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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Balancing Water Sustainability and Productivity Objectives in Microalgae Cultivation: Siting Open Ponds by Considering Seasonal Water-Stress Impact Using AWARE-US

Microalgae have great potential as an energy crop. Scaling-up algal biofuel production in the United States (US) should be done with careful attention to water stress. This study evaluates the regional and seasonal water-stress impact of potential algae-pond deployments in the US. Three site-selection strategies focusing on biomass yield, water-use efficiency (WUE), and water-stress impact, respectively, are applied and compared to meet a US algae biomass production target of 30 million metric tons/yr ash-free dry weight, which converts to 20.8 billion L renewable diesel, via hydrothermal liquefaction. Ranking algae ponds based on biomass yield leads to freshwater consumption of 2.66 km3/yr, resulting in the highest water-stress impact (39.1 US equivalent km3). Under the WUE scenario, water consumption is reduced by 81%, but biomass yield is reduced by 12%. In contrast, adding a water-stress constraint to the biomass-yield ranking reduces water consumption by 50% and water-stress impact by 97%, with a small yield reduction (1.7%). Results show that pond location has a significant effect on water stress and that water stress is not proportional to water consumption or yield. Furthermore, capturing seasonal water patterns is critical for planning because sites in water-abundant regions can have short-term but significant water-stress impacts.

algae, Biofuel, water scarcity footprint, hydrothe↗
NASA NTRS1992

Environmental projects. Volume 15: Environmental assessment: Proposed 1-megawatt radar transmitter at the Mars site

The Goldstone Deep Space Communications Complex (GDSCC), located in the Mojave Desert about 64.5 km (40 mi) north of Barstow, California. and about 258 km (160 mi) northeast of Pasadena, California, is part of the National Aeronautics and Space Administration's (NASA's) Deep Space Network (DSN), one of the world's larger and more sensitive scientific telecommunications and radio navigation networks. The Goldstone Complex is managed, technically directed, and operated for NASA by the Jet Propulsion Laboratory (JPL) of the California Institute of Technology in Pasadena, California. Activities at the GDSCC support the operation of six parabolic dish antennas located at five separate sites called Deep Space Stations (DSS's). Four sites, named Echo, Mars, Uranus, and Apollo, are operational for space missions, while the remaining Venus Site is devoted to research and development activities. The Mars Site at the GDSCC contains two antennas: the Uranus antenna (DSS 15, 34 m) and the Mars antenna (DSS 14, 70 m). This present volume deals solely with the DSS-14 Mars antenna. The Mars antenna not only can act as a sensitive receiver to detect signals from spacecraft, but it also can be used in radar astronomy as a powerful transmitter to send out signals to probe the solar system. At present, the Mars antenna operates as a continuous-wave microwave system at a frequency of 8.51 GHz at a power level of 0.5 MW. JPL has plans to upgrade the Mars antenna to a power level of 1 MW. Because of the anticipated increase in the ambient levels of radio frequency radiation (RFR), JPL retained Battelle Pacific Northwest Laboratories (BPNL), Richland, Washington, to conduct an environmental assessment with respect to this increased RFR. This present volume is a JPL-expanded version of the BPNL report titled Environmental Assessment of the Goldstone Solar System Radar, which was submitted to JPL in Nov. 1991. This BPNL report concluded that the operation of the upgraded Mars antenna at the GDSCC, with its increased potential electromagnetic radiation hazards and interferences, would have no significantly adverse biological, physical, or socioeconomic effects on the environment. Thus, a Finding of No Significant Impact (FONSI) is appropriate in accordance with local, State, Federal, and NASA environmental rules and regulations.

Source record↗
NASA NTRS1990

Mission design for an orbiting volcano observatory

The Mission to Planet Earth initiative will require global observation of land, sea, and atmosphere, and all associated phenomena over the coming years; perhaps for decades. A major phenomenon playing a major part in earth's environment is volcanic activity. Orbital observations, including IR, UV, and visible imaging, may be made to monitor many active sites, and eventually increase our understanding of volcanoes and lead to the predictability of eruptions. This paper presents the orbital design and maneuvering capability of a low cost, volcano observing satellite, flying in low earth orbit. Major science requirements include observing as many as 10 to 20 active sites daily, or every two or three days. Given specific geographic locations of these sites, it is necessary to search the trajectory space for those orbits which maximize overflight opportunities. Also, once the satellite is in orbit, it may be desirable to alter the orbit to fly over targets of opportunity. These are active areas which are not being monitored, but which give indications of erupting, or have in fact erupted. Multiple impulse orbital maneuvering methods have been developed to minimize propellant usage for these orbital changes.

Penzo, Paul A.↗
NASA NTRS1998

Strategies and Recommended Targets for Mars Surveyor Program Landing Sites

The two major constraints for selecting the Mars Surveyor Program (MSP) 2001 landing site at the time of this meeting are latitude (30'N to 15S) and elevation (< 2.5 km). The latitude belt will be narrowed down to a 15' sector after this workshop. This mission will demonstrate the capability to perform a precision landing, with the goal of achieving an accuracy of approximately 10 km, 3-sigma. There will be at least two different landing sites ('01 and '03) selected in the MSP. However, there should be an option of having the '05 sample return mission land in a different site and the '05 mission should be equipped with a rover for two reasons. The reasoning behind this follows: '05 lander/rover package should have the option of going to an independent site from either '01 or '03 because predecessor missions (orbital) may locate the "Ultimate Site"; '05 needs a rover to either: (A) explore and sample this "ultimate site" for sample return; (B) retrieve samples from '01 or '03 rovers, as a contingency, in case these rovers malfunction and cannot negotiate the trek back to the sample return vehicle.

Rice, James W., Jr.↗
DOE OSTI2020

Impacts of Voltage-Based Grid Support Functions on Energy Production of PV Customers

This paper presents the impact of inverter grid- support functions (GSFs) on photovoltaic (PV) customer energy production on a real distribution feeder in Oahu, HI. These autonomous GSFs based on local voltage measurements are good alternatives to increase PV hosting capacity. However, these functions can result in PV energy curtailment to the customer, and this study addresses the concerns about the impact of inverter GSFs through detailed quasi-static time series (QSTS) simulations. It proposes four metrics: maximum and average GSF curtailment, average increased generation and average net generation change, to assess the impact of a given control on PV systems located on customer sites. It was found that curtailment of PV production is negligible for customers where peak voltage is within ANSI C84.1 range. A reliable relationship between curtailment and peak customer voltage is demonstrated, suggesting that peak voltage could be used as an indicator of customer curtailment.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Uranium Mill Tailings Radiation Control Act Title II DOE Due Diligence and Lessons Learned from a Previous Site Transfer - 20352

Title II of the Uranium Mill Tailings Radiation Control Act (UMTRCA) established that a government agency will provide perpetual care for closed uranium and thorium ore-processing sites that were operating under an NRC source material license in 1978 or were licensed thereafter. Commercial owners (licensees) operating under an NRC or agreement state specific license when UMTRCA was passed are responsible for conducting reclamation of any byproduct material remaining from uranium-ore processing operations in accordance with an NRC or agreement state approved reclamation plan. Reclamation includes both surface and groundwater remedies. Upon completion of reclamation and approval by NRC, the site is required to be transferred to either the host state or the DOE for long-term surveillance and maintenance. Since UMTRCA's enactment, six Title II sites have been transferred to DOE; an additional 24 Title II sites are anticipated to be transferred before 2050. DoE's role mandated under UMTRCA Title II as the long-term care custodian is to perform 'monitoring, maintenance, and emergency measures necessary to protect the public health and safety.' UMTRCA requires that the licensee pay a long-term surveillance charge 'sufficient to cover the annual costs of site surveillance.' However, at some sites such as the Bluewater, New Mexico, Disposal Site, this mandate has required additional effort and expense by DOE, beyond the originally anticipated and intended scope within UMTRCA, but within the authority of DOE under UMTRCA. In 1997, the Bluewater site became the second UMTRCA Title II site to be transferred to DOE. The site was the location of a uranium mill operated from 1953 until 1982. The specific licensee began site reclamation in 1991, and by 1995 all tailings and contaminated materials were encapsulated in two tailings disposal cells and other disposal areas. In addition to surface contamination, milling activities impacted groundwater in the two upper aquifers. In 1989, the specific licensee attempted active groundwater remediation; however, no significant reduction in contaminant concentrations was observed. As a result, the specific licensee applied to NRC for alternate concentration limits (ACLs) in 1990, which were approved in 1996 as being protective, after additional corrective actions were performed. Since transfer of the Bluewater site to DOE, unforeseen challenges have occurred, requiring additional actions. The first challenge is the occurrence of surface depressions located on the northern section of the main tailings disposal cell. The depressions were first observed during DoE's initial inspection in 1998; however, evidence of these can be observed on satellite images taken prior to transfer. Since being first observed, the depressions have continued to grow both in depth and areal extent. Due to the design of the main tailings disposal cell, the depressions impede storm water from being effectively shed off the 101- hectare (250-acre) top slope of the main tailings disposal cell. Instead, storm water accumulates in the depressions, forming a large ephemeral pond that has stored up to 16.3 x 10{sup 6} liters (4.3 million gallons) of stormwater. The ponding poses a potential risk to the integrity of the main tailings disposal cell in the case of a large storm event, with the potential to cause the pond to overtop and erode the cover material and underlying waste. DOE has taken a number of short-term actions to monitor, measure, and reduce the ponding and is currently working with the US Army Corps of Engineers to design and construct a repair. Additional challenges are associated with groundwater at the Bluewater site. Nine wells were present on the 1335-hectare (3300-acre) site upon transfer. Groundwater compliance was called into question after the State of New Mexico reduced its uranium groundwater standard from 5.0 to 0.03 milligrams per liter in 2004, and when an ACL for uranium was exceeded in a site monitoring well in 2010. Acquiring historical groundwater data and subsequent evaluations as well as additional DOE groundwater monitoring led to installing 10 new monitoring wells and performing additional site hydrogeology recharacterization. DOE continues to evaluate groundwater conditions at the site and works with the NRC to determine regulatory requirements and a path forward. As a result of lessons learned at the Bluewater site and other Title II sites, improved processes have been implemented at a programmatic level to increase due diligence before site transfer and prevent similar issues from occurring at other UMTRCA Title II sites under long-term management. DoE's due diligence process is documented in the Process for Transition of UMTRCA Title II Disposal Sites to DOE for Long-Term Surveillance and Maintenance and is designed to ensure that DOE has no technical or compliance concerns with regulatory decisions that might compromise protectiveness following site transfer to DOE. Implementation of the due diligence process has increased DoE's role prior to site transfer and has been effective in identifying potential issues. Actions by NRC and specific licensees, in response to enhanced due diligence efforts by DOE, are expected to minimize, if not totally prevent, the need for unanticipated actions by DOE pertaining to the surface and groundwater remedies after site transfer. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Soil Temperature and Moisture within the Kougarok Fire Complex, Kougarok Road Mile Marker 86, Seward Peninsula, Alaska, 2019-2023

Daily averages of soil temperature and moisture measured once every hour at different heights located at Intensive Monitoring Stations within the Kougarok Fire Complex, Kougarok Road Mile Marker 86 site. Data were retrieved annually from 2019-2023. Package contains 21 *.CSV data files plus a file level metadata *.CSV, data dictionary *.CSV, data file inventory *.CSV, and sensor location site map *.JPG. Data files have header rows, NaN fields indicate invalid or missing data, and negative vertical offsets are above ground.The Kougarok tundra fire complex (KFC) is located north of Nome and the Kigluaik Mountains, near Quartz Creek and the Kougarok River. The site is accessed by foot from the end of the Nome-Taylor Highway (mile marker 86; also called the Kougarok or Beam Road). The KFC burned in six major fires in the decades since 1950 (Alaska Interagency Coordination Center, unpublished data). Lightning ignited five of these fires (1971, 1997, 2015, and 2019) and one was human caused (2002). The mosaic of overlapping fire scars allows for the study of repeat fires in the tundra which, until recently, was not a common phenomenon outside the boreal forest in Alaska. Our reference unburned tundra fire site is south of the KFC located at mile marker 80 of the Nome-Taylor Highway.The two most recent fires are the Mingvk Lake (2015; 21,698 acres burned from 7/27/2015 to 9/28/2015) and Garfield Creek (2019; 422 acres burned from 7/31/2019 to 8/20/19). The Mingvk Lake fire scar includes areas that burned 1-4x (1971, 1997, 2002), while the entirety of the Garfield Creek fire scar has burned 2x previously (1971, 2002).Previous research at the KFC focused on permafrost (Liljedahl et al. 2007; Narita et al. 2015; Iwahana et al. 2016; Tsuyuzaki, Iwahana, and Saito 2017) and vegetation (Narita et al. 2015; Hollingsworth et al. 2021) response to fire. The central Seward Peninsula is characterized by continuous permafrost with a thickness of 15 to 30 m and a mean active layer thickness of 56 cm (Hinzman et al. 2003). Sloping hills with mixed shrub–tussock tundra and tussock tundra vegetation in the uplands are characteristic of the region. Three micrometeorological towers near the Kougarok field site recorded a mean annual temperature of −2.4°C, mean January temperature of −23.1°C, mean July temperature of +11°C, and mean summer rainfall (June–August) of 94 mm from 2000 to 2006 (Liljedahl et al. 2007).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Whole-Voltage-Range Oxygen Redox in P2-Layered Cathode Materials for Sodium-Ion Batteries

Oxygen-redox of layer-structured metal-oxide cathodes has drawn great attention as an effective approach to break through the bottleneck of their capacity limit. However, reversible oxygen-redox can only be obtained in the high-voltage region (usually over 3.5 V) in current metal-oxide cathodes. Here, we realize reversible oxygen-redox in a wide voltage range of 1.5-4.5 V in a P2-layered Na 0.7 Mg 0.2 [Fe 0.2 Mn 0.6 $\square$0.2]O 2 cathode material, where intrinsic vacancies are located in transition-metal (TM) sites and Mg-ions are located in Na sites. Mg-ions in the Na layer serve as "pillars" to stabilize the layered structure during electrochemical cycling, especially in the high-voltage region. Intrinsic vacancies in the TM layer create the local configurations of "$\square$-O-$\square$", "Na-O-$\square$" and "Mg-O-$\square$" to trigger oxygen-redox in the whole voltage range of charge-discharge. Additionally, time-resolved techniques demonstrate that the P2 phase is well maintained in a wide potential window range of 1.5-4.5 V even at 10 C. It is revealed that charge compensation from Mn- and O-ions contributes to the whole voltage range of 1.5-4.5 V, while the redox of Fe-ions only contributes to the high-voltage region of 3.0-4.5 V. The orphaned electrons in the nonbonding 2p orbitals of O that point toward TM-vacancy sites are responsible for reversible oxygen-redox, and Mg-ions in Na sites suppress oxygen release effectively.

25 ENERGY STORAGE↗
DOE OSTI2023

Structures of the DarR transcription regulator reveal unique modes of second messenger and DNA binding

The mycobacterial repressor, DarR, a TetR family regulator (TFR), was the first transcription regulator shown to bind c-di-AMP. However, the molecular basis for this interaction and the mechanism involved in DNA binding by DarR remain unknown. Here we describe DarR-c-di-AMP and DarR-DNA structures and complementary biochemical assays. The DarR-c-di-AMP structure reveals a unique effector binding site for a TFR, located between DarR dimer subunits. Strikingly, we show this motif also binds cAMP. The location of the adenine nucleotide binding site between subunits suggests this interaction may facilitate dimerization and hence DNA binding. Indeed, biochemical assays show cAMP enhances DarR DNA binding. Finally, DarR-DNA structures reveal a distinct TFR DNA-binding mechanism involving two interacting dimers on the DNA. Thus, the combined data unveil a newly described second messenger binding motif and DNA binding mode for this important family of regulators.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2012

Three-Dimensional Analysis of Deep Space Network Antenna Coverage

There is a need to understand NASA s Deep Space Network (DSN) coverage gaps and any limitations to provide redundant communication coverage for future deep space missions, especially for manned missions to Moon and Mars. The DSN antennas are required to provide continuous communication coverage for deep space flights, interplanetary missions, and deep space scientific observations. The DSN consists of ground antennas located at three sites: Goldstone in USA, Canberra in Australia, and Madrid in Spain. These locations are not separated by the exactly 120 degrees and some DSN antennas are located in the bowl-shaped mountainous terrain to shield against radiofrequency interference resulting in a coverage gap in the southern hemisphere for the current DSN architecture. To analyze the extent of this gap and other coverage limitations, simulations of the DSN architecture were performed. In addition to the physical properties of the DSN assets, the simulation incorporated communication forward link calculations and azimuth/elevation masks that constrain the effects of terrain for each DSN antenna. Analysis of the simulation data was performed to create coverage profiles with the receiver settings at a deep space altitudes ranging from 2 million to 10 million km and a spherical grid resolution of 0.25 degrees with respect to longitude and latitude. With the results of these simulations, two- and three-dimensional representations of the area without communication coverage and area with coverage were developed, showing the size and shape of the communication coverage gap projected in space. Also, the significance of this communication coverage gap is analyzed from the simulation data.

Kegege, Obadiah↗
DOE OSTI2021

Assessment of Contaminant Bioaccumulation in Aquatic Biota on and Adjacent to the Oak Ridge Reservation—2020

This report provides information on contaminant concentrations in multiple wildlife prey species inhabiting or associated with water bodies on and downstream from the Oak Ridge Reservation (ORR), including regional reference sites. This information can be used to understand the nature and extent of contaminant exposure and transfer through the food web and to provide a baseline for evaluating temporal trends in contaminant exposure and accumulation. This information was gathered as part of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Five-Year Review (FYR) process, and it also addresses regulator comments on the annual Remediation Effectiveness Report (RER). This report summarizes the results of biological sampling completed in the spring and summer of 2020, prior to the 2021 FYR. Sampled locations included key sites upstream from the point sources of contaminants, along with watershed integration points on and off the ORR. Integration points are spatially the most important sampling sites because they capture biological responses to upstream contaminant inputs from both aqueous and groundwater sources, as well as responses to various remedial actions. These sites are most often located at a watershed administration unit boundary and may have regulatory significance for performance measures. In many cases, there are long-term biological and other monitoring data associated with these sites; these data generally fall within the areas of exposure and effects.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2018

Spatial Representativeness Error in the Ground-Level Observation Networks for Black Carbon Radiation Absorption

There is high uncertainty in the direct radiative forcing of black carbon (BC), an aerosol that strongly absorbs solar radiation. The observation-constrained estimate, which is several times larger than the bottom-up estimate, is influenced by the spatial representativeness error due to the mesoscale inhomogeneity of the aerosol fields and the relatively low resolution of global chemistry-transport models. Here we evaluated the spatial representativeness error for two widely used observational networks (AErosol RObotic NETwork and Global Atmosphere Watch) by downscaling the geospatial grid in a global model of BC aerosol absorption optical depth to 0.1° × 0.1°. Comparing the models at a spatial resolution of 2° × 2° with BC aerosol absorption at AErosol RObotic NETwork sites (which are commonly located near emission hot spots) tends to cause a global spatial representativeness error of 30%, as a positive bias for the current top-down estimate of global BC direct radiative forcing. By contrast, the global spatial representativeness error will be 7% for the Global Atmosphere Watch network, because the sites are located in such a way that there are almost an equal number of sites with positive or negative representativeness error.

Wang, Rong↗
NASA NTRS2012

NASA's Next Generation Space Geodesy Network

NASA's Space Geodesy Project (SGP) is developing a prototype core site for a next generation Space Geodetic Network (SGN). Each of the sites in this planned network co-locate current state-of-the-art stations from all four space geodetic observing systems, GNSS, SLR, VLBI, and DORIS, with the goal of achieving modern requirements for the International Terrestrial Reference Frame (ITRF). In particular, the driving ITRF requirements for this network are 1.0 mm in accuracy and 0.1 mm/yr in stability, a factor of 10-20 beyond current capabilities. Development of the prototype core site, located at NASA's Geophysical and Astronomical Observatory at the Goddard Space Flight Center, started in 2011 and will be completed by the end of 2013. In January 2012, two operational GNSS stations, GODS and GOON, were established at the prototype site within 100 m of each other. Both stations are being proposed for inclusion into the IGS network. In addition, work is underway for the inclusion of next generation SLR and VLBI stations along with a modern DORIS station. An automated survey system is being developed to measure inter-technique vectorties, and network design studies are being performed to define the appropriate number and distribution of these next generation space geodetic core sites that are required to achieve the driving ITRF requirements. We present the status of this prototype next generation space geodetic core site, results from the analysis of data from the established geodetic stations, and results from the ongoing network design studies.

Desai, S. D.↗
NASA NTRS1982

Radar prediction of absolute rain fade distributions for earth-satellite paths and general methods for extrapolation of fade statistics to other locations

The first absolute rain fade distribution method described establishes absolute fade statistics at a given site by means of a sampled radar data base. The second method extrapolates absolute fade statistics from one location to another, given simultaneously measured fade and rain rate statistics at the former. Both methods employ similar conditional fade statistic concepts and long term rain rate distributions. Probability deviations in the 2-19% range, with an 11% average, were obtained upon comparison of measured and predicted levels at given attenuations. The extrapolation of fade distributions to other locations at 28 GHz showed very good agreement with measured data at three sites located in the continental temperate region.

Goldhirsh, J.↗
NASA NTRS1984

Patterns of magnetic field merging sites on the magnetopause

Models of the magnetospheric and magnetosheath magnetic fields are used to determine the relative orientations of the two near the dayside magnetopause for the purpose of locating potential merging sites. Areas of the magnetopause with various degrees of antiparallelness for different Interplanetary fields as contour diagrams are studied. For southward and GSE-Y interplanetary field, the patterns obtained are consistent with those envisioned by Crooker in an earlier analysis which used simplified representations for the magnetic field geometry. Here the application of realistic models shows the locations of areas where any antiparallel component occurs. Merging sites for radial interplanetary fields are also illustrated. The results suggest that the geometrical configuration of the fields is suitable for merging over a large fraction of the magnetopause for interplanetary fields that are either primarily southward, GSE-Y, or radial (GSE-X) in direction.

Luhmann, J. G.↗
NASA NTRS1973

Application of remote sensing

Remote sensing and aerial photographic interpretation are discussed along with the specific imagery techniques used for this research. The method used to select sites, the results of data analyses for the Houston metropolitan area, and the location of dredging sites along the Houston Ship Channel are presented. The work proposed for the second year of the project is described.

Graff, W. J.↗
NASA NTRS1984

Patterns of potential magnetic field merging sites on the dayside magnetopause

Models of the magnetospheric and magnetosheath magnetic fields are used to determine the relative orientations of these fields at the dayside magnetopause in order to locate potential merging sites. Areas on the magnetopause with different fractional antiparallel components are displayed by contour diagrams for a variety of interplanetary field orientations. For interplanetary fields oriented perpendicular to the solar wind velocity the areas of nearly antiparallel field agree with those obtained by Crooker using simplified representations for the magnetic field geometry. Here, the application of more realistic models gives the locations of areas where any antiparallel component occurs. Potential merging sites for interplanetary fields with radial components are also illustrated. The results suggest that the topology of the magnetosheath and magnetospheric fields provides antiparallel components over a substantial fraction of the magnetopause for most interplanetary field orientations.

Luhmann, J. G.↗
NASA NTRS2016

Variation in Global Chemical Composition of PM2.5: Emerging Results from SPARTAN

The Surface PARTiculate mAtter Network (SPARTAN) is a long-term project that includes characterization of chemical and physical attributes of aerosols from filter samples collected worldwide. This paper discusses the ongoing efforts of SPARTAN to define and quantify major ions and trace metals found in fine particulate matter (PM (sub 2.5). Our methods infer the spatial and temporal variability of PM (sub 2.5) in a cost-effective manner. Gravimetrically weighed filters represent multi-day averages of PM (sub 2.5), with a collocated nephelometer sampling air continuously. SPARTAN instruments are paired with AErosol RObotic NETwork (AERONET) sun photometers to better understand the relationship between ground-level PM (sub 2.5) and columnar aerosol optical depth (AOD). We have examined the chemical composition of PM (sub 2.5) at 12 globally dispersed, densely populated urban locations and a site at Mammoth Cave (US) National Park used as a background comparison. So far, each SPARTAN location has been active between the years 2013 and 2016 over periods of 2-26 months, with an average period of 12 months per site. These sites have collectively gathered over 10 years of quality aerosol data. The major PM (sub 2.5) constituents across all sites (relative contribution plus or minus Standard Deviation) are ammoniated sulfate (20 percent plus or minus 11 percent), crustal material (13.4 percent plus or minus 9.9 percent), equivalent black carbon (11.9 percent plus or minus 8.4 percent), ammonium nitrate (4.7 percent plus or minus 3.0 percent), sea salt (2.3 percent plus or minus 1.6 percent), trace element oxides (1.0 percent plus or minus 1.1 percent), water (7.2 percent plus or minus 3.3 percent) at 35 percent relative humidity, and residual matter (40 percent plus or minus 24 percent). Analysis of filter samples reveals that several PM (sub 2.5) chemical components varied by more than an order of magnitude between sites. Ammoniated sulfate ranges from 1.1 microns per cubic meter (Buenos Aires, Argentina) to 17 microns per cubic meter (Kanpur, India in the dry season). Ammonium nitrate ranged from 0.2 microns per cubic meter (Mammoth Cave, in summer) to 6.8 microns per cubic meter (Kanpur, dry season). Equivalent black carbon ranged from 0.7 microns per cubic meter (Mammoth Cave) to over 8 microns per cubic meter (Dhaka, Bangladesh and Kanpur, India). Comparison of SPARTAN vs. coincident measurements from the Interagency Monitoring of Protected Visual Environments (IMPROVE) network at Mammoth Cave yielded a high degree of consistency for daily PM (sub 2.5) (r squared equals 0.76, slope equals 1.12), daily sulfate (r squared equals 0.86, slope equals 1.03), and mean fractions of all major PM (sub 2.5) components (within 6 percent). Major ions generally agree well with previous studies at the same urban locations (e.g. sulfate fractions agree within 4 percent for 8 out of 11 collocation comparisons). Enhanced anthropogenic dust fractions in large urban areas (e.g. Singapore, Kanpur, Hanoi, and Dhaka) are apparent from high Zn to Al ratios. The expected water contribution to aerosols is calculated via the hygroscopicity parameter kappa (sub v (volume)) for each filter. Mean aggregate values ranged from 0.15 (Ilorin) to 0.28 (Rehovot). The all-site parameter mean is 0.20 plus or minus 0.04. Chemical composition and water retention in each filter measurement allows inference of hourly PM (sub 2.5) at 35 percent relative humidity by merging with nephelometer measurements. These hourly PM (sub 2.5) estimates compare favourably with a beta attenuation monitor (MetOne) at the nearby US embassy in Beijing, with a coefficient of variation r squared equals 0.67 (number equals 3167), compared to r squared equals 0.62 when v (volume) was not considered. SPARTAN continues to provide an open-access database of PM (sub 2.5) compositional filter information and hourly mass collected from a global federation of instruments.

Snider, Graydon↗