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Efficient generation and amplification of intense vortex and vector laser pulses via strongly-coupled stimulated Brillouin scattering in plasmas

The past decade has seen tremendous progress in the production and utilization of vortex and vector laser pulses. Although both are considered as structured light beams, the vortex lasers have helical phase fronts and phase singularities, while the vector lasers have spatially variable polarization states and polarization singularities. In contrast to the vortex pulses that carry orbital angular momentum (OAM), the vector laser pulses have a complex spin angular momentum (SAM) and OAM coupling. Despite many potential applications enabled by such pulses, the generation of high-power/-intensity vortex and vector beams remains challenging. Here, we demonstrate using theory and three-dimensional simulations that the strongly-coupled stimulated Brillouin scattering (SC-SBS) process in plasmas can be used as a promising amplification technique with up to 65% energy transfer efficiency from the pump beam to the seed beam for both vortex and vector pulses. We also show that SC-SBS is strongly polarization-dependent in plasmas, enabling an all-optical polarization control of the amplified seed beam. Additionally, the interaction of such structured lasers with plasmas leads to various angular momentum couplings and decouplings that produce intense new light structures with controllable OAM and SAM. This scheme paves the way for novel optical devices such as plasma-based amplifiers and light field manipulators.

Physics↗

A data-driven model for thermodynamic properties of a steam generator under cycling operation

The varying electricity demand from coal power plants due to the intermittent nature of renewable sources leads to load-follow and on/off operations referred to as cycling. Cycling causes transients of properties such as pressure and temperature within various components of the steam generation system.These transients cause increased damage because of fatigue and creep-fatigue interactions shortening the life of components. An algorithm is developed to identify cycling operations from the gross power data. The data-driven model based on artificial neural networks (ANN) is developed using 10 years data from Coal Creek Station power plant located in North Dakota, USA to estimate properties of the steam generator components during cycling operations. Furthermore, the uniqueness of this model is the ability to predict component properties for the cycling as well as base-load operations and is reported for the first time. The ANN model estimates the component properties, for a given gross power profile and initial conditions, as they vary during cycling operations. As a representative example, the ANN estimates are presented for the superheater outlet pressure, reheater inlet temperature, and flue gas temperature at the air heater inlet. The changes in these variables as a function of the gross power over the time duration are compared with measurements to assess the predictive capability of the model. Mean square errors of 4.49E-04 for superheater outlet pressure, 1.62E-03 for reheater inlet temperature, and 4.14E-04 for flue gas temperature at the air heater inlet were observed.

01 COAL, LIGNITE, AND PEAT↗

New Safety Feedback Control Design to Guarantee Adequate Frequency Performance in Microgrids

Safety analysis of power systems is concerned with the system's ability to maintain critical variables within specified limits following a disturbance. Frequency control adequacy has become increasingly important as the system inertia decreases due to the increase in renewable energy penetration. Various controllers for inverters have been proposed to improve the system frequency response and few are capable to ensure the safety of the response. In this article, a diesel-wind energy system is considered and modeled as a switching system between normal, faulted, and post-fault modes. Further, a safety feedback controller is designed as a supplementary signal for a wind turbine generator such that the speed of the diesel generator stays within a permissible range in the presence of a finite energy disturbance. Numerical results on the modified 33-bus microgrid system obtained of the proposed novel approach indicate that the suggested control configuration can guarantee adequate frequency response without excessive conservativeness.

barrier function↗

A comparative study of two numerical approaches for solving Kim–Kim–Suzuki phase-field models

Among the standard multi-phase multi-component phase-field (PF) methods, the Kim–Kim–Suzuki (KKS) method has the advantage of decoupling interfacial energy from bulk energy and solving concentration as the conserved variable. There are two approaches to numerically solving a KKS method: the global solution approach (GSA) solves all variables in a global system simultaneously, and the local solution approach (LSA) solves phase concentrations locally using a Newton solver. This work compares the performance of LSA and GSA for solving four KKS models of increasing complexity with the finite element method using the MOOSE framework. The solution accuracy, degrees of freedom (DOFs), memory usage, and computational efficiency are compared. We find that GSA and LSA generate similar solutions, with a maximum difference of only 0.34%. For each model, LSA has a lower number of DOFs, utilizes less memory, and less wall time. Additionally, the savings of memory and wall time in LSA increase with increasing mesh density of the same model and are more pronounced in models with higher dimensionality and more nodes. However, GSA is easier to implement in existing codes and can better solve highly nonlinear systems by utilizing sophisticated solvers.

36 MATERIALS SCIENCE↗

CoarsenConf: Equivariant Coarsening with Aggregated Attention for Molecular Conformer Generation

Molecular conformer generation (MCG) is an important task in cheminformatics and drug discovery. The ability to efficiently generate low-energy 3D structures can avoid expensive quantum mechanical simulations, leading to accelerated virtual screenings and enhanced structural exploration. Several generative models have been developed for MCG, but many struggle to consistently produce high-quality conformers for meaningful downstream applications. To address these issues, we introduce CoarsenConf, which coarse-grains molecular graphs based on torsional angles and integrates them into an SE(3)-equivariant hierarchical variational autoencoder. Through equivariant coarse-graining, we aggregate the fine-grained atomic coordinates of subgraphs connected via rotatable bonds, creating a variable-length coarse-grained latent representation. Our model uses a novel aggregated attention mechanism to restore fine-grained coordinates from the coarse-grained latent representation, enabling efficient generation of accurate conformers. Furthermore, we evaluate the chemical and biochemical quality of our generated conformers on multiple downstream applications, including property prediction and large-scale oracle-based protein docking. Overall, CoarsenConf generates more accurate conformer ensembles compared to prior generative models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nickase fidelity drives EvolvR-mediated diversification in mammalian cells

Abstract In vivo genetic diversifiers have previously enabled efficient searches of genetic variant fitness landscapes for continuous directed evolution. However, existing genomic diversification modalities for mammalian genomic loci exclusively rely on deaminases to generate transition mutations within target loci, forfeiting access to most missense mutations. Here, we engineer CRISPR-guided error-prone DNA polymerases (EvolvR) to diversify all four nucleotides within genomic loci in mammalian cells. We demonstrate that EvolvR generates both transition and transversion mutations throughout a mutation window of at least 40 bp and implement EvolvR to evolve previously unreported drug-resistantMAP2K1variants via substitutions not achievable with deaminases. Moreover, we discover that the nickase’s mismatch tolerance limits EvolvR’s mutation window and substitution biases in a gRNA-specific fashion. To compensate for gRNA-to-gRNA variability in mutagenesis, we maximize the number of gRNA target sequences by incorporating a PAM-flexible nickase into EvolvR. Finally, we find a strong correlation between predicted free energy changes underlying R-loop formation and EvolvR’s performance using a given gRNA. The EvolvR system diversifies all four nucleotides to enable the evolution of mammalian cells, while nuclease and gRNA-specific properties underlying nickase fidelity can be engineered to further enhance EvolvR’s mutation rates.

Science & Technology - Other Topics↗

Charting a Path for Research and Development of Reliability and Resilience in South Asia's Power Sector

The power sector in South Asia faces several trends with the potential to impact its reliability and resilience. Rapidly increasing demand, coupled with an increasing reliance on variable renewable resources and the circular linkages with climate change points to an increasing need to understand the extent of climate impacts on both the electricity load and the electricity generation. These larger shifts are also coupled with opportunities near the grid edge that could have a large impact on system planning and operations, such as electrification of the transport sector, increased reliance on buildings to serve a broader set of loads and be flexible resources for utilities, more efficient use of industrial and agricultural loads, and growth in distributed energy resources such as rooftop solar and batteries. It is critical that as this transformation takes place that expectations for reliability and resilience of the grid continue to increase in the region. The South Asia Group for Energy (SAGE), composed of USAID, the US Department of Energy, and three national laboratories, has been tasked with providing an overview of the research and development resources necessary to understand the upcoming challenges for the power system as it pertains to reliability and resilience. This discussion paper identifies some of the key trends and connections that are important for power sector reliability and resilience and provides a starting point for eliciting feedback from power sector stakeholders about their experiences and needs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NASA GLOBE CLOUD GAZE: Creating Data Quality Flags for Citizen Science Cloud Observations Matched to NASA Satellite Data

The GLOBE Program, NASA’s largest and longest lasting citizen science program about the Earth, has been collecting cloud observations matched to multiple satellite data daily. The program’s cloud protocol is historically the most popular protocol as your eyes are the only instruments you need to collect observations of the sky. This dataset includes over 3,300,000 cloud observations with variables like total cloud cover, cloud type and opacity that are collocated to the nearest overpass times of geostationary satellites (GOES-15, GOES-16, GOES-17, Meteosat-8, Meteosat-11, or Himawari-8), or to Clouds and the Earth’s Radiant Energy System (CERES) instruments onboard Aqua and Terra, or the Cloud–Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite. In order to increase the usability of this dataset, the Community science project Leveraging Online and User Data through GLOBE And Zooniverse Engagement (CLOUD GAZE) has been developed to generate data quality flags of these ground-up and top-down perspectives of sky and clouds. Recently funded through NASA’s Citizen Science for Earth Systems Program, CLOUD GAZE has partnered with the Zooniverse online platform to obtain reference data and image tagging of sky photographs collected through The GLOBE Program’s clouds protocol. This paper will present the GLOBE Clouds dataset matched to NASA satellite data, integration of CLOUD GAZE to develop data quality flags, and research applications of the dataset (includes ground-up and top-down perspective comparisons, ground observations of dust storms and smoke plumes, and cloud observations in polar regions). The paper will also present on techniques and recommendations for classroom use and for community engagement, particularly for those looking to online resources.

Marilé Colón Robles↗

REopt Lite User Manual

REopt Lite evaluates the economic viability of grid-connected solar photovoltaics, wind, combined heat and power, and electric and thermal storage at commercial and small industrial sites. It allows building owners to identify the system sizes and dispatch strategies that minimize the site’s life cycle cost of energy. REopt Lite also estimates the amount of time on-site generation and storage can sustain the site's critical load during a grid outage and allows the user the choice of optimizing for energy resilience. It is primarily used to inform project development decisions and to support research on the factors that drive project feasibility for market development and policy analysis. It is available through a web interface, application programing interface, and open-source code. This user manual provides an overview of the model, including its capabilities and typical applications; inputs and outputs; economic calculations; technology descriptions; and model parameters, variables, and equations. The model is highly flexible and is continually evolving to meet the needs of each analysis. Therefore, this report is not an exhaustive description of all capabilities, but rather a summary of the core components of the model.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The National Solar Radiation Database (NSRDB) Fiscal Years 2019-2021(Final Report)

The National Solar Radiation Database (NSRDB) is the leading public source of high-resolution solar resource data in the United States, with more than 166,000 users annually. This database represents the state of the art in satellite-based estimation of solar resource information and uses a unique physics-based modeling approach that enables improvements in accuracy with the deployment of the next-generation geostationary satellites. Making the highest quality, state-of-the-art, regularly updated data sets available on a timely basis for users reduces costs of solar deployment by providing accurate information for siting studies and system output prediction, and thereby reduces levelized cost of energy. Also, high-resolution information from the NSRDB enables moving beyond levelized cost of energy when valuing the impact of renewables on the grid. Additionally, the NSRDB enables the integration of large amounts of solar on the grid by providing critical information about solar availability and variability that is used to enhance grid reliability and power quality.

14 SOLAR ENERGY↗

National Climate Database (NCDB)

The National Climate Database (NCDB) is a high resolution, bias-corrected climate dataset consisting of the three most widely used variables of solar radiation- global horizontal (GHI), direct normal (DNI), and diffuse horizontal irradiance (DHI)- as well as other meteorological data. The goal of the NCDB is to provide unbiased high temporal and spatial resolution climate data needed for renewable energy modeling. The NCDB is modeled using a statistical downscaling approach with Regional Climate Model (RCM)-based climate projections obtained from the North American Coordinated Regional Climate Downscaling Experiment (NA-CORDEX; linked below). Daily climate projections simulated by the Canadian Regional Climate Model 4 (CanRCM4) forced by the second-generation Canadian Earth System Model (CanESM2) for two Representative Concentration Pathways (RCP4.5 or moderate emissions scenario and RCP8.5 or highest baseline emission scenario) are selected as inputs to the statistical downscaling models. The National Solar Radiation Database (NSRDB) is used to build and calibrate statistical models.

Array↗

GLAST and Ground-Based Gamma-Ray Astronomy

The launch of the Gamma-ray Large Area Space Telescope together with the advent of a new generation of ground-based gamma-ray detectors such as VERITAS, HESS, MAGIC and CANGAROO, will usher in a new era of high-energy gamma-ray astrophysics. GLAST and the ground based gamma-ray observatories will provide highly complementary capabilities for spectral, temporal and spatial studies of high energy gamma-ray sources. Joint observations will cover a huge energy range, from 20 MeV to over 20 TeV. The LAT will survey the entire sky every three hours, allowing it both to perform uniform, long-term monitoring of variable sources and to detect flaring sources promptly. Both functions complement the high-sensitivity pointed observations provided by ground-based detectors. Finally, the large field of view of GLAST will allow a study of gamma-ray emission on large angular scales and identify interesting regions of the sky for deeper studies at higher energies. In this poster, we will discuss the science returns that might result from joint GLAST/ground-based gamma-ray observations and illustrate them with detailed source simulations.

McEnery, Julie↗

High–Performance NiCo 2 O 4 /Graphene Quantum Dots for Asymmetric and Symmetric Supercapacitors with Enhanced Energy Efficiency

For the sustainable growth of future generations, energy storage technologies like supercapacitors and batteries are becoming more and more common. However, reliable and high-performance materials’ design and development is the key for the widespread adoption of batteries and supercapacitors. Quantum dots with fascinating and unusual properties are expected to revolutionize future technologies. However, while the recent discovery of quantum dots honored with a Nobel prize in Chemistry, their benefits for the tenacious problem of energy are not realized yet. In this context, herein, chemical-composition tuning enabled exceptional performance of NiCo 2 O 4 (NCO)/graphene quantum dots (GQDs) is reported, which outperform the existing similar materials, in supercapacitors. A comprehensive study is performed on the synthesis, characterization, and electrochemical performance evaluation of highly functional NCO/GQDs in supercapacitors delivering enhanced energy efficiency. The high-performance, functional NCO/GQDs electrode materials are synthesized by the incorporation of GQDs into NCO. The effect of variable amount of GQDs on the energy performance characteristics of NCO/GQDs in supercapacitors is studied systematically. In-depth structural and chemical bonding analyses using X-ray diffraction (XRD) and Raman spectroscopic studies indicate that all the NCO/GQDs composites crystallize in the spinel cubic phase of NiCo 2 O 4 while graphene integration evident in all the NCO/GQDs. The scanning electron microscopy imaging analysis reveals homogeneously distributed spherical particles with a size distribution of 5–9 nm validating the formation of QDs. The high-resolution transmission electron microscopy analyses reveal that the NCOQDs are anchored on graphene sheets, which provide a high surface area of 42.27 m 2 g –1 and high mesoporosity for the composition of NCO/GQDs-10%. In addition to establishing reliable electrical connection to graphene sheets, the NCOQDs provide reliable 3D-conductive channels for rapid transport throughout the electrode as well as synergistic effects. Chemical-composition tuning, and optimization yields NCO/GQDs-10% to deliver the best specific capacitance of 3940 Fg –1 at 0.5 Ag –1 , where the electrodes retain ≈98% capacitance after 5000 cycles. The NCO/GQD-10%//AC asymmetric supercapacitor device demonstrates outstanding energy density and power density values of 118.04 Wh kg –1 and 798.76 W kg –1 , respectively. The NCO/GQDs-10%//NCO/GQDs-10% symmetric supercapacitor device delivers excellent energy and power density of 24.30 Wh kg –1 and 500 W kg –1 , respectively. These results demonstrate and conclude that NCO/GQDs are exceptional and prospective candidates for developing next-generation high-performance and sustainable energy storage devices.

25 ENERGY STORAGE↗

Spatiotemporal Variability in Wind Turbine Blade Leading Edge Erosion

Wind turbine blade leading edge erosion (LEE) reduces energy production and increases wind energy operation and maintenance costs. Degradation of the blade coating and ultimately damage to the underlying blade structure are caused by collisions of falling hydrometeors with rotating blades. The selection of optimal methods to mitigate/reduce LEE are critically dependent on the rates of coating fatigue accumulation at a given location and the time variance in the accumulation of material stresses. However, no such assessment currently exists for the United States of America (USA). To address this research gap, blade coating lifetimes at 883 sites across the USA are generated based on high-frequency (5-min) estimates of material fatigue derived using a mechanistic model and robust meteorological measurements. Results indicate blade coating failure at some sites in as few as 4 years, and that the frequency and intensity of material stresses are both highly episodic and spatially varying. Time series analyses indicate that up to one-third of blade coating lifetime is exhausted in just 360 5-min periods in the Southern Great Plains (SGP). Conversely, sites in the Pacific Northwest (PNW) exhibit the same level of coating lifetime depletion in over three times as many time periods. Thus, it may be more cost-effective to use wind turbine deregulation (erosion-safe mode) for damage reduction and blade lifetime extension in the SGP, while the application of blade leading edge protective measures may be more appropriate in the PNW. Annual total precipitation and mean wind speed are shown to be poor predictors of blade coating lifetime, re-emphasizing the need for detailed modeling studies such as that presented herein.

Pryor, Sara C. (ORCID:0000000348473440)↗

Drying of tundra landscapes will limit subsidence-induced acceleration of permafrost thaw: Modeling Archive

This Modeling Archive is in support of a NGEE Arctic publication in review "Drying of tundra landscapes will limit subsidence-induced acceleration of permafrost thaw". The study used a cryohydrology model to assess the potential risk of abrupt permafrost thaw triggered by melting ground ice, a key open question associated with permafrost response to a warming Arctic. The spatially resolved simulations are for a small catchment 465 ice-wedge polygons in polygonal tundra near Utqiagvik, Alaska in the high-emissions RCP8.5 climate scenario. The simulations are compared to runoff, evapotranspiration and subsidence in the current climate and agree well. The study used the ATS code configured as an intermediate-scale cryohydrology model (Advanced Terrestrial Simulator, Version v2). The archive includes input files for spinup (1985 to 2005) and projections (2006 to 2100 - the manuscript reports 2006 to 2098). Three of the projections include the effects of subsidence and microtopography change with different depth profiles of ice content corresponding to the median, 20th percentile and 80th percentile. The fourth projection has subsidence turnoff and uses the reference case (median) ice content. Spatially averaged or aggregated output variables are included for the projections. Selected checkpoint files for the projections and postprocessing scripts are also included. Files included are *.xml; *.h5; *.exo; *.py; *.sh, *. nb, mesh files, and one file in the original Excel format plus *.csv and *.pdf to conserve formatting contained in the original file. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Diffuse Jovian aurora influenced by plasma injection from Io

The paper demonstrates that the broad band of whistler-mode waves observed within the high density torus surrounding Io is consistent with electron cyclotron generation. Cyclotron resonant instability of Jovian energetic electrons is enhanced due to the lower resonant electron energy within the equatorial high density plasma torus surrounding the orbit of Io. The higher energy resonant electron scattering and the corresponding energetic electron lifetimes indicate that an efficient local acceleration process is required to replenish the precipitating relativistic electrons. Calculated energy deposition into the Jovian atmosphere should provide a dominant source of middle atmospheric ionization and excite a continuous band of diffuse auroral emission. It is suggested that the diffuse Jovian aurora should be influenced by the variable volcanic activity on Io which is thought to be an important source of plasma, since the cyclotron scattering process is strongly influenced by the ambient equatorial thermal plasma density.

Thorne, R. M.↗

Effects of variables upon pyrotechnically induced shock response spectra

Throughout the aerospace industry, large variations of 50 percent (6 dB) or more are continually noted for linear shaped charge (LSC) generated shock response spectra (SRS) from flight data (from the exact same location on different flights) and from plate tests (side by side measurements on the same test). A research program was developed to investigate causes of these large SRS variations. A series of ball drop calibration tests to verify calibration of accelerometers and a series of plate tests to investigate charge and assembly variables were performed. The resulting data were analyzed to determine if and to what degree manufacturing and assembly variables, distance from the shock source, data acquisition instrumentation, and shock energy propagation affect the SRS. LSC variables consisted of coreload, standoff, and apex angle. The assembly variable was the torque on the LSC holder. Other variables were distance from source of accelerometers, accelerometer mounting methods, and joint effects. Results indicated that LSC variables did not affect SRS as long as the plate was severed. Accelerometers mounted on mounting blocks showed significantly lower levels above 5000 Hz. Lap joints did not affect SRS levels. The test plate was mounted in an almost free-free state; therefore, distance from the source did not affect the SRS. Several varieties and brands of accelerometers were used, and all but one demonstrated very large variations in SRS.

Smith, J. L.↗

Energy storage in combined gas-electric energy transitions models: The case of California

California’s vision for a net-zero future by 2045 relies heavily on variable renewable energy systems. Thus, energy storage - particularly long-duration storage - could play a fundamental role in reliably supplying low-carbon electricity. We study energy storage using the BRIDGES model, a combined gas-electric capacity expansion model for California across multiple investment periods (2025-2045), modeled with progressively decreasing carbon emission targets to a zero emissions by 2045. This least-cost optimization model includes renewable gas production via power-to-gas, long-term storage of energy in gaseous form, electric energy storage such as through batteries and hydrogen storage, and renewable energy generation, all with capacity tracking and investment. Multiple scenarios are evaluated to examine the sensitivity of the optimal storage portfolio to system-level and sector-level parameters. The scenario results show that all electric energy storage systems - which vary in storage duration - are deployed and required in a net-zero California in 2045, amounting to around 75 GW of storage capacity. Lithium ion systems make up approximately 80% of this power capacity and supply most short-run storage needs. Hydrogen storage - in the form of a power-to-gas-to-power system - emerges as a replacement to conventional natural gas storage, comprising most of the total energy storage capacity (~ 4 TWh). This capacity is less than 5% of the current natural gas storage capacity (94 TWh), indicating sufficient room for repurposing part of the gas infrastructure. A demand-side sensitivity analysis proves that higher electricity demand correlates with more builds of Li-ion batteries, while higher industrial heat demand leads to more builds of long-duration storage systems in a net-zero economy. Furthermore, power-to-gas systems satisfy part of the industrial heat demand by locally supplying renewable gas, which overtakes the traditional centralized gas storage and transfers through pipelines, casting significant doubts on the future of the large-scale gas infrastructure.

03 NATURAL GAS↗