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At least 901 records · Page 50

Analysis of Launch Vehicle Liftoff Debris: Historical Perspective from Space Shuttle and Application to Artemis I

Human exploration-class launch vehicles are inherently prone to debris due to the extreme environments generated during pre-launch operations, liftoff, and flight. The use of cryogenic propellants often requires thermal protection system (TPS) coatings, typically foam, to maintain the propellant conditions in the tank and prevent an accumulation ice on the external surface of the vehicle. Some ice growth is to be expected at umbilical interfaces, vents, flanges, or brackets where it is difficult to apply TPS. This ice may come loose at any time due to wind on the launch pad, structural vibration and acoustics after rocket ignition, or aerodynamic forces during flight. This phenomena is especially apparent on vehicles with no TPS, such as the Saturn V rockets used in the Apollo Program, see Figure 1. During propellant tanking, the thermal contraction of the underlying substrate may generate cracks in the TPS (Figure 1). Chunks of TPS can release due to the expansion of ingested gas from cryopumping or from aerodynamic forces if the crack creates an offset surface. Most foams will also have a certain amount of “popcorning” where small pieces of foam will pop off during flight because of the differential between the static surface pressure and the pressure of the gas trapped in the foam cell structure. There are a number of other coating or closeout materials that may be shed from the vehicle and become debris. During pre-launch operations and liftoff, the vehicle may also be exposed to debris originating from the launch pad or ground support equipment. This debris is separate from foreign object debris, or FOD, which is not intended to be present and is strictly controlled through operations and maintenance procedures. In this case, debris is generated from hardware and materials that are necessary for launch and are subject to the intense vibration, acoustics, and direct plume impingement of the launch environment. Examples include ice from umbilicals, tape and tie wraps that protect cables, and rust or corrosion from the launch platform. While NASA has historically been aware of debris as a potential issue that could cause a failure resulting in loss of mission, loss of vehicle, or loss of crew, the likelihood and severity of that risk was not always well understood or given sufficient weight in program and flight decisions. After the Space Shuttle Columbia accident (STS-107), the investigation found that foam TPS debris shed from the external tank was the proximate cause of the damage to the orbiter wing. Six previous observations of debris released from the foam ramp that covered the bipod connecting the forward end of the orbiter to the external tank resulted in minor changes or were determined to be accepted flight risks. Two occurrences of bipod ramp foam loss were not identified until the STS-107 investigation. Despite the damage inflicted by these debris strikes, the Shuttle Program Requirements Control Board deemed the vehicle safe to fly. During the Return to Flight effort following the Columbia disaster, NASA Engineering developed a process for the assessment of debris transport, impact, and damage tolerance to support independent assessments of risk by NASA Safety and Mission Assurance (S&MA). Under this system, each element (vehicle or ground system) defines a catalog of all expected debris based on launch history, component testing, or analysis. Debris transport analysis (DTA) is conducted using the debris catalog characteristics and potential flow transport mechanisms (e.g., vehicle aerodynamics, gravity, wind, plume-driven). The predicted debris impact locations and velocities are provided to the hardware owners, who use available test data and analysis to determine whether each component can withstand the impacts. In cases where the element hardware may be severely damaged or fail, the options are to mitigate the debris source through some change in design or operation, or to work with S&MA to try to characterize the probability of the impact and damage for program risk acceptance. Because of the differences in debris characteristics and transport, the DTA has been divided between the Liftoff and Ascent regimes. The development and application of Liftoff DTA methodology from the Shuttle Program to the current Artemis Program is the subject of this paper. Liftoff DTA covers the time from the start of pre-launch operations at the launch pad, up until the vehicle clears the launch tower and there is no longer any interaction with ground systems. Debris transport during this period is broadly classified as either gravity, wind, and plume-entrained (GWPE) or plume driven (PD). GWPE debris is generally lower speed, travelling in a forward-to-aft direction. PD transport includes flow features from the rocket ignition transient, as well as plume impingement and recirculation that occur as the vehicle lifts off the launch platform. In these cases, the debris typically moves in an aft-to-forward direction at higher speeds. The applicable transport mechanisms must be considered for each piece of debris depending on the material, and release location and time. For example, rust or metallic debris from the tower could fall (GWPE) and impact the vehicle before landing on the launch platform deck where it could be also be transported by plume impingement (PD). However, falling ice (GWPE) from an umbilical is unlikely to survive impact with the vehicle or launch platform and be available for PD transport. Modeling of debris transport is accomplished using a set of DTA tools which simulate debris trajectories subject to a reference frame acceleration (i.e., gravity) and aerodynamic drag. Where the trajectory encounters a solid surface, the debris is allowed to rebound with a specified coefficient of restitution. The drag is calculated by interpolating the fluid state at each point in the debris trajectory from high-fidelity computational fluid dynamics (CFD) simulations of the launch vehicle and pad. The CFD data may either be static (steady state or time averaged), typically for GWPE transport, or dynamic (time-accurate) for PD flow features like the ignition transient. Examples of the CFD flow field solutions for the Space Launch System (SLS) rocket and launch pad are shown in Figure 2. Typical SLS debris trajectory predictions from DTA are illustrated in Figure 3. The final version of this paper will include a more detailed examination of the Liftoff DTA process developed during the Shuttle Program, and how it has been augmented and applied to the SLS rocket under the Artemis Program. Comparisons with debris observations from the Artemis I launch will demonstrate validation of the tools and methodology.

Debris↗

Pathways to formulate lightweight and ultra-lightweight 3D printable cementitious composites

Here, this paper studies the pathways to formulate lightweight and ultra-lightweight 3D printable cementitious composites. A hybrid approach was proposed by combining the advantages of traditional chemical-induced foaming (foaming approach) and lightweight particulate inclusions (synthetic foam approach). A comprehensive experimental program was conducted to evaluate the effects of foaming agents and fly ash cenosphere (FAC) on the printability, microstructure, mechanical and thermal properties of 3D printed samples. The results showed that the hybrid approach could produce a mixture with a density as low as 470 kg/m 3 while ensuring good flowability and buildability owing to the lubricating effect of foaming and supporting skeleton formed by FAC. In addition, a three-step homogenization procedure was also developed to predict the effective elastic modulus and thermal conductivity of 3D printable cementitious composites and cementitious foam. The findings of the study highlighted the effectiveness of the hybrid approach in formulating 3D printable ultra-lightweight cementitious composites in thermal insulation and acoustic applications.

36 MATERIALS SCIENCE↗

Pool boiling heat transfer characteristics of low-GWP refrigerants in a horizontal tube bundle configuration

Heat transfer enhancement techniques have been adapted on the shell side to improve the overall performance of the flooded evaporators, such as finned tubes. In recent years, it has been demonstrated that the metal foam structure can offer enhanced heat transfer performance under pool boiling conditions. However, there are not much research in the open literature that examine the feasibility of metal foam embedded tubes in horizontal tube bundle configurations. Therefore, this paper proposed a novel metal foam embedded tube (i.e., foam embedded outside the tube) to improve the heat transfer behavior of flooded evaporators. Further, the experiments were performed on a horizontal tube bundle with a staggered arrangement. Moreover, the performance of low global warming potential (GWP) refrigerants (R-1234yf and R-1234ze(E)) is compared against R-134a for both plain tubes and metal foam tubes with porosities of 81%, 75%, and 62%. The results showed that a metal foam tube with a porosity of 62% showed a maximum heat transfer coefficient (HTC) enhancement of 291% compared to the plain tube. As compared with R-134a, the HTCs of R-1234yf and R-1234ze(E) are nearly 10% higher and 5% lower, respectively.

42 ENGINEERING↗

Simulation of DWPF Chemical Process Cell Using a Reaction Calorimeter

The Defense Waste Processing Facility (DWPF) converts liquid radioactive waste into glass using a Sludge Receipt Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) in addition to other processes. The SRAT and SME processes can be simulated on a small-scale using the Mettler-Toledo Reaction Calorimeter (RC1). This equipment is able to automate the execution and monitoring of experiments involving nonradioactive chemical simulants. During the chemical processing of sludge in the SRAT process, foam begins to form and can foam over the reaction vessel. The current antifoam used at DWPF creates a risk of increased flammability and has a limited pH range. Usually, mercury is circulated back into the reaction vessel during the SRAT process, making it difficult to remove. To combat foam over, novel antifoams will be tested during the boil-up process using the RC1. To improve mercury extraction, 3D-printed coalescer columns will be tested within the Mercury Water Wash Tank (MWWT) of the RC1. Testing of Simulant Sludge Batch 6 (SB6) was performed to ensure: the sludge would form a stable foam at boiling during full SRAT/SME runs; the antifoam would reduce the amount of foam within the vessel The sludge and a Precipitate Reactor Feed Tank (PRFT) simulant with monosodium titanate (MST) were mixed separately, combined, and then heated to boiling. As shown below, the antifoam used was able to eliminate the foam within the vessel, as expected. The FormLabs Form2 3D Printer can be used to create roughly 3-inch tall and 1-inch diameter columns from clear and ceramic resins. The columns will utilize chemical and physical forces to draw the mercury out of a condensed offgas stream leaving the RC1 reaction vessel. These columns will be tested during full SRAT/SME runs on the basis of how well they are able to collect elemental mercury. In preparation for full-scale runs, the RC1 equipment was assembled onto a custom table and tested with water runs. The software used to control automation, iControl, has a user-friendly interface that allows the experiment to be altered as needed. An example of the data recorded during an experimental run is represented in Figure 1 below. Water runs were utilized as a way to prove if the RC1 system was functioning in the following areas: Boil-up rates, Chemical additions using pumps, Temperature readings, Balance readings, Probe readings, Offgas system, Agitation. Future Plans: Five novel antifoams will be tested during full SRAT/SME runs. The most effective antifoam will be utilized in DWPF's Chemical Process Cell. The design of the Mercury Extraction Coalescer can be further manipulated to increase the extraction of not only elemental mercury, but other heavy metals in environmental remediation processes as well.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Aircraft seat cushion materials tests

Five component level flammability tests were conducted in a 400 cubic foot chamber to determine the products of combustion and relative destruction of coated (with fire-retardants) and uncoated polyurethane foams during exposure of the foams to a large flaming ignition source for five minutes. The test results indicate that the improved state-of-the-art polyurethane foams without the added fire retardant and coating treatments were not significantly better than untreated older less fire-resistant polyurethane foams. however, by treating and coating the state-of-the-art foams, the production of toxic gases was delayed and the destruction of the foam limited.

Bricker, R. W.↗

In situ processing methods for composite fuselage sandwich structures

Conventional sandwich structure fabrication methods are labor intensive and high in cost. A low cost method is needed to produce lightweight sandwich structures. Sundstrand has developed a series of in situ composite fabrication methods in which the raw materials (skin and core materials) are placed in a closed mold, and the component is produced in one heating cycle. Internal pressure is generated by chemical agents during the thermal cycles, which consolidates the skins and produces the foam core. The finished part is a net-shape composite sandwich structure with skins and a foamed core. The in situ process reduces cost by eliminating several secondary operations that are used in conventional fabrication methods. Further, a strong molecular bond is produced between the core and skin, which eliminates adhesive bonding and prevents a weak bond section in the sandwich structure. In this investigation, we evaluated the feasibility of the in situ process using thermoset materials currently under consideration for commercial airplane fuselage applications, such as keel sections. The materials used were Hercules 855340 toughened epoxy resin in both liquid and powder forms, and 3M Scotchply PR500 resin, manufactured by 3M Corporation, in powder form. We successfully foamed these resins and produced experimental panels with AS-4/855340 Hercules prepreg skins. Chopped fibers were added to the core to increase performance of the foam. Mechanical property testing on these panels showed properties competitive with other foams. Additional experiments are required to optimize the in situ foam core sandwiches for specific properties and applications.

Saatchi, Hossein↗

A water blown urethane insulation for use in cryogenic environments

Thermal Protection Systems (TPS) of NASA's Space Shuttle External Tank include polyurethane and polyisocyanurate modified polyurethane foam insulations. These insulations, currently foamed with CFC 11 blowing agent, serve to maintain cryogenic propellant quality, maintain the external tank structural temperature limits, and minimize the formation of ice and frost that could potentially damage the ceramic insulation on the space shuttle orbiter. During flight the external tank insulations are exposed to mechanical, thermal and acoustical stresses. TPS must pass cryogenic flexure and substrate adhesion tests at -253 C, aerothermal and radiant heating tests at fluxes up to approximately 14 kilowatts per square meter, and thermal conductivity tests at cryogenic and elevated temperatures. Due to environmental concerns, the polyurethane insulation industry and the External Tank Project are tasked with replacing CFC 11. The flight qualification of foam insulations employing HCFC 141b as a foaming agent is currently in progress; HCFC 141b blown insulations are scheduled for production implementation in 1995. Realizing that the second generation HCFC blowing agents are an interim solution, the evaluation of third generation blowing agents with zero ozone depletion potential is underway. NASA's TPS Materials Research Laboratory is evaluating third generation blowing agents in cryogenic insulations for the External Tank; one option being investigated is the use of water as a foaming agent. A dimensionally stable insulation with low friability, good adhesion to cryogenic substrates, and acceptable thermal conductivity has been developed with low viscosity materials that are easily processed in molding applications. The development criteria, statistical experimental approach, and resulting foam properties will be presented.

Blevins, Elana↗

Development of Lead Free Energy Absorber for Space Shuttle Blast Container

The Space Shuttle vehicle (SSV) is connected to the mobile launch platform (MLP) by four aft skirt hold down studs on each solid rocket booster (SRB). Prior to lift-off, the frangible nuts inside the aft skirt blast containers (BC) are severed into two nut halves by two pyrotechnic booster cartridges. This action releases the SSV and allows the hold down studs to eject through the aft skirt bore and then down into the MLP. USBI has been tasked to upgrade the BC for two specific reasons; 1. to eliminate lead for environmental concerns, and 2. to reduce the chance of nut recontact with the holddown stud. Nut recontact with the stud has been identified as a likely contributor to stud hangups. This upgrade will replace the lead liner with an aluminum foam material. The aluminum foam used as a energy absorber is a proven design in many other aerospace/defense applications. Additional benefits of using the open cell, energy absorbent aluminum foam in place of the solid lead liner are: A. Lead handling/ exposure, and possible contamination, along with hazardous waste disposal will be eliminated; B. Approximately 200 lbs. weight savings will be contributed to each Space Shuttle flight by using aluminum foam over lead; C. The new aluminum liner is designed to catch all shrapnel from frangible nuts thus virtually eliminating chance of foreign object debris (FOD) exiting the HDP, and causing potential damage to the vehicle; D. Potential of using the lighter aluminum liner over lead, allows for easier assembly and disassembly of blast container elements, also allowing for improvements in safety, operator handling, and efficiency of operations. Six BC firing tests will be required to determine if the new liner material will perform in a way to decrease the chance of stud hangups and enhance the ability of the BC to retain blast debris. Testing will be performed at the Kennedy Space Center (KSC) facility known as the Launch Equipment Test Facility (LETF), and will simulate the SRB hold- down post, with actual BC hardware and pyrotechnics assembled, and then test fired. Initial testing was performed in 1997 using a frangible nut in a static drop test over lead and aluminum foam sheet materials. The aluminum foam showed a dramatic improvement of energy absorption over the lead liner material. Proof-of-Principle testing at the KSC-LETF commenced in May, 1998, and is expected to be completed by June, 1998.

Ingram, T.↗

Comparison of Computerized Sway Referencing and Standing on a Compliant Surface

Background: By removing vision and altering somatosensory inputs, we can examine the contributions of the vestibular system on balance control. Computerized Dynamic Posturography (CDP) systems accomplish this by using a dynamic plate that moves in proportion to the sway of the subject. A potential alternative to CDP is the use of a compliant foam surface. The goal of this study was to compare postural sway during each condition. Methods: Thirty-two healthy subjects (16 male and 16 female) were tested on a Equitest computerized posturography system and on a 5 inch thick block of foam (NeuroCom International; Clackamas, OR). Subjects performed three trials with their head erect and five trials with dynamic head tilts ( 20 at 0.33Hz) in the anterior-posterior (AP) plane. Subjects were instructed to stand quietly with their arms folded and eyes closed for each trial lasting 20 seconds. The sway in both AP and medial-lateral (ML) planes was calculated for each trial, as well as the total sway path length. Results: In general, AP sway tended to be greater on the Equitest than on foam and greater during the head movement trials than the head erect. The ML sway was consistently higher on foam and did not vary between head erect and moving conditions. Sway path length was consistently greater for head erect trials on foam and tended to be greater for head movement trials on the Equitest. The addition of head movements increases AP sway and the total path length. Conclusions: Based on the increase of sway in the ML direction, it is important to quantify sway in all directions when on a compliant foam surface.

Dean, S. Lance↗

Large Scale Shearography Inspection of the Space Shuttle External Fuel Tank

Shearography was successfully used to inspect the damaged region of ET122 for nonvisible damage. The shearography inspection was extensive covering over 3100 square feet of foam and lasting 9 months. Most foam damage was visible and shearography results confirmed that foam damage in visibly impacted regions did not extend outside the area with visible damage. Of the 21 nonvisible defect indications detected with shearography, none were determined to be actual foam damage. Inspections were intentionally conservative since no experience base was available for debris damaged foam. Shearography results were used in conjunction with tactile and visual inspection to support the acceptance of the foam application allowing the tank to move forward for refurbishment.

Ussery, Warren↗

Fast Response, Open-Celled Porous, Shape Memory Effect Actuators with Integrated Attachments

This invention relates to the exploitation of porous foam articles exhibiting the Shape Memory Effect as actuators. Each foam article is composed of a plurality of geometric shapes, such that some geometric shapes can fit snugly into or around rigid mating connectors that attach the Shape Memory foam article intimately into the load path between a static structure and a moveable structure. The foam is open-celled, composed of a plurality of interconnected struts whose mean diameter can vary from approximately 50 to 500 microns. Gases and fluids flowing through the foam transfer heat rapidly with the struts, providing rapid Shape Memory Effect transformations. Embodiments of porous foam articles as torsional actuators and approximately planar structures are disposed. Simple, integral connection systems exploiting the ability to supply large loads to a structure, and that can also supply hot and cold gases and fluids to effect rapid actuation are also disposed.

Jardine, Andrew Peter↗

Thermal Protection System Application to Composite Cryotank Technology Demonstrator

The EM41 Thermal Protection System (TPS) team contributed to the success of the Composite Cryotank Technology Demonstrator (CCTD) manufacturing by developing and implementing a low-cost solution to apply cryoinsulation foam on the exterior surface of the tank in the NASA Marshall Space Flight Center (MSFC) TPS Development Facility, Bldg. 4765. The TPS team used techniques developed for the smallscale composite cryotank to apply Stepanfoam S-180 polyurethane foam to the 5.5-meter CCTD using a manual spray process. Manual spray foam technicians utilized lifts and scaffolding to access the barrel and dome sections of the large-scale tank in the horizontal orientation. During manufacturing, the tank was then oriented vertically, allowing access to the final barrel section for manual spray foam application. The CCTD was the largest application of manual spray foam performed to date with the S-180 polyurethane foam and required the TPS team to employ best practices for process controls on the development article.

Protz, Alison↗

Eco-friendly passive radiative cooling using recycled packaging plastics

Passive daytime radiative cooling, requiring zero external energy consumption, is a promising cooling strategy achieved by simultaneously reflecting solar irradiance and thermally radiating heat into the cold outer space (~3 K) through the atmospheric transparency window. However, current materials for passive radiative cooling face huge challenges, such as complicated fabrication approaches, expensive raw materials, and environmental requirements for practical applications. In line with the urgent need for plastic recycling to curb global environmental pollution, the recycled plastics are used to fabricate a passive radiative cooling material. Herein, the foam-paper composite (FPC) with excellent self-cooling capability is fabricated by a simple crushing-and-mixing procedure using recycled polystyrene (PS) foam and printer paper. The superhydrophobic PS foam particles not only protect the FPC from water damage for field applications but also reinforce its solar reflectivity via their porous structure. The cellulose fibers in printer paper can efficiently emit infrared thermal radiation into the cold outer space and bond dispersed PS foam particles together, further increasing its mechanical strength. The combination of highly diffusely reflective PS foam particles and fiber-based printer paper results in a reflectivity of 96% in the solar spectrum, a sub-ambient cooling performance of 8.4 degrees C, and a maximum radiative cooling power of 90 W/m2 during a 24-h cycle. Meanwhile, the FPC with high humidity can maintain its high solar reflectivity, which promotes its application in humid subtropical areas. Further, the low material cost and ease of fabrication will provide a path for effective daytime radiative cooling, especially in less developed areas.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Evaluation of different getter substrates using two-dimensional gas chromatography with time of flight mass spectrometry

We report while understanding hydrogen uptake by organic based getters such as 1,4-bis(phenylethynyl)benzene (DEB) combined with a palladium(0)bis(dibenzylideneacetone) (Pd(dba) 2 ) catalyst is essential, another crucial element to understand is the decomposition of the DEB, Pd(dba) 2 , and/or substrate material. The breakdown of these materials may create unwanted volatiles, which may interact with and lead to deterioration of sensitive materials. Moreover, it is critical to understand if different substrates cause the getter and/or catalyst to degrade in different manners. Utilizing comprehensive two-dimensional gas chromatography (GC×GC) with time-of-flight mass spectrometry (TOFMS), the presence of volatiles located in the headspace of various DEB/Pd(dba) 2 getter substrates is examined. These samples include a getter infused silicone foam, a hydrogenated getter infused silicone foam, an activated carbon getter pellet, and a hydrogenated activated carbon getter pellet. Application of Fisher ratio (F-ratio) analyses lead to the identification of several compounds that are generated or consumed through the hydrogenation process. These include benzene derivatives such as bibenzyl, benzaldehyde, and vinyl benzoate in the activated carbon pellets and 1,5-diphenyl-3-pentanone, toluene, styrene, and 1–1'(2-pentene 1,5-diyl)bis benzene in the silicone foams, and alkane/alkene derivatives such undecane, 4-tridecene, and decane in the activated carbon pellets and 2,6-dimethyl undecane in the silicone foams. Further comparison of the different hydrogenated getter substrates (e.g. activated carbon pellet and silicone foam) indicates that the different substrates alter the decomposition products created from the degradation of the DEB and Pd(dba) 2 .

47 OTHER INSTRUMENTATION↗

Effect of glass forming additives on low-activity waste feed conversion to glass

A significant effort was invested in the past to develop and refine mathematical models that relate the composition of nuclear waste glasses with their properties, such as viscosity, electrical conductivity, or chemical durability. However, less attention has been paid to the formulation of the melter feed itself, such as the chemical form and the particle size of the glass forming and modifying additives (GFMA), which have a significant effect on the feed-to-glass conversion process during melting. To address this issue, we systematically changed the mineral composition of a simulated low-activity waste melter feed and inspected its melting behavior. When substituting minerals with corresponding oxides and hydroxides, we found that different alumina sources (kyanite, gibbsite, boehmite, or corundum) had the strongest effect on the feed melting process, whereas the sources of Ca, Mg, and Zr had little effect. Further, the x-ray diffraction analysis showed that the alumina sources differ in their dissolution kinetics: early dissolving alumina sources, such as gibbsite (Al(OH) 3 ) and boehmite (AlO(OH)), increase the transient glass-forming melt viscosity at early stages, when gases still evolve, causing extended foaming, whereas alumina sources that dissolve at high temperatures, such as kyanite (Al 2 SiO 5 ) and corundum (Al 2 O 3 ), keep the transient glass-forming melt viscosity low and lead to a faster foam collapse. Using viscosity-composition relationship to estimate the viscosity of transient glass-forming melts in the primary foaming range, we found that the primary foam began to collapse at 360 to 800 Pa s, and fully collapsed between 65 and 260 Pa s. This result agrees with our previous studies, according to which the glass-forming melt viscosity at the cold cap foam bottom ranged from 24 to 85 Pa s.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Viscosity of glass-forming melt at the bottom of high-level waste melter feed cold caps: Effects of temperature and incorporation of solid components

At the final stages of conversion of melter feed (glass batch) to molten glass, the transient glass-forming melt becomes a continuous liquid phase encapsulating dissolving solid particles and gas bubbles that produce primary foam at the bottom of the cold cap (the reacting melter feed in an electric glass melting furnace). The glass-forming melt viscosity plays a dominant role in primary foam formation, stability, and eventual collapse, thus affecting the rate of melting (the glass production rate per cold cap area). For several melter feeds designed for nuclear waste vitrification, we have traced the glass-forming melt viscosity during the final stages of feed-to-glass conversion as it changes in response to changing temperature and composition (resulting from dissolving solid particles). Starting with a relatively low values at the moment when the melt connects, melt viscosity reaches maximum within the primary foam layer and then decreases to its final melter-operating temperature value. We paid a particular attention to the cold-cap bottom—the boundary between the primary foam layer and the thermal boundary layer—where the melt viscosity affects the rate of melting predominantly through its effect on the temperature at which primary foam is collapsing.

Lee, Seung Min↗

Boron nitride: Novel ceramic reductant for low‐activity waste vitrification

Abstract During vitrification of radioactive wastes, excessive foaming reduces processing rates within melters by hindering heat transfer from the molten glass pool to the reacting melter feed. Formulations of low‐activity waste (LAW) melter feeds, for vitrification at the Waste Treatment and Immobilization Plant at the Hanford Site, conventionally include the addition of sucrose to mitigate excessive foaming by hastening the denitration process. However, incomplete combustion of sucrose produces organics such as acetonitrile (C 2 H 3 N) that may exceed bounding limits of downstream effluent treatment facilities. Using boron nitride (BN) as an alternate reductant to sucrose, in a representative LAW melter feed reduced C 2 H 3 N production by 90% by preventing the low‐temperature sucrose–nitrate reactions. Furthermore, foaming was suppressed due to the higher decomposition temperature of BN than H 3 BO 3 meaning a delayed reaction of a large fraction of boron with the transient glass‐forming melt until above the foam onset temperature, thus reducing the quantity and viscosity of the connected melt and trapping less gas in the foam layer.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Preshot Report for the NIF Discovery Science DDCyl Campaign: D_Hyd_DDCyl_DRT_DDD/EEE/FFF

The first Discovery Science shot day with the NIF DDCyl campaign demonstrated that Rayleigh-Taylor instability growth during the deceleration phase is scale-invariant for targets that varied in radial dimension and implosion time-scale by a factor of three. Smaller cylindrical implosions at the OMEGA laser facility were compared to the larger cylinders fielded in our first NIF outing. Both sets of targets had an initial m = 20 sinusoidal perturbation machined on the inner surface of an embedded aluminum marker layer, with the amplitude larger by the same factor of three for the NIF-scale targets. We observed growth factors of 14 at late time (t=λ = 7:7 ns, where λ = 1 for OMEGA and λ = 3 for NIF). These used a high density (300 mg/cm³) CH foam core, providing a very long period of deceleration before the rebounding shock hit the incoming spike tips, but the final convergence was only CR≈ 2:25. For our second shot day with this campaign, we are attempting to increase the convergence ratio to CR≥ 5 before reshock, while still measuring instability growth during the convergence/deceleration phase. As discussed in previous reports, the best way to increase convergence before reshock is to lower the density of the central foam. The preshot designs called for the use of a 30 mg/cm³ CH foam, though the as-built foams are closer to 40-42 mg/cm³, which is predicted to result in a final CR≈ 5:1 before reshock. Other than the lower foam density, the target design is identical to those used previously.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗