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Equilibrium Slab Models of Lyman-Alpha Clouds

We model the L(sub y(alpha)) clouds as slabs of hydrogen with an ionizing extragalactic radiation field incident from both sides. In general, the equilibrium configuration of a slab at redshift z approx. less than 5 is determined by a balance of the gas pressure, gravity (including the effects of a dark matter halo), and the pressure exerted by the inter-galactic medium, P(sub ext). These models have been used to make predictions of the number of slabs as a function of the neutral hydrogen column density, N(sub H). A break in the curve is predicted at the transition between regimes where gravity and pressure are the dominant confining forces, with a less rapid decrease at larger N(sub H). The transition from optically thin to optically thick slabs leads to a gap in the distribution, whose location is governed largely by the spectrum of ionizing radiation. There are certain parallels between lines of sight through the outer HI disk of spiral galaxy with increasing radius, and the progression from damped, to Lyman limit, to forest clouds. We discuss briefly the possibility that at least some of the observed low z forest clouds may be a separate population, associated with galaxies, as suggested by the observations of Bahcall et al. This population could dominate the forest at present if the dark matter attached to galaxies should lead to gravity confinement for this disk population, while the isolated clouds remain pressure confined. The formalism developed in this paper will allow a more detailed study. We also discuss a more general parameter study of the equilibrium configuration of slabs, including mock gravity and L(sub y(alpha)) photon trapping.

Charlton, Jane C.↗

Mode Spectra of Natural Disturbances in a Circular Jet and the Effect of Acoustic Forcing

A modal spectrum technique was used to study coherent instability modes triggered by naturally occurring disturbances in a circular jet. This technique was applied to a high Reynolds number jet for both untripped and tripped nozzle exit boundary layers, with both cases having a core turbulence level of 0.15 percent. The region up to the end of the potential core was dominated by the axisymmetric mode, with the azimuthal modes dominating further downstream. The growth of the azimuthal modes was observed closer to the nozzle exit for the jet with a transitional boundary layer. Whether for locally parallel flow or slowly diverging flow, even at low levels of acoustic forcing, the inviscid linear theory is seen to be inadequate for predicting the amplitude of the forced mode. In contrast, the energy integral approach reasonably predicts the evolution of the forced mode.

Raman, G.↗

Radiance Measurement for Low Density Mars Entry

We report measurements of radiance behind a shock wave in Martian simulant (96% CO2, 4% N2) atmosphere at conditions relevant for aerodynamic decelerators. Shock waves are generated in the NASA Ames Electric Arc Shock Tube (EAST) facility at velocities from 6-8 km/s and freestream densities from 1.2-5.9 x 10(exp -4) kilograms per cubic meter (0.05-0.25 Torr, corresponding to 35-50 km altitude). Absolute radiance is measured as a function of wavelength and position in the shock. Radiance measurements extend from the vacuum ultraviolet to near infrared (120-1650 nm). As at higher density/velocity, radiation is dominate by CO 4th positive radiation in the vacuum ultraviolet, though CN contribution is also significant. At most low density conditions, the shock does not relax to equilibrium over several centimeters. A small number of measurements in the mid-infrared were performed to quantify radiation from the fundamental vibrational transition in CO, and this is found to be a minor contributor to the overall radiance at these speeds. Efforts to extend test time and reliability in the 60 cm (24) shock tube will be discussed in the full paper.

Cruden, Brett A.↗

Hybrid Wing Body (HWB) Slat Noise Analysis

This paper presents an analysis of the slat noise for Hybrid Wing Body (HWB) aircraft, based on a database from a 3% scale wind tunnel test. It is shown that the HWB slats are one of the dominant noise components, characterized by its broad spectral shape with a peak frequency that depends on both the mean flow velocity and the aircraft angle of attack, the former following the conventional Strouhal number scaling and the latter explainable by the dependence of the coherence length of the slat unsteady flows on the aircraft angle of attack. While the overall levels of the slat noise are shown to approximately follow the fifth power law in the flow Mach number, the effects of the Mach number manifest themselves in the noise spectra in both the amplitude and the spectral shape. The slat noise amplitude is shown to also depend on the angle of attack, assuming a minimum in the range of 3 to 5 degrees and increasing when the angle of attack moves away from this range. These features are all modeled and incorporated in slat noise prediction methodologies, extending the prediction capability from conventional aircraft designs to HWB configurations. Comparisons between predictions and data show very good agreements both in various parametric trends and in the absolute levels. The HWB aircraft is designed to operate at angles of attack much higher than those of conventional aircraft. This is shown to significantly increase the HWB slat noise. To further illustrate, the test data are extrapolated to full scale and compared with the slat noise of the Boeing 777 aircraft, showing that the former is higher the latter.

Guo, Yueping↗

Aerosol–Ice Formation Closure: A Southern Great Plains Field Campaign

Prediction of ice formation in clouds presents one of the grand challenges in the atmospheric sciences. Immersion freezing initiated by ice-nucleating particles (INPs) is the dominant pathway of primary ice crystal formation in mixed-phase clouds, where supercooled water droplets and ice crystals coexist, with important implications for the hydrological cycle and climate. However, derivation of INP number concentrations from an ambient aerosol population in cloud-resolving and climate models remains highly uncertain. We conducted an aerosol-ice formation closure pilot study using a field-observational approach to evaluate the predictive capability of immersion freezing INPs. The closure study relies on co-located measurements of the ambient size-resolved and single-particle composition and INP number concentrations. The acquired particle data serve as input in several immersion freezing parameterizations, that are employed in cloud-resolving and climate models, for prediction of INP number concentrations. We discuss in detail one closure case study in which a front passed through the measurement site, resulting in a change of ambient particle and INP populations. We achieved closure in some circumstances within uncertainties, but we emphasize the need for freezing parameterization of potentially missing INP types and evaluation of the choice of parameterization to be employed. Overall, this closure pilot study aims to assess the level of parameter details and measurement strategies needed to achieve aerosol-ice formation closure. The closure approach is designed to accurately guide immersion freezing schemes in models, and ultimately identify the leading causes for climate model bias in INP predictions.

ice formation↗

New physics in multi-lepton tau decays

Dark particles with lepton-flavor-violating couplings to the tau lepton can induce rare neutrinoless $τ$ decays with large final state multiplicities. We study models where transitions of the type $τ^\pm\to \ell^\pm\,ϕ$, with $ϕ$ a light new particle, initiate a chain of decays in the dark sector that terminate with decays into electrons, muons, or pions. These decay cascades appear as rare five or even seven-body $τ$ decays with multiple reconstructable resonances. We survey several representative models: kinetically mixed dark photon, gauged $L_i-L_j$ models, and other more exotic charge assignments such as chiral $U(1)'$ extensions of the Standard Model. The main new ingredient is the possibility of flavor violation at very high scales. In these models, a number of channels that have not yet been searched for experimentally, such as $τ\to 5μ$, $τ\to 3μ\,2e$, $τ\to μ\,4e$, and hadronic channels like $τ\to μ\,4π$, typically dominate over the previously-considered signatures such as $τ\to 3μ$. While some of the models, such as the gauged $L_i-L_j$ ones, also contain more challenging channels with missing energy due to decays to neutrinos, they can still be searched for via fully visible channels.

Ema, Yohei [Florida U.]↗

Electromagnetic Shower Reconstruction and Identification in FASER's Emulsion Detector for LHC Forward Neutrino Measurements

We present methods for electromagnetic shower reconstruction and identification in the FASERnu emulsion detector using 100 GeV and 200 GeV electron test-beam data from the CERN SPS H4 beamline. The reconstruction employs a clustering-based algorithm without energy-dependent tuning to determine shower axes. A multi-level identification chain comprising track pre-selection, a cut-based selection, and a BDT classifier achieves combined background rejection rates of 99.99% (100 GeV) and 99.94% (200 GeV). The method reaches total reconstruction and identification efficiencies of 58.9% (100 GeV) and 70.8% (200 GeV) evaluated from simulated samples. Energy reconstruction using the total number of reconstructed segments as the calorimetric estimator yields relative biases of +0.6% (100 GeV) and -0.8% (200 GeV), with resolutions of 25.4% and 22.6%, respectively. Systematic uncertainties on the energy reconstruction are dominated by variations in emulsion film detection efficiency, contributing (+10.9%/-8.2%) at 100 GeV and (+10.3%/-6.9%) at 200 GeV. The methodology provides a validated framework for electron neutrino identification with the FASERnu detector at the LHC.

Mammen Abraham, Roshan [UC, Irvine]↗

Probing Galaxy Formation and Submillimeter Surveys

Multiwavelength observations of galaxies have revealed that a significant fraction of the their stellar or accretion luminosity is absorbed and reradiated by dust at far-infrared (FIR) and submillimeter (submm) wavelengths. Submillimeter (850 micron) surveys conducted by the SCUBA instrument on the JCMT have detected a population of high redshift (z approximately equal to 1-4) ultraluminous infrared galaxies, that dominate the luminosity densities at those redshifts. Their cumulative contribution to the cosmic infrared background (CIB) detected by the COBE satellite is comparable to the observations, suggesting that at 850 microns the CIB is resolved into its constituent sources. This suggests that the early universe was much more dust enshrouded than the present one. FIR and submm surveys can therefore address fundamental questions regarding the early processes of galaxy formation and their evolution in number and luminosity over cosmic history. The scientific information that can be obtained from such surveys depend on a number of parameters, the most important of which are the diameter of the telescope and the wavelengths of the survey. We summarize the effect of these parameters on the scientific return from such surveys.

Dwek, Eli↗

Long carrier diffusion length in two-dimensional lead halide perovskite single crystals

Ruddlesden-Popper (RP) perovskites are two-dimensional semiconductors for high-performance optoelectronic devices. In this work, we report a long in-plane carrier diffusion length in 2D RP perovskite single crystals probed by scanning photocurrent microscopy. Carrier diffusion lengths of 7–14μm are observed when the number of PbI 6 –2 octahedra between organic spacers increases from 1 to 3. Using detailed light intensity and electric-field-dependent photocurrent measurements, we attribute the observed long diffusion length to the dominating dissociated free carrier transport. This is further validated by time-resolved photoluminescence measurements, where the decay lifetime increases in the presence of an electric field. From our experiments, we conclude that the in-plane transport in RP perovskites is efficient because of the partial free carrier generation, which overcomes strong excitonic effects. In conclusion, our results suggest that semiconducting devices fabricated from RP perovskite single crystals can be as efficient as their 3D counterparts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A dynamic likelihood approach to filtering transport processes: advection-diffusion dynamics

A Bayesian data assimilation scheme is formulated for advection-dominated advective and diffusive evolutionary problems, based upon the Dynamic Likelihood (DLF) approach to filtering. The DLF was developed specifically for hyperbolic problems –waves–, and in this paper, it is extended via a split step formulation, to handle advection-diffusion problems. In the dynamic likelihood approach, observations and their statistics are used to propagate probabilities along characteristics, evolving the likelihood in time. The estimate posterior thus inherits phase information. For advection-diffusion the advective part of the time evolution is handled on the basis of observations alone, while the diffusive part is informed through the model as well as observations. We expect, and indeed show here, that in advection-dominated problems, the DLF approach produces better estimates than other assimilation approaches, particularly when the observations are sparse and have low uncertainty. The added computational expense of the method is cubic in the total number of observations over time, which is on the same order of magnitude as a standard Kalman filter and can be mitigated by bounding the number of forward propagated observations, discarding the least informative data.

97 MATHEMATICS AND COMPUTING↗

Far-Infrared Water Line Emissions from Circumstellar Outflows

We have modeled the far-infrared water line emission expected from circumstellar outflows from oxygen-rich late-type stars, as a function of the mass-loss rate and the terminal outflow velocity. For each mass-loss rate and terminal outflow velocity considered, we computed self-consistently the gas density, temperature, outflow velocity, and water abundance as a function of distance from the star. We then used an escape probability method to solve for the equilibrium level populations of 80 rotational states of water and thereby obtained predictions for the luminosity of a large number of far-infrared rotational transitions of water. In common with previous models, our model predicts that water will be copiously produced in the warm circumstellar gas and that water rotational emission will dominate the radiative cooling. However, our use of a realistic radiative cooling function for water leads to a lower gas temperature than that predicted in previous models. Our predictions for the far-infrared water line luminosities are consequently significantly smaller than those obtained in previous studies. Observations to be carried out by the Infrared Space Observatory will provide a crucial test of the models presented here.

Chen, Wesley↗

Composition of Hydrothermal Vent Microbial Communities as Revealed by Analyses of Signature Lipids, Stable Carbon Isotopes and Aquificales Cultures

Extremely thermophilic microbial communities associated with the siliceous vent walls and outflow channel of Octopus Spring, Yellowstone National Park, have been examined for lipid biomarkers and carbon isotopic signatures. These data were compared with that obtained from representatives of three Aquificales genera. Thermocrinis ruber. "Thermocrinis sp. HI", Hydrogenobacter thermophilus TK-6, Aquifex pyrophilus and Aquifex aeolicus all contained phospholipids composed not only of the usual ester-linked fatty acids, but also ether-linked alkyls. The fatty acids of all cultured organisms were dominated by a very distinct pattern of n-C-20:1 and cy-C-21 compounds. The alkyl glycerol ethers were present primarily as CIS() monoethers with the expection of the Aquifex spp. in which dialkyl glycerol ethers with a boarder carbon-number distribution were also present. These Aquificales biomarker lipids were the major constituents in the lipid extracts of the Octopus Spring microbial samples. Two natural samples, a microbial biofilm growing in association with deposition of amorphous silica on the vent walls at 92 C, and the well-known 'pink-streamers community' (PSC), siliceous filaments of a microbial consortia growing in the upper outflow channel at 87 C were analyzed. Both the biofilm and PSC samples contained mono and dialkyl glycerol ethers with a prevalence of C-18 and C-20 alkyls. Phospholipid fatty acids were comprised of both the characteristic Aquificales n-C-20:1 and cy-C-21, and in addition, a series of iso-branched fatty acids from i-C-15:0 to i-C-21:0, With i-C-17:0 dominant in the PSC and i-C-19:0 in the biofilm, suggesting the presence of two major bacterial groups. Bacteriohopanepolyols were absent and the minute quantities of archaeol detected showed that Archaea were only minor constituents. Carbon isotopic compositions of the PSC yielded information about community structure and likely physiology. Biomass was C-13-depleted (10.9%) relative to available CO2 from the source water inorganic carbon pool with lipids further depleted by 6.3% relative to biomass The C-20-21 Aquificales fatty acids of the PSC were somewhat heavier than the iso-branched fatty acids. The carbon isotopic signatures of lipid biomarkers were also explored using a pure culture, T ruber, previously isolated from the PSC. Cells grown on C02 with O2 and both H2 and thiosulfate as electron donors were only slightly depleted (3.3%) relative to the C-source while cells grown on formate with O2 showed a major discrimination (19.7%), possibly the result of a metabolic branch point involving the assimilation of C-formate to biomass and the dissimilation to CO2 associated with energy production. T. ruber lipids were slightly heavier than biomass (+1.3%) whether cells were grown using CO2 or formate. Fatty acids from CO2 grown T. ruber cells were a so slightly heavier (average +2.1%) than biomass. The relatively depleted PSC C-20-21 fatty acids suggest that any associated Thermocrinis biomass would also be similarly depleted and much too light to be explained by growth on CO2. The C-fractionations determined with the pure culture suggest that growth of Thermocrinis in the PSC is more likely to occur on formate, presumably generated by geothermal activity. This study points to the value of the analysis of the structural and isotopic composition of lipid blomarkers both in pure culture studies, and in establishing community structure and physiology, as a complement to genomic profiles of microbial diversity. This is especially so when the members of the microbial community are novel and difficult to cultivate in the laboratory.

Jahnke, Linda L.↗

Natural variation in the consequences of gene overexpression and its implications for evolutionary trajectories

Copy number variation through gene or chromosome amplification provides a route for rapid phenotypic variation and supports the long-term evolution of gene functions. Although the evolutionary importance of copy-number variation is known, little is understood about how genetic background influences its tolerance. Here, we measured fitness costs of over 4000 overexpressed genes in 15 Saccharomyces cerevisiae strains representing different lineages, to explore natural variation in tolerating gene overexpression (OE). Strain-specific effects dominated the fitness costs of gene OE. We report global differences in the consequences of gene OE, independent of the amplified gene, as well as gene-specific effects that were dependent on the genetic background. Natural variation in the response to gene OE could be explained by several models, including strain-specific physiological differences, resource limitations, and regulatory sensitivities. This work provides new insight on how genetic background influences tolerance to gene amplification and the evolutionary trajectories accessible to different backgrounds.

59 BASIC BIOLOGICAL SCIENCES↗

Changes in rock matrix compressibility during deep CO 2 storage

Geologic carbon storage projects aim to permanently trap large volumes of CO 2 in reservoir rock sealed with low permeability layers. As high-pressure supercritical or liquid CO 2 is injected, hydromechanical and chemical processes caused by the reaction between the rock and acidic mixture of brine and CO 2 are initiated. The compressibility of reservoir rock needs to be properly characterized in order to assess the deformation and stability of the host formations, and there are a number of factors to be considered, including the matrix structure, solid, pores, and fluid. Here this study triggers from a fundamental question whether CO 2 treatment affects the compressibility of the rock matrix and its dominant composing solid minerals. Three different reservoir representatives are selected: Berea sandstone for silica-rich rock, and Apulian limestone and Indiana limestone for calcite-rich rock. Quartz and calcite are the main composing minerals of the reservoir rock, and their crystals are separately examined. Experimental methods are introduced for high-pressure CO 2 treatment of water-saturated materials, and measurements of the unjacketed and solid compressibilities are conducted. No change in the solid compressibility of the sandstone and quartz after CO 2 treatment is observed, whereas it increases by 18–21% for the limestones and by 15% for calcite. The latter observation is inconsistent with the ultrasonic wave velocities measurements and is believed to be due to the local dissolution of the calcite crystal surface. Our results show that only the solid matrix of the limestones becomes more compressible after CO 2 treatment. Consequent microimaging and mercury intrusion porosimetry analyses allowed observations of dissolution and precipitation of calcite, and creation of new connected and non-connected pores. Finally, the changes in limestone solid compressibilities and pore structure could significantly affect the rock properties and behavior during and after CO 2 injection and should be accounted for in the reservoir models.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Coupled Thermo-Hydro-Mechanical Processes in Fractured Rocks: Some Past Scientific Highlights and Future Research Directions

Abstract Coupled thermo-hydro-mechanical (THM) processes in fractured rocks have been a topic of intense scientific research for more than 30 years. The present paper takes a look into the past and highlights some scientific advances which are of an unusual “out-of-the-box” nature, and then looks forward and discusses possible directions of future research in this interesting field of study. Concerning future research directions, we see a trend from a focus on coupled THM processes in single fractures or a few interacting fractures, to the study of coupled THM behavior in complex fracture network systems where the fractures act collectively giving rise to local stress concentration points and points of large pressure gradients. Three examples of future research directions are presented. First is an effort towards identifying characterizing parameters of a fracture network that play a direct controlling role in major coupled THM phenomena (such as induced seismicity and flow channeling), rather than parameters of stochastic distributions of fractures in the network. The second example of research direction is accounting for the heterogeneity and hierarchy of fractures in a fault or fracture zone which has been associated with major THM events in a number of geo-energy projects. The third example is at the opposite end of the first; here it is recognized that in some cases, the coupled THM processes in fractured rocks may be controlled dominantly by only a few key bridges. Identification, characterization, and evaluation of these key bridges should be one of the important research directions in the coming days.

58 GEOSCIENCES↗

What fuel properties enable higher thermal efficiency in spark-ignited engines?

The Co-Optimization of Fuels and Engines (Co-Optima) initiative from the US Department of Energy aims to co-develop fuels and engines in an effort to maximize energy efficiency and the utilization of renewable fuels. Many of these renewable fuel options have fuel chemistries that are different from those of petroleum-derived fuels. Because practical market fuels need to meet specific fuel-property requirements, a chemistry-agnostic approach to assessing the potential benefits of candidate fuels was developed using the Central Fuel Property Hypothesis (CFPH). The CFPH states that fuel properties are predictive of the performance of the fuel, regardless of the fuel's chemical composition. In order to use this hypothesis to assess the potential of fuel candidates to increase efficiency in spark-ignition (SI) engines, the individual contributions towards efficiency potential in an optimized engine must be quantified in a way that allows the individual fuel properties to be traded off for one another. This review article begins by providing an overview of the historical linkages between fuel properties and engine efficiency, including the two dominant pathways currently being used by vehicle manufacturers to reduce fuel consumption. Then, a thermodynamic-based assessment to quantify how six individual fuel properties can affect efficiency in SI engines is performed: research octane number, octane sensitivity, latent heat of vaporization, laminar flame speed, particulate matter index, and catalyst light-off temperature. The relative effects of each of these fuel properties is combined into a unified merit function that is capable of assessing the fuel property-based efficiency potential of fuels with conventional and unconventional compositions.

42 ENGINEERING↗

Characterization of 3D printing filaments containing metal additives and their particulate emissions

Polylactic acid (PLA) filaments are widely used in fused filament fabrication (FFF) processes (3D printing). Filament additives such as metallic particles incorporated into PLA to modify functional and aesthetic features of print objects are becoming increasingly popular. However, the identities and concentrations of low percentage and trace metals in these filaments have not been well described in either the literature or product safety information included with the product. Here, we report the structures and concentrations of metals in selected Copperfill, Bronzefill and Steelfill filaments. We also report size-weighted number concentrations and size-weighted mass concentrations of particulate emissions as a function of print temperature for each filament. Particulate emissions were heterogenous in shape and size with airborne particles below 50 nm diameter dominating the size-weighted particle concentrations and larger particles (approximately 300 nm) dominating the mass weighted particle concentration. Results indicate that potential exposure to particles in the nano-size range increase when using print temperatures above 200o C. Because inhalation exposure to nanoparticles has been linked to adverse health outcomes, we suggest that using lower print temperatures for specific metal-fill filaments may reduce their operational hazard.

36 MATERIALS SCIENCE↗

Unimolecular dissociation dynamics of electronically excited HCO(Ã 2 A"): rotational control of nonadiabatic decay

The photoinduced unimolecular decay of the electronically excited HCO(Ã 2 A") is investigated in a combined experimental–theoretical study. The molecule is excited to the (1, n 2 , 0) combination bands, which decay via Renner–Teller coupling to the ground electronic state. The rovibrational state distribution of the CO fragment was measured via the high-n Rydberg H-atom time-of-flight method and calculated using a wave packet method on an accurate set of potential energy surfaces. It is shown that the non-adiabatic decay rate is strongly modulated by the HCO rotational angular momentum, which leaves unique signatures in the product state distribution. Finally, the experimentally observed bimodal rotational distribution of the dominant CO(v = 0) fragment is likely due to decay of different vibronic states populated by the excitation and modulated by the excited state lifetime, which is in turn controlled by the parent rotational quantum number.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗