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NASA NTRS1986

Are aromatic hydrocarbons the carriers of the diffuse interstellar bands in the visible?

Large Polycyclic Aromatic Hydrocarbons (PAH) are the likely origin of the Unidentified Infrared Emission Feature. The molecules or their ions are also attractive candidates for the carriers of the Diffuse Interstellar Bands (DIBs) in the visible range. The PAHs have optically active transitions in the visible spectrum; have the ability to survive the ultraviolet photons in the Diffuse Interstellar Medium; and are the most abundant among the detected molecular species after H2 and CO. In particular, PAHs are better candidates than the long carbon chains that were proposed previously.

Leger, A.↗

NASA NTRS1986

Why do interstellar grains exist?

There exists a discrepancy between calculated destruction rates of grains in the interstellar medium and postulated sources of new grains. This problem was examined by modelling the global life cycle of grains in the galaxy. The model includes: grain destruction due to supernovae shock waves; grain injection from cool stars, planetary nebulae, star formation, novae, and supernovae; grain growth by accretion in dark clouds; and a mixing scheme between phases of the interstellar medium. Grain growth in molecular clouds is considered as a mechanism or increasing the formation rate. To decrease the shock destruction rate, several new physical processes, such as partial vaporization effects in grain-grain collisions, breakdown of the small Larmor radius approximation for betatron acceleration, and relaxation of the steady-state shock assumption are included.

Seab, C. G.↗

NASA NTRS1985

Survival of interstellar matter in meteorities - Evidence from carbonaceous material

An interstellar origin has been attributed to certain organic and apparently elemental forms of C which occurs in carbonaceous meteorites. Evidence for such an origin comes from anomalous isotopic composition either of the C itself or of elements, such as N, H, or the noble gasses, which are combined with or trapped within the carbonaceous material. Suggested sources for these anomalous compositions include atmospheres of red giant stars, novae and super-novae, and interstellar molecular clouds.

Kerridge, J. F.↗

NASA NTRS1985

Observations of several new transitions of interstellar HCO

Four new transitions of the interstellar formyl radical, HCO have been detected. Five transitions are now known for interstellar HCO, and thus its identification is secure. The column density found by assuming NGC 2024 is an extended source is N subT(HCO) = (8.5 + or - 4.0) x 10 to the 12th/sq cm. This gives a fractional abundance (abundance relative to hydrogen) for NGC 2024 which agrees quite well with some theoretical predictions. Several unidentified lines were detected and are reported here. Tentative identification for some of the unidentified lines are suggested.

Snyder, L. E.↗

NASA NTRS1985

Meteoritic evidence that graphite is rare in the interstellar medium

Carbonaceous material from several distinct astrophysical environments that has been identified in primitive meteorites is discussed. Most of this material is not well crystallized graphite, but ranges from kerogenlike macromolecular organic matter to poorly graphitized carbon. Of the small fraction of the carbonaceous material which is graphite, most may have resulted from the graphitization of macromolecular precursors in the solar nebula. Since graphite is more stable than those precursors, preexisting interstellar graphite should have survived in meteorites to at least the same extent as did other forms of carbon. It is concluded from this dearth of graphite that graphitic carbon was not a major component of the interstellar dust at the time of the formation of the solar system.

Nuth, J. A.↗

NASA NTRS1986

Chemistry of chlorine in dense interstellar clouds

Laboratory experiments and theoretical modeling show that the chemistry of chlorine is fairly simple in dense interstellar clouds, with Cl and HCl as the only species whose fractional abundances are significant. The estimated fraction of gas-phase chlorine present as HCl lies between 25-65 percent, in good agreement with the recent observations of the ground state HCl transition by Blake, Keene, and Philips (1985). These results, combined with the observational limits on HCl, indicate that chlorine is not severely depleted in dense interstellar clouds.

Blake, G. A.↗

NASA NTRS1986

Measuring interstellar dust grains from the haloes of binary X-ray sources

A method for determining the location, size distribution, and composition of interstellar dust grains from the haloes of binary X-ray sources is described. The method is based on the time dependence of the halo X-ray emission during an eclipse of the point source. The distance of the dust cloud is inferred directly from observations of the growth of the dark circle around the eclipsed point source. Grain size distribution in the interstellar dust clouds is derived from the halo brightness profile at a given photon energy. The composition of the grains is obtained by observing the spectral features in the total optical depth due to X-ray scattering near the photoionization thresholds of the elements in the grains. The haloes become dim just below the ionization threshold, and sharply increase in function brightness as the photon energy increases beyond the absorption edge of the relevant atom. The method makes it possible to observe and analyze the halo emission during eclipse even without imaging the source. It is suggested that haloes probably account for the soft X-rays observed during eclipses and dips observed in sources including 4U1915-05 and X1755-338.

Xu, Y.↗

NASA NTRS1986

Measurements of X-ray scattering from interstellar grains

The results of an Einstein Observatory imaging proportional counter investigation of the halos produced by the scattering of X-rays from interstellar grains of four compact Galactic (low-latitude) and two extragalactic (high-latitude) X-ray sources are reported. It is found that the intensity of these halos correlates well with the amount of visual extinction and the distance through the Galaxy's dust layer: quantities which measure the column density of grains to a given source. From this result, and from the size and shape of the halos from the Galactic sources, a number of grain parameters are derived in the context of two alternate grain size distributions: the Mathis-Rumpl-Nordsieck (MRN) and the Oort-van de Hulst distributions, either of which is capable of producing the observed halos. Though no single grain size is capable of producing the shapes observed for these halos, a mean size of about 0.1 micron and a number density of about 10 to the -12th grains/cu cm produce the correct halo intensities. From the additional parameters determined from the size and shape of the halos, results concerning the amount of material in grains which are in general agreement with the observed depletion of the elements from the gas phase of the interstellar medium, as well as with the detailed predictions of the MRN size distribution, are found.

Mauche, C. W.↗

NASA NTRS1985

Infrared spectral identification of complex organic molecules in interstellar grains

The chemical evolution of interstellar grains leads ultimately to a comparison consisting largely of complex organic molecules. Comparison of infrared absorption spectra of laboratory produced analogue materials with astronomical observations confirm the the presence of similar molecules in interstellar space. The abundance of this complex organic matter derived from the strength of the absorption bands is of the order of ten million solar masses and is almost certainly as large or larger than all conceivable planets.

Greenberg, J. M.↗

NASA NTRS1986

The analysis of ensembles of moderately saturated interstellar lines

It is shown that the combined equivalent widths for a large population of Gaussian-like interstellar line components, each with different central optical depths tau(0) and velocity dispersions b, exhibit a curve of growth (COG) which closely mimics that of a single, pure Gaussian distribution in velocity. Two parametric distributions functions for the line populations are considered: a bivariate Gaussian for tau(0) and b and a power law distribution for tau(0) combined with a Gaussian dispersion for b. First, COGs for populations having an extremely large number of nonoverlapping components are derived, and the implications are shown by focusing on the doublet-ratio analysis for a pair of lines whose f-values differ by a factor of two. The consequences of having, instead of an almost infinite number of lines, a relatively small collection of components added together for each member of a doublet are examined. The theory of how the equivalent widths grow for populations of overlapping Gaussian profiles is developed. Examples of the composite COG analysis applied to existing collections of high-resolution interstellar line data are presented.

Jenkins, E. B.↗

NASA NTRS1986

Diffuse interstellar bands in low color excess stars. III

Measurements of the equivalent widths of the diffuse interstellar bands at 6284 A and 6613 A in the spectra of 23 stars with E(B-V) less than 0.1 mag are reported. The band strengths do not correlate with interstellar H2 column density. They are probably produced by molecular mantles on grains or very stable molecules such as the polycyclic aromatic hydrocarbons.

Kumar, C. K.↗

NASA NTRS1986

Cool interstellar matter in early-type galaxies

IRAS fluxes of early-type galaxies have been examined. From studying a magnitude-limited sample, it seems that although the statistics are poor, perhaps a third of these objects and possibly even more have an appreciable amount of dust. In general, the infrared emission is strongest at 100 microns, and quite often the far-infrared luminosity of an early-type galaxy can be well in excess of 10 to the 8th solar luminosities. The data are most easily understood if the infrared results from dust reprocessing of starlight. Within 3 kpc of the center of an early-type galaxy, there may be more cold matter than hot gas; recent models that the interstellar media of these objects are composed primarily of hot gas appear to be oversimplifications. The X-ray data do indicate that the thermal pressure in the early-type galaxies often is sufficiently high that in view of the expected low temperatures of their interstellar clouds, it can be speculated that the cold material that is present may be forming low-mass stars.

Jura, M.↗

NASA NTRS1986

Observational discrimination between modes of shock propagation in interstellar clouds: Predictions of CH+ and SH+ column densities in diffuse clouds

Considerable effort in recent years has been devoted to the study of shocks in the diffuse interstellar medium. This work has been motivated partly by the observations of rotationally excited states of H2, and partly by the realization that species such as CH(+), OH and H2O might be formed preferentially in hot, post-shock gas. The problem of CH(+) and the difficulties encountered when trying to explain the high column densities, observed along lines of sight to certain hot stars, have been reviewed earlier. The importance of a transverse magnetic field on the structure of an interstellar shock was also demonstrated earlier. Transverse magnetic fields above a critical strength give rise to an acceleration zone or precursor, in which the parameters on the flow vary continuously. Chemical reactions, which change the degree of ionization of the gas, also modify the structure of the shock considerably. Recent work has shown that large column densities of CH(+) can be produced in magnetohydrodynamic shock models. Shock speeds U sub s approx. = 10 km/s and initial magnetic field strengths of a few micro G are sufficient to produce ion-neutral drift velocities which can drive the endothermic C(+)(H2,H)CH(+) reaction. It was also shown that single-fluid hydrodynamic models do not generate sufficiently large column densities of CH(+) unless unacceptably high shock velocities (u sub s approx. 20 km/s) are assumed in the models. Thus, the observed column densities of CH(+) provide a constraint on the mode of shock propagation in diffuse clouds. More precisely, they determine a lower limit to the ion-neutral drift velocity.

Flower, D. R.↗

NASA NTRS1986

The organic component of interstellar grains

The 3.4 micron absorption feature observed in the spectrum of a number of Galactic Center (GC) sources indicates the presence of organic molecules in the interstellar medium. It is ascribed to the C-H stretch vibration of tetrahedrally bonded carbon. From the observed features due to the interstellar organic material, an estimate was made of its composition and abundance. The ratio of the number of C-H groups of tetrahedrally to those of trigonally bonded carbon was 1.5, the cosmic abundance of carbon was .00037, and the depth of the silicate absorption toward the GC was taken equal to 3.6.

Schutte, W. A.↗

NASA NTRS1986

Studies of interstellar vibrationally-excited molecules

Several molecules thus far have been detected in the ISM in vibrationally-excited states, including H2, SiO, HC3N, and CH3CN. In order for vibrational-excitation to occur, these species must be present in unusually hot and dense gas and/or where strong infrared radiation is present. In order to do a more thorough investigation of vibrational excitation in the interstellar medium (ISM), studies were done of several mm-wave transitions originating in excited vibrational modes of HCN, an abundant interstellar molecule. Vibrationally-excited HCN was recently detected toward Orion-KL and IRC+10216, using a 12 meter antenna. The J=3-2 rotational transitions were detected in the molecule's lowest vibrational state, the bending mode, which is split into two separate levels, due to l-type doubling. This bending mode lies 1025K above ground state, with an Einstein A coefficient of 3.6/s. The J=3-2 line mode of HCN, which lies 2050K above ground state, was also observed toward IRC+10216, and subsequently in Orion-KL. Further measurements of vibrationally-excited HCN were done using a 14 meter telescope, which include the observations of the (0,1,0) and (0,2,0) modes towards Orion-KL, via their J=3-2 transitions at 265-267 GHz. The spectrum of the J=3-2 line in Orion taken with the 14 meter telescope, is shown, along with a map, which indicates that emission from vibrationally-excited HCN arises from a region probably smaller than the 14 meter telescope's 20 arcsec beam.

Ziurys, L. M.↗

NASA NTRS1986

Multi-level study of C3H2: The first interstellar hydrocarbon ring

Cyclic species in the interstellar medium have been searched for almost since the first detection of interstellar polyatomic molecules. Eleven different C3H2 rotational transitions were detected; 9 of which were studied in TMC-1, a nearby dark dust cloud, are shown. The 1 sub 10 yields 1 sub 01 and 2 sub 20 yields 2 sub 11 transitions were observed with the 43 m NRAO telescope, while the remaining transitions were detected with the 14 m antenna of the Five College Radio Observatory (FCRAO). The lines detected in TMC-1 have energies above the ground state ranging from 0.9 to 17.1 K and consist of both ortho and para species. Limited maps were made along the ridge for several of the transitions. The HC3N J = 2 yields 1 transition were mapped simultaneously with the C3H2 1 sub 10 yields 1 sub 01 line and therefore can compare the distribution of this ring with a carbon chain in TMC-1. C3H2 is distributed along a narrow ridge with a SE - NW extension which is slightly more extended than the HC2N J = 2 yields 1. Gaussian fits gives a FWHP extension of 8'5 for C3H2 while HC3N has a FWHP of 7'. The data show variations of the two velocity components along the ridge as a function of transition. Most of the transitions show a peak at the position of strongest HC3N emission while the 2 sub 21 yields 2 sub 10 transition shows a peak at the NH3 position.

Madden, S. C.↗

NASA NTRS1986

The abundance of interstellar sulphur and zinc in high density sight-lines

On the basis of early absorption line studies of individual lines of sight with the Copernicus satellite, chlorine, sulphur and zinc were classed together as elements which showed little or no depletion, relative to hydrogen, in the interstellar medium. The abundances of other less volatile elements, such as Fe and Mg were found to vary widely from one sight-line to another with gas-phase abundances in some cases being orders of magnitude below their solar counterparts. Detailed studies are reported of the depletion/density behavior of two other volatile elements which were previously considered to be virtually undepleted, S and Zn, using equivalent width data from both Copernicus and IUE observations. The results provide further evidence that the established dependence of depletion on n bar (H) extends to volatile elements and show that their use as tracers of metallicity, or for estimating hydrogen column densities, may lead to large errors in sight-lines through dense regions. It now appears that such elements may take part in the surface chemistry of grains and be important constituents of grain mantle material, although they probably do not contribute significantly to the bulk mass of grains. Due to the very similar atomic masses and ionization potentials of sulphur and phosphorous, the thermal velocity distributions of the singly ionized species of these elements in interstellar clouds should be very similar. However, a comparison of Doppler widths (b-values) derived for SIT and PIT in the same sight-lines from the Bohlin et al Copernicus equivalent width measurements has revealed an unexpected systematic discrepancy of a factor of approx. 1.7. This Discrepancy indicates that the normally adopted oscillators strengths of the PII lambda lambda 1153 and 1302 A lines may require revision.

Harris, A. W.↗

NASA NTRS1986

On the interpretation of the beta(sub p) relation in interstellar clouds

Troland and Heiles (1986) have recently presented an updated compilation of observational data concerning the relationship between the interstellar magnetic field strength B and the gas density rho (or, equivalently, the particle density n). One of the main findings of their survey was that B remains constant over the density range 0.1 - approx. 100 cu. cm and shows evidence for increase only a higher densities. They compared this result with theoretical predictions based on the Parker-instability scenario for the formation and evolution of interstellar clouds in the presence of the galactic magnetic field. In this picture, low-density gas is driven by the magnetic Rayleigh-Taylor instability into magnetic valleys, where it accumulates into denser concentrations. The gas initially flows along the magnetic field lines and there is little increase of the field strength with density; B only starts to rise when n becomes large enough for self-gravity to begin competing with the magnetic stresses. For a cloud mass of approx. 1,000 sub M and the measured background field strength, the critical density for contraction in approx. 75 cu. cm. Troland and Heiles therefore concluded that this scenario is basically consistent with the observations. This conclusion is debated.

Koenigl, A.↗