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At least 901 records · Page 50

An implicit, sharp numerical treatment of viscous terms at arbitrarily shaped liquid-gas interfaces in evaporative flows

We report a novel methodology for accurate treatment of viscous terms in evaporation problems. The proposed scheme is an extension of the sharp viscous treatment of Kang et al. (2000) [7] to 3D phase change problems. To ensure accuracy and grid converging solutions, a new implicit approach to computing viscous fluxes across the phase interfaces is proposed, which was previously unavailable in fixed grid numerical schemes. Analytical relations were derived for the jump in velocity gradients across the 2D and 3D phase interfaces, an important constituent of the proposed scheme. The relations show a non-vanishing jump in the tangential gradients across the phase interface that are associated with evaporative flux and interfacial curvature. The proposed methodology demonstrated first order accuracy in canonical test cases. It is general and applicable to arbitrarily oriented interfaces, and can be readily implemented in existing evaporation flow solvers.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Harvest legacies and climate change interact to shape forest structure and biomass through time

Forest structural change driven by climate trends has been observed worldwide and is expected to increase in the future. Management of forest structure has been an important tool for mitigating the impacts of climate change but forest structure may shift independently of management goals as it interacts with climate change. Here, we investigated the long-term impacts of harvest-based management strategies on structure and resistance to climate-induced biomass loss using a process-based ecosystem model for a midwestern USA hardwood forest. We identified aboveground biomass loss events and compared the cumulative number of these events following a five-year period of active management under four management strategies and two climate change scenarios. Management legacy had the clearest impact on climate-driven biomass loss over the mid-term (∼25 years) with the shelterwood scenario experiencing no loss events during this period. However, by the end of the century legacy effects faded and climate change severity became the driver of differences as greater warming scenarios experienced twice the loss events, and end-of-century loss events were 3–10 times more frequent than mid-century events. We found that while structure was distinct among harvest scenarios through the mid-century, differences were negligible by the end-of-century; identical to when management correlated with loss event frequency. Here, we found that loss events were preceded by a drop in precipitation two years prior, while no specific forest structure preceded a loss event. However, the structures preceding a biomass loss event were distinct across different legacies, implying additional influences of past management.

54 ENVIRONMENTAL SCIENCES↗

Storylines for the 1997 New Year’s Flood: The role of watershed antecedent conditions and future warming in shaping discharge in the Truckee River watershed

The 1997 New Year’s flood was among the most devastating floods in the Truckee River watershed located in western Nevada. This event resulted from complex interactions of flood drivers, such as extreme precipitation, wet antecedent watershed conditions, warm temperatures and rapid snowmelt. We leveraged simulated forcings from the regionally refined mesh capabilities of the Energy Exascale Earth System Model (RRM-E3SM) and a process-based hydrological model to recreate the 1997 New Year’s flood for the Truckee River watershed across four climate warming levels ranging from the current temperatures to + 4° C. For each scenario, we conducted ensemble simulations with the same forcing but with 100 different seasonal watershed antecedent conditions, which were randomly sampled from long-term hydrological simulations. The results show that the 1997 New Year’s flood can be reproduced or exceeded consistently only when the antecedent watershed conditions are wet, specifically when streamflows are above the 75th percentile of the climatological value. There is negligible change in ensemble mean peakflows for Truckee River near Reno; however, there are increases of 18% and 14% under the warming levels of + 3° C and + 4° C, respectively. The increases in peakflows under future climate warming are attributed to wetter antecedent watershed conditions and enhanced snowmelt. Furthermore, the largest increases in peakflows occur at small, high-elevation headwater basins along the Sierra Nevada crest. This study highlights that changes in extreme flood events will result from the complex interplay of multiple flood drivers. It also demonstrates the potential of storyline approaches to analyze future realizations of these extreme events under different climate scenarios.

Climate change impact study↗

How alkyl branching shapes structure in imidazolium and pyrrolidinium NTf 2 ionic liquids

High-energy X-ray scattering experiments and molecular dynamics (MD) simulations were carried out on ionic liquids (ILs) consisting of 1-alkyl-3-methylimidazolium and 1-alkyl-1-methylpyrrolidinium cations. These cations were paired with bis(trifluoromethylsulfonyl)amide anions and identical alkyl tails were used for both cationic species. The goal of this work is to investigate how the nanoscale structure of the ionic liquid changes with the length and with the degree of branching of the alkyl tail, for ILs having a common anion. We investigate spatial correlations in the intermolecular region, focusing on the intrinsic charge-charge interactions that characterize all ionic liquids, as well as the nanoscale domain segregation that is present in IL species with significant nonpolar components.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗