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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 919 records · Page 51
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

A noninteractive procedure for land-use determination

A complete operational procedure designed for use by the U.S. Army Corps of Engineers for the determination of land-use information for hydrologic planning purposes is reported. The procedure combines photo interpretation techniques and the batch-mode computer analysis of Landsat digital data. Since the operational constraints preclude the use of dedicated, interactive image processing facilities, several novel approaches to geometric correction, classification, and data input/output were developed. The procedure is summarized, and examples of the application of the procedure to urban watersheds are described. In spite of the constraints, the procedure provides results comparable in accuracy and lower in cost than those provided by commercial services using interactive techniques.

Ford, G. E.↗
NASA NTRS1986

Theoretical kinetic computations in complex reacting systems

Nasa Lewis' studies of complex reacting systems at high temperature are discussed. The changes which occur are the result of many different chemical reactions occurring at the same time. Both an experimental and a theoretical approach are needed to fully understand what happens in these systems. The latter approach is discussed. The differential equations which describe the chemical and thermodynamic changes are given. Their solution by numerical techniques using a detailed chemical mechanism is described. Several different comparisons of computed results with experimental measurements are also given. These include the computation of (1) species concentration profiles in batch and flow reactions, (2) rocket performance in nozzle expansions, and (3) pressure versus time profiles in hydrocarbon ignition processes. The examples illustrate the use of detailed kinetic computations to elucidate a chemical mechanism and to compute practical quantities such as rocket performance, ignition delay times, and ignition lengths in flow processes.

Bittker, David A.↗
NASA NTRS1990

An approach for targeting landers and penetrators using orbital optical navigation

Onboard orbital optical navigation data is analyzed with the purpose of generating topographic maps for selecting a landing site. It is suggested that a near-real time orbit-determination process be used for solving a large set of parameters including the spacecraft orbit and primary-body gravity field, the rotational properties of the planetary body, the coordinates of surface features, and the camera-pointing and orientation angles of each picture. A batch-sequential formulation of the standard least-squares problem is employed, along with backward smoothing and a square-root formation filter. An experiment in which over 100 images of Phobos are processed to estimate about 2000 parameters is presented, with emphasis on coordinate systems, transforming points on the reference surface to images in the picture, parameter estimation, and cartographic accuracy.

Wang, Tseng-Chan↗
NASA NTRS1978

LSSA large area silicon sheet task continuous Czochralski process development

A Czochralski crystal growing furnace was converted to a continuous growth facility by installation of a premelter to provide molten silicon flow into the primary crucible. The basic furnace is operational and several trial crystals were grown in the batch mode. Numerous premelter configurations were tested both in laboratory-scale equipment as well as in the actual furnace. The best arrangement tested to date is a vertical, cylindrical graphite heater containing small fused silicon test tube liner in which the incoming silicon is melted and flows into the primary crucible. Economic modeling of the continuous Czochralski process indicates that for 10 cm diameter crystal, 100 kg furnace runs of four or five crystals each are near-optimal. Costs tend to asymptote at the 100 kg level so little additional cost improvement occurs at larger runs. For these conditions, crystal cost in equivalent wafer area of around $20/sq m exclusive of polysilicon and slicing was obtained.

Rea, S. N.↗
DOE OSTI2016

Reconfirmation of frit 803 based on the January 2016 sludge batch 9 reprojection

On January 11, 2016, Savannah River Remediation (SRR) provided the Savannah River National Laboratory (SRNL) with a Sludge Batch 9 (SB9) reprojection that was developed from the analyzed composition of a Tank 51 sample. This sample was collected after field washing had been completed in Tank 51 to support the alternate reductant task. Based on this reprojection, Frit 803 is still a viable option for the processing of SB9 under sludge-only operations and coupled (Actinide Removal Process (ARP) product with and without monosodium titanate (MST)) operations. The maximum projected volumes of ARP product that can be transferred from the Precipitate Reactor Feed Tank (PRFT) per Sludge Receipt and Adjustment Tank (SRAT) batch and the resulting Na 2 O concentrations in the SRAT for coupled operations were determined. The Na 2 O concentrations in the SRAT resulting from the maximum projected ARP product transfer volumes are consistent with those from the previous assessments that were based on the August 2015 projections. Regardless of the presence or absence of MST in the ARP product, the contribution of Na 2 O to the resulting glass will be similar at the same waste loading (WL). These projected volumes of ARP product are not anticipated to be an issue for SB9. The actual transfer volumes from the PRFT to the SRAT are determined based upon the analyzed Na 2 O concentrations in the PRFT samples, which has resulted in larger transfer volumes than those allowed by the projections for Sludge Batch 8 (SB8). An operating window of 32-40% WL around the nominal WL of 36% is achievable for both sludge-only and coupled operations; however, each of the glass systems studied does become limited by waste form affecting constraints (durability) at higher volumes of ARP product and WLs of 41-42%.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

In-situ qualification and physics-based process design for aerosol jet printing via spatially correlated light scattering measurements

Aerosol jet printing is a contactless, digital, and additive technique broadly used for manufacturing flexible, hybrid, and conformal electronics. However, batch-to-batch variability has hindered widespread industry adoption and scaling to production volumes. Recently, light scattering measurements have emerged as a tool to measure aerosol volume fraction – a key parameter determining deposition rate – and have proven an effective feedback source for closed loop control on timescales ranging from minutes to hours. Here, the efficacy of light scattering measurements as a tool for in-situ qualification over shorter time durations is explored. To be the linear relationship between light scattering measurements and deposition rate was validated at 500 ms time intervals, allowing deposition rate to be mapped to positional coordinates and providing a new data stream to drive quality control assessments. Because light scattering measurements are indicative of a physical process parameter, they were substituted into equations for resistance and sheet resistance, resulting in predictions nominally within 10% of measured values for sets of printed devices. Finally, to highlight a more active utility, light scattering measurements were employed in a print repair framework, successfully repairing prints with randomly induced defects to within 5% of the measured resistance of a control set.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Atmosphere Explorer control system software (version 2.0)

The Atmosphere Explorer Control System (AECS) was developed to provide automatic computer control of the Atmosphere Explorer spacecraft and experiments. The software performs several vital functions, such as issuing commands to the spacecraft and experiments, receiving and processing telemetry data, and allowing for extensive data processing by experiment analysis programs. The AECS was written for a 48K XEROX Data System Sigma 5 computer, and coexists in core with the XDS Real-time Batch Monitor (RBM) executive system. RBM is a flexible operating system designed for a real-time foreground/background environment, and hence is ideally suited for this application. Existing capabilities of RBM have been used as much as possible by AECS to minimize programming redundancy. The most important functions of the AECS are to send commands to the spacecraft and experiments, and to receive, process, and display telemetry data.

Mocarsky, W.↗
DOE OSTI2016

The function of Sn(II)-apatite as a Tc immobilizing agent

Technetium-99 is a radioactive contaminant of high concern at many nuclear waste storage sites. At the U.S. Department of Energy Hanford Site, 99Tc is a component of low-activity waste (LAW) fractions of the nuclear tank waste, which are highly caustic, high ionic strength and have high concentrations of chromate. Removal of 99Tc from LAW streams would greatly benefit the site remediation process. In this study, we investigated the removal of 99Tc(VII), as pertechnetate, from deionized water (DIW) and a LAW simulant using two solid sorbents, tin (II) apatite (Sn-A) and SnCl2 through batch sorption testing and solid phase characterization. Sn-A showed higher levels of removal of Tc from both DIW and LAW simulant compared with the SnCl2. Scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/XEDS) and X-ray adsorption spectroscopy (XAS) of Sn-A following batch experiments in DIW showed that TcO4- is reduced to Tc(IV) on the Sn-A surface with no incorporation into the lattice structure of Sn-A. The performance of Sn-A in the LAW simulant was lowered due to a combined effect of the high alkalinity, which lead to an increased dissolution of Sn from the Sn-A, and a preference for the reduction of Cr(VI) over Tc(VII).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

GPU acceleration of hybrid functional calculations in the SPARC electronic structure code

We present a Graphics Processing Unit (GPU)-accelerated version of the real-space SPARC electronic structure code for performing hybrid functional calculations in generalized Kohn–Sham density functional theory. In particular, we develop a batch variant of the recently formulated Kronecker product-based linear solver for the simultaneous solution of multiple linear systems. We then develop a modular, math kernel based implementation for hybrid functionals on NVIDIA architectures, where computationally intensive operations are offloaded to the GPUs, while the remaining workload is handled by the central processing units (CPUs). Considering bulk and slab examples, we demonstrate that GPUs enable up to 8× speedup in node-hours and 80× in core-hours compared to CPU-only execution, reducing the time to solution on V100 GPUs to around 300 s for a metallic system with over 6000 electrons, and significantly reducing the computational resources required for a given wall time.

Kohn-Sham density functional theory↗
DOE OSTI2024

Mercury Testing with Sludge Batch 10 Tank 40 Simulant

Savannah River Mission Completion (SRMC) requested that researchers at Savannah River National Laboratory (SRNL) perform testing designed to examine why the Defense Waste Processing Facility (DWPF) is not collecting elemental mercury in the Mercury Water Wash Tank (MWWT). In order for DWPF to recover mercury, mercuric oxide must first be reduced to elemental mercury. The elemental mercury must then be steam stripped, condense, and coalesce in the Mercury Water Wash Tank (MWWT) during chemical processing in the Sludge Receipt and Adjustment Tank (SRAT). The efficiency of these steps was investigated in a series of laboratory scale SRAT experiments under the nitric-glycolic and nitric-formic flowsheets utilizing Momentive Y-17112 and Antifoam 747. Mercury speciation in the Slurry Mix Evaporator Condensate Tank (SMECT) and condensate streams was also examined. The key conclusions from these experiments are as follows: Mercury II Oxide may not be fully reduced to elemental mercury during acid addition at 93°C. Higher temperatures, i.e., boiling may be necessary to fully reduce Mercury II Oxide. The highest percent mercury recovery (71 %) in the MWWT was observed in the MS-NGA-17112 experiment (nitric-glycolic acid flowsheet with Momentive Y-17112), which is how DWPF is currently operating the SRAT.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2013

The use of carbon stable isotope ratios in drugs characterization

Isotopic Ratio Mass Spectrometry (IRMS) is an effective toll to be used for drug product authentication. The isotopic composition could be used to assist in the differentiation between batches of drugs and assist in the identification of counterfeit materials on the market. Only two factors affect the isotopic ratios in pharmaceutical components: the isotopic composition of the raw materials and the synthetic processes performed upon them. Counterfeiting of pharmaceutical drugs threatens consumer confidence in drug products companies' economical well-being. In this preliminary study, the analyzed samples consist in two types of commercially available analgesics, which were purchases from Romanian pharmacies. Differences in δ{sup 13}C between batches from −29.7 to −31.6% were observed, demonstrating that this method can be used to differentiate among individual drug batches and subsequently identify counterfeits on the market. On the other hand, carbon isotopic ratios differences among producers were recorded, the variations being between −31.3 to −34.9% for the same type of analgesic, but from different manufactures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Simulant Development of Potential 200 West Area Waste Feeds

Preliminary planning for retrieval, qualification, and pretreatment of waste in Hanford’s 200 West Area (200W) has begun as part of the West Area Risk Management project. Experimental studies to technically mature pretreatment process operations will likely be needed because of the uniqueness of 200W waste. Pacific Northwest National Laboratory formulated five simulants to represent 200W-qualified feed based on the preliminary flowsheet provided by Washington River Protection Solutions, LLC. The simulant recipes were devised using applicable historical information as a reference point to support the use of the flowsheet waste vectors, which were combined into five distinct groups. These five groups formed the basis for the liquid composition targets that were adapted into recipes using charged-balanced salt species. The liquid phase recipes were batched in 1-L quantities and analyzed at Pacific Northwest National Laboratory. Once confirmed to be stable, the liquid solutions were tested for compatibility with candidate solid components. Specific solid components were recommended based on cross-examining the proposed solid phases in the flowsheet with relevant data from the literature. Mixtures of solid components were added to aliquots of the liquid batches and sub-sampled to measure particle size distribution. The measured distribution was compared to independently created benchmark distributions appropriate for each simulant. This process was iterated until a solid phase composition that resulted in a representative particle size distribution was found. After the final compositions were confirmed, a suite of chemical and physical characterization data was collected. This report describes the simulant basis, formulation methodology, laboratory measurements, and data collected for the recipes recommended to represent 200W waste feeds.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

A Novel Continuous Ultrasound-Assisted Leaching Process for Rare Earth Element Extraction: Environmental and Economic Assessment

Rare earth elements (REEs) make up integral components in personal electronics, healthcare instrumentation, and modern energy technologies. REE leaching with organic acids is an environmentally friendly alternative to traditional extraction methods. Our previous study demonstrated that batch ultrasound-assisted organic acid leaching of REEs can significantly decrease environmental impacts compared to traditional bioleaching. The batch method is limited to small volumes and is unsuitable for industrial implementation. This study proposes a novel approach to increase reaction volume using a continuous ultrasound-assisted organic acid leaching method. Laboratory experiments showed that continuous ultrasound-assisted leaching increased the leaching rate (µg/h) 11.3–24.5 times compared to our previously reported batch method. Techno-economic analysis estimates the cost of the continuous approach using commercially purchased organic acids is $\$$9465/kg of extracted REEs and $\$$4325/kg of extracted REEs, using gluconic acid and citric acid, respectively. The sensitivity analysis reveals that substituting commercially purchased organic acids with microbially produced biolixiviant can reduce the process cost by approximately 99% while minimally increasing energy consumption. Environmental assessment shows that most of the emissions stemmed from the energy required to power the ultrasound reactor. We concluded that increased leaching capacity using a continuous ultrasound-assisted approach is feasible, but process modifications are needed to reduce the environmental impact.

54 - ENVIRONMENTAL SCIENCES/GLOBAL CLIMATE CHANGE ↗
DOE OSTI2023

Combined Algal Processing for the Synthesis of Liquid Oleofuels and Products (CAPSLOC) - WBS 1.3.4.204

Combined Algal Processing for the Synthesis of Liquid Oleofuels and Products (CAPSLOC) aims to develop a biorefinery concept that is composition-agnostic and enables economically, environmentally, and socially viable biofuel production by maximizing the value from each fraction. To achieve this, we have employed an iterative approach between R&D and TEA/LCA to establish process targets and quantify improvements in the minimum fuel selling price (MFSP), reduce carbon intensity, and support the state of technology (SOT). We have surveyed various methods for biomass pretreatment and successfully demonstrated pre-pilot scale pretreatment in batch mode. Using techniques such as lipid modification, fermentation, mild oxidative treatment (MOT), and carbonization, we have developed biofuel precursors and a range of value-added co-products. Our project has demonstrated significant improvements in key aspects of algae processing, particularly in pretreatment technologies suitable for variable composition, co-products available from lipid and extracted solid streams, conditioning and fermenting high-protein hydrolysates, and recovering nitrogen (N) and phosphorus (P) nutrients for recycling to cultivation ponds. The success of this project will support the commercialization of a sustainable microalgal biorefinery industry.

biofuel↗
DOE OSTI2017

Chromium (VI) reduction in acetate- and molasses-amended natural media: empirical model development

Stimulating indigenous microbes to reduce heavy metals from highly toxic oxidized species to more benign reduced species is a promising groundwater remediation technique that has already seen successful field applications. Designing such a bio-remediation scheme requires a model incorporating the kinetics of nonlinear bio-geochemical interactions between multiple species. With this motivation, we performed a set of microcosm experiments in natural sediments and their indigenous pore water and microbes, generating simultaneous time series for concentrations of Cr(VI), an electron donor (both molasses and acetate were considered), and biomass. Molasses was found to undergo a rapid direct abiotic reaction which eliminated all Cr(VI) before any biomass had time to grow. This was not found in the acetate microcosms, and a distinct zero-order bio-reduction process was observed. Existing models were found inappropriate and a new set of three coupled governing equations representing these process dynamics were developed and their parameters calibrated against the time series from the acetate-amended microcosms. Cell suspension batch experiments were also performed to calibrate bio-reduction rates in the absence of electron donor and sediment. The donor used to initially grow the cells (molasses or acetate) was found not to impact the reduction rate constants in suspension, which were orders of magnitude larger than those explaining the natural media microcosm experiments. This suggests the limited utility of kinetics determined in suspension for remedial design. Scoping studies on the natural media microcosms were also performed, suggesting limited impact of foreign abiotic material and minimal effect of diffusion limitation in the vertical dimension. These analyses may be of independent value to future researchers.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1982

Next generation communications satellites: multiple access and network studies

Efficient resource allocation and network design for satellite systems serving heterogeneous user populations with large numbers of small direct-to-user Earth stations are discussed. Focus is on TDMA systems involving a high degree of frequency reuse by means of satellite-switched multiple beams (SSMB) with varying degrees of onboard processing. Algorithms for the efficient utilization of the satellite resources were developed. The effect of skewed traffic, overlapping beams and batched arrivals in packet-switched SSMB systems, integration of stream and bursty traffic, and optimal circuit scheduling in SSMB systems: performance bounds and computational complexity are discussed.

Meadows, H. E.↗
DOE OSTI2018

Effects of Blending and In-Tank Pretreatment on Direct Feed Hanford High Level Waste Vitrification - 18434

A direct feed high level waste (DFHLW) option is under consideration for early operations of the Hanford Tank Waste Treatment and Immobilization Plant (WTP). In this option, the Pretreatment Facility would be bypassed in order to support an earlier start-up of the HLW Vitrification Facility. For HLW, this would mean that ultrafiltration and caustic leaching that would otherwise have been performed either would not be performed or would be replaced by interim pretreatment functions such as in-tank washings. These changes could result in higher aluminum contents, higher chromium contents, higher fractions of supernate, and lower solids contents in the HLW feed. As a result, glass formulations and downstream vitrification operations will be impacted. In the present work, we investigate the effects of various waste blending and in-tank pretreatment scenarios on DFHLW glass waste loadings, canister counts, and processing rates. Eleven source tanks and five waste groups were selected for the studies of waste blending. In addition, the five waste groups selected were the subjects of an in-tank pretreatment study. Glass property-composition models and melter test data were used to calculate waste loadings, canister counts, processing rates, and treatment durations for a range of DFHLW scenarios. The processing scenarios were defined by the types of waste blending and in-tank pretreatment that were assumed. Blending cases were evaluated that ranged between the 'No Blend' and 'Total Blend' extremes and included pairwise blending (blending of two source tanks, either completely or in various proportions) and macro-batches formed from various combinations of the source tanks. Over 36,000 possible pairwise blending scenarios were evaluated and an optimal retrieval/blending sequence was identified. The waste loading of this optimal sequence is within 0.03 wt% of the 'Total Blend' case. Further, a total of 38 retrieval sequences were identified that have waste loadings within 0.1 wt% of the 'Total Blend' case. To evaluate the effects of in-tank pretreatment, an in-tank wash/settle/decant process was assumed and tank-specific wash factors were employed. Washing of the macro-batch blends gave a general increase in HLW loading, decrease in canister count, and decrease in glass yield. Glass yields are towards the low end of the values expected for the WTP, which could lead to lower than nominal glass production rates. The waste loading increases and canister count reductions with washing were small for two of the wastes indicating that direct treatment of the unwashed waste may be practical. For wastes that are relatively low in sulfate and halides, excessive washing is counterproductive. The results highlight the importance of maintaining high solids content in the HLW feed to maintain glass production rates. The results also illustrate that the optimum washing strategy will need to be evaluated on a tank-to-tank basis. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Characterisation and heat treatment of chloride-contaminated and humidified PuO2 samples

To mimic the reactions that have occurred between plutonium dioxide (PuO2) and degraded polyvinyl chloride during prolonged storage, batches of PuO2 powders with varying specific surface area (4-38m2 g1) were exposed to dry hydrogen chloride gas forming a surface-sorbed exchangeable chloride species that was readily leached by dilute caustic solution. One batch was also humidified under a 95% relative humidity atmosphere. Heat treatment at temperatures between 100 and 950 C steadily reduced the leachable chloride content at least when the initial leachable chloride surface coverage was calculated to be > 0.5 monolayer (ML). Variations between samples are attributed to differences in surface area as well as production route and period of interim storage in air or humidified atmospheres. The data are consistent with surface species and reactions proposed in the literature for HCl adsorption on to TiO2. This indicates that it is interactions between hydrogen chloride/chloride and water/hydroxyl species on the PuO2 surface that are key to understanding the behaviour of these materials when heated in a furnace. These data will inform the design of a future thermal stabilisation process for chloride-contaminated PuO2.

Sutherland-Harper, Sophie↗