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At least 901 records · Page 50

Laser spectroscopy of the CN radical and astrophysical applications

The formation of CN radicals by flash photolysis of a number of parent molecules was monitored by laser induced fluorescence in the B2Sigma(plus)-X2Sigma(plus) transition of CN. The rotational and vibrational energy of the newly formed radicals in the X state was measured directly. Formation of CN(A2Pi) in the lower vibrational levels was determined by an indirect method based on resonant energy transfer to higher vibrational levels of the ground state. These laboratory studies have shown that high initial internal excitation of CN with rotational levels of maximum N equals 50-70 is the rule. In general, the formation of simple molecules in excited states is commonly the case. There appear to be astrophysical systems where radiation from these excited levels may be detectable. Such observations would serve as a probe of molecular formation.

Cody, R. J.↗

Radiation-Induced Leukemia at Doses Relevant to Radiation Therapy: Modeling Mechanisms and Estimating Risks

Because many cancer patients are diagnosed earlier and live longer than in the past, second cancers induced by radiation therapy have become a clinically significant issue. An earlier biologically based model that was designed to estimate risks of high-dose radiation induced solid cancers included initiation of stem cells to a premalignant state, inactivation of stem cells at high radiation doses, and proliferation of stem cells during cellular repopulation after inactivation. This earlier model predicted the risks of solid tumors induced by radiation therapy but overestimated the corresponding leukemia risks. Methods: To extend the model to radiation-induced leukemias, we analyzed in addition to cellular initiation, inactivation, and proliferation a repopulation mechanism specific to the hematopoietic system: long-range migration through the blood stream of hematopoietic stem cells (HSCs) from distant locations. Parameters for the model were derived from HSC biologic data in the literature and from leukemia risks among atomic bomb survivors v^ ho were subjected to much lower radiation doses. Results: Proliferating HSCs that migrate from sites distant from the high-dose region include few preleukemic HSCs, thus decreasing the high-dose leukemia risk. The extended model for leukemia provides risk estimates that are consistent with epidemiologic data for leukemia risk associated with radiation therapy over a wide dose range. For example, when applied to an earlier case-control study of 110000 women undergoing radiotherapy for uterine cancer, the model predicted an excess relative risk (ERR) of 1.9 for leukemia among women who received a large inhomogeneous fractionated external beam dose to the bone marrow (mean = 14.9 Gy), consistent with the measured ERR (2.0, 95% confidence interval [CI] = 0.2 to 6.4; from 3.6 cases expected and 11 cases observed). As a corresponding example for brachytherapy, the predicted ERR of 0.80 among women who received an inhomogeneous low-dose-rate dose to the bone marrow (mean = 2.5 Gy) was consistent with the measured ERR (0.62, 95% Cl =-0.2 to 1.9). Conclusions: An extended, biologically based model for leukemia that includes HSC initiation, inactivation, proliferation, and, uniquely for leukemia, long-range HSC migration predicts, %Kith reasonable accuracy, risks for radiationinduced leukemia associated with exposure to therapeutic doses of radiation.

Shuryak, Igor↗

A conjecture on global flow dynamics

Recent observations by the Yohkoh and Ulysses spacecraft have instilled a new appreciation for the role of the ever-evolving geometry and topology of the coronal magnetic structure in shaping and influencing the global solar wind outflow. While many issues concerning the global evolution of large-scale interplanetary flow structures await resolution, we focus here on one specific problem. Namely, we argue that when considering the impact of solar activity on heliosphere scales, rather more attention should be directed toward ascertaining the nature and implications of long-term. Large-scale changes in the corona than toward the more dramatic and highly visible manifestations of solar activity, such as flares and coronal mass ejections (CMEs). That is, while energetic CMEs unquestionably disrupt the interplanetary medium locally and for a time by the broader measure they prompt lasting, wide-spread heliospheric response only when they occur as the agent of substantial, long-term change in the global configuration of the corona. In support, we point to various evidences of coronal change associated with major episodes of heliospheric disruption, and we discuss the limitations imposed by current observation techniques. In addition, we offer dynamical arguments (illustrated by a simple dynamical simulation) that when the coronal configuration changes quickly enough over sufficient spatial scale, a re-adjustment wave linking the initial and final quasi-steady flow states must propagate out from the Sun. This wave is transitory and global, and its amplitude can grow to substantial proportions with heliocentric distance. Moreover, the readjustment wave occurs whether or not the corona needs to expel CMEs to reconfigure itself. We suggest that it is this wave (and not so much the remnants of the initiating CMEs) that constitutes global merged interaction regions in the outer heliosphere.

Pizzo, V. J.↗

Grinding kinetics and equilibrium states

The temporary and permanent equilibrium occurring during the initial stage of cement grinding does not indicate the end of comminution, but rather an increased energy consumption during grinding. The constant dynamic equilibrium occurs after a long grinding period indicating the end of comminution for a given particle size. Grinding equilibrium curves can be constructed to show the stages of comminution and agglomeration for certain particle sizes.

Opoczky, L.↗

Activated recombinative desorption: A potential component in mechanisms of spacecraft glow

The concept of activated recombination of atomic species on surfaces can explain the production of vibrationally and translationally excited desorbed molecular species. Equilibrium statistical mechanics predicts that the molecular quantum state distributions of desorbing molecules is a function of surface temperature only when the adsorption probability is unity and independent of initial collision conditions. In most cases, the adsorption probability is dependent upon initial conditions such as collision energy or internal quantum state distribution of impinging molecules. From detailed balance, such dynamical behavior is reflected in the internal quantum state distribution of the desorbing molecule. This concept, activated recombinative desorption, may offer a common thread in proposed mechanisms of spacecraft glow. Using molecular beam techniques and equipment available at Los Alamos, which includes a high translational energy 0-atom beam source, mass spectrometric detection of desorbed species, chemiluminescence/laser induced fluorescence detection of electronic and vibrationally excited reaction products, and Auger detection of surface adsorbed reaction products, a fundamental study of the gas surface chemistry underlying the glow process is proposed.

Cross, J. B.↗

United States microgravity programs

The U.S. Microgravity Program encompasses research initiatives of the NASA Office of Space Science and Applications and Office of Commercial Programs. NASA involvement in space missions extends to the U.S Microgravity Laboratory, the International Microgravity Laboratory, the Space Life Sciences Mission, and planned activities aboard the Japanese and German Spacelab missions. Flight programs under the aegis of NASA's Centers for the Commercial Development of Space will employ the Space Shuttle-based Commercial Middeck Augmentation Module and the Suborbital and Orbital Expendable Launch Vehicles. The projected Space Station will include a significant microgravity program.

Ott, Richard H.↗

Comments on the BLAG model - The carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years

A self-consistent method of determining initial conditions for the model presented by Berner, Lasaga, and Garrels (1983) (henceforth, the BLAG model) is derived, based on the assumption that the CO2 geochemical cycle was in steady state at t = -100 m.y. (million years). This initialization procedure leads to a dissolved magnesium concentration higher than that calculated by Berner, Lasaga, and Garrels and to a low ratio of dissolved calcium to bicarbonate prior to 60 m.y. ago. The latter prediction conflicts with the geologic record of evaporite deposits, which requires that this ratio remain greater than 0.5. The contradiction is probably caused by oversimplifications in the BLAG model, such as the neglect of the cycles of organic carbon and sulfur.

Kasting, J. F.↗

Comments on the BLAG model: the carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years

A self-consistent method of determining initial conditions for the model presented by Berner, Lasaga, and Garrels (1983) (henceforth, the BLAG model) is derived, based on the assumption that the CO2 geochemical cycle was in steady state at t = -100 my (million years). This initialization procedure leads to a dissolved magnesium concentration higher than that calculated by Berner, Lasaga, and Garrels and to a low ratio of dissolved calcium to bicarbonate prior to 60 my ago. The latter prediction conflicts with the geologic record of evaporite deposits, which requires that this ratio remain greater than 0.5. The contradiction is probably caused by oversimplifications in the BLAG model, such as the neglect of the cycles of organic carbon and sulfur.

Evolution, Planetary↗

Mars: The initial emplacement of ground ice in response to the thermal evolution of its early crust

Given the geomorphic evidence for the widespread occurrence of water and ice in the early martian crust, and the difficulty involved in accounting for this distribution given the present climate, it has been suggested that the planet's early climate was originally more Earth-like, permitting the global emplacement of crustal H2O by direct precipitation as snow or rain. The resemblance of the martian valley networks to terrestrial runoff channels, and their almost exclusive occurrence in the planet's ancient (approximately 4 billion year old) heavily cratered terrain, is often cited as evidence of just such a period. An alternative school of thought suggests that the early climate did not differ substantially from that of today. Advocates of this view find no compelling reason to invoke a warmer, wetter period to explain the origin of the valley networks. Rather, they cite evidence that the primary mechanism of valley formation was ground water sapping, a process that does not require that surface water exist in equilibrium with the atmosphere. However, while sapping may successfully explain the origin of the small valleys, it fails to address how the crust was initially charged with ice as the climate evolved towards its present state. Therefore, given the uncertainty regarding the environmental conditions that prevailed on early Mars, the initial emplacement of ground ice is considered from two perspectives: (1) that the early climate started warm and wet, but gradually cooled with time; and (2) that it never differed substantially from that of today.

Clifford, Stephen M.↗

The evolution of the early Martian climate and the initial emplacement of crustal H2O

Given the geomorphic evidence for the widespread occurrence of water and ice in the early Martian crust, and the difficulty involved in accounting for this distribution given the present climate, it has been suggested that the planet's early climate was originally more Earth-like, permitting the global emplacement of crustal H2O by direct precipitation as snow or rain. The resemblance of the Martian valley networks to terrestrial runoff channels and their almost exclusive occurrence in the planet's ancient (approximately 4-b.y.-old) heavily cratered terrain are often cited as evidence of just such a period. An alternative school of thought suggests that the early climate did not differ substantially from that of today. Advocates of this view find no compelling reason to invoke a warmer, wetter period to explain the origin of the valley networks. Rather, they cite evidence that the primary mechanism of valley formation was groundwater sapping, a process that does not require that surface water exists in equilibrium with the atmosphere. However, while sapping may successfully explain the origin of the small valleys, it fails to address how the crust was initially charged with ice as the climate evolved towards its present state. Therefore, given the uncertainty regarding the environmental conditions that prevailed on early Mars, the initial emplacement of ground ice is considered here from two perspectives: (1) the early climate started warm and wet, but gradually cooled with time, and (2) the early climate never differed substantially from that of today.

Clifford, S. M.↗

Control of Initialized Fractional-Order Systems

Due to the importance of historical effects in fractional-order systems, this paper presents a general fractional-order control theory that includes the time-varying initialization response. Previous studies have not properly accounted for these historical effects. The initialization response, along with the forced response, for fractional-order systems is determined. Stability properties of fractional-order systems are presented in the complex Airplane, which is a transformation of the s-plane. Time responses are discussed with respect to pole positions in the complex Airplane and frequency response behavior is included. A fractional-order vector space representation, which is a generalization of the state space concept, is presented including the initialization response. Control methods for vector representations of initialized fractional-order systems are shown. Nyquist, root-locus, and other input-output control methods are adapted to the control of fractional-order systems. Finally, the fractional-order differintegral is generalized to continuous order-distributions that have the possibility of including a continuum of fractional orders in a system element.

Hartly, Tom T.↗

Control of Initialized Fractional-Order Systems

Due to the importance of historical effects in fractional-order systems, this paper presents a general fractional-order control theory that includes the time-varying initialization response. Previous studies have not properly accounted for these historical effects. The initialization response, along with the forced response, for fractional-order systems is determined. Stability properties of fractional-order systems are presented in the complex w-plane, which is a transformation of the s-plane. Time responses are discussed with respect to pole positions in the complex w-plane and frequency response behavior is included. A fractional-order vector space representation, which is a generalization of the state space concept, is presented including the initialization response. Control methods for vector representations of initialized fractional-order systems are shown. Nyquist, root-locus, and other input-output control methods are adapted to the control of fractional-order systems. Finally, the fractional-order differintegral is generalized to continuous order-distributions that have the possibility of including a continuum of fractional orders in a system element.

Hartley, Tom T.↗

Effect of void-size distribution on the Hugoniot state at low shock pressures

In most theoretical and experimental investigations into the shock response of underdense solid media, the influence of the medium's mesostructure on the resulting pressure and degree of compaction has not been taken into account. In typical cases examined, shock pressures are well in excess of 1 GPa and this approach is clearly justified. However, at low pressures, calculations show that the distribution of void sizes can affect the final state achieved upon shocking the medium from a given initial porosity. This paper analyzes the response of porous aluminum to low pressure shocking and demonstrates a dependence of the final shocked state on the distribution of void sizes.

Griffiths, David J.↗

A bit serial sequential circuit

Normally a sequential circuit with n state variables consists of n unique hardware realizations, one for each state variable. All variables are processed in parallel. This paper introduces a new sequential circuit architecture that allows the state variables to be realized in a serial manner using only one next state logic circuit. The action of processing the state variables in a serial manner has never been addressed before. This paper presents a general design procedure for circuit construction and initialization. Utilizing pass transistors to form the combinational next state forming logic in synchronous sequential machines, a bit serial state machine can be realized with a single NMOS pass transistor network connected to shift registers. The bit serial state machine occupies less area than other realizations which perform parallel operations. Moreover, the logical circuit of the bit serial state machine can be modified by simply changing the circuit input matrix to develop an adaptive state machine.

Hu, S.↗

Data presentation techniques for rotating machinery malfunction diagnosis

Baseline steady state data is excellent for documentation of vibration signals at normal operating conditions. Assuming that a set of initial data was acquired with the machinery in a good state of repair, any future changes or deterioration in mechanical condition can be easily compared to the baseline information. Often this type of comparison will yield sufficient information for evaluation of the problem. However, many malfunctions require the analysis of transient data in order to identify the malfunction. Steady-state data formats consist of: Time Base Waveform, Orbit, Spectrum. Transient data formats consist of: Polar, Bode, Cascade. Our objective is to demonstrate the use of the above formats to diagnose a machine malfunction. A turbine-driven compressor train is chosen as an example. The machine train outline drawing is shown.

Spettel, T.↗

Estimation of time- and state-dependent delays and other parameters in functional differential equations

A parameter estimation algorithm is developed which can be used to estimate unknown time- or state-dependent delays and other parameters (e.g., initial condition) appearing within a nonlinear nonautonomous functional differential equation. The original infinite dimensional differential equation is approximated using linear splines, which are allowed to move with the variable delay. The variable delays are approximated using linear splines as well. The approximation scheme produces a system of ordinary differential equations with nice computational properties. The unknown parameters are estimated within the approximating systems by minimizing a least-squares fit-to-data criterion. Convergence theorems are proved for time-dependent delays and state-dependent delays within two classes, which say essentially that fitting the data by using approximations will, in the limit, provide a fit to the data using the original system. Numerical test examples are presented which illustrate the method for all types of delay.

Murphy, K. A.↗

Estimation of time- and state-dependent delays and other parameters in functional differential equations

A parameter estimation algorithm is developed which can be used to estimate unknown time- or state-dependent delays and other parameters (e.g., initial condition) appearing within a nonlinear nonautonomous functional differential equation. The original infinite dimensional differential equation is approximated using linear splines, which are allowed to move with the variable delay. The variable delays are approximated using linear splines as well. The approximation scheme produces a system of ordinary differential equations with nice computational properties. The unknown parameters are estimated within the approximating systems by minimizing a least-squares fit-to-data criterion. Convergence theorems are proved for time-dependent delays and state-dependent delays within two classes, which say essentially that fitting the data by using approximations will, in the limit, provide a fit to the data using the original system. Numerical test examples are presented which illustrate the method for all types of delay.

Murphy, K. A.↗

Modelling Greenland Outlet Glaciers

The objective of this project was to develop simple yet realistic models of Greenland outlet glaciers to better understand ongoing changes and to identify possible causes for these changes. Several approaches can be taken to evaluate the interaction between climate forcing and ice dynamics, and the consequent ice-sheet response, which may involve changes in flow style. To evaluate the icesheet response to mass-balance forcing, Van der Veen (Journal of Geophysical Research, in press) makes the assumption that this response can be considered a perturbation on the reference state and may be evaluated separately from how this reference state evolves over time. Mass-balance forcing has an immediate effect on the ice sheet. Initially, the rate of thickness change as compared to the reference state equals the perturbation in snowfall or ablation. If the forcing persists, the ice sheet responds dynamically, adjusting the rate at which ice is evacuated from the interior to the margins, to achieve a new equilibrium. For large ice sheets, this dynamic adjustment may last for thousands of years, with the magnitude of change decreasing steadily over time as a new equilibrium is approached. This response can be described using kinematic wave theory. This theory, modified to pertain to Greenland drainage basins, was used to evaluate possible ice-sheet responses to perturbations in surface mass balance. The reference state is defined based on measurements along the central flowline of Petermann Glacier in north-west Greenland, and perturbations on this state considered. The advantage of this approach is that the particulars of the dynamical flow regime need not be explicitly known but are incorporated through the parameterization of the reference ice flux or longitudinal velocity profile. The results of the kinematic wave model indicate that significant rates of thickness change can occur immediately after the prescribed change in surface mass balance but adjustments in flow rapidly diminish these rates to a few cm/yr at most. The time scale for adjustment is of the order of a thousand years or so.

vanderVeen, Cornelis↗