention recovers REE from previously unexploited waste streams, without need for development of new process equipment and while keeping a small footprint because of the volumes involved.

Noack, Clinton W.↗

Numerical Simulation of Critical Factors Controlling Heat Extraction from Geothermal Systems Using a Closed-Loop Heat Exchange Method

Closed-loop heat exchange for geothermal energy production involves injecting working fluid down a well that extends through the geothermal resource over a significant length to absorb heat by conduction through the well pipe. The well then needs to return to the surface for energy recovery and fluid re-injection to complete the cycle. We have carried out mixed convective-conductive fluid-flow modeling using a wellbore flow model for TOUGH2 called T2Well to investigate the critical factors that control closed-loop geothermal energy recovery. T2Well solves a mixed explicit-implicit set of momentum equations for flow in the pipe with full coupling to the implicit three-dimensional integral finite difference equations for Darcy flow in the porous medium. T2Well has the option of modeling conductive heat flow from the porous medium to the pipe by means of a semi-analytical solution which makes the computation very efficient because the porous medium does not have to be discretized. When the fully three-dimensional option is chosen, the porous medium is discretized and heat flow to the pipe is by conduction and convection, depending on reservoir permeability and other factors. Simulations of the closed-loop system for a variety of parameter values have been carried out to elucidate the heat recovery process. To the extent that convection may occur to aid in heat delivery to the pipe, the permeability of the geothermal reservoir, whether natural or stimulated, is an important property in heat extraction. The injection temperature and flow rate of the working fluid strongly control the ultimate energy recovery. Pipe diameter also plays a strong role in heat extraction, but is correlated with flow rate. Similarly, the choice of working fluid plays an important role, with water showing better heat extraction than CO2 for certain flow rates, while the CO2 has higher pressure at the production wellhead which can aid in surface energy recovery. In general, we find complex interactions between the critical factors that will require advanced computational approaches to fully optimize.

Oldenburg, Curtis↗

System and method for extracting ethanol from a fermentation broth

The present invention is directed to a system and method for producing an organic compound using fermentation wherein multiple components of the system are recycled within the system. The system and method allow for extraction of a high concentration of the organic compound from the fermentation broth in a continuous system that allows recycling of the biomass, aqueous fermentation broth and extraction solvents. The system and method are particularly well adapted for producing and extracting ethanol.

09 BIOMASS FUELS↗

Distributions and Extraction of Rare Earth Elements from Coal and Coal By-Products

NETL is leading a research effort to investigate, characterize, and extract rare earth elements (REE) from coal and coal by-products, including coal ash. Characterization of geologic core samples, coal mine wastes, and coal ash has led to interesting findings on the mode of occurrence and fate of rare earth minerals, such as monazite, in coal-based materials. Mineral associations and elemental distributions have been investigated and results indicate that Th is associated with light rare earth elements (LREE), possibly as monazite, and Zr is associated with heavy rare earth elements (HREE), possibly as zircon. Preliminary extractions of REE from coal ash using 2M hydrochloric acid (HCl) and sodium hydroxide (NaOH) hydrothermal pretreatment have been investigated. Sodium hydroxide solution pretreatment followed by an acid digestion was shown to increase extraction of REE to nearly 90% for coal ash.

Roth, Elliot↗

Organic light-emitting diodes comprising grating structures and light extraction layers

Embodiments described herein generally relate to organic light-emitting diodes (OLEDs) comprising a substrate, a light extraction layer, a first electrode, one or more organic layers, and a second electrode. In some embodiments, the light extraction layer is positioned between the substrate and the first electrode. According to some embodiments, an interface between the light extraction layer and the first electrode comprises a grating structure. The grating structure may, in certain cases, promote outcoupling of light generated within the OLED (e.g., through diffraction).

So, Franky Fat Kei↗

Electromagnetic waveguide based thermal energy extraction with emissive materials and modifications

The method presented uses thermally emissive materials for the extraction of heat through the use of electromagnetic waveguides, wherein the emissive material comprises materials which emit electromagnetic radiation due to thermal excitation, wherein the electromagnetic radiation is coupled to electromagnetic waveguides; a receiver adapted to receive the electromagnetic radiation for utilization, wherein the extracted electromagnetic radiation may propagate arbitrary distances inside the waveguides before the need for processing, for example, to maximize the temperature differential between the emissive material and that of the receiver; and the exchange of the chemical composition of some portion of the environment the apparatus is housed in. The thermal energy extraction apparatus described herein has the purpose of removing heat from a source for conversion to other forms of energy such as electricity and for thermal management applications. Wherein for heat management, the benefit of waveguides would constitute reduced interference with electronics through electromagnetic coupling.

Poole, Zsolt↗

Extraction of Deep Inelastic Cross Sections Using a 10.4 GeV Electron Beam and a Polarized Helium-3 Target

Experiment E12-06-121 at Jefferson Lab aims to do a precision measurement of the neutron spin structure function g2 using inclusive inelastic scattering of electrons over a large kinematic range of x and Q2. The third moment of the linear combination of the spin structure functions g1 and g2, d2, is one of the cleanest higher twist observables and contains information on quark-gluon correlations. It is connected to the \color polarizability or \color Lorentz force" of the nucleon. The experimental data taking was successfully conducted in Hall C using a longitudinally polarized electron beam with 10.4 GeV energy, and a polarized 3He gas target. The combination of the Super High Momentum Spectrometer (SHMS) and the High Momentum Spectrometer (HMS) allowed us to run the experiment for three constant Q2 values (3.0, 4.3, and 5.6 GeV2/c2) over a wide range of x (0:20 < x < 0:95) for the ?first time. To extract the neutron spin structure functions, precision determination of the unpolarized cross-sections and double spin asymmetries are required. The analysis of the deep inelastic scattering data and the results from the ?first measurements of unpolarized 3He cross-sections are reported in this work. The extracted cross-sections will be combined with the electron asymmetry results (ongoing work) to obtain the g2 and d2 of 3He. Finally, nuclear correction to the 3He results will have to be applied to extract g2 and d2 for the neutrons.

Roy, Murchhana↗

Color Sensor Comparison for Solvent Extraction Processes

Idaho National Laboratory is building Beartooth, a test bed to advance research into nuclear fuel cycle reprocessing. This test bed will give researchers the opportunity to study solvent extraction processes. Beartooth extraction operations will include the use of centrifugal contactors designed for the recovery and purification of special nuclear material from spent fuel. This new test bed facility provides researchers with the opportunity to study innovative technologies. As part of that initiative, this project will integrate non-traditional (atypical to a solvent extraction process) measurement sensors into a system of contactors to determine the state-of-health. These non-traditional sensors have the potential to enhance nuclear safeguarding efforts and other process activities. The non-traditional sensors include accelerometers, acoustic microphones, colorimetric, pH, conductivity, viscosity, density, and infrared cameras. This report documents the testing and evaluation of two different colorimetric RGB sensors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Mathematical methods for neutrino cross-section extraction

Precise modeling of neutrino-nucleus scattering is becoming increasingly important as accelerator-based oscillation experiments seek definitive answers to open questions about neutrino properties. To guide the needed model refinements, a growing number of experimental collaborations are pursuing a wide-ranging program of neutrino interaction measurements at GeV energies. A key step in most such analyses is cross-section extraction, in which measured event counts are corrected for background contamination and imperfect detector performance to yield cross-section results that are directly comparable to theoretical predictions. In this paper, I review the major approaches to cross-section extraction in the literature using representative examples from the MINERvA, MicroBooNE, and T2K experiments. I then present two mathematical techniques, blockwise unfolding and the conditional covariance background constraint, which overcome some limitations of typical cross-section extraction procedures.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction

Single-stage and multi-stage systems and methods for the recovery of critical elements in substantially pure form from lithium ion batteries are provided. The systems and methods include supported membrane solvent extraction using an immobilized organic phase within the pores of permeable hollow fibers. The permeable hollow fibers are contacted by a feed solution on one side, and a strip solution on another side, to provide the simultaneous extraction and stripping of elements from dissolved lithium ion cathode materials, while rejecting other elements from the feed solution. The single- and multi-stage systems and methods can selectively recover cobalt, manganese, nickel, lithium, aluminum and other elements from spent battery cathodes and are not limited by equilibrium constraints as compared to traditional solvent extraction processes.

Bhave, Ramesh R.↗

Extraction of Ln(III) and An(III) from Alkaline Solutions by Sulfonamide Ligands and Analogs - 20216

As part of our effort to develop advanced separations involving combined extraction of cesium, strontium, and actinides from High-Level Waste (HLW) at the Savannah River Site, we are now reporting highly efficient extraction of Sm(III) from aqueous media of various alkalinity by dichloromethane solutions of several ligands, including tri-sulfonamides, o-mono-sulfonamido-phenols and o-phenylenediamine- derived disulfonamides. Distribution experiments and DFT calculations provide insights on the complexation of Samarium vs Americium by these ligands. Further optimization of these ligands for extraction into highly lipophilic solvents and application to HLW simulants are underway. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

System and method for extracting ethanol from a fermentation broth

The present invention is directed to a system and method for producing an organic compound using fermentation wherein multiple components of the system are recycled within the system. The system and method allow for extraction of a high concentration of the organic compound from the fermentation broth in a continuous system that allows recycling of the biomass, aqueous fermentation broth and extraction solvents. The system and method are particularly well adapted for producing and extracting ethanol.

Abbas, Charles↗

A Model Based Approach to Extract Health Information from Textual Data

In current nuclear power plants (NPPs) a large amount of condition-based data is being generated and stored to assess and monitor component health and performance. The format of this data can be either numeric (e.g., pump vibration data) or textual (e.g., condition report which assess component health). While assessing component health from numeric data can be performed with a large variety of methods, the extraction of information from textual data still remains a challenge. Natural language processing (NLP) methods are starting to be deployed in current NPPs mainly to filter out incident reports (IRs) that are not safety related by employing supervised machine learning methods. However, these methods do not really provide the quantitative information that might be contained in IRs. This paper presents an approach to extract information from textual data (e.g., from IRs, maintenance reports) that is based on NLP data analytics methods coupled with model-based system engineer (MBSE) models. NLP methods are employed to perform syntactic and semantic analyses. Syntactic analysis analyzes the grammatical structure of a sentence; such analysis includes: part of speech (POS) tagging (i.e., identification of grammatic elements of each string - e.g., nouns, verbs), named entity recognition (i.e., identification of text entities - e.g., names, dates, events), and relation extraction (e.g., coreference resolution). On the other hand, semantic analysis is designed to analyze the logic structure of a sentence. Through a specific set of rules, our methods can identify whether a sentence contains health information of a component (e.g., degraded performance, anomaly behavior) or the causal relationship between two events (i.e., a cause-effect pair). An innovative element of our approach is that semantic analysis relies on MBSE models to identify links between textual elements. MBSE are diagrams designed to represent system and component dependencies (from both a form and functional point of view). In our approach, MBSE models emulate system engineer knowledge about component/system architecture. This paper presents in detail how the integration of NLP methods and MBSE models is performed. Few analysis examples focusing on centrifugal pumps are presented.

97 - MATHEMATICS AND COMPUTING↗

Rapid extraction of short-lived isotopes from a buffer gas cell for use in gas-phase chemistry experiments, Part II: On-line studies with short-lived accelerator-produced radionuclides

We report a novel combination of advanced gas-chromatography and detection systems coupled to a buffer-gas cell was characterized on-line to allow gas-phase chemical studies of accelerator-produced short-lived α -decaying mercury, francium, and astatine isotopes. These were produced in 40 Ar- and 48 Ca-induced nuclear fusion–evaporation reactions, subsequently isolated in the recoil separators MARS at Texas A&M University, USA, and TASCA at GSI Darmstadt, Germany, before being thermalized in a buffer-gas-stopping cell. From the latter, the nuclear reaction products were extracted into gas-phase chromatographic systems, suitable for registering α-decaying short-lived radionuclides, such as isotopes of superheavy elements. Efficiencies of 21(3)% for 204-209 Fr were reached for the extraction into the optimized miniCOMPACT gas-chromatography setup, indicating that this technique enables the identification of isotopes of volatile as well as non-volatile elements. These studies guide the path towards chemical investigations of superheavy elements beyond flerovium, which are out of reach with currently used setups.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗