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At least 901 records · Page 50

Are Milky-Way-like galaxies like the Milky Way? A view from SDSS-IV/MaNGA

ABSTRACT In this paper, we place the Milky Way (MW) in the context of similar-looking galaxies in terms of their star-formation and chemical evolution histories. We select a sample of 138 Milky Way analogues (MWAs) from the SDSS-IV/MaNGA survey based on their masses, Hubble types, and bulge-to-total ratios. To compare their chemical properties to the detailed spatially-resolved information available for the MW, we use a semi-analytic spectral fitting approach, which fits a self-consistent chemical-evolution and star-formation model directly to the MaNGA spectra. We model the galaxies’ inner and outer regions assuming that some of the material lost in stellar winds falls inwards. We also incorporate chemical enrichment from type II and Ia supernovae to follow the alpha-element abundance at different metallicities and locations. We find some MWAs where the stellar properties closely reproduce the distribution of age, metallicity, and alpha enhancement at both small and large radii in the MW. In these systems, the match is driven by the longer time-scale for star formation in the outer parts, and the inflow of enriched material to the central parts. However, other MWAs have very different histories. These divide into two categories: self-similar galaxies where the inner and outer parts evolve identically; and centrally-quenched galaxies where there is very little evidence of late-time central star formation driven by material accreted from the outer regions. We find that, although selected to be comparable, there are subtle morphological differences between galaxies in these different classes, and that the centrally-quenched galaxies formed their stars systematically earlier.

79 ASTRONOMY AND ASTROPHYSICS↗

Imaging with HST the Time Evolution of Eta Carinae's Colliding Winds

We report new HST/STIS observations that map the high-ionization forbidden line emission in the inner arcsecond of Eta Car, the first that fully image the extended wind-wind interaction region of the massive colliding wind binary. These observations were obtained after the 2009.0 periastron at orbital phases 0.084, 0.163, and 0.323 of the 5.54-year spectroscopic cycle. We analyze the variations in brightness and morphology of the emission, and find that blue-shifted emission (-400 to -200 km/s is symmetric and elongated along the northeast-southwest axis, while the red-shifted emission (+ 100 to +200 km/s) is asymmetric and extends to the north-northwest. Comparison to synthetic images generated from a 3-D dynamical model strengthens the 3-D orbital orientation found by Madura et al. (2011), with an inclination i approx. 138deg, argument of periapsis omega approx. 270deg, and an orbital axis that is aligned at the same PA on the sky as the symmetry axis of the Homunculus, 312deg. We discuss the potential that these and future mappings have for constraining the stellar parameters of the companion star and the long-term variability of the system.

Gull, Theodore R.↗

Domain Nucleation and Growth in an Epitaxially Grown Wurtzite Ferroelectric

Ferroelectric domain nucleation and growth in epitaxial (Al, B, Sc)N films grown on n-GaN substrates are explored using a combination of ferroelectric property measurements and scanning transmission electron microscopy, including novel in situ switching studies. The films are electrically switched to nitrogen-polar (N-polar) and metal-polar (M-polar) configurations, attaining a remanent polarization of 120 µC cm −2 with coercive fields of ≈6 MV cm −1 . In the initial switching cycle, the ferroelectric domains nucleate near the bottom n-GaN electrode and develop domain walls with zigzag morphologies, while residual “dead layers” that do not switch from the as-deposited orientation persist at the top and bottom electrodes. The in situ microscopy experiments reveal that domain walls propagate fastest in the lateral direction, parallel to the electrode/film interface. These findings provide insights into the domain dynamics and structural evolution of wurtzite ferroelectrics, offering implications for next-generation electronic devices.

36 MATERIALS SCIENCE↗

Crystal structure of a guanine nucleotide exchange factor encoded by the scrub typhus pathogen Orientia tsutsugamushi

Rho family GTPases regulate an array of cellular processes and are often modulated by pathogens to promote infection. In this work, we identify a cryptic guanine nucleotide exchange factor (GEF) domain in the OtDUB protein encoded by the pathogenic bacterium Orientia tsutsugamushi. A proteomics-based OtDUB interaction screen identified numerous potential host interactors, including the Rho GTPases Rac1 and Cdc42. We discovered a domain in OtDUB with Rac1/Cdc42 GEF activity (OtDUB GEF ), with higher activity toward Rac1 in vitro. While this GEF bears no obvious sequence similarity to known GEFs, crystal structures of OtDUB GEF alone (3.0 Å) and complexed with Rac1 (1.7 Å) reveal striking convergent evolution, with a unique topology, on a V-shaped bacterial GEF fold shared with other bacterial GEF domains. Structure-guided mutational analyses identified residues critical for activity and a mechanism for nucleotide displacement. Ectopic expression of OtDUB activates Rac1 preferentially in cells, and expression of the OtDUBGEF alone alters cell morphology. Cumulatively, this work reveals a bacterial GEF within the multifunctional OtDUB that co-opts host Rac1 signaling to induce changes in cytoskeletal structure.

59 BASIC BIOLOGICAL SCIENCES↗

Conditional filamentation as an adaptive trait of bacteria and its ecological significance in soils

Bacteria can regulate cell morphology in response to environmental conditions, altering their physiological and metabolic characteristics to improve survival. Conditional filamentation, in which cells suspend division while continuing lateral growth, is a strategy with a range of adaptive benefits. Here, we review the causes and consequences of conditional filamentation with respect to bacterial physiology, ecology and evolution. We describe four major benefits from conditional filamentation: stress tolerance, surface colonization, gradient spanning and the facilitation of biotic interactions. Adopting a filamentous growth habit involves fitness trade-offs which are also examined. We focus on the role of conditional filamentation in soil habitats, where filamentous morphotypes are highly prevalent and where environmental heterogeneity can benefit a conditional response. Here, to illustrate the use of information presented in our review, we tested the conditions regulating filamentation by the forest soil isolate Paraburkholderia elongata 5N T . Filamentation by P. elongata was induced at elevated phosphate concentrations, and was associated with the accumulation of intracellular polyphosphate, highlighting the role of filamentation in a phosphate-solubilizing bacterium. Conditional filamentation enables bacteria to optimize their growth and metabolism in environments that are highly variable, a trait that can impact succession, symbioses, and biogeochemistry in soil environments.

59 BASIC BIOLOGICAL SCIENCES↗

The Surface Roughness of Terrains on Mars

The RMS roughness measurements produced by Neumann et al. from Mars Orbiter Laser Altimeter (MOLA) data provide unique information about surface height variations at an effective length scale of < 75 m. Roughness at this scale is important not only for landing site safety considerations, but also for assessment of landscape evolution, which depends on emplacement mechanisms and erosional/depositional processes. Here we present an examination of the global surface roughness map with discussion of terrain types and potential formation and/or alteration mechanisms. Spatially coherent terrain types were identified based on inspection of the roughness map. These terrains were further characterized through analysis of morphology and geology using MOLA topography, MOC wide-angle, and MOC narrow-angle images as well as the geologic maps produced by Scott & Tanaka and Greeley & Guest. All of these data were used to explore potential formation and modification processes.

K S Deal↗

Effects of Solute Concentrations on Kinetic Pathways in Ni-Al-Cr Alloys

The kinetic pathways resulting from the formation of coherent gamma'-precipitates from the gamma-matrix are studied for two Ni-Al-Cr alloys with similar gamma'-precipitate volume fractions at 873 K. The details of the phase decompositions of Ni-7.5Al-8.5Cr at.% and Ni-5.2Al-14.2Cr at.% for aging times from 1/6 to 1024 h are investigated by atom-probe tomography, and are found to differ significantly from a mean-field description of coarsening. The morphologies of the gamma'-precipitates of the alloys are similar, though the degrees of gamma'-precipitate coagulation and coalescence differ. Quantification within the framework of classical nucleation theory reveals that differences in the chemical driving forces for phase decomposition result in differences in the nucleation behavior of the two alloys. The temporal evolution of the gamma'-precipitate average radii and the gamma-matrix supersaturations follow the predictions of classical coarsening models. The compositional trajectories of the gamma-matrix phases of the alloys are found to follow approximately the equilibrium tie-lines, while the trajectories of the gamma'-precipitates do not, resulting in significant differences in the partitioning ratios of the solute elements.

Booth-Morrison, Christopher↗

Thermal Gradient Effects on Redox Evolution and Volatility-Driven Fractionation in Ternary U/Ce/Cs Condensates

Understanding how thermal history influences redox evolution and chemical fractionation is essential for characterizing high-temperature condensation in complex materials, including nuclear debris. Here, we tested the hypothesis that distinct thermal regimes in a plasma flow reactor influence redox pathways and elemental partitioning in ternary U/Ce/Cs systems. A configurable plasma flow reactor was modified with an external tube furnace to impose two distinct thermal gradients: continuous ambient cooling and a furnace-assisted thermal hold-up near 1400 K followed by rapid cooling. Transmission electron microscopy characterized phase identity, morphology, and nanoscale element distributions, while inductively coupled plasma-mass spectrometry quantified bulk elemental ratios. Across both thermal regimes, uranium and cerium condensed as UO 2 and CeO 2 as dominant refractory oxide products. Uranium partially oxidized to α-UO 3 during extended ambient cooling, while furnace-assisted hold-up preserved UO 2 and produced partial reduction of cerium to Ce 2 O 3 . Cesium remained volatile upstream and condensed later in the reactor, forming Cs 2 O and Cs-uranate phases with the highest incorporation after thermal hold-up. Bulk ICP-MS measurements supported these observations. U/Ce ratios remained comparatively stable and Cs displayed delayed and apparent transient enrichment that matched the nanoscale measurements. This integrated approach provides a quantitative method for linking thermal gradients to redox evolution and volatility-driven fractionation. These results show how the plasma flow reactor can identify where equilibrium descriptions remain adequate and where kinetic effects from residence time and temperature history must be considered when interpreting condensation behavior in multicomponent systems.

and nuclear chemistry↗

Propagation and Breaking at High Altitudes of Gravity Waves Excited by Tropospheric Forcing

An anelastic approximation is used with a time-variable coordinate transformation to formulate a two-dimensional numerical model that describes the evolution of gravity waves. The model is solved using a semi-Lagrangian method with monotone (nonoscillatory) interpolation of all advected fields. The time-variable transformation is used to generate disturbances at the lower boundary that approximate the effect of a traveling line of thunderstorms (a squall line) or of flow over a broad topographic obstacle. The vertical propagation and breaking of the gravity wave field (under conditions typical of summer solstice) is illustrated for each of these cases. It is shown that the wave field at high altitudes is dominated by a single horizontal wavelength; which is not always related simply to the horizontal dimension of the source. The morphology of wave breaking depends on the horizontal wavelength; for sufficiently short waves, breaking involves roughly one half of the wavelength. In common with other studies, it is found that the breaking waves undergo "self-acceleration," such that the zonal-mean intrinsic frequency remains approximately constant in spite of large changes in the background wind. It is also shown that many of the features obtained in the calculations can be understood in terms of linear wave theory. In particular, linear theory provides insights into the wavelength of the waves that break at high altitudes, the onset and evolution of breaking. the horizontal extent of the breaking region and its position relative to the forcing, and the minimum and maximum altitudes where breaking occurs. Wave breaking ceases at the altitude where the background dissipation rate (which in our model is a proxy for molecular diffusion) becomes greater than the rate of dissipation due to wave breaking, This altitude, in effect, the model turbopause, is shown to depend on a relatively small number of parameters that characterize the waves and the background state.

Prusa, Joseph M.↗

cis -Regulatory Elements in Plant Development, Adaptation, and Evolution

cis-Regulatory elements encode the genomic blueprints that ensure the proper spatiotemporal patterning of gene expression necessary for appropriate development and responses to the environment. Accumulating evidence implicates changes to gene expression as a major source of phenotypic novelty in eukaryotes, including acute phenotypes such as disease and cancer in mammals. Moreover, genetic and epigenetic variation affecting cis-regulatory sequences over longer evolutionary timescales has become a recurring theme in studies of morphological divergence and local adaptation. Here, we discuss the functions of and methods used to identify various classes of cis-regulatory elements, as well as their role in plant development and response to the environment. We highlight opportunities to exploit cis-regulatory variants underlying plant development and environmental responses for crop improvement efforts. Although a comprehensive understanding of cis-regulatory mechanisms in plants has lagged behind that in animals, we showcase several breakthrough findings that have profoundly influenced plant biology and shaped the overall understanding of transcriptional regulation in eukaryotes.

59 BASIC BIOLOGICAL SCIENCES↗

Calibrating the Ordovician Radiation of marine life: implications for Phanerozoic diversity trends

It has long been suspected that trends in global marine biodiversity calibrated for the Phanerozoic may be affected by sampling problems. However, this possibility has not been evaluated definitively, and raw diversity trends are generally accepted at face value in macroevolutionary investigations. Here, we analyze a global-scale sample of fossil occurrences that allows us to determine directly the effects of sample size on the calibration of what is generally thought to be among the most significant global biodiversity increases in the history of life: the Ordovician Radiation. Utilizing a composite database that includes trilobites, brachiopods, and three classes of molluscs, we conduct rarefaction analyses to demonstrate that the diversification trajectory for the Radiation was considerably different than suggested by raw diversity time-series. Our analyses suggest that a substantial portion of the increase recognized in raw diversity depictions for the last three Ordovician epochs (the Llandeilian, Caradocian, and Ashgillian) is a consequence of increased sample size of the preserved and catalogued fossil record. We also use biometric data for a global sample of Ordovician trilobites, along with methods of measuring morphological diversity that are not biased by sample size, to show that morphological diversification in this major clade had leveled off by the Llanvirnian. The discordance between raw diversity depictions and more robust taxonomic and morphological diversity metrics suggests that sampling effects may strongly influence our perception of biodiversity trends throughout the Phanerozoic.

Non-NASA Center↗

The Time Evolution of Eta Carinae's Colliding Winds

We report new HST/STIS observations that map the high-ionization forbidden line emission in the inner arc second of Eta Car, the first that fully image the extended wind-wind interaction region of the massive colliding wind binary. These observations were obtained after the 2009.0 periastron at orbital phases 0.084, 0.163, and 0.323 of the 5.54-year spectroscopic cycle. We analyze the variations in brightness and morphology of the emission, and find that blue-shifted emission (-400 to -200 km/s is symmetric and elongated along the northeast-southwest axis, while the red-shifted emission (+ 100 to +200 km/s) is asymmetric and extends to the north-northwest. Comparison to synthetic images generated from a 3-D dynamical model strengthens the 3-D orbital orientation found by Madura et al. (2011), with an inclination i = 138 deg, argument of periapsis w = 270 deg, and an orbital axis that is aligned at the same P A on the sky as the symmetry axis of the Homunculus, 312 deg. We discuss the potential that these and future mappings have for constraining the stellar parameters of the companion star and the long-term variability of the system. Plain-Language Abstract: With HST, we resolved the interacting winds of the binary, Eta Carinae. With a 3-D model, we find the binary orbit axis is aligned to the Homunculus axis. This suggests a connection between the binary and Homunculus ejection mechanism.

Gull, Theodore R.↗

Evolution of Ni-Mo/MgO during catalytic methane pyrolysis to produce base-growth nanotubes

Catalytic pyrolysis of methane is a promising approach for affordable hydrogen production without CO 2 emissions. While this process is thermodynamically appealing compared to steam reforming, the high stability of methane requires severe conditions, making catalyst stability challenging. Here, we report the behavior of a highly promising Ni-Mo/MgO catalyst, which greatly outperforms its Ni/MgO, Mo/MgO, and Ni-Mo/SiO 2 counterparts at atmospheric pressure. At 800°C, nearly 229 g of carbon nanotubes per gram of Ni are produced. We propose that this superior performance results from the phase evolution of the catalyst, which exsolves stable nickel catalyst particles under reaction conditions. We further reveal that molybdenum carbide formation reduces sintering and adheres the active catalytic particles to the support throughout the reaction, enabling catalyst reuse. Several characterization techniques (same-spot TEM, XPS, XRD, and Raman) are employed to examine catalyst morphology at every step, fostering a deeper understanding of its catalytic activity and stability.

36 MATERIALS SCIENCE↗

The geomorphology of Rhea - Implications for geologic history and surface processes

Morphological analyses of landforms on Rhea are used to define three physiographic provinces: cratered terrain 1 undifferentiated; cratered terrain 1 lineated; and cratered terrain 2. The important statigraphic relationships between the different provinces are examined with respect to major impact basins and tectonic features. It is shown that the formation of multiringed basins may have caused, or at least controlled the locations of major resurfacing and mantling events. The diameters of the central peaks relative to the impact crater diameters are found to be significantly larger than those within the craters of the moon or Mercury. Both cratered and noncrater lineaments have regional orientations which do not fit current global or regional stress models. On the basis of the morphological analysis, a chronological order is established for the origin of the three provinces: the cratered terrain 1 province was formed first; and cratered terrain 1 lineated and cratered terrain 2 were formed second, and last, respectively. It is shown that the chronological order is generally consistent with current theoretical models of the evolution of Rhea.

Moore, J. M.↗

Fluvial valleys and Martian palaeoclimates

Theoretical models of early Martian atmospheric evolution describe the maintenance of a dense CO2 atmosphere and a warm, wet climate until the end of the heavy-bombardment phase of impacting. However, the presence of very young, earthlike fluvial valleys on the northern flank of Alba Patera conflicts with this scenario. Whereas the widespread ancient Martian valleys generally have morphologies indicative of sapping erosion by the slow outflow of subsurface water, the local Alba valleys were probably formed by surface-runoff processes. Because subsurface water flow might be maintained by hydrothermal energy inputs and because surface-runoff valleys developed late in Martian history, it is not necessary to invoke drastically different planet-wide climatic conditions to explain valley development on Mars. The Alba fluvial valleys can be explained by hydrothermal activity or outflow-channel discharges that locally modified the atmosphere, including precipitation and local overland flow on low-permeability volcanic ash.

Gulick, Virginia C.↗

Investigating microstructure evolution in block copolymer membranes

Block copolymer self-assembly in conjunction with nonsolvent-induced phase separation (SNIPS) has been increasingly leveraged to fabricate integral-asymmetric membranes. The large number of formulation and processing parameters associated with SNIPS, however, has prevented the reliable construction of high performance membranes. In this study, we apply dynamical self-consistent field theory to model the SNIPS process and investigate the effect of various parameters on the membrane morphology: solvent selectivity, nonsolvent selectivity, initial film composition, and glass transition composition. We examine how solvent selectivity and concentration of polymers in the film impact the structure of micelles that connect to form the membrane matrix. In particular, we find that preserving the order in the surface layer and forming a connection between the supporting and surface layer are nontrivial and sensitive to each parameter studied. Furthermore, the effect of each parameter is discussed, and suggestions are made for successfully fabricating viable block copolymer membranes.

36 MATERIALS SCIENCE↗

Morphological Modulation of TiO 2 Nanotube via Optimal Anodization Condition for Solar Water Oxidation

With the depletion of fossil fuels and the rising global demand for energy, photoelectrochemical (PEC) water splitting presents a promising solution to avert an energy crisis. Titanium dioxide (TiO 2 ), an n -type semiconductor, has gained popularity as a photoanode due to its remarkable PEC properties. Nevertheless, inherent challenges such as a wide band gap (~3.2 eV), charge recombination, and slow oxygen evolution reaction (OER) rates at the surface limit its practical application by constraining light absorption. To overcome these limitations, we have developed TiO 2 nanotubes (NTs) using a facile anodization method. This study examines the impact of anodization growth parameters on solar water oxidation performance. Specifically, TiO 2 NTs with modified anodization time (referred to as TiO 2 -6) showed a 3.5-fold increase in photocurrent density compared to the as-grown TiO 2 NTs. Furthermore, electrochemical analyses, such as electrochemical impedance spectroscopy (EIS), indicated a significant decrease in charge transfer resistance following the adjustment of on-off anodization time. Additionally, the TiO 2 -6 photoanode demonstrated a higher electrochemically active surface area (ECSA) than other samples. Therefore, optimal nanostructuring parameters are crucial for enhancing the PEC properties of TiO 2 NTs. Overall, our findings offer valuable insights for fabricating high-quality TiO 2 NTs photoanodes, contributing to developing efficient PEC systems for sustainable energy production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Charting the southern seas - The evolution of the lunar Mare Australe

Mare Australe has been subjected to at least four major episodes of basalt eruption ranging in age from early Imbrian to Eratosthenian. The basalts were emplaced largely in flood eruptions from at least 197 vents located on post-basin impact crater floors. The youngest basalts occur in an annulus near the outer edge of the basin. The fill thickness apparently reflects a multiring structure for the post-impact morphology of the Australe basin; the thin basaltic fill was not sufficient a load to produce tectonic rilles, but mare ridges are present and exhibit a prominent north-south alignment.

Whitford-Stark, J. L.↗