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At least 919 records · Page 51

Development of an 8-cm engineering model thruster system

Electric propulsion has been shown to offer major advantages over the techniques currently employed for the control of earth satellites. For a user to realize these advantages, however, requires the availability of a proven, operationally flight-ready propulsion system. Currently an Engineering Model of an 8-cm ion thruster propulsion system is under development. The system includes the thruster unit with its associated reservoir, thruster gimbaling subsystem, and power processing unit. This paper describes the EM System with special emphasis on hardware design and system performance.

Herron, B. G.↗

Short-circuit current improvement in thin cells with a gridded back contact

The use of gridded back contact on thin silicon solar cells 50 micrometers was investigated. An unexpected increase in short circuit current of almost 10 percent was experienced for 2 cm x 2 cm cells. Control cells with the standard continuous contact metallization were fabricated at the same time as the gridded back cells with all processes identical up to the formation of the back contact. The gridded back contact pattern was delineated by evaporation of Ti-Pd over a photo-resist mask applied to the back of the wafer; the Ti-Pd film on the controls was applied in the standard fashion in a continuous layer over the back of the cell. The Ti-Pd contacts were similarly applied to the front of the wafer, and the grid pattern on both sides of the cell was electroplated with 8-10 micrometers of silver.

Giuliano, M.↗

The development of an 85-kW (thermal) steam Rankine solar receiver

The receiver is a once-through monotube boiler designed for steam/electric and process steam applications at pressures up to 17.24 MPa (2500 psia) and temperatures up to 704 C (1300 F). The unit is 76.2 cm (30.0 in.) in diameter and 95.8 cm (37.7 in.) in length; it weighs 220 kg (485 lb). Its heat transfer surface, which is 45.7 cm (18 in.) in diameter by 57 cm (22.4 in.) long, is an Inconel 625, cylindrical, tube-coil assembly composed of primary and reheat sections. A test unit was successfully operated at up to 6.9 MPa (1000 psia) and 704 C (1300 F) with solar input from a 11-m-dia parabolic dish concentrator.

Wright, C. C.↗

Discovery of a nitrogen-rich UV-bright star in the globular cluster M5

Observations of a UV bright source in the globular cluster M5 using instrumentation on the Black Brant rocket are reported. Imagery was obtained by two cameras operating at 1540 A and 2360 A and bandpasses of 350 A and 880 A. The instruments are prototypes for cameras to be flown with the Spacelab. The UV-emitting object in the cluster was located off-center. Comparison of the data with data from the IUE for short-wavelength radiation indicated a temperature in the range 25,000-50,000 K, with a dereddened flux for the continuum near 1550 A of 4.2 x 10 to the -13th ergs/sq cm per sec per A. The object is concluded to be a post-AGB star with an envelope which has experienced CNO processing.

Bohlin, R. C.↗

Japan's participation in space station design: Feasibility study of GaAs solar cells for space station applications

The report gives the results of feasibility studies and a cost analysis done on GaAs solar battery cells for space stations. The studies and their results are as follows: (1) Cell size - The 2 x 4 cm cell size was found superior to the 4 x 4 cm cell; (2) Manufacturing technology - Overall, LPE crystal growth was found more suitable than MO-CVD. Current technology for post-growth processes and applying large-area cover glass can be used with few or no modifications; (3) Cell assemblies - Tests for mechanical and thermal stresses encountered from assembly through operation are recommended; (4) Procuring materials - Steps should be taken to avoid sharp price increases due to a speculative gallium market. There are no problems with arsenic materials; (5) Production facilities - The capital investment needed remains to be determined, but a working area of 4000 m2 will be required; (6) Cell costs to be determined; (7) Cell development-supply plan - Two-year lead time will be needed to develop the necessary technology and prepare for production.

Source record↗

A GPS measurement system for precise satellite tracking and geodesy

NASA is pursuing two key applications of differential positioning with the Global Positioning System (GPS): sub-decimeter tracking of earth satellites and few-centimeter determination of ground-fixed baselines. Key requirements of the two applications include the use of dual-frequency carrier phase data, multiple ground receivers to serve as reference points, simultaneous solution for use position and GPS orbits, and calibration of atmospheric delays using water vapor radiometers. Sub-decimeter tracking will be first demonstrated on the TOPEX oceanographic satellite to be launched in 1991. A GPS flight receiver together with at least six ground receivers will acquire delta range data from the GPS carriers for non-real-time analysis. Altitude accuracies of 5 to 10 cm are expected. For baseline measurements, efforts will be made to obtain precise differential pseudorange by resolving the cycle ambiguity in differential carrier phase. This could lead to accuracies of 2 or 3 cm over a few thousand kilometers. To achieve this, a high-performance receiver is being developed, along with improved calibration and data processing techniques. Demonstrations may begin in 1986.

Yunck, T. P.↗

Coronal plasmas on the sun and nearby stars

The current understanding of the quiescent, or non-flaring, microwave emission from solar active regions is summarized. The thermal radiation mechanisms that account for most of the quiescent emission is reviewed, while it is also pointed out that current-amplified magnetic fields or non-thermal radiation may be required in some instances. The 20 cm radiation of coronal loops and the thermal cyclotron lines that accurately specify their magnetic field strength are discussed. The 20 cm and X ray emission of the coronal plasma are then compared. The coronae of nearby stars is next discussed, where coherent radiation processes seem to prevail. Some thoughts toward directions for future exploration are given.

Lang, Kenneth R.↗

The correlation between far-IR and radio continuum emission from spiral galaxies

A sample of 30 galaxies selected for their intense IRAS flux at 60 and 100 micron using the Arecibo telescope at 21 cm to measure the continuum and HI line luminosities were observed. The centimeter wave continuum correlates very well with the far-infrared flux, with a correlation coefficient as high as that found for other samples, and the same ratio between FIR and radio luminosities. Weaker correlations are seen between the FIR and optical luminosity and between the FIR and radio continuum. There is very little correlation between the FIR and the HI mass deduced from the integral of the 21 cm line. The strength of the radio continuum correlation suggests that there is little contribution to either the radio and FIR from physical processes not affecting both. If they each reflect time integrals of the star formation rate then the time constants must be similar, or the star formation rate must change slowly in these galaxies.

Dickey, John M.↗

High-speed assembly language (80386/80387) programming for laser spectra scan control and data acquisition providing improved resolution water vapor spectroscopy

An assembly language program using the Intel 80386 CPU and 80387 math co-processor chips was written to increase the speed of data gathering and processing, and provide control of a scanning CW ring dye laser system. This laser system is used in high resolution (better than 0.001 cm-1) water vapor spectroscopy experiments. Laser beam power is sensed at the input and output of white cells and the output of a Fabry-Perot. The assembly language subroutine is called from Basic, acquires the data and performs various calculations at rates greater than 150 faster than could be performed by the higher level language. The width of output control pulses generated in assembly language are 3 to 4 microsecs as compared to 2 to 3.7 millisecs for those generated in Basic (about 500 to 1000 times faster). Included are a block diagram and brief description of the spectroscopy experiment, a flow diagram of the Basic and assembly language programs, listing of the programs, scope photographs of the computer generated 5-volt pulses used for control and timing analysis, and representative water spectrum curves obtained using these programs.

Allen, Robert J.↗

Infrared Pyrometry From Room Temperature To 700 Degrees C

Consistent readings obtained when specimens prepared appropriately. New method largely overcomes limitations. Transmission of infrared increased by replacing customary metal-coated glass viewing port with quartz viewing port covered with tantalum mesh. Commercially available infrared microscope with focal distance of 53 cm focuses on spot only 1 mm wide on specimen. Microscope operated as radiometer. Output of detector varies by several orders of magnitude, processed by logarithmic amplifier before reading.

Wheeler, Donald R.↗

Infrared diffuse reflectance spectra of carbonaceous chondrites: Amount of hydrous minerals

Infrared diffuse reflectance spectra (2.53-25 microns) of some carbonaceous (C) chondrites were measured. The integrated intensity of the absorption bands near 3 microns caused by hydrous minerals were compared with the modal content of hydrous minerals for the meteorites. The CM and CI chondrites show larger values of the intergated intensity than those of the unique C chondrites Y82162, Y86720 and B7904, suggesting that the amount of hydrous minerals in the CM and CI chondrites is larger, which supports the contention that hydrous minerals were dehydrated by thermal metamorphism in the unique chondrites. Orgueil (CI) has the largest value of the integrated intensity among the C chondrites we measured and shows a sharp absorption band at 3685/cm (2.71 microns) that is not seen in the spectra of the CM chondrites. There is an excellent correlation between the observed hydrogen content in C chondrites and the integrated intensity. The CM chondrites show a wide variation in the strength of absorption bands at 1470/cm (6.8 microns), despite the similarity in absorption features near 3 micron for all CM chondites. The 1470/cm band could be due to the presence of some hydrocarbons but may also be a result of terrestrial alteration processes.

Miyamoto, M.↗

Chromium Diffusion Doping on ZnSe Crystals

Chromium doped zinc selenide crystal have recently been demonstrated to be a promising material for near-IR room temperature tunable lasers which have an emission range of 2-3 micrometers. In this study a new diffusion doping process has been developed for incorporation of Cr(+2) ion into ZnSe wafers. This process has been successfully performed under isothermal conditions, at temperatures above 800 C. Concentrations in excess of 10(exp 19) Cr(+2) ions/cu cm, an order of magnitude larger than previously reported in melt grown ZnSe material, have been obtained by diffusion doping, as estimated from optical absorption measurements. The diffusivity was estimated to be about 10(exp -8) sq cm/sec using a thin film diffusion model. Resistivity was derived from current-voltage measurements and in the range of 10(exp 13) and 10(exp 16) omega-cm. The emission spectra and temperature dependent lifetime data will also be presented and discussed.

Journigan, Troy D.↗

HPLC Characterization of Phenol-Formaldehyde Resole Resin Used in Fabrication of Shuttle Booster Nozzles

A reverse phase High Performance Liquid Chromatographic method was developed to rapidly fingerprint a phenol-formaldehyde resole resin similar to Durite(R) SC-1008. This resin is used in the fabrication of carbon-carbon composite materials from which Space Shuttle Solid Rocket Booster nozzles are manufactured. A knowledge of resin chemistry is essential to successful composite processing and performance. The results indicate that a high quality separation of over 35 peaks in 25 minutes were obtained using a 15 cm Phenomenex LUNA C8 bonded reverse phase column, a three-way water-acetonitrile-methanol nonlinear gradient, and LTV detection at 280 nm.

Young, Philip R.↗

Three-Gorge Reservoir: A 'Controlled Experiment' for Calibration/Validation of Time-Variable Gravity Signals Detected from Space

With the advances of measurements, modern space geodesy has become a new type of remote sensing for the Earth dynamics, especially for mass transports in the geophysical fluids on large spatial scales. A case in point is the space gravity mission GRACE (Gravity Recovery And Climate Experiment) which has been in orbit collecting gravity data since early 2002. The data promise to be able to detect changes of water mass equivalent to sub-cm thickness on spatial scale of several hundred km every month or so. China s Three-Gorge Reservoir has already started the process of water impoundment in phases. By 2009,40 km3 of water will be stored behind one of the world s highest dams and spanning a section of middle Yangtze River about 600 km in length. For the GRACE observations, the Three-Gorge Reservoir would represent a geophysical controlled experiment , one that offers a unique opportunity to do detailed geophysical studies. -- Assuming a complete documentation of the water level and history of the water impoundment process and aided with a continual monitoring of the lithospheric loading response (such as in area gravity and deformation), one has at hand basically a classical forwardinverse modeling problem of surface loading, where the input and certain output are known. The invisible portion of the impounded water, i.e. underground storage, poses either added values as an observable or a complication as an unknown to be modeled. Wang (2000) has studied the possible loading effects on a local scale; we here aim for larger spatial scales upwards from several hundred km, with emphasis on the time-variable gravity signals that can be detected by GRACE and follow-on missions. Results using the Green s function approach on the PREM elastic Earth model indicate the geoid height variations reaching several millimeters on wavelengths of about a thousand kilometers. The corresponding vertical deformations have amplitude of a few centimeters. In terms of long-wavelength spherical harmonics, the induced geoid height variations are very close to the accuracy of GRACE- recoverable gravity field, while the low-degree (2 to 5) harmonics should be detectable. With a large regional time-variable gravity signal, the Three-Gorge experiment can serve as a useful calibration/verification for GRACE (including the elastic loading effects), and future gravity missions (especially for visco-elastic yielding as well as underground water variations).

Chao, Benjamin F.↗

Modeling a Civil Event Case Study for Consequence Management Using the IMPRINT Forces Module

A critical challenge in the Consequence Management (CM) domain is the appropriate allocation of necessary and skilled military and civilian personnel and materiel resources in unexpected emergencies. To aid this process we used the Forces module in the Improved Performance Research Integration Tool (IMPRINT). This module enables analysts to enter personnel and equipment capabilities, prioritized schedules and numbers available, along with unexpected emergency requirements in order to assess force response requirements. Using a suspected terrorist threat on a college campus, we developed a test case model which exercised the capabilities of the module, including the scope and scale of operations. The model incorporates data from multiple sources, including daily schedules and frequency of events such as fire calls. Our preliminary results indicate that the model can predict potential decreases in civilian emergency response coverage due to an involved unplanned incident requiring significant portions of police, fire and civil responses teams.

Gacy, Marc↗

Using a Blender to Assess the Microbial Density of Encapsulated Organisms

There are specific NASA requirements for source-specific encapsulated microbial density for encapsulated organisms in non-metallic materials. Projects such as the Mars Science Laboratory (MSL) that use large volumes of non-metallic materials of planetary protection concern pose a challenge to their bioburden budget. An optimized and adapted destructive hardware technology employing a commercial blender was developed to assess the embedded bioburden of thermal paint for the MSL project. The main objective of this optimization was to blend the painted foil pieces in the smallest sizes possible without excessive heating. The small size increased the surface area of the paint and enabled the release of the maximum number of encapsulated microbes. During a trial run, a piece of foil was placed into a blender for 10 minutes. The outside of the blender was very hot to the touch. Thus, the grinding was reduced to five 2-minute periods with 2-minute cooling periods between cycles. However, almost 20% of the foil fraction was larger (>2 mm). Thus, the largest fractions were then put into the blender and reground, resulting in a 71% increase in particles less than 1 mm in size, and a 76% decrease in particles greater than 2 mm in size. Because a repeatable process had been developed, a painted sample was processed with over 80% of the particles being <2 mm. It was not perceived that the properties (i.e. weight and rubber-like nature) of the painted/foil pieces would allow for a finer size distribution. With these constraints, each section would be ground for a total of 10 minutes with five cycles of a 2-minute pulse followed by a 2-minute pause. It was observed on several occasions that a larger blade affected the recovery of seeded spores by approximately half an order of magnitude. In the standard approach, each piece of painted foil was aseptically removed from the bag and placed onto a sterile tray where they were sized, cut, and cleaned. Each section was then weighed and placed into a sterile Waring Laboratory Blender. Samples were processed on low speed. The ground-up samples were then transferred to a 500-mL bottle using a sterile 1-in. (.2.5-cm) trim brush. To each of the bottles sterile planetary protection rinse solution was added and a modified NASA Standard Assay (NASA HBK 6022) was performed. Both vegetative and spore plates were analyzed.

Benardini, James N.↗

Proton Selective Nanoporous Atomically Thin Graphene Membranes for Vanadium Redox Flow Batteries

Angstrom-scale proton-selective pores in atomically thin 2D materials present fundamentally new opportunities for advancing proton exchange membranes (PEMs). Vanadium Redox Flow Batteries (VRFBs) for grid-scale energy storage require PEMs with high areal proton conductance (>1 S cm −2 ) and minimal vanadium ion (VO 2+ ) crossover. However, state-of-the-art Nafion 212 membranes (N212 ≈50 µm thick), suffer from persistent VO 2+ crossover reducing performance and efficiency. Here, a layered PEM is demonstrated, comprising monolayer CVD graphene with Angstrom-scale proton-selective pores introduced via Ar plasma, integrated with an ultra-thin ≈300 nm polybenzimidazole (PBI) layer and sandwiched between two Nafion 211 (25 µm thick) layers. The layered architecture facilitates scalable membrane fabrication by mitigating defects while processing and facile stacking of graphene layers allows stochastic non-selective defect isolation enabling exceptionally low VO 2+ crossover (selectivity (H + areal conductance / VO 2+ permeability) ≈6709 × 10 6 S min cm −4 ), with proton conductance >8 S cm −2 . Systematic transport experiments supported by resistance-based transport modelling elucidate the role of defect size, defect isolation, and sealing, as well as layering/stacking, to enable orders of magnitude (>671× over N212) improvements in selectivity, along with areal proton conductance >8 S cm −2 . This work highlights the potential of atomic-scale proton-selective defect engineering in 2D materials, in conjunction with facile stacking and layering of materials as strategies for scalable, high-performance advances in PEMs for energy, electrochemical, and separation applications beyond VRFBs.

Chaturvedi, Pavan [Vanderbilt Univ., Nashville, TN↗

Analysis of bipolar membranes for electrochemical CO 2 capture from air and oceanwater

Carbon dioxide (CO 2 ) must be removed from the atmosphere to mitigate the negative effects of climate change. However, the most scalable methods for removing CO 2 from the air require heat from fossil-fuel combustion to produce pure CO 2 and continuously regenerate the sorbent. Bipolar-membrane electrodialysis (BPM-ED) is a promising technology that uses renewable electricity to dissociate water into acid and base to regenerate bicarbonate-based CO 2 capture solutions, such as those used in chemical loops of direct-air-capture (DAC) processes, and in direct-ocean capture (DOC) to promote atmospheric CO 2 drawdown via decarbonization of the shallow ocean. In this study, we develop an experimentally validated 1D model for the electrochemical regeneration of CO 2 from bicarbonate-based carbon capture solutions and seawater using BPM-ED. For DAC, our experimental and computational results demonstrate that pH swings induced by BPM water dissociation drive the formation of CO 2 at the cation-exchange layer|catholyte interface with energy-intensities of less than 150 kJ mol -1 . However, high rates of bubble formation increase energy intensity at current densities >100 mA cm -2 . Correspondingly, accelerating water dissociation catalysis and enacting bubble removal could enable CO 2 recovery at energy intensities <100 kJ mol -1 and current densities >100 mA cm -2 . For DOC, mass transport limitations associated with low carbon concentrations in oceanwater suggest that DOC is best suited for clean production of acid and base usable in downstream processes. Further, these results provide design principles for industrial-scale CO 2 recovery using BPM-ED.

54 ENVIRONMENTAL SCIENCES↗