Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “diffusion processes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 901 records · Page 50

Soil physical and thermal properties from soil samples at multiple locations at Teller Road Site, Seward Peninsula, Alaska, 2019

This dataset contains results of the laboratory analysis of soil samples collected across the watershed located at miles #27 along the Teller road, near Nome, AK. The dataset includes 124 soil samples retrieved from 52 locations during the first week of August 2019. The soil samples were collected in the top 1.2 m of soil with volume known samples, analyzed with a thermal analyser to infer thermal parameters (thermal conductivity, volumetric heat capacity and thermal diffusivity), and then processed in a lab for estimation of their bulk density, water content, carbon and nitrogen content, soil texture, and elemental fractions. This dataset has one csv file and one pdf file.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Nuclear processes associated with peculiar A-type stars.

A discussion is given of the various roles that nuclear reactions may play in production of anomalous abundances of elements in peculiar A stars. The effects which may be expected to occur both in the surface nuclear reactions and in some possible internal reactions that can occur in advanced stages of stellar evolution are considered. It is suggested that various features of peculiar A stars may require simultaneous operation of two or more of the processes of surface diffusion, surface nuclear reactions, and internal nuclear reactions.

Cameron, A. G. W.↗

Water vapor diffusion membranes

The program is reported, which was designed to define the membrane technology of the vapor diffusion water recovery process and to test this technology using commercially available or experimental membranes. One membrane was selected, on the basis of the defined technology, and was subjected to a 30-day demonstration trial.

Holland, F. F., Jr.↗

On the modeling of the scalar correlations necessary to construct a second-order closure description of turbulent reacting flows

A tentative scheme is proposed for constructing second-order closure models of turbulent reacting flows, with particular reference to mixing processes in turbulent diffusion flows. The model is based on the concepts of typical structure and typical eddy, and treats various hypothetical turbulent flame situations, including the time dependence of species mass fractions passing a point in the flame, the most typical occurrence of species mass fractions, and the case of a rather bizarre typical eddy which shows the effects of nonmixedness.

Donaldson, C. DUP.↗

Mercury ion thruster research, 1977

The measured ion beam divergence characteristics of two and three-grid, multiaperture accelerator systems are presented. The effects of perveance, geometry, net-to-total accelerating voltage, discharge voltage and propellant are examined. The applicability of a model describing doubly-charged ion densities in mercury thrusters is demonstrated for an 8-cm diameter thruster. The results of detailed Langmuir probing of the interior of an operating cathode are given and used to determine the ionization fraction as a function of position upstream of the cathode orifice. A mathematical model of discharge chamber electron diffusion and collection processes is presented along with scaling laws useful in estimating performance of large diameter and/or high specific impluse thrusters. A model describing the production of ionized molecular nitrogen in ion thrusters is included.

Wilbur, P. J.↗

Creep of oxide dispersion strengthened materials (with special reference to TD nichrome)

It was shown that the creep behavior of oxide dispersion strengthened (ODS) alloys is controlled principally by the creep properties of the matrix of the alloy devoid of particles. Thus, diffusion controlled slip process determine the rate controlling step in such materials. The role of the particles is to stabilize a fine substructure which is invariant with the creep stress over a wide range of stress. This characteristic leads to negligible strain hardening during creep and suggests that creep relations developed for pure metals and many solid solution alloys at constant structure should be used to describe the creep of ODS alloys. A second characteristics of the ODS alloys is that a stress may exist below which creep will not occur (threshold stress).

Lin, J.↗

On the kinetics of volatile loss from chondrites

Data by Lipschutz and coworkers (1975, 1976, 1977) on thermal release of Tl, Bi, and In from primitive chondrites are reexamined to obtain information on the nature and activation energy (E) of release processes: desorption, volume diffusion, and decomposition of the host phase. For the Allende C3 chondrite, the main release for Bi and Tl between 400 and 700 C is shown to be apparently due to desorption of a surface layer, coupled with grain boundary diffusion as the slow step. Further, the main release of In above 600 C and the small tails of Bi and Tl between 700 and 1000 C are observed to represent probably volume diffusion. Results for Abee and other primitive meteorites were found to be essentially similar, except for a very abrupt 500 C release of Tl from Krymka (81%) and Bi from Tieschitz (70%). It is suggested that this release may represent decomposition of a thermolabile phase in a late condensate, such as organic matter or phyllosilicates.

Alaerts, L.↗

Magnetic field reconnection

A reasonably detailed description is obtained of the current status of our understanding of magnetic field reconnection. The picture that emerges is of a process, simple in concept but extremely complicated and multifaceted in detail. Nonlinear MHD processes in the external flow region, governed by distant boundary conditions, are coupled to nonlinear microscopic plasma processes in the diffusion region, in a manner not clearly understood. It appears that reconnection may operate in entirely different ways for different plasma parameters and different external boundary conditions. Steady reconnection may be allowed in some cases, forbidden in others, with intermediate situations involving impulsive or pulsative events.

Sonnerup, U. O.↗

Forward- and reverse-bias tunneling effects in n/+/p silicon solar cells

Excess currents due to field-assisted tunneling in both forward and reverse bias directions have been observed in n(+)-p silicon solar cells. These currents arise from the effect of conducting paths produced in the depletion layer by n(+) diffusion and cell processing. Forward-bias data indicate a small potential barrier with height of 0.04 eV at the n(+) end of conducting paths. Under reverse bias, excess tunneling currents involve a potential barrier at the p end of the conducting paths, the longer paths being associated with smaller barrier heights and dominating at the lower temperatures. Low-reverse-bias data give energy levels of 0.11 eV for lower temperatures (253-293 K) and 0.35 eV for higher temperatures (293-380 K). A model is suggested to explain the results.

Garlick, G. F. J.↗

Semiconductor photoelectrochemistry

Semiconductor photoelectrochemical reactions are investigated. A model of the charge transport processes in the semiconductor, based on semiconductor device theory, is presented. It incorporates the nonlinear processes characterizing the diffusion and reaction of charge carriers in the semiconductor. The model is used to study conditions limiting useful energy conversion, specifically the saturation of current flow due to high light intensity. Numerical results describing charge distributions in the semiconductor and its effects on the electrolyte are obtained. Experimental results include: an estimate rate at which a semiconductor photoelectrode is capable of converting electromagnetic energy into chemical energy; the effect of cell temperature on the efficiency; a method for determining the point of zero zeta potential for macroscopic semiconductor samples; a technique using platinized titanium dioxide powders and ultraviolet radiation to produce chlorine, bromine, and iodine from solutions containing their respective ions; the photoelectrochemical properties of a class of layered compounds called transition metal thiophosphates; and a technique used to produce high conversion efficiency from laser radiation to chemical energy.

Buoncristiani, A. M.↗

Growth of crystals from solutions in low gravity (A0139A)

The objective of the low gravity crystal growth experiments is to develop a novel solute diffusion method for growing single crystals. The experiments will utilize specially designed reactors with three or more compartments separated by valves to keep the reactant solutions and solvent separated until the apparatus reaches low gravity. There will be a mechanism for opening the valves automatically to initiate the diffusion and growth processes. The reactant reservoirs will be large enough to take advantage of the time provided by the Long Duration Exposure Facility (LDEF) flight. An array of several reactors will be mounted in a 12-in.-deep end center tray located on the Earth-facing end of the LDEF. Several reactors operating simultaneously will allow experimentation with more than one crystal growth system and/or variations of conditions for each. The reactors will be enclosed in a vacuum tight container and will be surrounded by thermal insulation. The temperature (approximately 35 deg C) will be regulated and any departures from the desired temperature will be recorded. Power requirements will be provided by LiSO2 batteries.

Lind, M. D.↗

Surfaces

Techniques for the characterization of surface cleanliness and roughness for predicting the quality of an adhesive bond are outlined. Generally, smooth surfaces are only available from cleavage of crystalline materials along a natural cleavage plane. Films must be deposited on metal surfaces to achieve the same smoothness. Once the surfaces are clean, however, reaction with the ambient atmosphere becomes likely through diffusive and absorption processes, producing asperities. Electron diffraction, Auger electron, and X ray emission spectroscopy are used to characterize surface condition. Once the surface is observed to be clean, the application of an adhesive will usually prohibit separation along the adhesive; separation is then confined to the weaker of the two materials. Finally, the use of polytetrafluorothylene adhesive to test the adhesion between polymers and metal surfaces is described.

Buckley, D. H.↗

N(+)-N and O(+)-O interaction energies, dipole transition moments, and transport cross sections

Complete sets of ion-atom interaction energies have been computed for nitrogen and oxygen with accurate large scale structure calculations. The computed energies agree well with the accurate potential curves available from spectroscopic measurement. The state functions from the nitrogen calculations have been applied to determine the transition moment for all allowed dipole transitions. These results can be combined to compute a detailed radiation spectrum such as that required to define the highly nonequilibrium environment of aeroassisted orbital transfer vehicle (AOTV). The long-range interaction energies have been used to determine the ion-atom resonance charge exchange cross sections that are important for transport processes such as diffusion. A calculation to determine reliable transport properties for energies that include the AOTV temperature range from these computed properties is described.

Partridge, H.↗

Quantitative Schlieren analysis applied to holograms of crystals grown on Spacelab 3

In order to extract additional information about crystals grown in the microgravity environment of Spacelab, a quantitative schlieren analysis technique was developed for use in a Holography Ground System of the Fluid Experiment System. Utilizing the Unidex position controller, it was possible to measure deviation angles produced by refractive index gradients of 0.5 milliradians. Additionally, refractive index gradient maps for any recorded time during the crystal growth were drawn and used to create solute concentration maps for the environment around the crystal. The technique was applied to flight holograms of Cell 204 of the Fluid Experiment System that were recorded during the Spacelab 3 mission on STS 51B. A triglycine sulfate crystal was grown under isothermal conditions in the cell and the data gathered with the quantitative schlieren analysis technique is consistent with a diffusion limited growth process.

Brooks, Howard L.↗

Simulation studies for surfaces and materials strength

Three different investigations based on computer simulations were carried out. Simulation calculations were performed using model potentials with two- and three-body interactions which were represented by the Mie and the Axilrod-Teller potentials, respectively. In the first part, to analyze stability criteria for simple crystals, a parametrical investigation was performed and stability regions for five different crystalline structures were determined with respect to potential energy parameters. To simulate some of the basic surface processes such as diffusion and nucleation, in the second and third parts, silicon surfaces were considered as a specific example. In these studies diffusion of adatoms on stepped surfaces were simulated and energetics associated with the formation of kink sites were calculated.

Halicioglu, Timur↗

Microgravity nucleation and particle coagulation experiments support

A preliminary model for diffusion between concentric hemispheres was adapted to the cylindrical geometry of a microgravity nucleation apparatus, and extended to include the effects of radiation and conduction through the containment walls. Computer programs were developed to calculate first the temperature distribution and then the evolving concentration field using a finite difference formulation of the transient diffusion and radiation processes. The following estimations are made: (1) it takes approximately 35 minutes to establish a steady temperature field; (2) magnesium vapors released into the argon environment at the steady temperature distribution will reach a maximum supersaturation ratio of approximately 10,000 in the 20-second period at a distance of 15 cm from the source of vapors; and (3) approximately 750W electrical power will be required to maintain steady operating temperatures within the chamber.

Lilleleht, L. U.↗

Hot gas in evolving galaxy clusters and groups - Implications for the microwave and X-ray backgrounds

A phenomenological model for the luminosity function of galaxy groups and clusters allows its evolution to be described in terms of the two-point galaxy correlation function. The observable properties of hot gas in virialized groups and clusters at high redshift have been computed. These include the spectral distortion by Comptonization of the cosmic blackbody spectrum, fluctuations in the cosmic microwave background arising by this same process, and the diffuse X-ray background and fluctuations therein arising from thermal emission by the intracluster gas.

Schaeffer, Richard↗