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At least 901 records · Page 50

Infrared Spectra and Optical Constants of Astronomical Ices: III. Propane, Propylene, and Propyne

Infrared (IR) spectra of the hydrocarbon ices C3H8 (propane), C3H6 (propylene, propene), and C3H4 (propyne, methylacetylene) are relevant to the study of the low-temperature chemistry and spectroscopy of objects within and beyond the Solar System, but IR band strengths and absorption coefficients are lacking for these compounds. Here we present new IR spectra of crystalline and non-crystalline forms of C3H8, C3H6, and C3H4. Measurements of ice density and refractive index also are reported, two quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, abundances of propane, propylene, and propyne in extraterrestrial environments and in laboratory experiments. Suggestions and interpretations are offered regarding the multiple crystalline forms of propane and propylene observed. Applications and extensions are described.

Ices↗

Infrared spectra and optical constants of astronomical ices: III. Propane, propylene, and propyne

Infrared (IR) spectra of the hydrocarbon ices C3H8 (propane), C3H6 (propylene, propene), and C3H4 (propyne, methylacetylene) are relevant to the study of the low-temperature chemistry and spectroscopy of objects within and beyond the Solar System, but IR band strengths and absorption coefficients are lacking for these compounds. Here we present new IR spectra of crystalline and non-crystalline forms of C3H8, C3H6, and C3H4. Measurements of ice density and refractive index also are reported, two quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, abundances of propane, propylene, and propyne in extrater-restrial environments and in laboratory experiments. Suggestions and interpretations are offered regarding the multiple crystalline forms of propane and propylene observed. Applications and extensions are described.

Reggie L. Hudson↗

Plasma for Crewed Transit and Planetary Habitation

As human exploration moves beyond low Earth orbit, innovative life support and resource production systems become forerunners for human colonization. Plasma systems allow for complex chemical processes while mitigating consumable needs. Plasma technology and applications can redefine the space environment. With this, scientists at NASA are looking to close known space technology gaps and create a paradigm shift in space-based applications. NASA’s Kennedy Space Center is exploring the use of low-temperature plasma for applications in agriculture, sanitation, regolith reduction, waste gasification, water activation, and nutrient recovery techniques. Using low temperature plasmas, we report on the success criteria and experimental results for plasma applications for crewed transit and planetary habitation.

Waste management↗

The Stop-and-Go Mechanism: Towards an Integrated Approach to Model Seismicity, Outgassing, Deformation, and Thermal Unrest at Active Volcanoes

Connecting the geophysical and geochemical signals recorded at and above the surface of volcanoes with source mechanisms is fundamental to understand transitions from quiescence to eruption, and to integrate the behavior of volcanoes with their regional seismotectonic and hydrological context. Some of these signals include shallow volcanic tremor, a long-lasting (minutes-to-years) ground vibration detected in volcanic areas during unrest; volcanic outgassing, which shows intriguing periodicities over multiple scales, as revealed by space-borne instruments and by ground-based, high-frequency (~1 Hz), sampling methods; inflation and deflation of volcanic edifices, commonly associated with subsurface volume changes; and large-scale (from a few to tens of km2), low-temperature, thermal anomalies, a newly-discovered signal that has been observed to emerge on volcanic flanks from months-to-years prior to gas- and magma-driven eruptions. Traditionally, these geophysical and geochemical signals have been modelled independently, which limits our interpretation of subsurface processes and thus our assessment of unrest. In this work, we show through lumped-parameter models, numerical simulations, and preliminary laboratory experiments that many of the signals recorded around volcanoes can be integrated into a common “stop-and-go” mechanism. In particular, we found that they can arise spontaneously when taking into account the feedbacks between the temporary accumulation of gas and/or magma in the crust (“stop”), and the diffusive transfer of gas and heat towards the surface (“go”). For example, we find that the “stop-and-go” mechanism can explain: (i) the emergence of monochromatic, broadband, and harmonic tremor; (ii) the periodic components commonly observed in volcanic outgassing time series; (iii) the link between large-scale thermal anomalies and shallow hydrothermal systems; (iv) the reported time lags between large-scale thermal anomalies and deformation; and (v) the breathing of potentially destructive volcanic calderas. The “stop-and-go” mechanism provides a consistent and realistic framework to link multiple geophysical and geochemical signals with the processes leading to volcanic unrest and eruption.

volcanoes↗

Infrared Spectra and Optical Constants of Astronomical Ices: III. Propane, Propylene, and Propyne

Infrared (IR) spectra of the hydrocarbon ices C3H8 (propane), C3H6 (propylene, propene), and C3H4 (propyne, methylacetylene) are relevant to the study of the low-temperature chemistry and spectroscopy of objects within and beyond the Solar System, but IR band strengths and absorption coefficients are lacking for these compounds. Here we present new IR spectra of crystalline and non-crystalline forms of C3H8, C3H6, and C3H4. Measurements of ice density and refractive index also are reported, two quantities needed to compute IR absorption coefficients, band strengths, optical constants, and, ultimately, abundances of propane, propylene, and propyne in extraterrestrial environments and in laboratory experiments. Suggestions and interpretations are offered regarding the multiple crystalline forms of propane and propylene observed. Applications and extensions are described.

Reggie L Hudson↗

New Candidate Extreme T Subdwarfs from the Backyard Worlds: Planet 9 Citizen Science Project

Schneider et al. presented the discovery of WISEA J041451.67−585456.7 and WISEA J181006.18−101000.5, which appear to be the first examples of extreme T-type subdwarfs (esdTs; metallicity ≤−1 dex, T(eff) ≲ 1400 K). Here, we present new discoveries and follow-up of three T-type subdwarf candidates, with an eye toward expanding the sample of such objects with very low metallicity and extraordinarily high kinematics, properties that suggest membership in the Galactic halo. Keck/NIRES near-infrared spectroscopy of WISEA J155349.96+693355.2, a fast-moving object discovered by the Backyard Worlds: Planet 9 citizen science project, confirms that it is a mid-T subdwarf. With H(W2) = 22.3 mag, WISEA J155349.96+693355.2 has the largest W2 reduced proper motion among all spectroscopically confirmed L and T subdwarfs, suggesting that it may be kinematically extreme. Nevertheless, our modeling of the WISEA J155349.96+693355.2 near-infrared spectrum indicates that its metallicity is only mildly subsolar. In analyzing the J155349.96+693355.2 spectrum, we present a new grid of low-temperature, low-metallicity model atmosphere spectra. We also present the discoveries of two new esdT candidates, CWISE J073844.52−664334.6 and CWISE J221706.28−145437.6, based on their large motions and colors similar to those of the two known esdT objects. Finding more esdT examples is a critical step toward mapping out the spectral sequence and observational properties of this newly identified population.

Aaron M. Meisner↗

Solar Power System and Radioisotope Thermoelectric Generation Technologies at Jupiter-Saturn-Uranus Environments: New Insights and Paradigms

Power system selection for outer planet destinations, such as Jupiter, Saturn, and Uranus and beyond, is complex, involving and dependent on many interdisciplinary factors such as power system mass, specific power, cost, mechanical and electrical integration, and natural radiation environment. Low solar irradiance at Jupiter, Saturn, and Uranus systems (i.e., 50, 15, and 4 W/m2 , respectively) makes solar power systems challenging in mechanical / electrical integration and accommodating radiation environments. More costly radioisotope thermoelectric generator (RTG) systems can help proposed missions overcome radiation environment and spacecraft control challenges at Jupiter, Saturn, and Uranus. NASA’s Jet Propulsion Laboratory (JPL) has recently made significant strides in demonstrating high-efficiency, radiation-hard solar cell technologies for low-irradiance, low-temperature (LILT) applications, and high-efficiency thermoelectric (TE) materials and modules for higher-specific-power RTGs. Stateof-art multi-junction solar cells now routinely demonstrate high efficiencies of 30-34% at LILT (9.5AU and -165°C), making solar arrays a viable option for many near-term Saturn mission concepts. Emerging technologies like LILToptimized solar cells have recently demonstrated even higher efficiencies of 37% at 9.5AU and -165°C and 30% lower mass than the state-of-art, offering the prospect of ~3W/kg array-level, end-of-life specific powers under Saturn conditions. Having already demonstrated the tremendous utility of RTGs on Mars and in deep-space missions (e.g., Galileo at Jupiter, New Horizons at Pluto), NASA is now developing and demonstrating new TE materials and modules (e.g., skutterudites, La3-x Te4, and Zintls) for increasing RTG specific power (up to >8.5 W/kg), which strongly impacts an RTG’s mass, fuel utilization, and modularity in the power system trade domain. New accomplishments in both areas highlight the renewed requisite for updated comparisons and trade-offs in power output, specific power and mass, cost, mechanical and electrical integration, new technology timelines, and natural radiation impacts between new LILT-optimized photovoltaic technologies and next-generation RTG technologies. This work discusses and demonstrates how new LILT-based technologies are now allowing one to consider and design solar power systems for Saturn orbit and beyond, and are changing the potential cost-mass trade-offs between emerging solar power technologies and newly-envisioned RTG technologies. Key updated system mass and cost trade-offs between high-performance LILT solar technologies and new RTG technologies are presented, reinforcing and refining power selection criteria supporting possible future NASA deep-space science and exploration missions to Mars, the Jupiter system (Europa, Ganymede), the Saturn system (Titan, Enceladus), Uranus, and beyond. Key trade-offs in other above-mentioned interdisciplinary factors between these two power technologies are also discussed.

Bairstow, Brian K.↗

Indigenous Organic Matter Associated with Unusual Low Temperature Aqueous Secondary Phases in the Mars Meteorite Nakhla

In freshly fractured chips of the Mars meteorite Nakhla, we found carbonaceous phases intimately associated with secondary aqueous alteration phases, both mineral and amorphous, interpreted to have formed through the low-temperature, mineral-water dissolution of the host Martian basalt.We have characterized the nature of carbonaceous matter and spatially associated secondary phases within Nakhla using a multidisciplinary suite of optical and electron beam instrumentation(Thomas-Keprta et al., 2022). Secondary Phases: The preserved secondary mineral phases are best described as ‘juvenile’ hydrated amorphous silica formed when water interacts with mafic rocks. Although amorphous silica on Earth rarely persists through geologic time due to alteration into other phases, e.g.,microcrystalline opal-CT and eventually quartz, the lack of maturation of primarily amorphous silica with embedded nano phase ferrihydrite in Nakhla infers these phases formed in a limited water environment by low temperature, circumneutral pH fluids stabilized by the presence of coexisting amorphous silica.Additionally, we report the presence of the ferrous hydroxycarbonate mineral chukanovite (Fe2(OH)2CO3)within some of the secondary mineral aggregates studied. Organic Matter:Indigenous Nakhla carbonaceous matter is present both in condensed phases and in a dispersed state spatially associated with secondary alteration phases. In the former, discrete refractory micron to submicron assemblages were identified that appear macromolecular in nature and, in several cases, associated with F and, in one case, significant N. While organically bound Fhas yet to be detected remotely on Mars, the identification of organic N within one of the carbonaceous phases is considered a prerequisite for Martian astrobiological potential. Summary: Neither the intimate association of carbonaceous matter with secondary phases nor the identification of chukanovite have been previously reported in any of the Martian meteorites.A variety of habitability-related metastable solid-phase, oxidation-reduction, and organic-molecular sample attributes in Nakhla formed hundreds of millions of years ago near Mars’ surface; these alteration products persisted on Mars until very recentlyand resemble the amorphous materials observed at Gale crater by Mars Science Laboratory CuriosityRover (Rampe et al., 2020).Similar phases may be expected to occur elsewhere on Mars (e.g., Jezerocrater). References: Rampe E. B. et al.(2020) Mineralogy and geochemistry of sedimentary rocks and eolian sediments in Gale crater, Mars: A review after six Earth years of exploration with Curiosity.Geochemistry80, 125605; Thomas-Keprta K.L. et al. (2022) Indigenous carbon-rich matter associated with unusual aqueous alteration features in Nakhla: Complex formation and preservation history. Geochim. et Cosmochim. Acta320, 41-78 (online).

Mars meteorite↗

Laminar Non-Premixed Flames of Gaseous Fuel Aboard the International Space Station

From late 2017 to early 2022, six independent studies with flames of gaseous fuels were conducted on the International Space Station (ISS) in the U.S. combustion research facility. An exploration of flames at the extremes of high sooting and high dilution was conducted with a coaxial coflow burner, where the fuel and oxidizer velocities were typically matched. An investigation of electric-field effects also used the same coflow burner as well as a simple gas-jet burner, with a circular electrode mesh, downstream of the burner, at voltages of either polarity up to 10 kV. A study focused on material flammability in a quiescent atmosphere emulated the burning of condensed-phased fuels using cylindrical burners with a flat perforated outlet instrumented to measure the heat flux to the burner, i.e., emulated fuel. Three studies of soot processes, flame dynamics, and low-temperature combustion used porous spherical burners, yielding a nominally one-dimensional flame structure. The objectives and selected findings of each investigation will be briefly discussed after a short review of the advantages of studying combustion in microgravity, earlier ISS research, and the experimental hardware and its operation.

flames↗

Radiation-induced D/H Exchange Rate Constants in Aliphatics Embedded in Water Ice

Gas-phase and solid-state chemistry in low-temperature interstellar clouds and cores leads to a D/H enhancement in interstellar ices, which is eventually inherited by comets, meteorites, and even planetary satellites. Hence, the D/H ratio has been widely used as a tracer for the origins of extraterrestrial chemistry. However, the D/H ratio can also be influenced by cosmic rays, which are ubiquitous and can penetrate even dense interstellar molecular cores. The effects of such high-energy radiation on deuterium fractionation have not been studied in a quantitative manner. In this study, we present rate constants for radiation-induced D-to-H exchange for fully deuterated small (1–2 C) hydrocarbons embedded in H2O ice at 20 K and H-to-D exchange for the protiated forms of these molecules in D2O ice at 20 K. We observed larger rate constants for H-to-D exchange in the D2O ice versus D-to-H exchange in H2O ice, which we have attributed to the greater bond strength of C–D versus C–H. We find that the H-to-D exchange rate constants are smaller for protiated methane than ethane, in agreement with bond energies from the literature. We are unable to obtain rate constants for the unsaturated and reactive hydrocarbons ethylene and acetylene. Interpretation of the rate constants suggest that D/H exchange products are formed in abundance alongside radiolysis products. We discuss how our quantitative and qualitative data can be used to interpret the D/H ratios of aliphatic compounds observed throughout space.

Ice destruction↗

Indigenous Organic Matter Associated with Unusual Low Temperature Aqueous Secondary Phases in the Mars Meteorite Nakhla

The Martian meteorite Nakhla provides demonstrates evidence of mineral-water interactions that occurred in the Martian regolith within the last 1 Ga, as well as the presence of trace indigenous organic matter. The aim of our research is threefold: [1] provide a context in which to interpret alteration features; [2] determine the physical and chemical environment during alteration; and, [3] investigate the hypothesis that the formation of alteration phases was intimately involved in the accumulation and/or preservation of organic matter. In freshly fractured chips of the Mars meteorite Nakhla, we found carbonaceous matter intimately associated with secondary aqueous alteration phases interpreted to have formed through the low-temperature, mineral-water dissolution of the host Martian basalt. We have characterized the nature of carbonaceous matter and spatially associated secondary phases within Nakhla using a multidisciplinary suite of analytical instrumentation. The aim of our research is to provide a context to interpret the formation of secondary alteration assemblages within the Mars meteorite Nakhla and determine whether, and if so the extent to which, these phases participated in the accumulation and preservation of Martian organic matter.

Mars meteorite↗

I-Xe Dating of Aqueous Alteration in the CI Chondrite Orgueil: I. Magnetite and Ferromagnetic Separates

The I-Xe system was studied in a ferromagnetic sample separated from the Orgueil CI carbonaceous chondrite with a hand-held magnet and in two magnetite samples, one chemically separated before and the other one after neutron irradiation. This work was done in order to investigate the effects of chemical separation by LiCl and NaOH on the I-Xe system in magnetite. Our test demonstrated that the chemical separation of magnetite before irradiation using either LiCl or NaOH, or both, does not contaminate the sample with iodine and thus cannot lead to erroneous I-Xe ages due to introduction of uncor-related128*Xe. The I-Xe ages of two Orgueil magnetite samples are mutually consistent within experimental uncertainties and, when normalized to an absolute time scale with the reevaluated Shallowater aubrite standard, place the onset of aqueous alteration on the CI parent body at 4564.3 ± 0.3 Ma, 2.9 ± 0.3 Ma after formation of the CV Ca-AI-rich inclusions (CAIs). The I-Xe age ofthe ferromagnetic Orgueil separate is 3.4 Ma younger, corresponding to a closure of the I-Xe system at 4560.9 ± 0.2 Ma. These and previously published I-Xe data for Orgueil (Hohenberg et al., 2000) indicate that aqueous alteration on the CI parent body lasted for at least 5 Ma. Although the two magnetite samples gave indistinguishable I-Xe ages, their temperature release profiles differed. One of the two Orgueil magnetites released less radiogenic Xe than the other, 80% of it corresponding to the low-temperature peak of the release profile, compared to only 6% in case of the second Orgueil magnetite sample. This could be due to the difference in iodine trapping efficiencies for magnetite grains of different morphologies. Alternatively, the magnetite grains with the lower radiogenic Xe concentrations may have formed at a later stage of alteration when iodine in an aqueous solution was depleted.

I-Xe systematics↗

Molecular Inventory and Comparative Organic Profiling of A Homogenized Aggregate Sample From Asteroid (101955) Bennu

Evaluating the distribution and diversity of solvent-soluble organic molecules in extraterrestrial materials provide information about the physicochemical environments where prebiotic chemistry occurred and is essential for assessing the inventory of prebiotic compounds available to the early Earth. In this work, we conducted a comprehensive molecular characterization of solvent-soluble organic compounds in a homogenized aggregate sample (ID: OREX-800107-128) of unsorted regolith from asteroid (101955) Bennu returned by NASA’s OSIRIS-REx mission. Using two-dimensional gas chromatography coupled with high-resolution time-of-flight mass spectrometry (GC×GC-HRMS), we identified 87 organic compounds across several molecular classes, including alkanes, polycyclic aromatic hydrocarbons, and nitrogen-, oxygen-, and sulfur-bearing species. Comparison with the organic inventory of CI (Orgueil), C2-ungrouped (Tagish Lake and Tarda), and CM2 (Murchison) carbonaceous chondrites revealed that Bennu sample OREX-800107-128 is most similar to Tagish Lake and Tarda yet compositionally distinct from all of these meteorites. This Bennu sample exhibits a relatively high abundance of low-molecular-weight aromatics (e.g., toluene), pyridine derivatives, and sulfur species such as dimethyl sulfite, consistent with episodic low-temperature aqueous alteration. The presence of these organic compounds suggests that this material experienced chemically diverse processes in the parent body conducive to complex organic synthesis, including aldol condensation reactions responsible for N- and O-bearing compounds. We also compared the molecular distributions of this Bennu sample and previously analyzed samples from (162173) Ryugu to assess potential common origins between these two carbonaceous asteroids. Bennu shows more chemically diverse and nitrogen-rich organic materials than Ryugu. While both asteroids share broadly similar primitive compositions, the observed chemical differences indicate distinct evolutionary histories within a likely common formation environment though whether Bennu and Ryugu derive from a single compositionally heterogeneous parent body or from multiple closely related progenitors remains unresolved. Further detailed comparative analyses of material from Bennu, Ryugu, and specific carbonaceous meteorites (e.g., Tagish Lake and Tarda) will provide new insights into how the N-rich molecular profile observed in Bennu samples was formed and evolved in the outer Solar System.

sample return↗

A Review of Superconducting Electric Machines with On-Board Cryocoolers

This paper reviews the evolution and emerging direction of superconducting electric machines that employ onboard cryocoolers integrated directly into the rotor, eliminating the need for cryogenic fluid coupling and, in some cases, rotary seals. Traditional low-temperature superconducting (LTS) machines relied on external cryogenic systems and liquid helium transfer couplers, which introduced excessive complexity, poor reliability, and significant parasitic energy losses. The advent of high-temperature superconductors (HTS) has enabled compact, closed-cycle cryocoolers that support self-contained, fluid-free refrigeration architectures suitable for rotating applications. This paper examines the key technological challenges associated with on-board cryocooler integration and reviews three representative efforts by KAIST, NASA, and Hinetics, each illustrating distinct strategies and milestones toward practical implementation. KAIST demonstrated early proof-of-concept for rotating machines with on-board cryocoolers, NASA developed a shaft-integrated Stirling-type pulse tube cryocooler for a 1.4 MW hybrid-electric motor, and Hinetics achieved full-scale validation of a self-contained HTS rotor incorporating a commercial Stirling cryocooler and spoke-suspension torque tube. Collectively, these achievements confirm the technical feasibility of on-board cryogenic refrigeration and highlight steady progress toward compact and efficient superconducting rotating systems across various applications. Embedding cryocoolers directly within the rotor enables practical, efficient, and commercially viable superconducting propulsion technologies.

Cryogenics↗

List of Commercial and Advanced Developmental Niobium-Based Alloys of the Space Age

This report compiles a list of commercial and developmental niobium-based alloys developed during the Space Age (late 1950s through mid-1970s) for extreme-temperature applications, including rocket engine thrust chambers, hypersonic re-entry thermal protection systems, and space fission reactor loops. Niobium (Nb) was widely pursued because it provided the lowest density (~8.6 g/cc) among the primary refractory metals, a high melting temperature (~2470°C), exceptional low-temperature ductility, good formability, and compatibility with liquid alkali metals. An evaluation of physical metallurgy mechanisms, focusing on solid-solution strengthening via heavy refractory solutes (W, Mo, Ta), dual-purpose reactive solutes (Hf, Zr, Ti), and dispersion strengthening using carbides, nitrides, and oxides is presented. Additionally, the report compares Western and Soviet Union metallurgical approaches, explaining how supply chain factors and manufacturing infrastructure influenced element selection, interstitial chemistry, and alloy identification/naming conventions. Cataloging these historical alloy chemical compositions serves as a foundational reference for modern alloy additive manufacturing, thermodynamic CALPHAD modeling, and machine-learning discovery pipelines for next-generation extreme-environment niobium-based alloys.

Physical Metallurgy↗

A Review of Direct Ink Writing of Polymer Derived Ceramics

With the growing demand for materials capable of withstanding extreme temperatures and pressures, ceramic components with exceptional corrosion resistance and reliable mechanical properties have experienced a significant surge in demand. However, traditional ceramic forming methods involve high-temperatures and energy-intensive processes that often struggle to produce complex parts or composites efficiently. Polymer-Derived Ceramics (PDCs) offer a transformative solution by using polymeric precursors that can be converted into a wide variety of silicon-based and non-silicon-based ceramics through heat treatment. The polymeric nature of PDC precursors enables the fabrication of geometrically intricate components using conventional polymer-forming techniques at significantly lower processing temperatures. Furthermore, PDCs are well-suited for additive manufacturing (AM), allowing the production of complex structural and functional components through cost-effective, low-temperature processes. By leveraging the diverse properties of PDC materials – each with unique advantages and limitations – manufacturers can optimise performance for specific applications. This review provides an overview of the types of PDCs developed to date and their broad range of applications. Specifically, it delves into the Direct Ink Writing (DIW) process, exploring its rheological requirements and the critical role of fillers in tailoring the rheological properties of polymeric precursors to meet the specific demands of DIW.

Victoria Bishop↗

Progress Towards Improved Analysis of TES X-ray Data Using Principal Component Analysis

The traditional method of applying a digital optimal filter to measure X-ray pulses from transition-edge sensor (TES) devices does not achieve the best energy resolution when the signals have a highly non-linear response to energy, or the noise is non-stationary during the pulse. We present an implementation of a method to analyze X-ray data from TESs, which is based upon principal component analysis (PCA). Our method separates the X-ray signal pulse into orthogonal components that have the largest variance. We typically recover pulse height, arrival time, differences in pulse shape, and the variation of pulse height with detector temperature. These components can then be combined to form a representation of pulse energy. An added value of this method is that by reporting information on more descriptive parameters (as opposed to a single number representing energy), we generate a much more complete picture of the pulse received. Here we report on progress in developing this technique for future implementation on X-ray telescopes. We used an 55Fe source to characterize Mo/Au TESs. On the same dataset, the PCA method recovers a spectral resolution that is better by a factor of two than achievable with digital optimal filters.

Low-temperature detectors A[center dot] Transition↗