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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Ignition of mixtures of SiH sub 4, CH sub 4, O sub 2, and Ar or N sub 2 behind reflected shock waves

Ignition delay times in mixtures of methane, silane, and oxygen diluted with argon and nitrogen were measured behind reflected shock waves generated in the chemical kinetic shock tube at Langley Research Center. The delay times were inferred from the rapid increase in pressure that occurs at ignition, and the ignition of methane was verified from the emission of infrared radiation from carbon dioxide. Pressures of 1.25 atm and temperatures from 1100 K to 1300 K were generated behind the reflected shocks; these levels are representative of those occurring within a supersonic Ramjet combustor. Expressions for the ignition delay time as a function of temperature were obtained from least squares curve fits to the data for overall equivalence ratios of 0.7 and 1.0. The ignition delay times with argon as the diluent were longer than those with nitrogen as the diluent. The infrared wavelength observations at 4.38 microns for carbon dioxide indicated that silane and methane ignited simultaneously (i.e., within the time resolution of the measurement). A combined chemical kinetic mechanism for mixtures of silane, methane, oxygen, and argon or nitrogen was assembled from one mechanism that accurately predicted the ignition of methane and a second mechanism that accurately predicted silane hydrogen ignition. Comparisons between this combined mechanism and experiment indicated that additional reactions, possibly between silyl and methyl fragments, are needed to develop a good silane methane mechanism.

Mclain, A. G.↗
NASA NTRS1982

The rings of Uranus

Stellar occultation data on the Uranian rings are summarized. Spatial resolution is 0.1 km, for positions of ring segments, 4 km for structural details. The system consists of 9 narrow rings with average geometric albedo of 0.02. The data are well fitted by a kinematic model that describes the rings as ellipses, inclined to the equatorial plane of Uranus and precess due to harmonic terms in the Uranian potential fields. The main characteristics of the Uranian ring system that need a confirmed theoretical explanation are: narrow rings; sharp edges; uniform orbital precession; origin of the eccentricities and inclinations; the structure of the epsilon ring; the structure of the eta ring; and the origin of the ring system.

Elliot, J. L.↗
NASA NTRS1985

Magnetic probing of the solar interior

The magnetic field patterns in the region beneath the solar photosphere is determined. An approximate method for downward extrapolation of line of sight magnetic field measurements taken at the solar photosphere was developed. It utilizes the mean field theory of electromagnetism in a form thought to be appropriate for the solar convection zone. A way to test that theory is proposed. The straightforward application of the lowest order theory with the complete model fit to these data does not indicate the existence of any reasonable depth at which flux conservation is achieved.

Benton, E. R.↗
NASA NTRS1985

Hadron thermodynamics in relativistic nuclear collisions

Various phenomenological models based on statistical thermodynamical considerations were used to fit the experimental data at high P sub T to a two temperature distribution. Whether this implies that the two temperatures belong to two different reaction mechanisms, or consequences of Lorentz-contraction factor, or related in a fundamental way to the intrinsic thermodynamics of Space-Time can only be revealed by further theoretical and experimental investigations of high P sub T phenomena in extremely energetic hadron-hadron collisions.

Ammiraju, P.↗
NASA NTRS1985

Average features of the muon component of EAS or = 10(17) eV

Three 10 sq m liquid scintillators were situated at approximately 0 m, 150 m and 250 m from the center of the Haverah Park array. The detectors were shielded by lead/barytes giving muon detection thresholds of 317 MeV, 431 MeV and 488 MeV respectively. During part of the operational period the 431 MeV threshold was lowered to 313 MeV for comparison purposes. For risetime measurement fast phototubes were used and the 10% to 70% amplitude time interval was parameterized by T sub 70. A muon lateral density distribution of the form rho mu (R theta) = krho(500)0.94 1/R(1 + R/490)-eta has been fitted to the data for 120 m R 600 m and 0.27 (500) 2.55. The shower size parameter (500) is the water Cerenkov response at 500 m from the core of the extensive air showers (EAS) and is relatable to the primary energy. The results show general consistency.

Blake, P. R.↗
NASA NTRS1985

The longitudinal development of muons in cosmic ray air showers at energies 10(15) - 10(17) eV

The relationship between longitudinal development of muons and conventional equi-intensity cuts is carefully investigated. The development of muons in Extensive Air Showers (EAS) has been calculated using simulation with a scaling violation model at the highest energies and mixed primary composition. Profiles of equi-intensity cuts expected at observation altitudes of 550, 690 and 930/sq cm can fit the observed data very well.

Source record↗
NASA NTRS1984

Absolute intensity measurements of CO2 bands in the 2395-2680/cm region

Absolute intensities for over 800 transitions belonging to twelve bands of (C-12)(O-16)2, (O-16)(C-12)(O-18), (O-16)(C-12)(O-17), and (O-16)(C-13)(O-18) molecules in the 2395-2680/cm spectral region have been derived using a nonlinear least-squares spectral fitting procedure. The data used in the analysis were recorded at room temperature and low pressure with the 0.01/cm resolution Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory. The measured intensities obtained for each band have been analyzed to derive the vibrational band intensity and F-factor coefficients. The results are compared with other published values.

Malathy Devi, V.↗
NASA NTRS1984

Pressure and temperature dependence of the reaction NO2 + NO3 + M yields N2O5 + M

The pressure and temperature dependences of the reaction NO2 + NO3 + M which yields N2O5 + M are investigated by using the flash photolysis/visible absorption technique in which the pseudo-first-order decay of NO3 is monitored as a function of total pressure (20-700 torr), diluent gas (M = He and N2), and temperature (236-358 K). The reaction is found to be in the falloff region in the 20-700 torr pressure range with collision efficiencies increasing in the order He less than N2. Falloff parameters are obtained by fitting the experimental data to the falloff equation of Troe and co-workers. The expression for k1(N2 concentration, T) is obtained and compared with the evaluations presented in the NASA (DeMore, 1983) and CODATA (Baulch et al., 1982) reviews of kinetic data for atmospheric chemistry. Both evaluations are based on N2O5 thermal decomposition data coupled with estimates of the equilibrium constant. The significance of the reactions for atmospheric chemistry rests not only on their rates but on the extent to which they result in a permanent sink for NOX.

Kircher, C. C.↗
NASA NTRS1985

The occultation of AG + 29 deg 398 by 93 Minerva

The occultation of AG + 29 deg 398 by 93 Minerva on 22 November 1982 was successfully observed at 10 sites. The data are best fitted by a circular limb profile having a diameter of 170.8 + or - 1.4 km, a value that agrees well with the published radiometric diameter for this asteroid. However, evidence of significant departure from a spherical shape is found in the occultation observations and in photometric measurements of Minerva made at Lowell Observatory over several months. Additional observations are needed to specify definitively the three-dimensional figure of Minerva.

Millis, R. L.↗
NASA NTRS1985

Spallogenic Be-10 in the Jilin chondrite

The Be-10 contents measured in eight bulk samples of the Jilin meteorite range from 5.05 + or - 0.55 to 16.3 + or - 1.7 dpm/kg, more than threefold, and correlate with the Ne-21 contents. A least-squares fit of these data has a positive intercept on the Be-10 axis which can be explained in terms of a two-stage irradiation. The second, more recent stage lasted 0.57 + or - 0.14 Myr. Model calculations give first-stage Be-10/Ne-21 age ranging from 6.2 to 7.1 Myr.

Pal, D. K.↗
NASA NTRS1985

X-ray spectrum and variability of 3C 120

The X-ray luminosity of 3C 120 is variable by a factor of 2.5 on time scales of days to months. The spectral slope of the 2-10 keV X-rays changes systematically in the sense that the higher intensity states are steeper. Simple power laws fitted to the data are consistent with an energy index alpha of 0.51 + or - 0.13 at minimum intensity and 0.83 + or - 0.03 at maximum, with a continuous variation in between. A more complicated spectral shape cannot be ruled out, but changes in absorbing column density alone cannot explain the data. The results are interpreted in terms of beamed synchrotron emission from a relativistic jet, a model which has been invoked previously for the spectra of BL Lac objects. The spectral variability is in marked contrast to the behavior of 3C 273, another superluminal source in which the X-ray spectral index is constant to a high degree of accuracy despite variability in time scales and amplitudes which are quite similar to those of 3C 120. The difference may be due to the degree of beaming of the respective core components. Another model which is consistent with the data involves thermal emission from isothermal shocks in a hot (approximately 10 to the 8th K) medium. Thermal Compton and spherical accretion X-ray source models do not reproduce the correct behavior of alpha versus flux.

Halpern, J. P.↗
NASA NTRS1985

Conformational properties, torsional potential, and vibrational force field for methacryloyl fluoride - An ab initio investigation

The structure, torsional potentials, vibrational spectra, and harmonic force fields for s-cis and s-trans isomers of methacryloyl fluoride are examined to understand the conformational properties of the molecules and their relationship to macroscopic polymer properties. The structure is found to be in good agreement with experiment. It is shown by calculations that the energy difference between the cis and the transisomers is less than 1 kcal/mol at both the split valence and the split valence polarized levels, with the trans form favored. Analysis of the torsional potentials indicates that a rigid rotor model provides a reasonable description of the motion of the COF group in the molecule. The torsional barrier to interconvert the s-trans to the s-cis form is found to be 7.0 kcal/mol. A fit of the data to a three-term Fourier series shows that it is possible to reproduce the experimentally derived barrier, even though a direct determination indicates that the barrier is higher.

Laskowski, B. C.↗
NASA NTRS1985

Precision ozone vapor pressure measurements

The vapor pressure above liquid ozone has been measured with a high accuracy over a temperature range of 85 to 95 K. At the boiling point of liquid argon (87.3 K) an ozone vapor pressure of 0.0403 Torr was obtained with an accuracy of + or - 0.7 percent. A least square fit of the data provided the Clausius-Clapeyron equation for liquid ozone; a latent heat of 82.7 cal/g was calculated. High-precision vapor pressure data are expected to aid research in atmospheric ozone measurements and in many laboratory ozone studies such as measurements of cross sections and reaction rates.

Hanson, D.↗
NASA NTRS1985

Role of long-wavelength degrees of freedom in the rod-to-coil transition in polymers

An analytical model is fitted to experimental data to show that rod-to-coil (RTC) transformations in single strand polymers (SSPs) are close to true phase transitions. The RTC are known to occur when the temperature or pH of a solvent in which the SSP is immersed is varied abruptly. Long wavelength degrees of freedom in the SSPs induce long range interactions in the molecule which lead to a first order phase transition. The Landau formalism suggests that a long-range ordered state can appear at a low temperature. A microscopic model of the phonon degrees of freedom identifies the nonzero temperature threshold at which the phase transition will occur. The phenomenology described is similar to a previous model for transitions in double-strand polymers.

Goldenfeld, N.↗
NASA NTRS1985

Mesospheric Winds at Jicamaraca, Peru (12 Deg S, 77 Deg SW), November 19-21, 1981

The altitude of mean zonal wind in the mesosphere during the whole daytime observations is given. Positive value refers to eastward. At around 70 km, wind corresponds to summer easterly, and changes to westerly with increasing altitude above about 77 km. These are fairly compatible with known features of zonal wind at this latitude. Contour plot shows local time variations of zonal wind with daytime mean subtracted and averaged over three days. Shaded area designated westward wind with contour level of 2 m/s. The daily variation is almost in phase with altitude in the 65 to 80 km region. Thus the semidiurnal tide with long vertical wavelength is inferred to exist. Above 80 km, phase tilt occurs which indicates the contribution of the propagating diurnal component. Here the combination of dc and 12-hr component is fitted to the data below 80 km. The altitude profiles of the amplitude and phase of this semidiurnal component are shown.

Aso, T.↗
NASA NTRS1985

The Jovian stratosphere in the ultraviolet

Models of the spectral reflectivity at the center of the disk of Jupiter from 1450 to 3150 angstroms are presented. The reflectivity was computed from 30 low-dispersion IUE spectra taken during the 1978-1980 solar maximum. A vertically inhomogeneous radiative transfer program was used to compute model reflectivities of various stratospheric compositions for comparison. Ammonia and acetylene are well determined because they show narrow absorption bands in the ultraviolet. Possible compositions to improve the fit to the data below 1800 angstroms are suggested. The data are too noisy to detect possible CO Cameron band absorption near 2000 angstroms.

Wagener, R.↗
NASA NTRS1984

Barrier height determination on Schottky contacts formed at the back contact-semiconductor interface of degraded solar cells

A method is described of determining an equivalent circuit for solar cells which have degraded as a result of the formation of a rectifying Schottky barrier at the back contact. An excellent fit of experimental data has been achieved using SCEPTRE with an equivalent circuit derived from the shape of the measured current voltage characteristics. One key parameter of the Schottky barrier diode, the reverse saturation current, can be used to determine the barrier potential. The barrier potential increases as the cell is stressed with 0.5 volts being a typical experimentally determined value for a degraded cell.

Misiakos, K.↗
NASA NTRS1986

Photometry of resolved galaxies. V - NGC 6822

Three-color CCD frames of the local group irregular galaxy NGC 6822 have been reduced to GRI photometry for 3475 stars using RICHFLD point-spread function fitting techniques. The data are compared with earlier work on this galaxy, particularly with Kayser (1966) on a star-by-star basis. Color-magnitude diagrams are constructed from the data and compared with both theoretical stellar model tracks and the expected foreground star contamination. A luminosity function for the blue stars is derived; comparison of this luminosity function with those of 10 other irregular galaxies indicates that NGC 6822 has a typical young star population. The stellar birthrate and initial mass function are estimated for this galaxy. The slope at the bright end of the mass function looks similar to recent results for the Galaxy, the Magellanic Clouds, and the irregular galaxy Sextans A. NGC 6822 appears to be presently forming stars at a slower rate for its mass than Sextans A or the Magellanic Clouds.

Hoessel, J. G.↗