Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Ca”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 919 records · Page 51

High-velocity interstellar gas toward HD 169454

The interstellar spectrum of HD 169454 reveals Na D and Ca K absorption at about + 100 km/s. Measurements made at high resolution resolve 4 narrow (about 2-3 km/s) features whose N(Ca II)/N(Na I) ratios are small. This high-velocity gas is, therefore, unique in that it resembles local quiescent gas, not shocked gas. Redshifted gas is also seen in moderate-resolution spectra of faint stars lying in the same portion of the sky as HD 169454. The resulting picture is one in which a supernova explosion or stellar winds within the Sct OB3 association at a distance of about 1.5 kpc is pushing quiescent gas away from the sun. The gas is seen only in stars estimated to be at most 3 kpc, but greater than 2 kpc, away. If HD 169454 is at this greater distance, its absolute magnitude would be about -9, making it the second most luminous B star in the Galaxy.

Federman, S. R.↗

Structural review of the Vredefort dome

The structure of the older-than-3.2-Ga Archean basement and Archean-to-Precambrian sedimentary/volcanic rocks (3.07 to ca. 2.2 Ga) in the center of the Witwatersrand Basin to the southwest of Johannesburg (South Africa) is dominated by the ca. 2.0-Ga megascopic Vredefort 'Dome' structure. The effect of the 'Vredefort event' is demonstrably large and is evident within a northerly arc of about 100 km radius around the granitic core of the structure. Northerly asymmetric overturning of the strata is observed within the first 17 km (strata is horizontal in the south), followed by a 40-km-wide rim synclinorium. Fold and fault structures (normal, reverse, and strike-slip) are locally as well as regionally concentrically arranged with respect to the northern and western sides of the structure. The unusual category of brittle deformation, the so-called 'shock deformation', observed in the collar strata has attracted worldwide attention over the past two decades. These deformation phenomena include the presence of coesite and stishovite, mylonites, and pseudotachylites, cataclasis at a microscopic scale, and the ubiquitous development of multiply striated joint surfaces (which include shatter cones, orthogonal, curviplanar, and conjugate fractures). The macroscopic to microscopic deformation features have led to the formulation of various hypotheses to account for the origin of the Vredefort structure: (1) tectonic hypotheses--deep crustal shear model, doming and N-directed thrust fault model, fold interference model, and diapir model; (2) the exogenous bolide impact hypothesis; and (3) the endogenous cryptoexplosion model.

Colliston, W. P.↗

Diagnostics of electron-heated solar flare models. III - Effects of tapered loop geometry and preheating

A series of hydrodynamic numerical simulations of nonthermal electron-heated solar flare atmospheres and their corresponding soft X-ray Ca XIX emission-line profiles, under the conditions of tapered flare loop geometry and/or a preheated atmosphere, is presented. The degree of tapering is parameterized by the magnetic mirror ratio, while the preheated atmosphere is parameterized by the initial upper chromospheric pressure. In a tapered flare loop, it is found that the upward motion of evaporated material is faster compared with the case where the flare loop is uniform. This is due to the diverging nozzle seen by the upflowing material. In the case where the flare atmosphere is preheated and the flare geometry is uniform, the response of the atmosphere to the electron collisional heating is slow. The upward velocity of the hydrodynamic gas is reduced due not only to the large coronal column depth, but also to the increased inertia of the overlying material. It is concluded that the only possible electron-heated scenario in which the predicted Ca XIX line profiles agree with the BCS observations is when the impulsive flare starts in a preheated dense corona.

Emslie, A. G.↗

Stratification of chemical elements in the atmosphere of the Ap star 53 Camelopardalis

A detailed abundance analysis of Cr, Fe, Mn, Ca, and Ti in the Ap star 53 Cam from IUE high-resolution spectra has been performed. It is found that UV lines give significantly lower abundance than visible lines for Cr and Fe. Theoretical spectra of Cr II line calculated with the stratified chromium abundance distributions predicted a priori by the diffusion-mass loss model match well both visible and UV lines. The spectral shape of the Ca II K line and its variation are well accounted for by the diffusion model with mass loss. A spectrum synthesis with a stratified abundance well reproduces the observations. These findings provide convincing evidence for stratification in the photosphere of 53 Cam.

Babel, J.↗

Line profile variations in M giants - Clues to mass-loss and chromospheric heating mechanisms

Analysis is presented of time-series, high dispersion spectra of the Mg II, k, Ca II H, and K lines of the semiregular giants Rho Per (M4 II-III, periodicity of about 50 days), R Lyr (M5 III, period of about 46 days), and g Her (M6 III, period of about 90 days). The fine error sensor on the IUE satellite and ground based UBV photometry was used to relate line profile variations to photospheric variations. The above mentioned stars were selected to study the relative importance of convective motions and global stellar pulsations in determining the structure of the outer atmospheres. Small amplitude changes, but substantial changes in the profiles of Mg II and Ca II lines were detected. It is contended that the observed variability is due to changes in chromospheric conditions and not variations within the circumstellar shell. The picture of a steady state chromosphere, which is modulated on long time scales, is corroborated by these observations. Localized heating is found in g Her.

Judge, P. G.↗

The CR (Renazzo-type) carbonaceous chondrite group and its implications

A petrologic, geochemical, and oxygen isotropic study of the CR chondrites including Renazzo, Al Rais, El Djouf 001 and the paired Acfer meteorites, EET87770 and the paired samples, MAC87320, Y790112, Y793495, and Y791498 is presented. It is concluded that the CR group is characterized by abundant large multilayered, Fe, Ni metal-rich, type I chondrules; abundant matrix and dark inclusions; unique assemblages of serpentine and chlorite-rich phyllosilicates and Ca-carbonates; Ca-carbonate rims on chondrules; abundant Fe, Ni metal with a positive Ni vs. Co trend and a solar Ni:Co ratio; and amoeboid olivine aggregates with Mn-rich and Mn-poor forsterite.

Weisberg, Michael K.↗

Spectra of low-mass helium star models and the type Ic supernova SN 1987M

The question of whether the low-mass helium star models reproduce the helium-poor Type Ic spectrum of SN 1987M is investigated by comparing the theoretical spectrum from the 3.3-solar-mass model of Shigeyama et al. (1990) to observations of SN 1987M reported by Filippenko et al. (1990). The results indicate a number of positive correlations between the observed and the computed spectra. In both types of spectra, Ca II, O I, and Mg I emission lines dominate at late times, and, if extensive composition mixing is imposed, good fits can be made to the shapes of the emission features and good agreement can be found with the observed ratio of the forbidden and IR triplet blends of Ca II. The former indicates that the 3.3-solar-mass model predicts the proper density/velocity structure, and the latter indicates that the computed temperature structure is consistent with the observation though the lines are too strong relative to the continuum. This result is roughly independent of the He abundance. The computed and observed spectra are consistent with a small Ni-56 production in contrast to Type Ia thermonuclear events whose spectra are dominated by Fe-group lines at late times.

Swartz, Douglas A.↗

Oxygen isotopic composition of individual olivine grains from the Allende meteorite

The oxygen isotopic composition of a variety of individual olivine grains (including refractory forsterite grains, cores of isolated olivine grains, FeO-rich rims, and individual matrix olivine grains) from the Allende CV3 meteorite was investigated by ion microprobe mass spectrometry, in order to obtain information on the formation mechanism of these samples. It was found that the most primitive (i.e., refractory) olivine in Allende is far less enriched in O-16 than are spinel and pyroxene in Ca,Al-rich inclusions, suggesting that Allende olivine must have formed in an environment that is less enriched in O-16 compared to the gas from which Ca,Al-inclusions are formed. FeO-rich (26-30 wt pct) rims of isolated olivine grains are significantly higher in delta-O-17 and delta-O-18 than forsteritic cores, suggesting that these rims formed by condensation from an oxidized gas with higher delta-O-17 than delta-O-18. Matrix olivine was found to be highest in FeO and to have the lowest enrichment in O-16.

Weinbruch, S.↗

Geochemistry and petrogenesis of proterozoic mafic dykes in north Kerala, southwestern Indian Shield - Preliminary results

Mafic dyke intrusions occur in three distinct orientations ( NNW-SSE and NW-SE and NE-SW) in north Kerala regions, the southwestern part of the Indian Shield. Dating of two NNW-SSE trending dykes by K-Ar method has yielded Middle Proterozoic ages (ca. 1660 Ma and ca. 1420 Ma respectively). Our initial geochemical results on these dyke rocks (0.65-0.15 wt pct K2O, 0.37-0.38 wt pct P2O5, 3.30-1.00 wt pct TiO2, 11-1 p.p.m. Rb, 250-90 p.p.m. Sr, 230-40 p.p.m. Ba, 160-40 p.p.m. Zr, and 30-10 x chondrite rare earth elemental abundances) indicate a transitional character between abyssal and plateau tholeiites. Petrogenetic modelling suggests that the dyke compositions have been derived by different degrees of partial melting of a heterogenous source mantle. The mantle sources with accessory amphibole and/or garnet, variably enriched in LREE and LIL elements, are compatible with the observed geochemical data.

Radhakrishna, T.↗

A catalog of chromospherically active binary stars (second edition)

The catalog contains 206 spectroscopic binary systems with at least one late-type component that shows Ca II H and K emission in its spectrum. These systems include the classical RS CVn binaries and BY Dra binaries. The catalog summarizes information on the photometric, spectroscopic, orbital, and physical properties of the systems as well as space motions and positions. Up to 42 'parameters' for each stellar system are listed followed by the appropriate reference to direct interested colleagues to the original papers. A comprehensive selection of further information for each star is given in the individual notes. In addition, the catalog contains a candidate list of 138 stars that have similar characteristics but are not definitely known binaries or have not had Ca II H and K emission observed.

Strassmeier, K. G.↗

Calcium depletion in cooling-flow nebulae and the origin of the line-emitting gas

We present upper limits on the forbidden Ca II 7291 A flux from emission-line nebulae in cluster cooling flows. The observed lack of forbidden Ca II emission indicates that gas-phase calcium is underabundant in cooling-flow nebulae and is most likely depleted onto dust grains. If calcium in the line-emitting filaments is largely bound into dust, then these filaments probably did not condense out of the hot intracluster gas.

Donahue, Megan↗

The stability of hibonite and other aluminous phases in silicate melts: Implications for the origin of hibonite-bearing inclusions

Phase fields in which hibonite (Hib) and silicate melt coexist with spinel (Sp), CaAl4O7 (CA2), gehlenitic melilite (Mel), anorthite (An), or corundum (Cor) in the system CaO-MgO-Al203-SiO2-TiO2 (CMAST) were determined and activity models developed for Mel and Hib solid solutions. Experimentally determined partition coefficients for Ti between Hib and coexisting melt, D sub t, vary from 0.8 to 2.1 and generally decrease with increasing TiO2 content in the liquid (L). Based on Ti partioning between Hib and melt, bulk inclusion compositions and Hib-saturated liquid use phase diagrams, the Hib in Fluffy Type A inclusions (FTA's) from Allende and at least some of the Hib from Hib-rich inclusions is relict; much of the Hib from Hib-glass spherules probably crystallized from a melt under nonequilibrium conditions. Bulk compositions for all of these Ca-Al-rich inclusions (CAI's) are consistent with an origin as Mel + Hib + Sp + perovskite (Pv) proto-inclusions in which Mel was partially altered. In some cases, the proto-inclusion was partially or completely melted with vaporization occurring over a period of time sufficient to remove any Na introduced by the alteration process but frequently insufficient to dissolve all of the original hibonite. If equilibration temperatures based on Hib-bearing CAI's reflect condensation in a cooling gas of solar composition, then Hib + Cor condensed at approximately 1260 C (referenced to 10 exp -3 atm) and Hib + Sp + Mel at approximately 1215 +/- 10 C. Simple thermochemical models for the substitution of trace elements into the Ca-site of meteoritic Hib suggest that virtually all Eu is divalent in early condensate Hibs but that Eu(2+)/Eu(3+) decreases by a factor of 20 or more during the course of condensation, primarily because the ratio is proportional to the partial pressure of Al, which decreases dramatically as aluminous phases condense. The relative sizes of Eu and Yb anomalies in meteoritic Hibs and CAI's may be influenced by this effect.

Beckett, J. R.↗

Alkali-granitoids as fragments within the ordinary chondrite Adzhi-Bogdo: Evidence for highly fractionated, alkali-granitic liquids on asteroids

Adzhi-Bogdo is an ordinary chondrite regolith breccia (LL3-6) that fell October 30, 1949 in Gobi Altay, Mongolia. The rock consists of submm- to cm-sized fragments embedded in a fine-grained elastic matrix. The breccia contains various types of clasts, some of which must be of foreign heritage. Based on chemical compositions of olivine some components have to be classified as L-type. Components of the breccia include chondrules, impact melts (some are K-rich, similar to those found in other LL-chondrites, highly recrystalized rock fragments ('granulites'), pyroxene-rich fragments with achondritic textures, and alkali-granitoidal fragments that mainly consist of K-feldspar and quartz or tridymite. Probably, this is the first report on granitoids from asteroids. It can be ruled out that these fragments represent huge rock assemblages of the parent body like granites do on Earth. Therefore, to avoid misunderstandings, these rocks will be designated as granitoids. In one thin section four granitoids were observed. The main phases within these clasts are K-feldspar and SiO2-phases. Minor phases include albite, Cl-apatite, whitlockite, ilmenite, zircon, Ca-poor pyroxene, and an unidentified Na,Ti-bearing silicate. Based on chemical composition and on optical properties quartz appears to be the SiO2-phase in two fragments, whereas tridymite seems to occur in the other two. The calculated formula of the unknown Na,Ti-rich silicate is very close to (Na,Ca)2.7(Fe,Mg)6(Ti)1.3(Si)7(O)24. Quartz and K-feldspar can reach sizes of up to 700 microns. Thus, the fragments can be described as coarse-grained (by chondritic standards). This is especially the case considering that quartz and K-feldspar are very rare minerals in ordinary chondrites. Representative analyses of minerals from some granitoidal clasts are given. Based on the mineral compositions and the modal abundances the bulk compositions were calculated. Besides these granitoidal rocks, pyroxene-rich fragments occur that show exsolution textures that are similar to those found in eucrites.

Bischoff, A.↗

Anomalous REE patterns in unequilibrated enstatite chondrites: Evidence and implications

We present here a study of Rare Earth Element (REE) microdistributions in unequilibrated enstatite chondrites (EOC's). Although the whole rock REE contents are similar in both unequilibrated and equilibrated chondrites, the host minerals of these refractory elements are different. In the least equilibrated ordinary chondrites (UOC's), the REE reside mainly in glass whereas, in their more equilibrated counterparts, the bulk of the REE is in calcium phosphate, a metamorphic mineral that formed by oxidation of phosphorous originally contained in metal. In the smaller group of enstatite (E) chondrites, calcium phosphate is absent and the phase that contains the highest REE concentrations is a minor mineral, CaS (oldhamite), which contains approximately 50 percent of the total Ca present. In E chondrites, elements typically considered to be lithophiles (such as Ca and Mn) occur in sulfides rather than silicates. This indicates formation under extremely reducing conditions, thus in a region of the solar nebula distinct from those that supplied the more abundant ordinary and carbonaceous chondrites. Previously, we observed a variety of REE patterns in the oldhamite of UEC's; they range from almost flat to some with pronounced positive Eu and Yb anomalies. Here, we searched for complementary REE patterns in other minerals from E chondrites and found them in the major mineral, enstatite. Whenever Eu and Yb anomalies are present in this mineral, they are always negative.

Crozaz, Ghislaine↗

Solar wind-induced secondary ions and their relation to lunar surface composition

Based on previous laboratory experiments simulating solar wind sputtering of lunar surface materials, it appears that solar wind ions sputter secondary ions in sufficient numbers to be measured from low-altitude lunar orbit. Solar wind protons are hundreds of times less efficient than those used in standard secondary ion mass spectrometry; nevertheless secondary ions of Na, Mg, Al, Si, K, Ca, Mn, Ti and Fe were observed sputtered from sample simulants of mare and highland soils. These secondary ion fluxes depend both on concentration in the soil and on probability of ionization; yields of easily ionized elements such as K and Na are relatively much greater than those for the more electronegative elements and compounds. The principal geochemical indicator elements Na, Mg, Al, Si, K, Ca, Ti, Mn and Fe are nevertheless detectable. However, it has not been shown that the observed secondary ions vary strictly one-to-one with their concentrations in the geochemically distinct soil simulants used here. While we have a first order understanding of secondary ion sputtering, it is not clear that the observed ion yields can be linked with great accuracy to the simulant's composition. The simulants were analyzed by electron microprobe to establish their detailed composition. The observed secondary ion fluxes can then be compared with the microprobe results. For example Ti(+) fluxes from the three simulants correspond to the true composition with accuracies of better than 10 percent for the high-Ti basalt, and about 20 percent for the low-Ti simulant. The highlands simulant produced a statistically insignificant Ti(+) count rate. Here we discuss the results of further SIMS experiments using the ASU/Center for Solid State Science facility. With careful isolation and preparation of samples, we avoid the problems of the previous experiments. In particular, we will make use of ground-up sample to mimic the sputtering behavior of regolith, and will avoid charging by placing the soil on a conducting indium substrate. We report the results of a blind test of the SIMS technique using a sample of unknown composition.

Elphic, R. C.↗

Optimization of the Processing Parameters of High Temperature Superconducting Glass-Ceramics: Center Director's Discretionary Fund Final Report

A number of promising glass forming compositions of high Tc superconducting Ba-Sr-Ca-Cu-O (BSCCO) materials were evaluated for their glass-ceramic crystallization ability. The BSCCO ceramics belonging to the class of superconductors in the Ba-Sr-Ca-Cu-O system were the focus of this study. By first forming the superconducting material as a glass, subsequent devitrification into the crystalline (glass-ceramic) superconductor can be performed by thermal processing of the glass preform body. Glass formability and phase formation were determined by a variety of methods in another related study. This study focused on the nucleation and crystallization of the materials. Thermal analysis during rapid cooling aids in the evaluation of nucleation and crystallization behavior. Melt viscosity is used to predict glass formation ability.

Ethridge, E. C.↗

Terrestrial Environment (Climatic) Criteria Guidelines for Use in Aerospace Vehicle Development, 1993 Revision

Guidelines on terrestrial environment data specifically applicable in the development of design requirements/specifications for NASA aerospace vehicles and associated equipment development are provided. The primary geographic areas encompassed are the John F. Kennedy Space Center, FL; Vandenberg AFB, CA; Edwards AFB, CA; Michoud Assembly Facility, New Orleans, LA; John C. Stennis Space Center, MS; Lyndon B. Johnson Space Center, Houston, TX; and the White Sands Missile Range, NM. In addition, a section was included to provide information on the general distribution of natural environmental extremes in the conterminous United States that may be needed to specify design criteria in the transportation of space vehicle subsystems and components. A summary of climatic extremes for worldwide operational needs is also included. Although not considered as a specific vehicle design criterion, a section on atmospheric attenuation was added since sensors on certain Earth orbital experiment missions are influenced by the Earth's atmosphere. The latest available information on probable climatic extremes is presented and supersedes information presented in TM X-64589, TM X-64757, TM X-78118, and TM-82473. Information is included on atmospheric chemistry, seismic criteria, and on a mathematical model to predict atmospheric dispersion of aerospace engine exhaust cloud rise and growth. There is also a section on atmospheric cloud phenomena. The information is recommended for use in the development of aerospace vehicle and associated equipment design and operational criteria, unless otherwise stated in contract work specifications. The environmental data are primarily limited to information below 90 km.

Johnson, D. L.↗

Partial melting of ordinary chondrites: Lost City (H) and St. Severin (LL)

Eucrites and diogenites are examples of asteroidal basalts and orthopyroxenites, respectively. As they are found intermingled in howardites, which are inferred to be regolith breccias, eucrites and diogenites are thought to be genetically related. But the details of this relationship and of their individual origins remain controversial. Work by Jurewicz et al. showed that 1170-1180 C partial melts of the (anhydrous) Murchison (CM) chondrite have major element compositions extremely similar to primitive eucrites, such as Sioux County. However, the MnO contents of these melts were about half that of Sioux County, a problem for the simple partial melting model. In addition, partial melting of Murchison could not produce diogenites, because residual pyroxenes in the Murchison experiments were too Fe- and Ca-rich and were minor phases at all but the lowest temperatures. A parent magma for diogenites needs an expanded low-calcium pyroxene field. In their partial melting study of an L6 chondrite, Kushiro and Mysen found that ordinary chondrites did have an expanded low-Ca pyroxene field over that of CV chondrites (i.e., Allende), probably because ordinary chondrites have lower Mg/Si ratios. This study expands that of both Kushiro and Mysen and Jurewicz et al. to the Lost City (H) and St. Severin (LL) chondrites at temperatures ranging from 1170 to 1325 C, at an fO2 of one log unit below the iron-wuestite buffer (IW-1).

Jurewicz, Amy J. G.↗