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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51

A variable geometry combustor for broadened properties fuels

A program was conducted to design and develop a variable geometry combustor, sized for the cycle and envelope of a large commercial turbofan engine. The combustor uses a variable area swirl cup to control stoichiometry in the primary combustion zone. Potential advantages of this design include improved capability to burn non-standard fuels, short system length, and increased operating temperature range for advanced high performance engine cycles. After considerable development, key program emissons and performance goals were met with the variable geometry combustor. Primary development efforts were to evolve improved variable swirl cup configurations. In particular, air leakage through the variable area swirl cup had a strong effect on low power emissions and performance, while smoke level at high power was affected by features for improved mixing of the fuel and swirler air flow. Additional design and development is still needed to evolve a practical variable geometry combustor.

Dodds, W. J.↗

2017 NE-4 Nuclear Technologies Research and Development (NTRD) Achievements Report

Fiscal year (FY) 2017 initiated new and reestablished presidential and departmental nuclear energy priorities for the U.S. Department of Energy (DOE), Office of Nuclear Energy (DOE-NE) that will: • Support the Administration’s priorities to achieve U.S. energy dominance and economic prosperity through U.S. technology leadership • Support DOE-NE mission priorities and goals for the existing nuclear fleet, advanced reactor pipeline and national fuel cycle infrastructure • Focus on early stage research, and effective cooperation with industry, academia, and other government agencies • Propose investments to maintain and improve capabilities and infrastructure to conduct leading-edge science, research, and technology development. DOE-NE’s mission priorities will focus on the existing nuclear fleet, advanced reactor pipeline, and fuel cycle infrastructure. Therefore, the DOE Nuclear Technology Research and Development (NE-4) mission aligned to (1) support the research and development (R&D) of innovative reactor technologies that may offer improved safety, functionality, and affordability and (2) conduct research to reduce long-term technical barriers for advanced nuclear energy systems, including space fission systems. Key activities to execute this mission include: • To achieve the NE-4 mission priorities, two major programs with eight R&D campaigns are engaged in impactful research, development, demonstration, and deployment: Fuel Cycle Technologies (FCT) Program • Fuel Cycle Options Campaign evaluates complex fuel cycle options and provides performance metrics on various systems and scenarios to improve the knowledge of interdependencies between technologies and different systems. • Advanced Fuels Campaign performs science-based R&D on accident tolerant fuels in addition to advanced light-water reactor (LWR) fuel and transmutation fuel. • Joint Fuel Cycle Studies (JFCS) is a collaboration with the Republic of Korea to assess the feasibility and nonproliferation of electrochemical recycling to manage used fuel. • Material Recovery and Waste Form Development (MRWFD) Campaign researches advanced fuel cycle material recovery and waste management capabilities to improve fuel cycle performance with less processing and waste generation. • Material Protection, Control, and Accountability Technologies (MPACT) Program develops tools and capabilities to secure the next generation nuclear materials management and safeguards for nuclear fuel cycles. Advanced Reactor Technologies (ART) Program • Fast Reactors Campaign targets benefits in either resource utilization or waste management and possesses favorable features for small reactor applications and plutonium management. • Gas-Cooled Reactors Campaign seeks to raise the technological readiness of high temperature gas-cooled reactors (HTGRs) and other reactor concepts utilizing coated particle fuel, graphite, or helium coolant by performing high risk, enabling research and development that commercial developers are unable or unwilling to undertake in the current energy market. • ART Energy Conversion (EC) Project provides solutions to convert heat from an advanced reactor to useful products that support commercial application of the reactor designs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Alternating Between Software Models and Real Hardware in the System Integration Lab for theIncremental Development of the Space Launch System Program Avionics

The MSFC System Integration Lab (SIL) supports avionics development of NASA’s Space Launch System—a new U.S. heavy-lift launch vehicle for NASA’s next generation of human space exploration beyond low-Earth orbit. The SIL facility allows for the incremental development of system components by either hosting real hardware in the loop and/or software models of those components. Through this functionality test teams are able to evaluate overall system performance as components are designed, built and modified. Early hardware/software integration and testing reduces risks and saves overall cost and schedule throughout a program/project life cycle. By performing early hardware/software integration, potential architecture and interface-related problems can be identified, and thus reduce associated risk as early in the design cycle as possible when problems are the least expensive to resolve while also improving the design and requirements. This presentation will illustrate the power of employing a hardware in the loop simulation system for the development of novel spacecraft avionics.

Space Launch System↗

Upgrading the Performance and Stability of Lithium, Manganese-Rich Layered Oxide Cathodes with Combined-Formic Acid and Spinel Coating Treatment

We report improving sluggish rate performance and cycling stability of Li, Mn-rich cathode materials (LMR) is of great importance for practical implementation. Here, dual surface modification on LMR particles with formic acid washing and spinel coating improves the electrochemical performance. Dilute formic acid can remove the Li2CO3 surface impurities and selectively reduce Ni while significantly increasing specific surface area by ~32 %, unlocking more electrochemically active surfaces. Spinel coating enhances cycle stability by suppressing detrimental side reactions at electrode-electrolyte interfaces at high voltage. Post-annealing temperature was found to significantly affect the cathode performance. Higher temperature favors diffusion of transition metal (TM)/Li ions of the spinel coating from surface to the bulk, removing the coating by possible reconstruction into the layered structure and thus degrading the performance. The spinel coating also appears to increase Co 3+ segregation on the particle surface. Compared to the original material, the optimized sample demonstrates 47 % higher capacity retention at 3C and retains 89 % of initial capacity after 150 cycles at 0.5C. Besides, the specific energy density of 523 Wh kg -1 can be attained after 150 cycles at 0.5C. Moreover, the post-cycling analysis of modified sample verifies a better structural integrity with less particle cracking. Altogether, this study portrays an alternative strategy to overcome the shortcomings of LMR cathode materials.

25 ENERGY STORAGE↗

Off-design performance of an organic Rankine-vapor compression cooling cycle using R1234ze(E)

In this study, a 264 kW th organic Rankine-vapor compression cycle (ORVC) was experimentally tested over a range of conditions to quantify the individual impact of off-design external conditions. The ORVC was designed to recover waste heat at 91 °C, reject heat to a liquid condenser stream at 30 °C, and produce chilled water at 7 °C. Here, the condenser heat rejection temperature was varied from 16.6 °C to 32.6 °C, the chilled water delivery temperature was varied between 2.1 °C and 13.1 °C, and the heat input temperature was varied from 91 °C to 120 °C. As the condenser heat rejection temperature decreased, the coefficient of performance (COP) of the ORVC improved from 0.558 at 30 °C to 0.682 at 16.6 °C, despite a reduction in compressor isentropic efficiency. Although the chilled water temperature variation had almost no impact on the organic Rankine cycle performance, the compressor efficiency decreased when the delivery temperature was below 7 °C. At the highest chilled water temperature, 13.1 °C, the COP of the ORVC was 0.643. Compressor stall was noted when the condenser heat rejection temperature was greater than 32.6 °C and the chilled water delivery temperature was below 2.1 °C. Increasing the driving heat source inlet temperature improved the COP of the ORVC and the thermal efficiency of the organic Rankine power cycle, while decreasing the efficiency of the compressor and the COP of vapor compression cycle. In addition, the integrated part load value of the system was determined through experimentation to be 0.682, which provides a realistic estimate of real-world performance.

30 DIRECT ENERGY CONVERSION↗

Full Concentration Gradient-Tailored Li-Rich Layered Oxides for High-Energy Lithium-Ion Batteries

Lithium-rich layered oxides (LLOs) are prospective cathode materials for next-generation lithium-ion batteries (LIBs), but severe voltage decay and energy attenuation with cycling still hinder their practical applications. In this study, a series of full concentration gradient-tailored agglomerated-sphere LLOs are designed with linearly decreasing Mn and linearly increasing Ni and Co from the particle center to the surface. The gradient-tailored LLOs exhibit noticeably reduced voltage decay, enhanced rate performance, improved cycle stability, and thermal stability. Without any material modifications or electrolyte optimizations, the gradient-tailored LLO with medium-slope shows the best electrochemical performance, with a very low average voltage decay of 0.8 mV per cycle as well as a capacity retention of 88.4% within 200 cycles at 200 mA g –1 . These excellent findings are due to spinel structure suppression, electrochemical stress optimization, and Jahn-Teller effect inhibition. Further investigation shows that the gradient-tailored LLO reduces the thermal release percentage by as much as about 41% when the battery is charged to 4.4 V. This study provides an effective method to suppress the voltage decay of LLOs for further practical utilization in LIBs and also puts forward a bulk-structure design strategy to prepare better electrode materials for different rechargeable batteries.

36 MATERIALS SCIENCE↗

Highly Conductive, Lightweight, Low-Tortuosity Carbon Frameworks as Ultrathick 3D Current Collectors

The growing demand for advanced energy storage techniques and devices has driven the energy storage market to strive for higher performance, longer cycling life, and better safety. Thick electrode design enabling more electroactive materials has the potential to significantly improve the energy density on device level yet faces major challenges of slow ion transport and high deformability. In this work, inspired by natural wood materials with aligned channels along the tree growth direction, a highly conductive, lightweight, and low-tortuosity carbon framework (CF) directly carbonized from natural wood as an ultrathick 3D current collector is demonstrated. Benefiting from the uniqueness of the multichanneled CF, an ultrathick 3D electrode of lithium iron phosphate filled carbon framework with a large thickness of 800 µm and active material mass loading of 60 mg cm -2 delivers a rational capacity of 7.6 mAh cm -2 (95 Ah L -1 based on volume), long cycling life, and lower deformability with enhanced mechanical properties. This work presents a design concept for thick electrode toward high performance energy storage devices that are not limited to lithium-ion batteries.

09 BIOMASS FUELS↗

Building the I (Interoperability) of FAIR for performance reproducibility of large-scale composable workflows in RECUP

Abstract-Scientific computing communities increasingly run their experiments using complex data- and compute-intensive workflows that utilize distributed and heterogeneous architectures targeting numerical simulations and machine learning, often executed on the Department of Energy Leadership Computing Facilities (LCFs). We argue that a principled, systematic approach to implementing FAIR principles at scale, including fine-grained metadata extraction and organization, can help with the numerous challenges to performance reproducibility posed by such workflows. We extract workflow patterns, propose a set of tools to manage the entire life cycle of performance metadata, and aggregate them in an HPC-ready framework for reproducibility (RECUP). We describe the challenges in making these tools interoperable, preliminary work, and lessons learned from this experiment.

97 MATHEMATICS AND COMPUTING↗

Effect of hydrogen on irradiation creep and growth for ZIRLO alloy and Zr-1.0Nb - 2016-0058

The impact of hydrogen on the irradiation growth and creep of stress-relief annealed (SRA) ZIRLO{sup R} alloy and recrystallized annealed (RXA) Zr-1.0Nb cladding tubes is evaluated in this paper. The samples were charged with hydrogen in the range of approximately 160-720 ppm using the gaseous method. Biaxial in-reactor creep tests were performed after Cycle 1, Cycle 2, Cycle 3, and Cycle 4, on both as received and pre-charged hydrogen cladding tubes. Outside diameter and axial length measurements were performed on the samples. The results showed that hydrogen had no effect on the axial irradiation creep but a relatively large effect on the axial irradiation growth. Increasing hydrogen decreased the axial irradiation growth in RXA Zr-1.0 Nb, which was opposite from the behavior of SRA ZIRLO cladding. This unique hydrogen effect on the irradiation axial growth of RXA Zr-1.0Nb could be due to the different intergranular stress resulting from the fabrication process or the absence of alloying elements, including tin. The total axial strain of both Zr-1.0Nb and SRA ZIRLO cladding increased with increasing fast fluence, and Zr-1.0Nb increased at a faster rate relative to SRA ZIRLO cladding. In the diameter direction, hydrogen had a minimal effect on the total diameter strain and the diameter irradiation creep strain for both SRA ZIRLO samples and the RXA Zr-1.0Nb sample. This finding from in-reactor test is contrary to the out-reactor tests results from the literature that have shown that hydrogen significantly decreases thermal creep. The total diameter strain and diameter irradiation creep behavior for the SRA ZIRLO samples and RXA Zr-1.0Nb were similar. (authors)

36 MATERIALS SCIENCE↗

SST-GPU: An Execution -Driven CUDA Kernel Scheduler and Streaming-Multiprocessor Compute Model

Programmable accelerators have become commonplace in modern computing systems. Advances in programming models and the availability of massive amounts of data have created a space for massively parallel acceleration where the context for thousands of concurrent threads are resident on-chip. These threads are grouped and interleaved on a cycle-by-cycle basis among several massively parallel computing cores. The design of future supercomputers relies on an ability to model the performance of these massively parallel cores at scale. To address the need for a scalable, decentralized GPU model that can model large GPUs, chiplet-based GPUs and multi-node GPUs, this report details the first steps in integrating the open-source, execution driven GPGPU-Sim into the SST framework. The first stage of this project, creates two elements: a kernel scheduler SST element accepts work from SST CPU models and schedules it to an SM-collection element that performs cycle-by-cycle timing using SSTs Mem Hierarchy to model a flexible memory system.

97 MATHEMATICS AND COMPUTING↗

Practical Multi-Cycle Refueling Simulation of Stable Salt Reactors Based on REBUS Depletion Calculation

A Python software tool ReloadPy has been developed to assistant in formulating online refueling strategies for a family of stable salt reactors. ReloadPy wraps over the legacy fast reactor analysis codes REBUS, DIF3D, and PERSENT. These codes are used to perform single cycle depletion analysis and calculate reactivity worth and power density. ReloadPy determines a refueling assembly position to achieve the user-specified primary objective while satisfying constraints on various performance parameters such as the maximum power density, the maximum reactivity worth of reloaded assembly, and the minimum cycle length. Various capabilities of prescribing refueling sequence or a range of candidate refueling positions and restarting a previous simulation with altered options are implemented to reduce the required user’s efforts to investigate different refueling strategies. This report presents the computational models and methods and also serves as a user guide. Long-term simulation capabilities with different refueling strategies are demonstrated by a series of sample SSR refueling calculations with two-dimensional surrogate core models.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Antifoam Degradation Products in Off Gas and Condensate of Sludge Batch 9 Simulant Nitric-Formic Flowsheet Testing for the Defense Waste Processing Facility

Ten chemical processing cell (CPC) experiments were performed using simulant to evaluate Sludge Batch 9 for sludge-only and coupled processing using the nitric-formic flowsheet in the Defense Waste Processing Facility (DWPF). Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles were performed on eight of the ten. The other two were SRAT cycles only. Samples of the condensate, sludge, and off gas were taken to monitor the chemistry of the CPC experiments. The Savannah River National Laboratory (SRNL) has previously shown antifoam decomposes to form flammable organic products, (hexamethyldisiloxane (HMDSO), trimethylsilanol (TMS), and propanal), that are present in the vapor phase and condensate of the CPC vessels. To minimize antifoam degradation product formation, a new antifoam addition strategy was implemented at SRNL and DWPF to add antifoam undiluted.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Multi-Disciplinary Analysis for Future Launch Systems Using NASA's Advanced Engineering Environment (AEE)

A new engineering environment constructed for the purposes of analyzing and designing Reusable Launch Vehicles (RLVs) is presented. The new environment has been developed to allow NASA to perform independent analysis and design of emerging RLV architectures and technologies. The new Advanced Engineering Environment (AEE) is both collaborative and distributed. It facilitates integration of the analyses by both vehicle performance disciplines and life-cycle disciplines. Current performance disciplines supported include: weights and sizing, aerodynamics, trajectories, propulsion, structural loads, and CAD-based geometries. Current life-cycle disciplines supported include: DDT&E cost, production costs, operations costs, flight rates, safety and reliability, and system economics. Involving six NASA centers (ARC, LaRC, MSFC, KSC, GRC and JSC), AEE has been tailored to serve as a web-accessed agency-wide source for all of NASA's future launch vehicle systems engineering functions. Thus, it is configured to facilitate (a) data management, (b) automated tool/process integration and execution, and (c) data visualization and presentation. The core components of the integrated framework are a customized PTC Windchill product data management server, a set of RLV analysis and design tools integrated using Phoenix Integration's Model Center, and an XML-based data capture and transfer protocol. The AEE system has seen production use during the Initial Architecture and Technology Review for the NASA 2nd Generation RLV program, and it continues to undergo development and enhancements in support of its current main customer, the NASA Next Generation Launch Technology (NGLT) program.

Monell, D.↗

Performance Baseline for Direct-Fired sCO2 Cycles

NETL has conducted an evaluation of the performance and emissions for a direct coal-fired supercritical CO2 (sCO2) power plant, which has recently received interest as a potentially lower-cost, fossil-fuelled power source with inherent amenability to carbon capture. This study describes a baseline coal-fired cycle configuration, where coal is first gasified and cleaned in order to avoid introducing sulfur and particulate matter into the sCO2 cycle, with the sCO2 cycle’s oxy-combustor operating on syngas. The baseline sCO2 plant design yields a net plant thermal efficiency of 37.7% (HHV), with 98.1% CO2 capture at 99.4% purity. This compares favorably to the reference IGCC plant, which has a 31.2% net HHV thermal efficiency, and 90.1% CO2 capture rate at 99.99% purity. The sensitivity of the sCO2 plant’s performance to its process variables is discussed, as well as their effect on plant operability and cost surrogate variables.

Shelton, Walter↗

Performance Baseline for Direct-Fired sCO2 Cycles

NETL has conducted an evaluation of the performance and emissions for a direct coal-fired supercritical CO2 (sCO2) power plant, which has recently received interest as a potentially lower-cost, fossil-fuelled power source with inherent amenability to carbon capture. This study describes a baseline coal-fired cycle configuration, where coal is first gasified and cleaned in order to avoid introducing sulfur and particulate matter into the sCO2 cycle, with the sCO2 cycle’s oxy-combustor operating on syngas. The baseline sCO2 plant design yields a net plant thermal efficiency of 37.7% (HHV), with 98.1% CO2 capture at 99.4% purity. This compares favorably to the reference IGCC plant, which has a 31.2% net HHV thermal efficiency, and 90.1% CO2 capture rate at 99.99% purity. The sensitivity of the sCO2 plant’s performance to its process variables is discussed, as well as their effect on plant operability and cost surrogate variables.

Weiland, Nathan↗

Demonstration and Evaluation of Lightweight High Performance Quad-Pane Windows

Ten high-performance quad-pane windows (five quad-pane with suspended film and five quad-pane with thin glass) were installed at Building 41 of the Denver Federal Center in Colorado as part of a demonstration project to assess their thermal performance, life cycle costs, and deployment potential for replacing older single-pane windows. The U.S. Department of Energy's National Renewable Energy Laboratory performed several different evaluations to assess the viability of the quad-pane windows for GSA applications. Some of these assessments were performed with models, while others required onsite evaluations including time series measurements.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗