Nighttime molecular oxygen densities in the 100-130-km region from Schumann-Runge absorption.
Nighttime molecular O densities between 100- 130 km determined from Schumann-Runge absorption data for successive far UV spectra of hot star
Moos, H. W.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The Raman spectra of N-14O2 and N-15O2 solids at 20 K
The Raman spectra of N-14O2 and N-15O2 have been studied at 20 K. The far infrared of N-14O2 at 20 K was also measured. The data were assigned on the basis of a C-sub 2 nu molecular model. Normal coordinate calculations were performed for a variety of assignments. The assignment that yielded the best fit is presented. The solid state effects are discussed.
Durig, J. R.↗
Rocket exhaust plume impingement on the Voyager spacecraft
In connection with the conduction of the long-duration Voyager missions to the outer planets and the sophisticated propulsion systems required, it was necessary to carry out an investigation to avoid exhaust plume impingement problems. The rarefied gas dynamics literature indicates that, for most engineering surfaces, the assumption of diffuse reemission and complete thermal accommodation is warranted in the free molecular flow regime. This assumption was applied to an analysis of a spacecraft plume impingement problem in the near-free molecular flow regime and yielded results to within a few percent of flight data. The importance of a correct treatment of the surface temperature was also demonstrated. Specular reflection, on the other hand, was shown to yield results which may be unconservative by a factor of 2 or 3. It is pointed out that one of the most difficult portions of an exhaust plume impingement analysis is the simulation of the impinged hardware. The geometry involved must be described as accurately and completely as possible.
Baerwald, R. K.↗
An ab initio investigation of the structure, vibrational frequencies, and intensities of HO2 and HOCl
The infrared spectral intensities for HOCl and HO2 have been calculated using a new ab initio technique. Theoretical results for the geometries, vibrational frequencies, and the dipole moments of these species are also reported. All of the calculations were performed at the SCF level using near Hartree-Fock quality basis sets. The results for the molecular geometries and the vibrational frequencies are in good agreement with available experimental data. It is believed that the computed intensities are accurate to at least 50%. The results should be helpful in attempts to determine the stratospheric abundance of HOCl and HO2 by in situ infrared spectroscopic measurements.
Komornicki, A.↗
Effects of the Shuttle Orbiter fuselage and elevon on the molecular distribution of water vapor from the flash evaporator system
A concern has arisen regarding the emissive distribution of water molecules from the shuttle orbiter flash evaporator system (FES). The role of the orbiter fuselage and elevon in affecting molecular scattering distributions was nuclear. The effect of these components were evaluated. Molecular distributions of the water vapor effluents from the FE were measured. These data were compared with analytically predicted values and the resulting implications were calculated.
Richmond, R. G.↗
Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons
Isotopic measurements of individual geothermal hydrocarbons that are, as a group, of higher molecular weight than methane are reported. It is believed in light of this data that the principal source of hydrocarbons in four geothermal areas in western North America is the thermal decomposition of sedimentary or groundwater organic matter.
Des Marais, D. J.↗
Quantum chemical calculations for polymers and organic compounds
The relativistic effects of the orbiting electrons on a model compound were calculated. The computational method used was based on 'Modified Neglect of Differential Overlap' (MNDO). The compound tetracyanoplatinate was used since empirical measurement and calculations along "classical" lines had yielded many known properties. The purpose was to show that for large molecules relativity effects could not be ignored and that these effects could be calculated and yield data in closer agreement to empirical measurements. Both the energy band structure and molecular orbitals are depicted.
Lopez, J.↗
Interstellar abundances and depletions inferred from observations of neutral atoms
Data on neutral atomic species are analyzed for the purpose of inferring relative elemental abundances and depletions in diffuse cloud cores, where it is assumed that densities are enhanced in comparison with mean densities over integrated lines of sight. Column densities of neutral atoms are compared to yield relative column densities of singly ionized species, which are assumed dominant in cloud cores. This paper incorporates a survey of literature data on neutral atomic abundances with the result that no systematic enhancement in the depletions of calcium or iron in cloud cores is found, except for zeta Ophiuchi. This may imply that depletions are not influenced by density, but other data argue against this interpretation. It is concluded either that in general all elements are depleted together in dense regions so that their relative abundances remain constant, or that typical diffuse clouds do not have significant cores, but instead are reasonably homogeneous. The data show a probable correlation between cloud-core depletion and hydrogen-molecular fraction, supporting the assumption that overall depletions are a function of density.
Snow, T. P.↗
Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula
The first interstellar hydrocarbon ring, cyclopropenylidene (C3H2) is being studied. Both a survey of galactic sources in several C3H2 transitions and a more detailed study of a subset of these sources are under way. In the latter category is a study of the nearby cold dark cloud TMC-1, which is a potential formation site for solar type stars. A spectra is shown of seven rotational transitions which have been observed at the Five College Radio Astronomy Observatory. Three of these were detected for the first time in any astronomical source: the 3 sub 30 to 2 sub 21 transition at 216 GHz, the 2 sub 21 to 1 sub 10 transition at 122 GHz, and the 1 sub 11 to 0 sub 00 transition at 52 GHz. From the data it is apparent that C3H2 is quite spacially extended in typical interstellar molecular clouds, and that at least in TMC-1 it is one of the most abundant organic molecules.
Irvine, W. M.↗
Giant H II regions in M81
H-alpha and VLA radio continuum observations at wavelengths of 6 and 20 cm are used to study the distribution of extinction and the distribution of giant radio H II regions along the spiral arms in M81. The radial distribution of visual extinction Av in the plane of M81 shows no trend, with an upper limit 0.1 mag/kpc for the radial extinction gradient and a mean Av of 1.1 + or - 0.4 mag. Nearly all the giant radio H II regions lie along the spiral arms or the inner H I ring. The radial distribution of the set of giant radio H II regions exhibits a strong maximum at a galactocentric distance R roughly 300 arcsec. Unless molecular hydrogen in M81 is also concentrated near R roughly 300 arcsec, the data disagree with Visser's (1980) model for star formation associated with a density wave. Some suggestions are made about how to change the ballistic particle model of Leisawitz and Bash to agree with the observed radial distribution of giant radio H II regions.
Kaufman, Michele↗
Fourier transform spectroscopy of the nu3 band of the N3 radical
The nu3 transitions of N3 radicals produced by HN3-Cl reactions in a multipass cell (effective path length 100 m) are investigated experimentally using a Fourier-transform spectrometer with maximum resolution 0.004/cm. A total of 176 rotation-vibration lines are listed in a table and used, in combination with published data on 240 optical lines (Douglas and Jones, 1965), to determine the nu3 molecular constants. The lower-than-expected value of the nu3 fundamental frequency (1644.6784/cm) is attributed to the vibronic interaction discussed by Kawaguchi et al. (1981).
Brazier, C. R.↗
WF/PC internal molecular contamination during system thermal-vacuum test
During the recent system thermal vacuum test of the Wide-Field/Planetary Camera (WF/PC), instrumentation was added to the WF/PC to characterize the internal molecular contamination and verify the instrument throughput down to 1470 angstroms. Analysis of data elements revealed two contaminants affecting the far-ultraviolet (FUV) performance of the WF/PC. The one contaminant (heavy volatile) is correlated with the electronic and housing temperature, and the contamination is significantly reduced when the electronics are operated below plus 8 degrees to plus 10 degrees C. The other contaminant (light volatile) is controlled by the heat pipe temperature, and the contamination is significantly reduced when the Thermal Electric Cooler (TEC) hot-junction temperature is below minus 40 degrees to minus 50 degrees C. The utility of contamination sensors located behind instruments during system tests was demonstrated.
Taylor, Daniel M.↗
Theoretical line shapes for rotational spectra of HCl in Ar
An interaction potential for HCl-Ar recently derived from spectra of van der Waals complexes (Hutson,1988) has been used to obtain converged close-coupling scattering S matrices from which pressure broadening (linewidth, line shift, and line coupling) cross sections have been computed within the Fano-Ben-Reuven formalism. Linewidths agree well with experimental data with the exception of the 0-1 line at low temperatures (an error of about 15 percent at 125 K). Line shifts, especially the largest, for the 0-1 line, are also in reasonable accord with experimental data. Line coupling is predicted to be quite small. The coupled-states molecular scattering approximation is found to be accurate except at very low collision energies. The infinite-order sudden approximations, on the other hand, is not reliable for this system. Inelastic scattering out of the spectroscopic levels accounts for only a fraction of the linewidth at thermal energies, especially in the lower rotational levels.
Green, Sheldon↗
Development of a Raman lidar simulation tool
Raman Lidar is a useful and powerful tool for remote probing of the atmosphere. With Raman Lidars, one can accurately determine the identity and concentration of a particular molecular specie present in the atmosphere. We present the results from a program to develop a simulation capability of Raman Lidar systems for the remote detection of atmospheric gases and/or air polluting hydrocarbons. Our model, which integrates remote Raman spectroscopy with SPARTA's BACKSCAT atmospheric lidar simulation package, permits accurate determination of the performance of a Raman Lidar system. The accuracy with which our model operates is due to the accurate calculation, at any given excitation wavelength, of the differential scattering cross section for the molecular specie under investigation. We show excellent correlation of our calculated cross section data with experimental data from the published literature. In addition, the use of our BACKSCAT package, which provides a user friendly environment to define the operating conditions, provides an accurate calculation of the atmospheric extinction at both the excitation and Raman shifted wavelengths. Our code can be used to accurately predict the performance of a Raman Lidar system, the concentration and identification of a specie in the atmosphere, or the feasibility of making Raman measurements.
Grasso, R. J.↗
Low-Density Nozzle Flow by the Direct Simulation Monte Carlo and Continuum Methods
Two different approaches, the direct simulation Monte Carlo (DSMC) method based on molecular gasdynamics, and a finite-volume approximation of the Navier-Stokes equations, which are based on continuum gasdynamics, are employed in the analysis of a low-density gas flow in a small converging-diverging nozzle. The fluid experiences various kinds of flow regimes including continuum, slip, transition, and free-molecular. Results from the two numerical methods are compared with Rothe's experimental data, in which density and rotational temperature variations along the centerline and at various locations inside a low-density nozzle were measured by the electron-beam fluorescence technique. The continuum approach showed good agreement with the experimental data as far as density is concerned. The results from the DSMC method showed good agreement with the experimental data, both in the density and the rotational temperature. It is also shown that the simulation parameters, such as the gas/surface interaction model, the energy exchange model between rotational and translational modes, and the viscosity-temperature exponent, have substantial effects on the results of the DSMC method.
Chung, Chang-Hong↗
HALOE Science Investigation
This cooperative agreement has investigated a number of spectroscopic problems of interest to the Halogen Occultation Experiment (HALOE). The types of studies performed are in two parts, namely, those that involve the testing and characterization of correlation spectrometers and those that provide basic molecular spectroscopic information. In addition, some solar studies were performed with the calibration data returned by HALOE from orbit. In order to accomplish this a software package was written as part of this cooperative agreement. The HALOE spectroscopic instrument package was used in various tests of the HALOE flight instrument. These included the spectral response test, the early stages of the gas response test and various spectral response tests of the detectors and optical elements of the instruments. Considerable effort was also expended upon the proper laboratory setup for many of the prelaunch tests of the HALOE flight instrument, including the spectral response test and the gas response test. These tests provided the calibration and the assurance that the calibration was performed correctly.
Benner, D. Chris↗
Measurement of HO2 and Other Trace Gases in the Stratosphere Using a High Resolution Far-Infrared Spectrometer
This report covers the time period 1 April 2001 to 31 December 2001. During this period we continued analyzing data from past flights, exploring issues such as radical partitioning, stratospheric transport, and molecular spectroscopy and further developed our beamsplitter technology.
Traub, Wes↗
Infrared Spectroscopy of Star Formation in Galactic and Extragalactic Regions
In this program we proposed to perform a series of spectroscopic studies, including data analysis and modeling, of star formation regions using an ensemble of archival space-based data from the Infrared Space Observatory's Long Wavelength Spectrometer and Short Wavelength Spectrometer, and to take advantage of other spectroscopic databases including the first results from SIRTF. Our empha- sis has been on star formation in external, bright IR galaxies, but other areas of research have in- cluded young, low or high mass pre-main sequence stars in star formation regions, and the galactic center. The OH lines in the far infrared were proposed as one key focus of this inquiry because the Principal Investigator (H. Smith) had a full set of OH IR lines from IS0 observations. It was planned that during the proposed 2-1/2 year timeframe of the proposal other data (including perhaps from SIRTF) would become available, and we intended to be responsive to these and other such spec- troscopic data sets. Three papers are included:The Infrared Lines of OH: Diagnostics of Molecular Cloud Conditions in Infrared Bright Galaxies; The Far-Infrared Spectrum of Arp 220; andThe Far-Infrared Emission Line and Continuum Spectrum of the Seyfert Galaxy NGC 1068.
Frogel, Jay↗